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Keywords = water film breakup

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22 pages, 6079 KiB  
Article
Numerical Simulation of Water Film Flow and Breakup on Anti-Icing Surface
by Changxian Zhang, Lei Liu, Yaping Hu and Pengfei Li
Aerospace 2024, 11(5), 352; https://doi.org/10.3390/aerospace11050352 - 29 Apr 2024
Viewed by 2150
Abstract
The flow and morphological characteristics of liquid water on the icing and anti-icing surfaces of aircraft are closely related to the icing characteristics and anti-icing surface temperature distribution. To predict the flow and breakup characteristics of a water film, a 3D model of [...] Read more.
The flow and morphological characteristics of liquid water on the icing and anti-icing surfaces of aircraft are closely related to the icing characteristics and anti-icing surface temperature distribution. To predict the flow and breakup characteristics of a water film, a 3D model of continuous water film flow and a model of water film breakup into rivulets on an anti-icing surface were constructed based on the icing model, and the corresponding methods for solving the models were developed. Using the NACA0012 airfoil as a simulation object, the changing characteristics of height and velocity for a continuous water film with time and the morphological characteristics of rivulets formed from the breakup of a continuous water film were simulated numerically. The results indicate that, with an increase in inflow velocity, the time required for the water film to completely cover the surface and reach stability decreases. Downstream in the water droplet impact zone, the calculated values of continuous water film height align well with experiments, as well as the stream height at the continuous water film rupture location with the experimental values. With the reasonable contact angle, the calculation error of the stream width is within 10%. Full article
(This article belongs to the Special Issue Deicing and Anti-Icing of Aircraft (Volume III))
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15 pages, 1261 KiB  
Article
Characteristics of Pre-Lens Tear Film Behavior in Eyes Wearing Delefilcon A Silicone Hydrogel Water Gradient Contact Lenses
by Norihiko Yokoi, Yuki Furusawa, Hiroaki Kato, Natsuki Kusada, Chie Sotozono, Petar Eftimov and Georgi As. Georgiev
Diagnostics 2023, 13(24), 3642; https://doi.org/10.3390/diagnostics13243642 - 12 Dec 2023
Cited by 1 | Viewed by 1814
Abstract
The pre-lens tear film (PLTF) over (i) delefilcon A silicone hydrogel water gradient (WG; 33–80% from core to surface) contact lenses (CLs) (SHWG-CLs) and (ii) subjects’ own non-WG soft CLs (SCLs) (SO-SCLs) was studied in 30 eyes of 30 subjects to assess the [...] Read more.
The pre-lens tear film (PLTF) over (i) delefilcon A silicone hydrogel water gradient (WG; 33–80% from core to surface) contact lenses (CLs) (SHWG-CLs) and (ii) subjects’ own non-WG soft CLs (SCLs) (SO-SCLs) was studied in 30 eyes of 30 subjects to assess the hypothesized PLTF stabilization over SHWG-CLs. In both eyes, delefilcon A SHWG-CLs (DAILIES TOTAL1®; Alcon, Fort Worth, TX, USA) or SO-SCLs were worn. After 15 min of wearing each lens, the tear meniscus radius (TMR, mm), lipid-layer interference grade (IG) and spread grade (SG), and non-invasive breakup time (NIBUT, seconds) were evaluated and compared between the SHWG-CLs and the SO-SCLs. The comparison between the SHWG-CL and SO-SCL groups (SHWG-CL and SO-SCL, mean ± SD) revealed that TMRs temporarily decreased and reached a plateau value after 15 min (0.21 ± 0.06; 0.21 ± 0.06) compared to the value prior to CL insertion (0.24 ± 0.08; 0.25 ± 0.08), with no significant difference between the two groups. The NIBUT, IG, and SG values after 15 min of wearing the CLs were (9.7 ± 3.7; 4.7 ± 4.2), (1.0 ± 0.2; 1.8 ± 1.0), and (1.1 ± 0.4; 1.9 ± 1.5), respectively, and all values were significantly better in the SHWG-CL group (p < 0.0001, p = 0.0039, and p < 0.0001, respectively). We found that compared to the SO-SCLs, the maintenance of the PLTF on the SHWG-CLs was supported by the thicker and more stable PLTF. Full article
(This article belongs to the Special Issue Diagnosis, Treatment and Management of Eye Diseases)
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13 pages, 1681 KiB  
Article
Evaluation of Therapeutic Capability of Emustil Drops against Tear Film Complications under Dry Environmental Conditions in Healthy Individuals
by Ali Abusharha, Ian E. Pearce, Tayyaba Afsar and Suhail Razak
Medicina 2023, 59(7), 1298; https://doi.org/10.3390/medicina59071298 - 14 Jul 2023
Cited by 6 | Viewed by 2392
Abstract
Background and Objectives: Dry eye disease (DED) is a multifactorial ailment of the tears and ocular surface. The purpose of this study was to assess the tear film physiology under controlled dry environmental conditions and compare the efficacy of oil-in-water emulsion drops [...] Read more.
Background and Objectives: Dry eye disease (DED) is a multifactorial ailment of the tears and ocular surface. The purpose of this study was to assess the tear film physiology under controlled dry environmental conditions and compare the efficacy of oil-in-water emulsion drops on tear film parameters in protection and relief treatment modalities under low-humidity conditions. Emustil eye drops were used after exposure to a low-humidity environment in the relief method, whereas, in the protection method, the drops were applied before exposure to low humidity. Materials and Methods: 12 normal male subjects (mean age 34.0 ± 7.0 years) were exposed to ultra-dry environmental conditions. A number of tear film measurements were carried out under desiccating environmental conditions in a controlled environment chamber (CEC), where the chamber temperature sat at 21 °C with a relative humidity (RH) of 5%. Keeler’s TearScope Plus and an HIRCAL grid were used to assess the tear break-up time and lipid layer thickness (LLT), and the evaporation rate was evaluated using a Servomed EP3 Evaporimeter. Results: LLT measurements showed that the dry environment affected LLT significantly (p = 0.031). The median grade of LLT dropped from grade 3 (50–70 nm) at 40% RH to grade 2 (13–50 nm) at 5% RH. A significant increase in LLT was seen after both modes of treatment, with a median LLT grade of 3 when the Emustil was used for both protection (p = 0.004) and relief (p = 0.016). The mean tear evaporation rate in normal environmental conditions (40%) was 40.46 ± 11.80 g/m2/h (0.11 µL/min) and increased sharply to 83.77 ± 20.37 g/m2/h (0.25 µL/min) after exposure to the dry environment. A minimal decrease in tear film evaporation rate was seen in relief; however, statistical tests showed that the decrease in tear film evaporation rate was not significant. Mean NITBUT dropped from 13.6 s at 40% RH to 6.6 s at 5% RH (p = 0.002). All NITBUT measurements at 5% RH (with or without the instillation of Emustil) were significantly lower than those at 40%. The instillation of Emustil at 5% RH resulted in a significant improvement in NITBUT for protection (p = 0.016) but this was not the case for relief (p = 0.0.56). Conclusions: A control environmental chamber (CEC) enables the analysis of tear film parameters comparable to those found in dry eye patients. This enables us to examine the capability of oil in emulsion drops to manage tear film disruption in healthy individuals. This study suggests that using Emustil oil-in-water emulsion before exposure to a dry environment should be advocated for people who work in dry environments. Full article
(This article belongs to the Section Ophthalmology)
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12 pages, 1763 KiB  
Article
Evaluation of Celligent® Biomimetic Water Gradient Contact Lens Effects on Ocular Surface and Subjective Symptoms
by Raúl Capote-Puente, José-María Sánchez-González, María Carmen Sánchez-González and María-José Bautista-Llamas
Diagnostics 2023, 13(7), 1258; https://doi.org/10.3390/diagnostics13071258 - 27 Mar 2023
Cited by 9 | Viewed by 2467
Abstract
This study aimed to evaluate the non-invasive and subjective symptoms associated with Lehfilcon A water gradient silicone hydrogel contact lenses with bacterial and lipid resistance technology. A prospective, longitudinal, single-centre, self-controlled study was conducted among silicone hydrogel contact lens wearers. Non-invasive analysis of [...] Read more.
This study aimed to evaluate the non-invasive and subjective symptoms associated with Lehfilcon A water gradient silicone hydrogel contact lenses with bacterial and lipid resistance technology. A prospective, longitudinal, single-centre, self-controlled study was conducted among silicone hydrogel contact lens wearers. Non-invasive analysis of the pre-lens tear film was performed using the Integrated Clinical Platform (ICP) Ocular Surface Analyzer (OSA), and the meibomian glands were evaluated with the Cobra® HD infrared meibographer. After 30 days of contact lens wear, the subjects were re-evaluated to determine the changes in conjunctival redness, subjective dry eye disease, tear meniscus height, lipid pattern, and non-invasive break-up time. Results showed that the lipid layer thickness decreased significantly from 2.05 ± 1.53 to 0.92 ± 1.09 Guillon patterns, and the tear meniscus height decreased from 0.21 ± 0.04 to 0.14 ± 0.03. The mean pre-lens non-invasive break-up time (NIBUT) significantly increased from 15.19 ± 9.54 to 25.31 ± 15.81 s. The standard Patient Evaluation of Eye Disease (SPEED) score also decreased from 7.39 ± 4.39 to 5.53 ± 4.83. The results suggest that Lehfilcon A significantly reduced lipid and aqueous tear film volume but improved break-up time and subjective dry eye symptoms. Full article
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22 pages, 16835 KiB  
Article
Experimental Study on the Dynamic Characteristics of Gas-Centered Swirl Coaxial Injector under Varying Ambient Pressure
by Xiaoguang Zhang, Wentong Qiao, Qixiang Gao, Dingwei Zhang, Lijun Yang and Qingfei Fu
Aerospace 2023, 10(3), 257; https://doi.org/10.3390/aerospace10030257 - 8 Mar 2023
Cited by 3 | Viewed by 3104
Abstract
To determine the dynamic characteristics of a gas-centered swirl coaxial injector under backpressure, an experimental system of dynamic injection in a backpressure chamber was constructed. Filtered water and nitrogen were used as simulant media for rocket propellants, which are typically used with this [...] Read more.
To determine the dynamic characteristics of a gas-centered swirl coaxial injector under backpressure, an experimental system of dynamic injection in a backpressure chamber was constructed. Filtered water and nitrogen were used as simulant media for rocket propellants, which are typically used with this kind of injector. An inertial flow pulsator was manufactured to generate the pulsation of the flows that feed to the liquid injector. The electric conductance method was adopted to measure liquid film thickness. After the pulsation of incoming flow in the feedline was tested, and the operating conditions for the injector to start pulsating were validated, the effects of the chamber backpressure and the recess length of the injector on the dynamic characteristics of spray, such as liquid film thickness, breakup length, and amplitude of pulsation, have been investigated in detail. Experimental results demonstrated that the increase in chamber backpressure prompts the liquid sheet to rupture earlier with a shorter breakup length, which results from the increased density of the ambient gas. Chamber backpressure suppresses the pulsation of the outlet flow, especially for a longer recess length. Moreover, a decrease in the recess length results in a reduction in breakup length due to an intense gas–liquid shearing in a narrower recess section. For a lower backpressure, the amplitude of outlet flow generally increases when the recess length increases. However, this phenomenon is not obvious for the conditions of higher backpressure and lower pulsation frequency. Full article
(This article belongs to the Special Issue Heat Transfer, Combustion and Flow Dynamics in Propulsion Systems)
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12 pages, 1702 KiB  
Article
Tear Film Dynamics between Low and High Contact Lens Dry Eye Disease Questionnaire (CLDEQ-8) Score with a Lehfilcon A Silicone Hydrogel Water Gradient Contact Lens: A Non-Invasive Methodology Approach
by Raúl Capote-Puente, María-José Bautista-Llamas and José-María Sánchez-González
Diagnostics 2023, 13(5), 939; https://doi.org/10.3390/diagnostics13050939 - 1 Mar 2023
Cited by 8 | Viewed by 2691
Abstract
The purpose of this study is to evaluate the tear film dynamics between individuals with low and high Contact Lens Dry Eye Disease Questionnaire (CLDEQ-8) scores when wearing Lehfilcon A silicone hydrogel water gradient contact lenses. In this study, we implemented a longitudinal, [...] Read more.
The purpose of this study is to evaluate the tear film dynamics between individuals with low and high Contact Lens Dry Eye Disease Questionnaire (CLDEQ-8) scores when wearing Lehfilcon A silicone hydrogel water gradient contact lenses. In this study, we implemented a longitudinal, single-location, self-comparison investigation. Variables measured included conjunctival redness, lipid layer thickness, tear meniscus height, first and mean non-invasive break-up time, CLDEQ-8, and standard patient evaluation of eye dryness (SPEED). In the second phase, participants were re-evaluated after 30 days of wearing the contact lenses to assess the tear film wearing the lenses. In a longitudinal comparison by group, we found that lipid layer thickness decreased 1.52 ± 1.38 (p < 0.01) and 0.70 ± 1.30 (p = 0.01) Guillon patterns degrees in the low and high CLDEQ-8 group, respectively. MNIBUT increased in 11.93 ± 17.93 (p < 0.01) and 7.06 ± 12.07 (p < 0.01) seconds. Finally, LOT increased in 22.19 ± 27.57 (p < 0.01) and 16.87 ± 25.09 (p < 0.01). In conclusion, this study demonstrates the effectiveness of Lehfilcon A silicone hydrogel water gradient contact lenses in improving tear film stability and reducing subjective dry eye symptoms in individuals with low and high CLDEQ-8 scores. However, it also led to an increase in conjunctival redness and a decrease in tear meniscus height. Full article
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18 pages, 6449 KiB  
Article
Simulation of and Experimental Research on Rivulet Model on Airfoil Surface
by Yanxia Lou, Xueqin Bu, Xiaobin Shen, Guiping Lin, Ruchen Zhang, Feixiong Zeng, Haichuan Jin, Kuiyuan Ma and Dongsheng Wen
Aerospace 2022, 9(10), 570; https://doi.org/10.3390/aerospace9100570 - 29 Sep 2022
Cited by 6 | Viewed by 2798
Abstract
The occurrence of aircraft icing can significantly affect flight performance. One of the most important aspects in the study of anti-icing technology for aircraft is the distribution of overflow water. Owing to the external airflow pressure, shear stress, and surface tension, the water [...] Read more.
The occurrence of aircraft icing can significantly affect flight performance. One of the most important aspects in the study of anti-icing technology for aircraft is the distribution of overflow water. Owing to the external airflow pressure, shear stress, and surface tension, the water film breaks up to form steady rivulets. Experiments on NACA0012 airfoil surfaces were conducted based on an open straight-flow and low-speed wind tunnel. Simultaneously, an engineered three-dimensional rivulet model considering the surface roughness was established based on the energy-minimum principle. A comparison between the simulation and experimental results shows that the errors in the water film breakup location and the flow velocity of rivulets are less than 20%, and the errors in the spacing and width of rivulets are less than 40%. In addition, the effects of surface temperature and uniform roughness on water film breakup were investigated. Furthermore, the rivulet model was applied to the numerical calculation of the thermal performance of hot-air anti-icing systems. The simulations reveal that the uniform roughness of the wing surface causes the water film to break earlier. As the surface roughness increases, the thickness, spacing, and width of the rivulets increase, and the rivulet flow velocity decreases. Full article
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15 pages, 1260 KiB  
Article
An Oral Polyphenol Formulation to Modulate the Ocular Surface Inflammatory Process and to Improve the Symptomatology Associated with Dry Eye Disease
by Dalia Ng, Juan Carlos Altamirano-Vallejo, Alejandro Gonzalez-De la Rosa, Jose Navarro-Partida, Jorge Eugenio Valdez-Garcia, Ricardo Acosta-Gonzalez, Juan Carlos Martinez Camarillo, Andres Bustamante-Arias, Juan Armendariz-Borunda and Arturo Santos
Nutrients 2022, 14(15), 3236; https://doi.org/10.3390/nu14153236 - 7 Aug 2022
Cited by 7 | Viewed by 4185
Abstract
Due to their antioxidant, anti-inflammatory, neuroprotective, and anti-angiogenic effects, polyphenols are first-rate candidates to prevent or treat chronic diseases in which oxidative stress-induced inflammation plays a role in disease pathogenesis. Dry eye disease (DED) is a common pathology, on which novel phenolic compound [...] Read more.
Due to their antioxidant, anti-inflammatory, neuroprotective, and anti-angiogenic effects, polyphenols are first-rate candidates to prevent or treat chronic diseases in which oxidative stress-induced inflammation plays a role in disease pathogenesis. Dry eye disease (DED) is a common pathology, on which novel phenolic compound formulations have been tested as an adjuvant therapeutic approach. However, polyphenols are characterized by limited stability and solubility, insolubility in water, very rapid metabolism, and a very short half-life. Thus, they show poor bioavailability. To overcome these limitations and improve their stability and bioavailability, we evaluated the safety and efficacy of an oral formulation containing among other compounds, polyphenols and omega-3 fatty acids, with the addition of a surfactant in patients with DED. Subjects were randomly assigned to one of four study groups including the study formulation (A), placebo (P), the study formulation + eye lubricant (A + L), and placebo + eye lubricant (P + L). Patients from the A and P groups were instructed to take two capsules every 24 h, while patients in the L groups also added one drop of lubricant twice a day for 12 weeks as well. Regarding safety, non-ocular abnormalities were observed during study formulation therapy. Liver function tests did not show any statistically significant difference (baseline vs. week 4). Concerning efficacy, there was a statistically significant difference between baseline, month 1, and month 3 in the OSDI (Ocular Surface Disease Index) test results in both treatment groups (group A and group A + L). Furthermore, both groups showed statistically significant differences between baseline and month 3 regarding the non-invasive film tear breakup time (NIF-BUT) score and a positive trend related to Shirmer’s test at month 3. The non-invasive average breakup time (NIAvg-BUT) score showed a statistically significant difference at month 3 when compared with baseline in the A + L group. The P + L group showed a statistically significant difference in terms of the OSDI questionary between baseline and month 3. Regarding the lissamine green staining, the A + L group showed a statistical difference between baseline and month 3 (p = 0.0367). The placebo + lubricant group did not show statistically significant differences. Finally, the placebo group did not show any data with statistically significant differences. Consequently, this polyphenol formulation as a primary treatment outperformed the placebo alone, and the polyphenol oral formulation used as an adjuvant to artificial tears was superior to the combination of the placebo and the artificial tears. Thus, our data strongly suggest that this polyphenol oral formulation improves visual strain symptoms and tear film status in patients with mild to moderate DED. Full article
(This article belongs to the Special Issue Anthocyanins and Human Health)
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16 pages, 6110 KiB  
Article
Hydrophobic Antiwetting of Aquatic UAVs: Static and Dynamic Experiment and Simulation
by Yihua Zheng, Zhimin Huang, Chengchun Zhang and Zhengyang Wu
Appl. Sci. 2022, 12(15), 7626; https://doi.org/10.3390/app12157626 - 28 Jul 2022
Cited by 4 | Viewed by 2455
Abstract
The adhesion of water to the surfaces of unmanned aerial vehicles (UAVs) adversely affects the function. The proposed UAVs will have underwater as well as flight capability, and these aquatic UAVs must shed water to resume flight. The efficient separation of the adhering [...] Read more.
The adhesion of water to the surfaces of unmanned aerial vehicles (UAVs) adversely affects the function. The proposed UAVs will have underwater as well as flight capability, and these aquatic UAVs must shed water to resume flight. The efficient separation of the adhering water from aquatic-UAV surfaces is a challenging problem; we investigated the application of hydrophobic surfaces as a potential solution. Using aquatic-UAV models, one with hydrophilic surfaces and the other with superhydrophobic anisotropic textured surfaces, the antiwetting mechanism of the hydrophobic surfaces was investigated using a simulated-precipitation system and instrumentation to measure the load of the water adhering to the aquatic UAV, and to measure the impact energies. When the model was stationary (passive antiwetting), no adhesion occurred on the superhydrophobic surfaces, while continuous asymmetric thick liquid films were observed on the hydrophilic surfaces. The superhydrophobic surfaces reduced the rain loading by 87.5%. The vibration and movement of the model (dynamic antiwetting, simulating flight motions) accelerated the separation process and reduced the contact time. The observed results were augmented by the use of computational fluid dynamics with lattice Boltzmann methods (LBM) to analyze the particle traces inside the droplets, the liquid phase velocity-field and pressure-field strengths, and the backward bouncing behavior of the derived droplet group induced by the moving surface. The synergy between the superhydrophobic surfaces and the kinetic energy of the droplets promotes the breakup of drops, which avoids the significant lateral unbalance observed with hydrophilic surfaces during simulated flight. Full article
(This article belongs to the Special Issue Bionic Design and Manufacturing of Innovative Aircraft)
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15 pages, 4456 KiB  
Article
Comparison of Dust Deposition Reduction Performance by Super-Hydrophobic and Super-Hydrophilic Coatings for Solar PV Cells
by Hao Lu and Chuanxiao Zheng
Coatings 2022, 12(4), 502; https://doi.org/10.3390/coatings12040502 - 8 Apr 2022
Cited by 25 | Viewed by 4476
Abstract
Dust deposition on solar photovoltaic (PV) cells will dramatically reduce the photovoltaic power output. Self-cleaning coating may be a novel method to decrease dust deposition problems. This paper compares self-cleaning performances and mechanisms of super-hydrophobic and super-hydrophilic coating on dirt deposition decrease for [...] Read more.
Dust deposition on solar photovoltaic (PV) cells will dramatically reduce the photovoltaic power output. Self-cleaning coating may be a novel method to decrease dust deposition problems. This paper compares self-cleaning performances and mechanisms of super-hydrophobic and super-hydrophilic coating on dirt deposition decrease for solar photovoltaic cells by experimental measurement. In the process of the deposition of dust on solar cells, covering glass, coated and uncoated, is conducted under natural settling conditions. Moreover, the dust removal efficiency of the glass samples with and without coatings is studied under water spraying conditions. The wettability of different surfaces, dust deposition mass, dust removal efficiency, self-cleaning mechanisms, and transmittance of glass samples are investigated and analyzed. Under natural settling conditions, the deposition mass reduction ratio by the super-hydrophilic coating is only 8.1%, while it can reach 85.8% by the super-hydrophobic coating because of surface micro-structures and low surface energy. However, after the water spraying process, the remaining dust mass ratio for the super-hydrophobic surface is only 16.5%, while it is 18.6% for the super-hydrophilic surface. The self-cleaning mechanism of super-hydrophobic coating is that most deposited particles of dust are removed from glass samples by the rolling of liquid droplets. However, the self-cleaning mechanism of super-hydrophilic coating is the breakup of the liquid film. Therefore, both coatings can effectively reduce dust deposition under water spraying conditions. The average transmittance of super-hydrophobic and super-hydrophilic coatings after the water spraying process is 91.1% and 86.4%, respectively, while it is only 61.1% for the uncoated glass sample. Full article
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12 pages, 2454 KiB  
Article
MPC Polymer Promotes Recovery from Dry Eye via Stabilization of the Ocular Surface
by Noriaki Nagai, Shunsuke Sakurai, Ryotaro Seiriki, Misa Minami, Mizuki Yamaguchi, Saori Deguchi and Eiji Harata
Pharmaceutics 2021, 13(2), 168; https://doi.org/10.3390/pharmaceutics13020168 - 27 Jan 2021
Cited by 7 | Viewed by 3740
Abstract
The polymer that includes 2-methacryloyloxy ethyl phosphorylcholine (MPC) is well-known as an effectively hydrating multifunction agent. In this study, we prepared an MPC polymer (MPCP) using radical polymerization with co-monomers—MPC/Stearyl Methacrylate/N,N-dimethylacrylamide—and evaluated the MPCP’s usefulness for dry eye treatment [...] Read more.
The polymer that includes 2-methacryloyloxy ethyl phosphorylcholine (MPC) is well-known as an effectively hydrating multifunction agent. In this study, we prepared an MPC polymer (MPCP) using radical polymerization with co-monomers—MPC/Stearyl Methacrylate/N,N-dimethylacrylamide—and evaluated the MPCP’s usefulness for dry eye treatment using a rabbit model treated with N-acetylcysteine. The MPCP particle size was 50–250 nm, and the form was similar to that of micelles. The MPCP viscosity (approximately 0.95 mPa·s) was 1.17-fold that of purified water, and a decrease in the transepithelial electrical resistance value (corneal damage) was not observed in the immortalized human corneal epithelial cell line HCE-T cell (HCE-T cell layer). The MPCP enhanced the water maintenance on the cornea, and the instillation of MPCP increased the lacrimal fluid volume and prolonged the tear film breakup time without an increase in total mucin contents in the lacrimal fluid of the normal rabbits. The therapeutic potential of the MPCP for dry eye was evaluated using an N-acetylcysteine-treated rabbit model, and, in our investigation, we found that MPCP enhanced the volume of lacrimal fluid and promoted an improvement in the tear film breakup levels. These findings regarding the creation and characteristics of a novel MPCP will provide relevant information for designing further studies to develop a treatment for dry eyes. Full article
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21 pages, 4767 KiB  
Article
Secondary Atomization of a Biodiesel Micro-Emulsion Fuel Droplet Colliding with a Heated Wall
by Alexander E. Ashikhmin, Nikita A. Khomutov, Maxim V. Piskunov and Vyacheslav A. Yanovsky
Appl. Sci. 2020, 10(2), 685; https://doi.org/10.3390/app10020685 - 18 Jan 2020
Cited by 23 | Viewed by 4620
Abstract
Using high-speed video recording, we establish the following regimes of hydrodynamic interaction of a biodiesel micro-emulsion fuel droplet with a heated wall: deposition (including drop spreading and receding), drop hydrodynamic breakup, and rebound. Collision regime maps are plotted using a set of dimensionless [...] Read more.
Using high-speed video recording, we establish the following regimes of hydrodynamic interaction of a biodiesel micro-emulsion fuel droplet with a heated wall: deposition (including drop spreading and receding), drop hydrodynamic breakup, and rebound. Collision regime maps are plotted using a set of dimensionless criteria: Weber number We = 470–1260, Ohnesorge number Oh = 0.146–0.192, and Reynolds number Re = 25–198. The scenarios of droplet hydrodynamic disintegration are studied for transient and film boiling. We also estimate the disintegration characteristics of a biodiesel micro-emulsion droplet (mean diameter of child droplets, their number, and evaporation surface area increase due to breakup). The study establishes the effect of water proportion on the micro-emulsion composition (8–16 vol.%), heating temperature (300–500 °C), droplet size (1.8–2.8 mm), droplet velocity (3–4 m/s), rheological properties of the examined compositions, and emulsifier concentration (10.45 vol.% and 20 vol.%) on the recorded characteristics. The results show that the initial liquid surface area can be increased 2–19 times. The paper analyzes ways to control the process. The hydrodynamic disintegration characteristics of a biodiesel micro-emulsion fuel droplet are compared using 2D and 3D recording. Full article
(This article belongs to the Special Issue Heat and Mass Transfer in Intense Liquid Evaporation)
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22 pages, 13082 KiB  
Article
Characteristics of Water and Urea–Water Solution Sprays
by Łukasz Jan Kapusta, Marek Sutkowski, Rafał Rogóż, Mohamed Zommara and Andrzej Teodorczyk
Catalysts 2019, 9(9), 750; https://doi.org/10.3390/catal9090750 - 6 Sep 2019
Cited by 26 | Viewed by 5515
Abstract
In spray studies related to selective catalytic reduction (SCR) systems a common approach is to replace the urea–water solution (UWS) with pure water, even though there is very limited detailed information on the spray properties for these two liquids obtained under the same [...] Read more.
In spray studies related to selective catalytic reduction (SCR) systems a common approach is to replace the urea–water solution (UWS) with pure water, even though there is very limited detailed information on the spray properties for these two liquids obtained under the same conditions using the same experimental equipment. Neither is it known how the possible differences in spray properties influence computational fluid dynamics (CFD) simulations. In this study, besides the flow characteristics, we compare both global and local spray parameters measured for UWS and pure water in the same conditions. To our knowledge, this is the first study which examines the influence on the injection process of replacing UWS with water over such a wide range. Moreover, the influence of different spray properties on CFD simulations is also examined. The experimental studies showed differences in almost all considered spray parameters. Moreover, different spray behaviour was noticed in terms of primary break-up. One important finding is that water and UWS sprays do have a similar Sauter mean diameter, but at the same time the droplet size distribution is considerably different. The simulation results indicated noticeable differences in terms of wall film formation; nevertheless, the overall mixing performance was not significantly affected. Full article
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12 pages, 3549 KiB  
Article
Effects of Lipid Saturation on the Surface Properties of Human Meibum Films
by Yana Nencheva, Aparna Ramasubramanian, Petar Eftimov, Norihiko Yokoi, Douglas Borchman and Georgi As. Georgiev
Int. J. Mol. Sci. 2018, 19(8), 2209; https://doi.org/10.3390/ijms19082209 - 28 Jul 2018
Cited by 29 | Viewed by 5488
Abstract
Elevated levels of acyl chain saturation of meibomian lipids are associated with vastly different effects: from enhanced tear film (TF) stability in infants to shortened TF breakup time in meibomian gland disease patients. Thus it is important to study the effect of saturation [...] Read more.
Elevated levels of acyl chain saturation of meibomian lipids are associated with vastly different effects: from enhanced tear film (TF) stability in infants to shortened TF breakup time in meibomian gland disease patients. Thus it is important to study the effect of saturation on the surface properties of human meibum (MGS). Therefore, MGS films (1, 2, 3, 4, 5, 10, 25, 50, 67, and 100% saturation) were spread at the air/water interface of a Langmuir surface balance. The layers’ capability to reorganize during dynamic area changes was accessed via the surface pressure (π)-area (A) compression isotherms and step/relaxation dilatational rheology studies. Film structure was monitored with Brewster angle microscopy. The raise in the % (at ≥10%) of saturation resulted in the formation of stiffer, thicker, and more elastic films at π ≥ 12 mN/m with the effects being proportional to the saturation level. At the same time, at low (≤10 mN/m) π the raise in saturation resulted in altered spreading and heterogeneous structure of MGS layers. The strong impact of saturation on MGS surface properties correlates with our recent spectroscopy study, which demonstrated that saturation induced increase of MGS acyl chain order, phase transition temperature, and cooperativity. Full article
(This article belongs to the Section Biochemistry)
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13 pages, 4152 KiB  
Article
Molecular Dynamics Study of Self-Assembly of Aqueous Solutions of Poly[9,9-bis(4-Sulfonylbutoxyphenylphenyl) Fluorene-2,7-diyl-2,2’-Bithiophene] (PBS-PF2T) in the Presence of Pentaethylene Glycol Monododecyl Ether (C12E5)
by Beverly Stewart and Hugh Douglas Burrows
Materials 2016, 9(5), 379; https://doi.org/10.3390/ma9050379 - 18 May 2016
Cited by 5 | Viewed by 4897
Abstract
Results are presented using molecular dynamics (MD) of the self-assembly of the conjugated polyelectrolyte poly[9,9-bis(4-sulfonylbutoxyphenylphenyl) fluorene-2,7-diyl-2,2’-bithiophene] (PBS-PF2T) with 680 mM pentaethylene glycol monododecyl ether (C12E5) in water. Simulations are used to examine the interaction between PBS-PF2T and C12 [...] Read more.
Results are presented using molecular dynamics (MD) of the self-assembly of the conjugated polyelectrolyte poly[9,9-bis(4-sulfonylbutoxyphenylphenyl) fluorene-2,7-diyl-2,2’-bithiophene] (PBS-PF2T) with 680 mM pentaethylene glycol monododecyl ether (C12E5) in water. Simulations are used to examine the interaction between PBS-PF2T and C12E5 and suggest a break-up of PBS-PF2T aggregates in solution. These systems are dominated by the formation of cylindrical phases at temperatures between 0 °C and 20 °C and also between 45 °C and 90 °C. More diffuse phases are seen to occur between 20 °C and 45 °C and also above 90 °C. Simulations are related to previous computational and experimental studies on PBS-PF2T aggregation in the presence of tetraethylene glycol monododecyl ether (C12E4) in bulk and thin films. Full article
(This article belongs to the Special Issue Surface Forces and Thin Liquid Films)
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