Search Results (11,486)

The discharge of metal-containing effluents into aquatic systems remains a major environmental concern because metal ions can persist in water bodies and accumulate in biological systems, potentially affecting ecosystem and human health. Among these contaminants, Cr(III) is frequently encountered in waste streams generated by industrial activities, making its removal an important objective in water quality management. This study investigated the adsorption behavior of Cr(III) using lignocellulosic biosorbents obtained from tamarind shell (Tamarindus indica) after water, H₂O₂, and HCl pretreatments, with particular emphasis on equilibrium behavior, thermodynamic characteristics, and pretreatment-induced physicochemical modifications. Batch adsorption experiments were conducted to evaluate equilibrium behavior. The highest adsorption capacity (41.6 mg g⁻¹) was obtained with the water-treated biosorbent at 60 °C. The equilibrium data were best represented by the Sips model, suggesting that Cr(III) adsorption occurred on surfaces containing adsorption sites with different energetic characteristics. Thermodynamic analysis revealed that the adsorption process was spontaneous, while the enthalpy changes indicated predominantly endothermic behavior for the pretreated biosorbents. ATR-FTIR, SEM, EDS, and XRD analyses were performed to characterize the biosorbents before and after adsorption. The characterization results indicated that oxygen-containing functional groups, particularly hydroxyl and carbonyl functionalities, were associated with the adsorption process. SEM images showed morphological changes associated with pore occupation, while EDS confirmed chromium adsorption and suggested possible ion-exchange mechanisms. XRD patterns indicated a mainly amorphous structure. The results demonstrated that pretreatment-induced modifications strongly influenced the adsorption performance of tamarind shell. Water pretreatment produced the most favorable adsorption behavior, yielding the highest adsorption capacity among the evaluated biosorbents. The combined interpretation of equilibrium, thermodynamic, and characterization results revealed a close relationship between surface properties and Cr(III) uptake. Full article

Scientific studies of mine closure and ecosystem management have become very important since the rate of coal mine closures in China has increased rapidly over the last decade. This study first analyzed spatiotemporal changes in land use and ecosystem services value (ESV) during the period 2000–2020 around the Kailuan Mining Area in Tangshan City. The area has a history of over 100 years of continuous mining activities in the region. The analyses used the PLUS model, multi-scenario simulation, and ESV equivalent factor method and multi-source data on land use, mining activities, socioeconomic factors, and climatic conditions. The study then projected land-use changes and spatiotemporal ESV characteristics for the year 2030 for two alternatives: (1) the Current Development Scenario (CDS), representing the current pace of development without mine closure; and (2) the Ecological Restoration Scenario (ERS), representing mine closure and ecological restoration. Key results include: (1) during 2000–2020, cultivated land and construction land were the primary land uses, with the overall trends showing decrease in cultivated, forest, pasture, and unused lands, varying water use areas, and continuously increasing construction land; (2) the revised ESV results show that total ESV declined from 31.27 million USD in 2000 to 25.30 million USD in 2020, a net decrease of 6.19 million USD, mainly because of cropland loss and degradation of forest and grassland; and (3) for 2030, the CDS projected a continued decline in total ESV to 24.30 million USD, whereas the ERS increased total ESV to 26.50 million USD, which is 2.19 million USD higher than the CDS and 1.20 million USD higher than the 2020 baseline. Compared with the CDS, the ERS increased cropland by 13.20 km² and reduced construction land by 10.06 km², indicating that reclaiming subsided water bodies and idle construction land into cropland and restored ecological land can enhance ecosystem services while mitigating subsidence-related risks. The framework can support data-driven post-mining land-use planning and ecological management in resource-based regions. Full article

The Amazon Basin and its rivers play a vital role in regional biodiversity, the carbon cycle, and socio-economic security. Through erosion and deposition, river planforms change over time, affecting local infrastructure, food security, and changes to ecosystems. Long-term monitoring is essential for observing these dynamics. Synthetic Aperture Radar (SAR) provides a method to consistently map river planform dynamics across large areas because it is largely independent of atmospheric conditions. This study presents an approach for deriving river planform metrics across the entire Amazon Basin using Sentinel-1 C-band SAR data. This approach followed three main steps: water mask generation, validation of the data and river metrics extraction. Sentinel-1 imagery from 2017 to 2025 was composited into quarterly mean images, after which Otsu thresholding was applied to derive water classifications. Additional post-processing steps were applied to reduce terrain- and seasonal effects. The final water masks were divided into water-change classes, validated using stratified sampling and achieved an overall accuracy of 98.5%. Quarterly river planform metrics, including sinuosity, mean channel width and migration rate, were derived using channel centerline extraction, but due to a lack of in situ validation data the river metric values have not been validated. The resulting time series provide insights into how river planform changes across all Amazon sub-basins from 2017 to 2025 can be monitored using SAR-based methods. The results reveal spatial differences in river dynamics between tributaries, mostly depending on flow pattern, up- or downstream path and location in the upper, middle or lower Amazon Basin. These findings demonstrate the potential of SAR time series for monitoring large-scale river planform dynamics. Full article

Vegetation phenology is a sensitive indicator of climate change in China’s drylands (aridity index, AI < 0.65). However, accurate phenological monitoring remains challenging due to low signal-to-noise ratios, persistent soil background interference, and the scarcity of ground phenological sites. Existing global phenology products also perform poorly in hyper-arid and arid regions. This study developed an optimal phenology detection framework for China’s drylands by systematically evaluating various vegetation indices, noise-reduction techniques, fitting functions, and dynamic thresholds against ground observations, generating a dataset at 500-m resolution spanning 2001–2024. Specifically, we determined vegetation index thresholds to distinguish vegetated from non-vegetated pixels based on 453 field survey sites. Our results indicate that the Normalized Difference Phenology Index (NDPI) coupled with a 10% threshold and polynomial fitting provided the highest accuracy for Start of Season (SOS) (RMSE = 12.02 days). For End of Season (EOS), EVI2 combined with a 70% threshold and self-weighted double-logistic fitting yielded superior performance (RMSE = 19.89 days). Compared to the MODIS global phenology product (MCD12Q2), our dataset demonstrates significantly higher accuracy (higher R and lower RMSE) and broader spatial coverage, particularly in hyper-arid and arid regions. Spatiotemporal analysis reveals that SOS was earlier while EOS was later in more arid areas, potentially reflecting the opportunistic life strategies of ephemeral plants. Notably, a trend of delayed SOS was observed in these regions, which we potentially linked to the shifts in precipitation regimes under global change. This optimized framework and the resulting Chinese dryland phenology dataset provide a robust foundation for assessing ecosystem resilience and carbon cycle dynamics in water-limited environments. Full article

Serratia marcescens has emerged as an important opportunistic pathogen in intensive care units (ICUs), where critically ill patients, invasive devices, antimicrobial exposure, and complex environmental reservoirs create favorable conditions for colonization, infection, and recurrent outbreaks. This narrative review synthesizes evidence from the past decade regarding the clinical and molecular epidemiology, environmental persistence, device-associated transmission, biofilm-mediated resistance, and infection-control strategies of S. marcescens in ICU settings. The literature was reviewed using an integrative approach informed by Ferrari’s narrative review framework, with thematic synthesis across clinical, microbiological, environmental, and genomic domains. Recent evidence indicates that ICU-associated S. marcescens infections frequently involve respiratory tract colonization, ventilator-associated pneumonia, bloodstream infection, urinary tract infection, and device-related transmission. Hospital water systems, sink drains, wet surfaces, ventilator circuits, reusable equipment, and contaminated antiseptic or liquid products may serve as persistent reservoirs, particularly when biofilm formation supports long-term survival and recurrent dissemination. At the molecular level, S. marcescens demonstrates substantial genomic diversity, intrinsic and acquired antimicrobial resistance, inducible AmpC β-lactamase activity, efflux-mediated tolerance, and plasmid-associated resistance gene transfer. This review particularly emphasizes the molecular determinants that enable S. marcescens to persist in ICU ecosystems, including AmpC-mediated β-lactam resistance, efflux-associated tolerance, quorum-sensing-regulated biofilm formation, plasmid-mediated horizontal gene transfer, and WGS-defined clonal transmission. Whole-genome sequencing, rapid molecular diagnostics, active surveillance, environmental sampling, and integrated infection-control bundles have become increasingly important for distinguishing clonal outbreaks from endemic transmission and guiding timely interventions. Emerging perspectives emphasize the need to combine antimicrobial stewardship, environmental engineering, respiratory-care auditing, anti-biofilm strategies, and AI-assisted real-time surveillance into adaptive ICU infection-control frameworks. Overall, S. marcescens should be regarded not merely as an episodic outbreak organism, but as a highly adaptable ICU-associated pathogen requiring multidisciplinary prevention strategies. Full article

Sustainable water remediation requires catalytic strategies that remove contaminants efficiently while reducing chemical input, byproduct formation, and ecological disturbance. Conventional radical-dominated advanced oxidation processes can rapidly degrade pollutants, but their reliance on high oxidant dosages and freely diffusing reactive oxygen species often causes matrix quenching, non-selective oxidation, low oxidant utilization, and potential ecological risks. Mild interfacial catalysis provides a materials-chemistry strategy to regulate oxidative intensity and direct contaminant transformation under environmentally relevant conditions. In this review, mild catalysts are defined by pathway-selective, interfacially confined, and environmentally compatible oxidation rather than by low dosage alone. Representative non-radical or low-intensity pathways, including singlet oxygen generation, surface-mediated electron transfer, high-valent metal–oxo species, and direct oxidative transfer processes, are discussed in relation to active-site structure, oxidant utilization, matrix tolerance, and byproduct control. We further summarize how coordination environments, defect chemistry, heteroatom configurations, nanoconfinement, and immobilized interfaces regulate reactive-species formation and interfacial charge transfer. Key material platforms, including single-atom catalysts, heteroatom-doped carbons, defect-engineered oxides, catalytic membranes, hydrogels, and floating or immobilized composites, are evaluated from mechanistic and application-oriented perspectives. Finally, catalyst regeneration, cost, microbial community responses, algae–bacteria balance, ecotoxicity, and long-term safety are discussed to guide sustainable aquatic ecosystem restoration. Full article

Floodplain wetlands are globally important ecosystems, yet altered hydrological regimes increasingly disrupt the balance between woody and non-woody vegetation. In Australia’s regulated Murray–Darling Basin, it remains unclear whether woody plant encroachment represents a persistent shift toward terrestrialisation or a dynamic process that can be periodically reversed by flooding. This study quantified long-term patterns of woody-vegetation encroachment and retreat across 32,000 ha of mapped wetlands in the mid-Murrumbidgee River floodplain from 1988 to 2023, and assessed how hydrological variability and floodplain connectivity mediate these dynamics. Using open, analysis-ready Earth observation data from Digital Earth Australia (DEA) within the Open Data Cube (ODC) framework, we combined DEA Land Cover for transition mapping, Water Observations for hydrological masking, Landsat surface reflectance for Enhanced Vegetation Index (EVI)-based spectral plausibility testing, and the Wetlands Insight Tool for qualitative temporal context. Woody-vegetation dynamics were strongly non-linear and closely linked to alternating drought and flood phases. During the Millennium Drought (2001–2009), mapped woody-cover decline exceeded 50% of wetland area in some sub-regions, whereas the post-drought recovery interval (2008–2013) produced encroachment exceeding 40% in the most affected areas. Across the full 35-year record, mean encroachment rates ranged from 85 to 250 ha yr⁻¹ among sub-regions, summing to approximately 865 ha yr⁻¹ of woody expansion across the floodplain, while retreat rates were lower overall (approximately 634 ha yr⁻¹), resulting in a net expansion of woody cover. Local hydrological connectivity strongly mediated these responses: infrequently inundated wetlands showed persistent terrestrialisation, whereas more frequently inundated, better-connected wetlands experienced periodic flood-driven retreat. Landsat-derived EVI broadly supported the mapped transitions, indicating general consistency with canopy greening and canopy decline, supporting the ecological plausibility of the detected changes. This open DEA–ODC workflow provides a transparent, transferable framework for operational wetland monitoring and demonstrates that maintaining natural flood frequency, duration, and connectivity is essential for sustaining the resilience of regulated floodplain systems. Full article

Petroleum exploitation in the Niger Delta has caused widespread contamination of mangrove ecosystems, yet studies that integrate total petroleum hydrocarbons (TPH) and metals in mangrove water are still very limited. This study presents the first dual-pollutant baseline assessment of TPH and five priority metals (Cd, Cr, Pb, Ni, Zn) in Bille mangrove water, a severely oil-impacted system supporting about 50,000 residents. Water samples were collected from six sites along a contamination gradient (flow station, pipeline passage, old bunkering site) and analyzed for TPH (C8–C40) and metals. All concentrations are reported in mg/L for direct comparability with World Health Organization (WHO) drinking-water guidelines and United States Environmental Protection Agency (USEPA) thresholds. TPH concentrations ranged from 0.18 to 57.66 mg/L, with Site 3 (pipeline passage) showing levels about 320-fold higher than reference sites and exceeding the WHO drinking-water guideline (0.05 mg/L) by up to 1153-fold. Cadmium (0.040–0.350 mg/L) and nickel (0.055–0.561 mg/L) exceeded WHO drinking-water guidelines (Cd 0.003 mg/L; Ni 0.07 mg/L) by 13–117- and up to 8-fold, respectively. Health risk assessment, using USEPA Risk Assessment Guidance for Superfund (RAGS) protocols, revealed a total cancer risk of 4.15 × 10⁻³ at Site 3, 41-fold above the USEPA acceptable threshold of 1 × 10⁻⁴, and extreme non-carcinogenic risk (Hazard Index = 20.03–25.51) at petroleum-infrastructure sites; cadmium contributed 86–88% of both carcinogenic and non-carcinogenic effects. Ecological risk indices classified Site 3 as extreme (Potential Ecological Risk Index = 722, against the Håkanson PERI = 600 “very-high-risk” threshold), mainly driven by cadmium (Er = 310–350) and nickel (Er = 140–150). Source apportionment using the Carbon Preference Index, enrichment factors, and strong TPH–metal correlations (r > 0.88, p < 0.01) clearly identified petroleum operations as the dominant contamination source. This work demonstrates the critical importance of integrated multi-pollutant assessments in petroleum-degraded mangrove water for guiding environmental protection and public-health interventions. Full article

Despite their size, small wetlands play a vital role in maintaining ecosystem stability. To clarify the pollution levels as well as potential ecological and health risks of potentially toxic elements (PTEs) in small wetlands, 85 water samples were collected from small wetlands in the Baghrash Lake Basin (BLB) of China, and six PTEs (As, Cd, Cu, Hg, Pb, and Zn) were determined for their contents. The Nemerow integrated pollution index (NPI) was adopted to evaluate PTE pollution levels. The ecological risk index (RI) and USEPA health risk assessment model were further applied to quantify potential ecological and health risks of PTEs, respectively. The results revealed that PTEs in small wetlands showed a slight pollution level, with an average NPI value of 0.73. Meanwhile, the integrated ecological risk index of PTEs showed a low ecological risk level, with an average RI value of 23.041. Health risk assessment results demonstrated that the non-carcinogenic risk of PTEs in small wetlands remained at a negligible level, while the carcinogenic risk stayed within acceptable limits for both local population groups: children and adults. Among all detected PTEs, Hg was identified as the primary pollutant and major ecological risk factor, while As posed the highest relative potential health risk while overall risks remained acceptable. The findings of this study can provide a scientific basis for the environmental protection of small wetlands in the BLB. Full article

The dumping of coal gangue poses significant risks to human health and ecosystems, necessitating ecological restoration in coal gangue mining areas. This study investigates the physical properties and water-retention characteristics of coal gangue–fly ash (CG-FA) substrates under varying coal gangue volume ratios and particle-size distributions, and evaluates their effects on alfalfa (Medicago sativa L.) growth. Six CG-FA volume ratios (5:5, 6:4, 7:3, 8:2, 9:1, 10:0) and seven particle-size distributions (1:1:1, 2:1:1, 3:1:1, 1:2:1, 1:3:1, 1:1:2, 1:1:3) were tested in 3 L pot experiments. Results showed that reducing coal gangue content significantly improved substrate structure, decreasing bulk density by 3.8–28.9% and increasing porosity by 9.8–64.4%, accompanied by enhanced water-retention capacity. The 5:5 volume ratio combined with a 1:2:1 particle-size distribution resulted in the highest alfalfa biomass, providing the best balance of substrate structure and water availability. From a resource-oriented perspective, the optimized CG–FA substrate enables the in situ utilization of coal-based solid wastes, reducing dependence on external soil resources while improving water retention and plant growth. These findings suggest potential advantages in resource utilization, economic feasibility, and environmental performance, providing a sustainable alternative for mine land restoration. Full article

The Gulf of Mexico, a geologically complex environment, supports mesophotic coral ecosystems, with reefs such as the Pinnacle Trend, Flower Garden Banks National Marine Sanctuary, the Florida Middle Ground reef system, and Pulley Ridge. Mountain Top Bank is a dome-shaped hardground feature located 60–150 m below the sea surface along the Mississippi–Alabama shelf. It appears to prolong the Pinnacle Trend towards the southeast, bridging the gap between mesophotic coral reefs east and west of the Mississippi Canyon. Shipborne high-resolution multibeam data (bathymetry, backscatter, and water-column) and an AUV photomosaic were collected over the site during several oceanographic expeditions. Data were analyzed and compiled into an ArcGIS geodatabase to produce the first benthic habitat map of Mountain Top Bank. The site is characterized by a network of outcrops and boulders interspersed within a predominately sandy environment. Different seabed features were correlated with the presence and abundance of a diverse array of biota across the phyla of Cnidaria, Porifera, Mollusca, Chordata, Echinodermata, and Rhodophyta. We found the benthic assemblage to be similar to those found at the Pinnacle Trend, supporting the hypothesis that Mountain Top Bank is part of the same reef system and acts as a topographic bridge between ecosystems on the east and west of the Mississippi Canyon. Full article

As the largest inter-basin water diversion project in eastern China, the Eastern Route of China’s South-to-North Water Diversion Project (ER-SNWDP) plays a crucial role in alleviating water shortages and ensuring regional ecological security. However, large-scale water diversion that uses natural lakes as impounded lakes across different basins has impacted on the structure and function of the original ecosystems. To explore the changes in the food web and ecosystem structure of the impounded lakes during different operation periods of the ER-SNWDP, we constructed Ecopath models for Hongze Lake in 2010–2011 (pre-operation), 2017–2018 (initial operation), and 2023–2024 (operational period). Our results showed that the trophic energy flow in Hongze Lake was dominated by the detrital food chain, with the highest trophic level ranging from 3.06 to 3.50. Energy flows at trophic levels I and II accounted for a high proportion of the total throughput, and the interactions between trophic levels were relatively simple, indicating that Hongze Lake is approaching a mature ecosystem. Compared with the pre-operation period, the average trophic level, food chain length, and energy conversion efficiency of Hongze Lake declined during the initial operation period, but rebounded during the operational period, though still remaining lower than the pre-operation period. Ecosystem stability followed a similar trajectory: the total primary production/total respiration (TPP/TR) and the system omnivory index (SOI) indicated that ecosystem maturity decreased during the initial operation and increased during the operational period. Fishing activities had negative effects on most functional groups during the pre-operation and initial operation periods, whereas the negative effects from zooplankton and non-native species groups increased during the operational period. Based on changes in the food web structure and ecosystem of Hongze Lake across different water diversion periods, we suggest that the management of Hongze Lake should establish precautionary fishing management measures targeting the effects of filter-feeding functional groups and non-native species, optimize the species and quantities of restocking initiatives, prioritize the protection of critical habitat integrity, and implement long-term ecological monitoring. Full article

Slaughterhouse wastewater introduces potentially toxic elements into aquatic ecosystems, yet bioaccumulation patterns in commercial fish species and associated human health risks remain underexplored in West Africa. This study quantified zinc (Zn), lead (Pb), iron (Fe), magnesium (Mg), chromium (Cr), and cadmium (Cd) in three ecologically distinct fish species—Oreochromis niloticus (Nile tilapia), Clarias gariepinus (African sharptooth catfish), and Mugil cephalus (Flathead grey mullet)—from two slaughterhouse-impacted rivers (Transamadi and Mgbuosimini) and a control site (Iwofe) in Rivers State, Nigeria. Metal concentrations were measured using atomic absorption spectrophotometry. Two-way ANOVA assessed species and location effects. Principal component analysis (PCA) was performed, with Mg used as a potential geogenic tracer, as its loading pattern was independent of Pb and Cd and consistent with the natural background. A Water Quality Index (WQI) classified Mgboshimini and Iwofe as having poor water quality (WQI > 75), while Transamadi had medium quality. Health risks were evaluated using estimated daily intake (EDI), target hazard quotients (THQ), and hazard indices (HI) following USEPA guidelines. Metal levels varied significantly by species and location (p < 0.001). Flathead grey mullet from Mgbuosimini had the highest Pb (1.50 ± 0.05 mg/kg) and Cd (0.41 ± 0.02 mg/kg), exceeding EU maximum levels for fish muscle (Pb 0.30 mg/kg, Cd 0.05 mg/kg) by 500% and 800%, respectively. PCA explained 77.5% of the variance, with Pb and Cd clustering as anthropogenic sources, while Mg loaded independently. THQ for Pb approached unity in Flathead grey mullet (0.88), and THQ for Cd reached 0.97. HI exceeded 1.0 in all species from Mgbuosimini, peaking at 2.07 in Flathead grey mullet. Uncertainty analysis (using ±SD) gave a HI range of 1.89–2.25 for this species, all above the safety threshold. Carcinogenic risk for Flathead grey mullet (3.97 × 10⁻⁴) approached the upper acceptable limit. Slaughterhouse effluent appears to elevate Pb and Cd burdens in fish, with detritivorous Flathead grey mullet posing the highest health risk. Exceedance of safety thresholds and HI > 1.0 indicate potential non-carcinogenic and carcinogenic risks. We recommend improved wastewater treatment and species-specific consumption advisories. Full article

Investigating the heterogeneity of ecosystem services (ESs) and their interactions plays a crucial role in refining spatial management. However, little is known about the spatiotemporal heterogeneity of ES interactions. This study quantified the spatiotemporal variations in ES interactions in Northeast China. It categorized different ES bundles through self-organizing maps and ranked the importance of drivers by SHapley Additive exPlanations (SHAP), thereby proposing targeted spatial management strategies. The results indicated that between 2000 and 2020, most ES pairs exhibited synergies, whereas a few ES pairs exhibited trade-offs. And the synergistic areas for habitat quality (HQ)–net primary productivity (NPP), HQ–soil retention (SR), and NPP-SR accounted for 67.79%, 65.29%, and 75.69% of the study region, respectively. Between 2000 and 2020, the area covered by the key synergetic bundle and habitat quality bundle first increased and then decreased. SHAP analysis indicated that NPP, SR, and water retention were most influenced by biophysical indicators, while HQ was primarily influenced by anthropogenic indicators. Based on research findings regarding ES bundles and their drivers, refined strategies for ecosystem management have been proposed. This study integrated knowledge of ES interactions into spatial management, providing a basis for maximizing ES benefits and addressing future climate change. Full article

Nutrient stoichiometry, particularly the balance of carbon (C), nitrogen (N), and phosphorus (P), plays a fundamental role in regulating freshwater ecosystem dynamics, primary production, and biogeochemical cycling. This study presents one of the first dedicated reviews to combine bibliometric mapping with ecological synthesis of C:N:P ratios in inland waters, drawing on 1004 publications indexed in the Web of Science Core Collection (2000–2025), comprising peer-reviewed articles and review articles refined by document type, language, and research area. Bibliometric mapping using VOSviewer (version 1.6.20) identified exponential growth in publications after 2010, with phosphorus dynamics and eutrophication emerging as the most-cited themes, while recent years have shown increasing attention to C:P ratios as reliable ecological indicators. Four dominant thematic clusters were identified: Nutrient Cycling and Biogeochemistry; Phytoplankton and Food Web Dynamics; Eutrophication and Water Quality; and Climate Change and Ecosystem Responses. Ecological synthesis demonstrated substantial deviations from the canonical Redfield ratio (106C:16N:1P), with pronounced stoichiometric variability across trophic states, latitudes, and ecosystem types. Case comparisons revealed high C:P ratios in Arctic and alpine lakes linked to dissolved organic carbon inputs, low N:P ratios in tropical waters that promote cyanobacterial dominance, and stable, low phosphorus concentrations in deep African lakes. These findings emphasize the significance of flexible stoichiometry in predicting ecosystem tipping points, managing harmful algal blooms (HABs), and guiding nutrient restoration strategies. By integrating bibliometric and ecological evidence, this study identifies C:P ratios as a promising candidate indicator that merits further field validation for freshwater management, while underscoring persistent research gaps in microbial stoichiometry, cross-scalar modeling, and policy uptake in the Global South. Full article