Search Results (145)

The construction industry remains one of the main contributors to environmental degradation due to its high material consumption and massive waste generation. This study introduces Granizzo, a hybrid methodological framework that integrates artificial intelligence (AI), parametric design, and digital fabrication to transform construction and demolition waste (CDW) into sustainable architectural mosaics. The workflow involves material selection, AI-driven classification of fragments, generative design algorithms for pattern optimization, and CNC-based experimental prototyping. A dataset comprising brick, cement, marble, glass, and stone fragments was analyzed using a Random Forest classifier, achieving an average accuracy above 90%. Parametric design algorithms based on circle packing and tessellation achieved up to 92% surface coverage, reducing voids and optimizing formal diversity compared to manually assembled mosaics. Prototypes fabricated with CNC molds exhibited 35% shorter assembly times and 20% fewer voids, confirming the technical feasibility of the proposed process. A preliminary Life Cycle Assessment (LCA) revealed measurable environmental benefits in energy savings and CO₂ reduction. The findings suggest that Granizzo constitutes a replicable methodological platform that merges digital precision and sustainable materiality, enabling a circular approach to architectural production and aligning with contemporary challenges of design innovation, material reuse, and computational creativity. Full article

This paper examined the effect of marble powder (MP) on air-cured cement-based materials when subjected to sulfuric acid (H₂SO₄) attack. Four MP replacement levels were tested: 0%, 5%, 10%, and 15% by weight of cement. The prepared samples were cured for 90 days prior to being exposed to H₂SO₄. Macroscopic tests for apparent density and compressive strength along with microstructural characterization using X-ray diffraction (XRD) and scanning electron microscopy (SEM) were performed to determine the effect of MP on the properties of the materials. The Rietveld method was used to analyze the amounts of different crystalline phases and amorphous calcium silicate hydrate (C-S-H). The obtained results indicate that 5% MP in air-cured cement -based materials exhibited the best behavior with acceptable resistance to acid attacks. This level of MP replacement was found to optimize the filler effect, improve the hydration process, and enhance the matrix density, which in turn reduces the permeability of the material and increases acid resistance. This is attributed to the balanced contribution of MP to phase formation, particularly calcite, which helps to counteract acid-induced dissolution, while also preserving the stability of C-S-H phases. This study provides a new perspective of the role of MP in influencing phase content (crystalline and amorphous phases) and their possible impacts on macroscopic properties such as apparent density and compressive strength. MP behaved as a filler, to improve hydration and resistance to acid attacks. Additionally, using MP as a replacement for ordinary Portland cement (OPC) offers a sustainable alternative by reducing waste and promoting the recycling of marble industry by-products, thereby contributing to environmental sustainability. It is recommended that, 5% MP is the optimal replacement content to enhance durability and mechanical properties in air-cured cement-based materials in aggressive environments, as it is both practical and achievable for infrastructure to be subjected to the aggressive environment. Full article

Waste stone powder is a major solid waste byproduct of stone operations. This study developed a novel “alkali activation-calcination” process that efficiently converts waste stone powder into high-value-added silicon-based materials (SSM). This study elucidated the morphological evolution of silicon during the conversion process and revealed the formation mechanism of active silicon. Through further integration of batch adsorption experiments and multi-technique characterization analysis, the immobilization efficacy of this material for heavy metals cadmium/lead was elucidated, revealing both direct and indirect interfacial reaction mechanisms. The results demonstrate that in-creasing the calcination temperature, alkali activator concentration, and calcination duration enhances the reactive silica content in SSM. NaOH as activator, the calcination process significantly reduces both the thermal decomposition temperature of raw materials and the initial temperature required for silicon conversion. Under optimized conditions (WG:MD:activator = 1:0.8:0.32, temperature = 800 °C, time = 1 h), the reactive silica content reached 24.30%. The generation rate of reactive silica is governed by the combined effects of interfacial chemical reactions and solid-phase product layer diffusion. Under idealized laboratory conditions, the maximum adsorption capacities (Qm) of SSM were determined to be 57.40 mg/g for cadmium and 496 mg/g for lead, which are significantly higher than those of many other adsorbents. Continuous desorption experiments and characterization analyses confirm that Cd and Pb adsorption by SSM is primarily driven by electro-static interactions, complexation, precipitation, and coordination, while ion ex-change plays a secondary role. Highly reactive silica facilitates interactions between Cd/Pb and oxygen-containing functional groups (e.g., -OH, ≡Si-OH, Si-O-Si), promoting precipitate formation for effective heavy metal removal. This work offers theoretical guidance for valorizing silica-rich waste rock powder. It is important to note, however, that while the adsorption capacity of SSM is encouraging, its practical implementation requires resolving key issues identified during the lab-to-application transition. Full article

Portland cement is widely used in construction, but it contributes significantly to global CO₂ emissions. This study evaluates the potential use of construction and demolition waste (CDW) and marble powder (MP) as supplementary cementitious materials, in line with circular economy goals. Both wastes were ground finer than cement and characterised chemically and physically. Binary and ternary blends with 5% and 10% replacement were tested in pastes and mortars for fresh properties, mechanical performance, and durability. Setting time, soundness, and workability remained within standard limits. Compressive strength decreased moderately, with 28-day activity indices between 82 and 88%, confirming the low reactivity of the supplementary cementitious materials. Sorptivity decreased in all mixes, and chloride resistance improved in the 10CDW and 10MP blends. However, the ternary mix showed increased chloride migration. Carbonation depth increased in all mixes, indicating the need for protective measures in carbonation-prone environments. Replacing 10% of cement with CDW or MP can avoid 70–80 kg of CO₂ per tonne of binder and reduce landfill waste. These materials can be used as low-carbon fillers in cement-based systems, provided that their durability limitations are considered in design. Full article

One of the environmental concerns today is the increasing amount of waste generated from marble quarrying and processing. This study evaluates the mechanical and durability properties of marble waste-modified rigid pavement material. A series of laboratory tests was conducted to obtain the properties of marble waste-modified rigid pavement material. The slump value decreases as the percentage of marble waste increases. As the percentage of marble waste increases, the dry density gradually decreases from 2770 kg/m³ to 2590 kg/m³. Comparison of the 7-day and 28-day compressive strength indicates that replacing the gravel with marble waste resulted in early strength gain, making it suitable for use in conditions that require early strength gain. The scanning electron microscopy results indicated higher calcium content for the 10% marble waste sample, which is responsible for the cementation and supports the higher compressive strength obtained for the sample at 7 days of curing, due to early strength gain. The study is the first to show the synergistic effect of marble waste on early strength and durability in rigid pavements. These findings showed that marble waste can be used as a modifier in rigid pavement materials. The study contributes to Sustainable Development Goals 9 and 11. Full article

The conversion of rough marble blocks into building products is environmentally intensive in terms of energy and water consumption and the generation of solid fragments and marble sludge (MS). This LCA study evaluates the environmental impact of two marble processing plants (for sawing and cutting) with respect to alternative scenarios of MS management including its (a) land disposal (baseline scenario—BS), (b) land disposal after filter pressing (current scenario—CS) and (c) partial valorization in cement mortars associated with the application of solar energy (eco-friendly scenario—ES). In this context, a “gate-to-gate” methodology is applied, while three main steps are considered: the sawing and cutting of marble blocks (main process) and the MS disposal and reuse. The LCA results indicate that terrestrial acidification (TAP), freshwater eutrophication (FEP), climate change and ozone depletion decreased by 10.8 to 37.1% by the adaptation of the BS and by 18 to 38.2% by the adaptation of the ES. At the same time, cumulative energy demand increases by 25.3% and 28.9%, respectively. The contribution analysis showed that the main process has the dominant effect on the examined categories. The contribution of the disposal step on TAP and FEP decreased by 61.6% and 47.9% via the application of the valorization technique. Full article

The rapid development in building construction has stimulated the replacement of cement in concrete with construction waste materials such as marble waste powder (MWP) and granite waste powder (GWP) to reduce the negative impact of cement production and to save natural resources. Therefore, the inclusion of these materials in concrete contributes to environmental sustainability by reducing cement consumption and promoting the reuse of industrial waste. The present study employs Response Surface Methodology (RSM) and, for the first time in a comparable context, the Neural Network Algorithm (NNA) as an advanced optimization and predictive tool to evaluate the synergistic effect of using GWP and MWP as partial cement replacements in concrete exposed to elevated temperatures. The study involved four independent variables: replacement level of GWP up to 9%, replacement level of MWP up to 9%, the degree of temperature (T) up to 800 °C, and the exposure duration (D) up to 2 h, while the dependent variable (output) was the compressive strength (CS). The ANOVA results revealed that the quadratic model outperformed the linear model in predicting the CS of concrete. The Quadratic model, derived from RSM, demonstrated superior performance in predicting CS values. However, the NNA model also showed high predictive accuracy (R² = 0.949; RMSE = 1.5297 MPa), effectively capturing the complex and nonlinear relationships among temperature, duration, and the cement replacement levels with GWP and MWP. The optimization results revealed that the maximum compressive strength of 39.4 MPa can be achieved at 8.92% GWP, 1.89% MWP, T of 247 °C, and D of 0.64 h with a desirability of 1. The proposed models provided valuable insights into the synergistic effects of granite and marble waste powders, supporting the design of sustainable, high-performance concrete with reduced environmental footprint and improved resource efficiency. Full article

Thermoplastic starch (TPS) is a biodegradable polymer from renewable sources, but its limited mechanical and thermal properties restrict wider industrial use compared to petroleum-based plastics. In this study, TPS-based biocomposites were developed and optimized by incorporating agricultural and mineral Residues: coffee husks (CH), potassium feldspar (PF), and Bahia Beige marble (BB) as reinforcements. Mechanical, thermal, and morphological characterizations were carried out, and a simplex–lattice mixture design was applied to optimize the formulations. The 70/20/5/5 (TPS/CH/PF/BB, wt.%) composition achieved the highest tensile strength (2.0 MPa) and elastic modulus (70.2 MPa), while the 90/0/5/5 formulation showed superior impact resistance. FTIR and SEM analyses confirmed effective filler dispersion and strong matrix–filler interactions. Scheffé polynomial models (R² > 87%) accurately predicted performance, highlighting the reliability of the statistical approach. From a sustainability perspective, this work demonstrates that upcycling coffee husks and mineral residues into TPS-based biocomposites contributes to waste reduction, landfill diversion, and the development of cost-effective biodegradable materials. The proposed systems offer potential for eco-friendly packaging and agricultural applications, reducing dependence on fossil-based plastics and mitigating the environmental footprint of polymer industries. Statistical optimization further enhances efficiency by minimizing experimental waste. Moreover, this research supports circular economy strategies and provides scalable, sustainable solutions for waste valorization. Full article

This paper investigates the design potential of post-consumer plastic waste through the Waste Driven Design (WDD) method, developed at IUAV University of Venice and implemented in both experimental and semi-industrial contexts. WDD proposes a situated and transdisciplinary approach, where waste is no longer regarded as a material to be discarded, but as a resource to be explored, transformed, and valorised. Using the Marble CAP case study—a new material derived from non-recyclable food packaging—the paper presents an iterative and scalable design process that combines technical experimentation, material storytelling, and application potential. The stages of the process are examined, from waste collection and cataloguing to the production of pressed sheets, which are tested under various conditions and finishes. The results demonstrate how, in design, material can become a catalyst for new aesthetics, languages, and production chains. Rather than concluding with the formal outcome, the project opens up spaces for critical and operational interventions along the supply chain, highlighting how design can contribute to imagining and activating alternative trajectories for waste transformation. Full article

This study investigates the potential of waste marble slurry as a partial replacement for ordinary Portland cement, with particular emphases on the influence of the water-to-cement (w/c) ratio and the objectives of determining the effect of water content and the optimum marble slurry concentration. Cement pastes were prepared with three w/c ratios (0.3, 0.4, and 0.5) and five substitution levels of marble slurry (0%, 5%, 10%, 15%, and 20%). Workability was assessed through mini slump flow tests, while mechanical performance was evaluated via compressive and flexural mechanical tests. The initial and final setting times were also investigated. Electrical resistivity measurements, combined with X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM), were used to examine chemical composition and microstructure. Results showed that marble slurry behaves as an inert filler, rather than a reactive component. Its incorporation, up to 10%, significantly improves the fresh properties and mechanical performance of mixes with higher w/c ratios (0.4 and 0.5). At lower w/c ratios (0.3), strength was adversely affected due to insufficient hydration. Electrical resistivity measurements indicated that pastes with w/c = 0.5 and up to 10% slurry replacement became slightly more resistant to electrical current, whereas mixes with lower w/c ratios (0.3 and 0.4) showed only minor reductions at 5% and 10% cement substitution. SEM imaging demonstrated a denser microstructure when marble slurry was incorporated, consistent with a filler effect. Marble slurry was also found to accelerate the setting of cement pastes, an effect most evident at lower w/c ratios and higher substitution levels. Overall, the findings highlight that waste marble slurry can be effectively utilized at moderate replacement levels in cement-based materials, contributing to sustainable construction practices by reducing cement consumption and marble waste disposal. Full article

This study presents a novel approach to the development of self-compacting concrete (SCC) by partially replacing both cement and fine aggregate (sand) with waste marble sludge (WMS), a byproduct of the marble industry. The research aims to evaluate the feasibility of incorporating this industrial waste into SCC to enhance sustainability without compromising performance. To assess the fresh and hardened properties of the proposed mixtures, a comprehensive experimental program was conducted. Tests included slump flow, T₅₀, and V-funnel for evaluating workability, as well as measurements of specific gravity, compressive strength, flexural strength, Brazilian tensile strength, and water absorption at 28 days of curing. The results demonstrated that the mix containing 5% cement replacement and 20% sand replacement with marble sludge exhibited the highest mechanical performance, achieving a compressive strength of 48.2 MPa, tensile strength of 3.9 MPa, and flexural strength of 4.4 MPa. Furthermore, increasing the percentage of cement replacement led to enhanced flowability, as evidenced by an increase in slump flow diameter and a reduction in V-funnel flow time, indicating improved workability. Overall, the findings suggest that controlled incorporation of WMS can produce SCC with desirable mechanical and rheological properties, offering a promising pathway for sustainable concrete production. In addition to the technical performance, a carbon footprint analysis was conducted to examine the environmental benefits of marble sludge utilization. The mixture with 10% cement and 20% sand replacement exhibited the lowest carbon footprint, while the 7.5% replacement level provided the best balance between strength and sustainability. Full article

This study evaluates the physical, mechanical, durability, and environmental properties of geopolymer mortars (GMs) produced using waste tire steel fibers (WTSFs), hemp fibers (HFs), waste marble powder (WMP), and recycled fine aggregates (RFAs). Within the scope of this study, fibers were incorporated as single and hybrid types at 0.5% and 1% by volume. The addition of HFs generally reduced dry unit weight, as well as compressive and flexural strength but increased fracture energy by nearly three times. The addition of WTSFs improved compressive and flexural strengths by up to 42% and enhanced fracture energy by 840%. Hybrid fibers increased the strength values by 21% and the fracture energy by up to four times, demonstrating a clear synergistic effect between HFs and WTSFs in enhancing crack resistance and structural stability. In the durability tests conducted within the scope of this study, HFs burnt at 600 °C, while WTSFs showed signs of corrosion under freeze–thaw and acid conditions; however, hybrid fibers combined the benefits of both materials, resulting in an effective preservation of internal structure. The fact that the materials used in the production of GM samples were waste or recycled products reduced the total cost to 188 USD/m³, and thanks to these materials and the carbon-negative properties of HFs, CO₂ emissions were reduced to 338 kg CO₂/m³. The presented study demonstrates the potential of using recycled and waste materials to create sustainable building materials in the construction industry. Full article

This research investigates the feasibility of producing eco-friendly self-compacting concrete (SCC) by partially replacing both fine and coarse natural aggregates with waste marble sludge (WMS), a byproduct of the marble industry. The objective is to evaluate whether this substitution enhances or compromises the concrete’s performance while contributing to sustainability. A comprehensive experimental program was conducted to assess fresh and hardened properties of SCC with varying WMS content. Fresh-state tests—including slump flow, T₅₀ time, and V-funnel flow time—were used to evaluate workability, flowability, and viscosity. Hardened properties were measured through compressive, flexural, and Brazilian tensile strengths, along with water absorption after 28 days of curing. The mix with 10% replacement of both sand and coarse aggregate showed the most balanced performance, achieving a slump flow of 690 mm and a V-funnel time of 6 s, alongside enhanced mechanical properties—compressive strength 48.6 MPa, tensile strength 3.9 MPa, and flexural strength 4.5 MPa—and reduced water absorption (4.9%). A complementary cost model quantified direct material cost per cubic meter and a performance-normalized efficiency metric (compressive strength per cost). The cost decreased monotonically from 99.1 $/m³ for the base mix to $90.7 $/m³ at 20% + 20% WMS (−8.4% overall), while the strength-per-cost peaked at the 10% + 10% mix (0.51 MPa/USD; +12% vs. base). Results demonstrate that WMS can simultaneously improve rheology and mechanical performance and reduce material cost, offering a practical pathway for resource conservation and circular economy concrete production. Full article

This study systematically investigates the utilization of marble industry waste—waste marble powder (WMP) as partial cement replacement and waste marble aggregates (WMA) as partial fine aggregate replacement—in self-compacting concrete (SCC). A detailed experimental program evaluated the effects of various replacement levels (5%, 10%, and 20% for WMP; 20%, 30%, and 40% for WMA) on compressive strength and durability, particularly resistance to aggressive sulfuric acid environments. Results indicated that a 5% WMP replacement increased compressive strength by 4.9%, attributed primarily to the filler effect, whereas higher levels (10–20%) led to strength reductions due to limited pozzolanic activity and cement dilution. In contrast, WMA replacement consistently enhanced strength (maximum increase of 11.5% at 30% substitution) due to improved particle packing and aggregate-paste interface densification. Durability tests revealed significantly reduced compressive strength losses and mass loss in marble-containing mixtures compared to control samples, with optimal acid resistance observed at 20% WMP and 40% WMA replacements. A comprehensive life cycle assessment demonstrated notable reductions in environmental impacts, including up to 20% decreases in Global Warming Potential (GWP) at 20% WMP replacement. A desirability-based eco-cost-mechanical optimization—simultaneously integrating mechanical strength, environmental indicators, and production cost—identified the 10% WMP substitution mix as the most sustainable option, achieving optimal balance among key performance criteria. These findings underscore the significant potential for marble waste reuse in SCC, promoting environmental sustainability, resource efficiency, and improved concrete durability in chemically aggressive environments. Full article

Given the relevance of sustainability, this study analyzed the impacts on water consumption in the production chain of ornamental stone pieces (marble and granite) and quartz-based composites. The goal was to compare the water demand throughout the process, from extraction to manufacturing, using 1 m³ blocks as the unit of analysis. This study was conducted in Bahia, a state with significant ornamental stone production, located in a semi-arid region with limited water availability. The methodology included data collection from participating companies, combined with sectorial information and the Ecoinvent version 3.3 database, modeled using the SimaPro 8.0 software. The impact assessment was carried out using the AWaRE (Water Scarcity Footprint) and ReCiPe Endpoint methods, following the guidelines of Life Cycle Assessment (LCA), as per ABNT NBR ISO 14040 standards. The results showed that marble and granite have lower water demand and environmental impact in the categories of particulate matter, human toxicity, ecotoxicity, eutrophication, and acidification when compared to quartz composites. The highest environmental impact occurred during the processing stage, which requires a large amount of water and generates effluents, losses, and particulate matter. The results indicate that marble and granite demand less water and exhibit lower environmental impacts—across categories like particulate matter, human toxicity, ecotoxicity, eutrophication, and acidification—than quartz composites. Notably, the processing stage incurred the highest environmental burden due to its intensive water use and consequent generation of effluents, losses, and particulate matter. These findings highlight the necessity of efficient water management and the adoption of circular economy principles—including water reuse and waste valorization—to promote long-term sustainability in the ornamental stone industry. Full article