Search Results (46)

First flush is one of the key phenomena in the dynamics of pollutants in urban drainage. It is affected by a number of factors, like the characteristics of urban surfaces and drainage systems, the rainfall patterns, the street sweeping frequency and efficiency, and the gully pot features. This paper discusses how a storm event can maximize pollution mass and concentration in first flush runoff. It turns out that the critical events derive from particular combinations of factors and not necessarily from the maximum values of rainfall depths or intensities. Full article

Cotton fiber consumption is higher than any other natural fiber due to its superior mechanical and physical properties. In the conventional reactive dyeing process, the dye undergoes hydrolysis due to hydrogen bonding and weak Van der Waals forces, yielding poor washing color fastness. Additionally, the post-dyeing wash-off process consumes significant amounts of water, energy, and time in order to remove the unreacted and hydrolyzed dye. Therefore, reactive dyes are predominantly utilized to color cotton fabrics as the covalent bond formed between dye and fiber results in excellent washing fastness for a wide range of colors, and improved ease of use. To support more efficient, economical, and sustainable reactive dyeing, polymers can be used as effective dye transfer inhibitors (DTIs) in the reactive wash-off process. In this study, poly(vinylpyrrolidone) (PVP) homopolymer and poly(vinylpyrrolidone)-co-poly(vinylimidazole) (PVP-co-PVI) were synthesized at different molecular weights. These polymers were then employed as DTIs to evaluate their performance during the wash-off process for dyed cotton fabrics treated with three reactive dyes (Reactive Red 195, Reactive Blue 221, and Reactive Yellow 145). It is noteworthy to mention that the alternative wash-off procedure involved only three stages, in contrast to the series of washing steps necessary in the conventional method. Evaluation of the DTIs was focused on parameters such as color strength, washing fastness, chemical oxygen demand (COD), as well as energy, water, and time consumption. The findings revealed that while the polymer DTIs generated minor differences in dyed fabric colors in comparison to conventional dyeing, they significantly improved washing fastness. The polymer DTIs studied display excellent potential to provide a much more sustainable dyeing process by saving 90% energy, 40% water, and 50% time versus conventional wash-off processing. The wastewater COD values from the polymer-assisted reactive dye wash-off process were higher for all reactive dyes tested than those from conventional processing. While the higher COD values are attributed to the lower water volumes, this finding highlights the need for further studies. In summary, PVP polymers successfully served as DTIs in the reactive dyeing washing-off process, providing massive water-energy-time efficiency improvements and, subsequently, a more sustainable process for cotton fabric dyeing. Full article

For the first time, the AGRUM model consortium—consisting of the agro-economic model RAUMIS, the water balance model mGROWA, the hydrological nutrient transport models DENUZ, WeKu and MEPhos, and the urban emission model MONERIS—was jointly set up throughout Germany (357,000 km²). This provided a nationwide consistent nutrient model to capture the current status of N and P inputs to surface waters from diffuse sources and urban areas. Diffuse nutrient emissions were quantified in high spatial resolution for the input pathways’ groundwater, drainage runoff, and natural interflow (100 m × 100 m), as well as for water erosion and wash-off (25 m × 25 m). The sum of diffuse nutrient inputs to surface waters is about 385,000 metric tons N/yr and ca. 11,530 metric tons P/yr. Urban emissions were quantified either as point source inputs (wastewater treatment plants, industrial direct dischargers) or at municipality scale for different collection and treatment systems, e.g., rainwater sewers or decentralized treatment plants, and sum up to ca. 95,000 t N/yr and 7500 t P/yr. As modelled, total N and P inputs into surface waters correspond well with observed N and P loads in rivers. The model results represent valuable information for water managers, being responsible for the preparation of management plans for the third management cycle of the EC Water Framework Directive spanning from 2021 to 2027. Full article

With the accelerated process of urbanization, air pollution has become increasingly severe. Garden plants can trap atmospheric particulate matter, which is of great significance for improving the urban ecological environment and promoting sustainable development. To investigate the dust retention effect of typical transportation green spaces in Nanjing, this study focuses on thirteen garden plants on Xuanwu Avenue in Nanjing. The dust retention capacity of these plants was determined using the wash-off method, while the microstructure of their leaf surfaces was observed using scanning electron microscopy. The results are as follows: Firstly, per unit leaf area, Liriope spicata, Ophiopogon japonicus, and Viburnum odoratissimum demonstrate solid dust retention abilities. Additionally, Viburnum odoratissimum, Prunus serrulata var. Lannesiana, and Liriope spicata show strong dust retention abilities per single leaf. Moreover, Platanus acerifolia, Viburnum odoratissimum, and Cinnamomum camphora have strong dust retention abilities per plant. Viburnum odoratissimum, Platanus acerifolia, and Prunus serrulata var. Lannesiana exhibit the most substantial dust retention capacities. Secondly, there is a significant negative correlation between dust retention per plant and the potassium content, while a significant positive correlation is observed with plant height, canopy height, and leaf width. Furthermore, there is a highly significant positive correlation between dust retention per unit leaf area and stomatal length and a highly significant negative correlation with leaf length. The surface microstructure of the blade mainly increases the dust retention capacity of the blade by increasing the friction of the leaf surface. Lastly, specific leaf surface microstructures, such as grooved epidermis and trichomes, enhance plants’ dust retention capacity. Consequently, for the future configuration of road green spaces in Nanjing, a mixed planting mode of trees, shrubs, and grass is recommended. Priority should be given to selecting plants with strong overall dust retention capabilities, such as Platanus acerifolia, Viburnum odoratissimum, and Prunus serrulata var. Lannesiana, to alleviate air pollution, improve the urban ecological environment, and achieve sustainable development. Full article

Many design principles for rain gauges that have the capacity to record rainfall intensity have been proposed or developed. These are here grouped into 15 categories, and the abilities and limitations of each are discussed. No standard or optimum method has emerged, despite more than 80 years of effort in the last two centuries, together with prior work from the 17th C onwards. Indeed, new methods continue to be explored for both point-based and area-wide collections of intensity data. Examples include the use of signal attenuation by rain along the tower-to-tower links of cellular phone networks, monitoring the speed of vehicle windscreen wipers, and exploiting the sound or vision from security and traffic-monitoring cameras. Many of these approaches have the potential to provide vastly more observation sites than conventional meteorological stations equipped with rain gauges. Some of these contemporary approaches seek to harness the potential of crowdsourced or citizen-science data. It is hoped that the present overview of methods will provide a guide for those wishing to collect or analyses rainfall intensity data for application in areas such as soil erosion processes, ecohydrology, agrochemical washoff, or urban flash flooding. Because rainfall intensity is one of the key aspects of the hydrologic cycle likely to respond as climate change and variability proceed, the choice of appropriate data collection methods has additional contemporary importance for the monitoring of regional and global precipitation changes. Full article

Biocidal coatings are known to minimize or terminate development of bacterial and fungicidal infections. In this paper, biocidal activity of seven cationic (co)polymers with amino groups—polyethyleneimine, polyallylamine, polydiallyldimethylammonium chloride/polyhexamethylene guanidine copolymer, diallyldimethylammonium chloride/SO₂ copolymer, linear and hyperbranched epichlorohydrin/dimethylamine copolymers, polydiallyldimethylammonium chloride—were tested toward Gram-positive and Gram-negative cells. The polymers showed a significant biocidal effect in both aqueous solution and after formation of polymer films on the hydrophilic glass plates. Polymer films were almost completely removed by water during 10 wash-off cycles, that finally resulted in the ultrathin monolayers with a thickness of several nanometers. A polyethyleneimine film showed the most resistance to water with a 50% loss after three wash-off cycles and 75% loss after six wash-off cycles. Binding and subsequent deactivation of pathogenic microorganisms occurs on the outer surface of cationic polymer films. It is expected that a gradual polymer wash-off will allow renewal of the outer film surface and thereby restore the biocidal properties of the polycationic coatings, including those with a nanoscale thickness. Full article

Positively charged polyelectrolytes hold significant potential as materials for creating antibacterial coatings. We examined the physicochemical and mechanical properties of the macromolecules in water solutions and in coatings for the series of branched polyethyleneimine (PEI) and linear polydiallyldimethylammonium chloride (PDADMAC) with different molecular weights. The microbiological study was conducted to analyze the biocidal activity of the polycation solutions and coatings towards foodborne bacteria. While the moisture saturation of the polycationic coatings and biocidal activity did not significantly depend on the chemical nature of charged groups or the molecular weight or architecture of macromolecules, the lowering of the molecular weight of polymers resulted in the loss of cohesive forces in the coatings and to a dramatic loss of stability when being washed off with water. The diffusion coefficient (D₀) of macromolecules was identified as a key parameter for the wash-off mechanism. Films formed by molecules with a D₀ below 1 × 10⁻⁷ cm²/s demonstrated a high resistance to wash-off procedures. We demonstrated that PEI and PDADMAC samples with high molecular weights showed high antimicrobial activity towards L. monocytogenes. Our results highlight the importance of macromolecule characteristics in the development of new biocidal coatings based on polycations. Full article

Biocidal compositions based on interpolyelectrolyte complexes and a low molecular weight antibiotic can become a promising material for creating biocidal coatings, as they combine wash-off resistance and dual biocidal action due to the biocide and the polycation. Molecular mass characteristics of polymers play an essential role in the physics and mechanical properties of the coatings. In this work, the properties of polydiallyldimethylammonium chloride (PDADMAC) coatings of various molecular weights are investigated and assumptions are made about the optimal molecular weight needed to create antibacterial compositions. To study the resistance to washing off and moisture saturation of the coatings, the gravimetric method was used, and the adhesive properties of the coatings were studied by dynamometry. It has been established that an increase in molecular weight affects the wash-off resistance of coatings, but does not affect moisture absorption and adhesion mechanics of coatings. All samples of PDADMAC were demonstrated to exhibit the same antibacterial activity. Thus, when developing systems for creating antibacterial coatings, it must be taken into account that in order to create stable coatings, the requirement to use PDADMAC with a high degree of polymerization is necessary for the coating desorption control during wash off-but not mandatory for the control of mechanical and antibacterial properties of the coating. Full article

Dynamic particulate matter (PM) behavior on leaves depends on rainfall events, leaf structural and physical properties, and individual tree crowns in urban forests. To address this dependency, we compared the observed relationships between PM wash-off ability and leaf traits on inner and outer crown-positioned leaves during rainfall events. Data showed significant differences in the PM wash-off ability between inner and outer crown-positioned leaves relative to rainfall events due to leaf macro- and micro-structure and geometric properties among tree species. Our results showed that PM wash-off effects on leaf surfaces were negatively associated with trichome density and size of leaf micro-scale during rainfall events. Specifically, Quercus acutissima with dense trichomes and micro-level surface roughness with narrow grooves on leaf surfaces showed lower total PM wash-off in both inner (−38%) and outer (105%) crowns during rainfall. Thus, their rough leaves in the inner crown might newly capture and/or retain more PM than smooth leaves even under rainfall conditions. More importantly, Euonymus japonicus, with a thin film-like wax coverage without trichome, led to higher total PM wash-off in both inner (368%) and outer (629%) crowns during rainfall. Furthermore, we studied the changes in PM wash-off during rainfall events by comparing particle size fractions, revealing a very significant association with macro-scale, micro-scale, and geometric features. Full article

Tagatose is a rare sugar that suppresses plant diseases, such as late blight of tomato, caused by Phytophthora infestans. Tagatose can be metabolized by some microorganisms and no information is available on its persistence on tomato leaves. The aim of this study was to assess the persistence of tagatose on tomato leaves under commercial greenhouse conditions. The amount of tagatose on tomato leaves and the inhibitory activity against P. infestans decreased seven days after spray application in the absence of rain wash-off. Potential tagatose-degrading bacteria were isolated from tomato leaves, and they belonged to Acinetobacter sp., Bacillus sp., Comamonas sp., Enterobacter sp., Methylobacterium sp., Microbacterium sp., Pantoea sp., Plantibacter sp., Pseudomonas sp., Ralstonia sp., Rhodococcus sp., Sphingobium sp., and Sphingomonas sp. Thus, indigenous phyllosphere microorganisms could partially metabolize tagatose laid on plant leaves after spray application, reducing the persistence of this fungal inhibitor on tomato leaves. Full article

The objective of this work was to determine the optimal conditions for the electrooxidation treatment in order to decolourise the effluents that contain reactive dyes. According to the results, when Na₂SO₄ is used as an electrolyte, the decolouration reactions follow first-order kinetics. However, when NaCl is present in the effluent, the first-order kinetics is stabilised after applying a minimal electric current value. The models obtained from the results show that the higher the concentration of NaCl, the lower the energy consumption. On the other hand, an increase in dye concentration leads to an increase in electrical consumption. In relation to the pH, the results show that it is not a key factor in the decolouration efficiency. Finally, the obtained model was applied to two real effluents. The feasibility of individually treating the effluents from the dyeing process and those from the subsequent wash-off process was evaluated. From an industrial application point of view, it is recommended to mix both effluents before treatment, especially when the dye concentration is high. Full article

In the wake of Chernobyl and Fukushima accidents, radiocesium has become a radionuclide of most environmental concern. The ease with which this radionuclide moves through the environment and is taken up by plants and animals is governed by its chemical forms and site-specific environmental characteristics. Distinctions in climate and geomorphology, as well as ¹³⁷Cs speciation in the fallout, result in differences in the migration rates of ¹³⁷Cs in the environment and rates of its natural attenuation. In Fukushima areas, ¹³⁷Cs was strongly bound to soil and sediment particles, with its bioavailability being reduced as a result. Up to 80% of the deposited ¹³⁷Cs on the soil was reported to be incorporated in hot glassy particles (CsMPs) insoluble in water. Disintegration of these particles in the environment is much slower than that of Chernobyl-derived fuel particles. The higher annual precipitation and steep slopes in Fukushima-contaminated areas are conducive to higher erosion and higher total radiocesium wash-off. Among the common features in the ¹³⁷Cs behavior in Chernobyl and Fukushima are a slow decrease in the ¹³⁷Cs activity concentration in small, closed, and semi-closed lakes and its particular seasonal variations: increase in the summer and decrease in the winter. Full article

Based on the different particle sizes of street dust, the potential pollution load of heavy metals from dry and wet atmospheric deposition to surface runoff in different functional areas of Zhengzhou city was estimated by using the rain-scour heavy metal index model. Compared to the EA, IA, and CA areas, RA and PA have a higher potential contribution to heavy metal runoff pollution from Road deposited sediments (RDS) than the other watersheds. Zhengzhou utilized the RDS index model to calculate pollution loads in various areas around Zhengzhou (EA, IA, CA, PA, and RA). In the different land-use areas, the RDS indices for pollutant load (RDS_index,load) and pollutant strength (RDS_{index,strength}) varied greatly, and the RDS _{index strength} values increased. RDS_index,load fell in the following order: IA > RA > PA > EA. Because the RDS index incorporates RDS characteristics such as the amount of RDS, grain sizes present, RDS mobility, and associated metals, the RDS_index,load and RDS_{index,strength} results did not merely match variability in the amounts of RDS found or metal concentrations in the RDS in various land-use areas. Metal’s presence in the dust is a direct health risk for humans and warrants immediate and effective pollution control and prevention measures in the city. Full article

Polymer coatings based on polycations represent a perspective class of protective antimicrobial coatings. Polydiallyldimethylammonium chloride (PDADMAC) and its water-soluble complexes with sodium polystyrenesulfonate (PSS) were studied by means of dynamic light-scattering, laser microelectrophoresis and turbidimetry. It was shown that addition of six mol.% of polyanion to polycation results in formation of interpolyelectrolyte complex (IPEC) that was stable towards phase separation in water-salt media with a concentration of salts (NaCl, CaCl₂, Na₂SO₄, MgSO₄) up to 0.5 M. Most of the polyelectrolyte coatings are made by layer-by-layer deposition. The utilization of water-soluble IPEC for the direct deposition on the surface was studied. The coatings from the PDADMAC and the PSS/PDADMAC complex were formed on the surfaces of hydrophilic glass and hydrophobic polyvinylchloride. It was found that formation IPEC allows one to increase the stability of the coating towards wash-off with water in comparison to individual PDADMAC coating on both types of substrates. The visualization of the coatings was performed by atomic force microscopy and scanning electron microscopy. Full article

Stormwater runoff from metal roofs has been a significant subject of discussion, especially when it comes to its treatment and the target concentrations that need to be achieved prior to discharge into the aquatic environment. To raise further awareness on this issue, occurrence, characterization, and also mitigation measures for metal roof runoff were analyzed using the example of copper and zinc roofs. These stormwater runoffs were found to contain metals in significant concentrations, mainly due to the wash-off of corrosion products by precipitation. Factors influencing metal corrosion and runoff concentrations were compiled. As Cu and Zn mainly occur in dissolved and thus bioavailable forms in roof runoff, harmful effects on the environment were detected. Therefore, adequate treatment of the runoff before discharge to groundwater or surface water is necessary to protect the aquatic environment. Vegetated infiltration swales as an sustainable urban drainage system enable a reduction in pollution loads. However, especially in densely built-up urban areas, stormwater quality improvement devices (SQIDs) offer an attractive alternative for pre-treating metal roof runoff, as they are mostly located underground. There is not yet a uniform legal approval system for SQIDs in Germany, but the German state of Bavaria has approved four types of SQIDs according to its own developed test criteria. Full article