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Keywords = volcanic geothermal monitoring

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25 pages, 6368 KiB  
Article
Development of a Thermal Infrared Network for Volcanic and Environmental Monitoring: Hardware Design and Data Analysis Software Code
by Fabio Sansivero, Giuseppe Vilardo and Ciro Buonocunto
Sensors 2025, 25(13), 4141; https://doi.org/10.3390/s25134141 - 2 Jul 2025
Viewed by 298
Abstract
Thermal infrared (TIR) ground observations are a well-established method for investigating surface temperature variations in thermally anomalous areas. However, commercially available technical solutions are currently limited, often offering proprietary products with minimal customization options for establishing a permanent TIR monitoring network. This work [...] Read more.
Thermal infrared (TIR) ground observations are a well-established method for investigating surface temperature variations in thermally anomalous areas. However, commercially available technical solutions are currently limited, often offering proprietary products with minimal customization options for establishing a permanent TIR monitoring network. This work presents the comprehensive development of a thermal infrared monitoring network, detailing everything from the hardware schematics of the remote monitoring station (RMS) to the code for the final data processing software. The procedures implemented in the RMS for managing TIR sensor operations, acquiring environmental data, and transmitting data remotely are thoroughly discussed, along with the technical solutions adopted. The processing of TIR imagery is carried out using ASIRA (Automated System of InfraRed Analysis), a free software package, now developed for GNU Octave. ASIRA performs quality filtering and co-registration, and applies various seasonal correction methodologies to extract time series of deseasoned surface temperatures, estimate heat fluxes, and track variations in thermally anomalous areas. Processed outputs include binary, Excel, and CSV formats, with interactive HTML plots for visualization. The system’s effectiveness has been validated in active volcanic areas of southern Italy, demonstrating high reliability in detecting anomalous thermal behavior and distinguishing endogenous geophysical processes. The aim of this work is to enable readers to easily replicate and deploy this open-source, low-cost system for the continuous, automated thermal monitoring of active volcanic and geothermal areas and environmental pollution, thereby supporting hazard assessment and scientific research. Full article
(This article belongs to the Special Issue Recent Advances in Infrared Thermography and Sensing Technologies)
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16 pages, 12646 KiB  
Article
Application of Time Series INSAR (SBAS) Method Using Sentinel-1 for Monitoring Ground Deformation of the Aegina Island (Western Edge of Hellenic Volcanic Arc)
by Ioanna-Efstathia Kalavrezou, Ignacio Castro-Melgar, Dimitra Nika, Theodoros Gatsios, Spyros Lalechos and Issaak Parcharidis
Land 2024, 13(4), 485; https://doi.org/10.3390/land13040485 - 9 Apr 2024
Cited by 16 | Viewed by 3890
Abstract
This study employs advanced synthetic aperture radar (SAR) techniques, specifically the small baseline subset (SBAS) method, to analyze ground deformation dynamics on Aegina, a volcanic island within the Hellenic Volcanic Arc. Using Sentinel-1 satellite data spanning January 2016 to May 2023, this research [...] Read more.
This study employs advanced synthetic aperture radar (SAR) techniques, specifically the small baseline subset (SBAS) method, to analyze ground deformation dynamics on Aegina, a volcanic island within the Hellenic Volcanic Arc. Using Sentinel-1 satellite data spanning January 2016 to May 2023, this research reveals different deformation behaviors. The towns of Aegina and Saint Marina portray regions of stability, contrasting with central areas exhibiting subsidence rates of up to 1 cm/year. The absence of deformation consistent with volcanic activity on Aegina Island aligns with geological records and limited seismic activity, attributing the observed subsidence processes to settlement phenomena from past volcanic events and regional geothermal activity. These findings reinforce the need for continuous monitoring of the volcanic islands located in the Hellenic Volcanic Arc, providing important insights for local risk management, and contributing to our broader understanding of geodynamic and volcanic processes. Full article
(This article belongs to the Special Issue Ground Deformation Monitoring via Remote Sensing Time Series Data)
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15 pages, 14866 KiB  
Technical Note
Estimation of the Uncertainties Introduced in Thermal Map Mosaic: A Case of Study with PIX4D Mapper Software
by Teresa Caputo, Eliana Bellucci Sessa, Enrica Marotta, Antonio Caputo, Pasquale Belviso, Gala Avvisati, Rosario Peluso and Antonio Carandente
Remote Sens. 2023, 15(18), 4385; https://doi.org/10.3390/rs15184385 - 6 Sep 2023
Cited by 6 | Viewed by 1931
Abstract
The aim of this study is to analyse problems related to thermal mapping obtained from thermal data acquired from unmanned aerial systems (UAS) equipped with thermal cameras. We focused on an accurate analysis of uncertainties introduced by the PIX4D Mapper software version 4.4.12 [...] Read more.
The aim of this study is to analyse problems related to thermal mapping obtained from thermal data acquired from unmanned aerial systems (UAS) equipped with thermal cameras. We focused on an accurate analysis of uncertainties introduced by the PIX4D Mapper software version 4.4.12 used to obtain the surface temperature maps of thermal images acquired using the UAS. To achieve this aim, we used artificial thermal references during the surveys, as well as natural hot targets, i.e., thermal anomalies in the Pisciarelli hydrothermal system in Campi Flegrei caldera (CFc). Artificial thermal targets, expressly created and designed for this goal, are a prototype here called “developed thermal target” (DTT) created by the drone laboratory at Istituto Nazionale di Geofisica e Vulcanologia—Osservatorio Vesuviano (INGV-OV). We show the results obtained through three surveys, and during the last two, thermal targets were positioned on land at different flight heights of the UAS. Different heights were also necessary to test the spatial resolution of the DTT with the used thermal camera as well as possible temperature differences between the raw images acquired via UAS with the thermal mapping obtained from the PIX4D Mapper software. In this work, we estimate the uncertainty that may be introduced by the mosaic procedure, and furthermore we find an attenuation of the measured temperatures introduced by the different distances between the thermal anomaly and sensor. These results appear to be of great importance for the subsequent calibration phase of the thermal maps, especially in cases where these methodologies are applied for the purposes of monitoring volcanic/geothermal areas. Full article
(This article belongs to the Special Issue Remote Sensing of Geothermal and Volcanic Environments)
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17 pages, 11046 KiB  
Article
Geothermal Explosion at the 2014 Landslide-Covered Area of the Geyser Valley, Kamchatka, Russian Far East
by Masoud Allahbakhshi, Alina V. Shevchenko, Alexander B. Belousov, Marina G. Belousova, Horst Kämpf and Thomas R. Walter
GeoHazards 2023, 4(1), 60-76; https://doi.org/10.3390/geohazards4010005 - 10 Mar 2023
Cited by 2 | Viewed by 3101
Abstract
Geyser geothermal fields are scenic volcanic landforms that often contain tens to hundreds of thermal spot vents that erupt boiling water or contain bubbling mud pools. The fields are potentially hazardous sites due to boiling water temperatures and changes in vent locations and [...] Read more.
Geyser geothermal fields are scenic volcanic landforms that often contain tens to hundreds of thermal spot vents that erupt boiling water or contain bubbling mud pools. The fields are potentially hazardous sites due to boiling water temperatures and changes in vent locations and eruption dynamics, which are poorly understood. Here we report on the rapid and profound changes that can affect such a geyser field and ultimately lead to a dangerous, unanticipated eruption. We studied the Geyser Valley, Kamchatka Peninsula, which is a field of geysers and other thermal features and boiling pools. Using high-resolution tri-stereo satellite data and unmanned aerial systems (UAS) with optical and thermal infrared cameras in 2018 and 2019, we were able to identify a newly emerging explosion site. Structure-from-motion analysis of data acquired before and after the explosion reveals morphological and thermal details of the new vent. The explosion site produced an aureole zone of more than 150 m3 of explosively redeposited gravel and clay, a slightly elliptical crater with a diameter of 7.5 m and a crater rim 0.30 m high. However, comparison with archives of photogrammetric data suggests that this site was thermally active years earlier and contained a crater that was obscured and covered by landslides and river sediments. The results allow us to develop a conceptual model and highlight the hazard potential of thermal features buried by landslides and clastic deposits. Sudden explosions may occur at similar sites elsewhere, highlighting the need for careful assessment and monitoring of geomorphological and hydrological changes at geyser sites in other regions. Full article
(This article belongs to the Collection Geohazard Characterization, Modeling, and Risk Assessment)
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16 pages, 5195 KiB  
Article
Detection of Geothermal Anomalies in Hydrothermal Systems Using ASTER Data: The Caldeiras da Ribeira Grande Case Study (Azores, Portugal)
by Jéssica Uchôa, Fátima Viveiros, Rafaela Tiengo and Artur Gil
Sensors 2023, 23(4), 2258; https://doi.org/10.3390/s23042258 - 17 Feb 2023
Cited by 6 | Viewed by 3885
Abstract
Current-day volcanic activity in the Azores archipelago is characterized by seismic events and secondary manifestations of volcanism. Remote sensing techniques have been widely employed to monitor deformation in volcanic systems, map lava flows, or detect high-temperature gas emissions. However, using satellite imagery, it [...] Read more.
Current-day volcanic activity in the Azores archipelago is characterized by seismic events and secondary manifestations of volcanism. Remote sensing techniques have been widely employed to monitor deformation in volcanic systems, map lava flows, or detect high-temperature gas emissions. However, using satellite imagery, it is still challenging to identify low-magnitude thermal changes in a volcanic system. In 2010, after drilling a well for geothermal exploration on the northern flank of Fogo Volcano on São Miguel Island, a new degassing and thermal area emerged with maximum temperatures of 100 °C. In the present paper, using the ASTER sensor, we observed changes in the near-infrared signals (15 m spatial resolution) six months after the anomaly emerged. In contrast, the thermal signal (90 m spatial resolution) only changed its threshold value one and a half years after the anomaly was recognized. The results show that wavelength and spatial resolution can influence the response time in detecting changes in a system. This paper reiterates the importance of using thermal imaging and high spatial resolution images to monitor and map thermal anomalies in hydrothermal systems such as those found in the Azores. Full article
(This article belongs to the Special Issue Satellite Remote Sensing for Volcanic Applications)
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8 pages, 718 KiB  
Communication
Cyanidiophyceae (Rhodophyta) Tolerance to Precious Metals: Metabolic Response to Palladium and Gold
by Maria Sirakov, Maria Palmieri, Manuela Iovinella, Seth J. Davis, Milena Petriccione, Maria Rosa di Cicco, Mario De Stefano and Claudia Ciniglia
Plants 2021, 10(11), 2367; https://doi.org/10.3390/plants10112367 - 3 Nov 2021
Cited by 15 | Viewed by 2522
Abstract
Polyextremophilic red algae, which belong to the class Cyanidiophyceae, are adapted to live in geothermal and volcanic sites. These sites often have very high concentrations of heavy and precious metals. In this study, we assessed the capacity of three strains of Galdieria [...] Read more.
Polyextremophilic red algae, which belong to the class Cyanidiophyceae, are adapted to live in geothermal and volcanic sites. These sites often have very high concentrations of heavy and precious metals. In this study, we assessed the capacity of three strains of Galdieria (G. maxima, G. sulphuraria, and G. phlegrea) and one strain of Cyanidiumcaldarium to tolerate different concentrations of precious metals, such as palladium (Cl4K2Pd) and gold (AuCl4K) by monitoring algal growths in cultures exposed to metals, and we investigated the algae potential oxidative stress induced by the metals. This work provides further understanding of metals responses in the Cyanidiophyceae, as this taxonomic class is developed as a biological refinement tool. Full article
(This article belongs to the Special Issue Cyanobacteria, Algae, and Plants; from Biology to Biotechnology)
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37 pages, 6490 KiB  
Article
Hydrothermal Alteration at the San Vito Area of the Campi Flegrei Geothermal System in Italy: Mineral Review and Geochemical Modeling
by Monica Piochi, Barbara Cantucci, Giordano Montegrossi and Gilda Currenti
Minerals 2021, 11(8), 810; https://doi.org/10.3390/min11080810 - 27 Jul 2021
Cited by 11 | Viewed by 4360
Abstract
The Campi Flegrei geothermal system sets in one of the most famous and hazardous volcanic caldera in the world. The geothermal dynamics is suspected to have a crucial role in the monitored unrest phases and in the eruption triggering as well. Numerical models [...] Read more.
The Campi Flegrei geothermal system sets in one of the most famous and hazardous volcanic caldera in the world. The geothermal dynamics is suspected to have a crucial role in the monitored unrest phases and in the eruption triggering as well. Numerical models in the literature do not properly consider the geochemical effects of fluid-rock interaction into the hydrothermal circulation and this gap limits the wholly understanding of the dynamics. This paper focuses on fluid-rock interaction effects at the Campi Flegrei and presents relevant information requested for reactive transport simulations. In particular, we provide: (1) an extensive review of available data and new petrographic analyses of the San Vito cores rearranged in a conceptual model useful to define representative geochemical and petrophysical parameters of rock formations suitable for numerical simulations and (2) the implemented thermodynamic and kinetic data set calibrated for the San Vito 1 well area, central in the geothermal reservoir. A preliminary 0D-geochemical model, performed with a different contribution of CO2 at high (165 °C) and low (85 °C) temperatures, firstly allows reproducing the hydrothermal reactions over time of the Campanian Ignimbrite formation, the most important deposits in the case study area. Full article
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11 pages, 5413 KiB  
Article
Thermal Monitoring of the Lithosphere by the Interaction of Deep Low-Frequency and Ordinary High-Frequency Earthquakes in Northeastern Japan
by Yota Suzuki, Hirofumi Muraoka and Hiroshi Asanuma
Energies 2021, 14(6), 1546; https://doi.org/10.3390/en14061546 - 11 Mar 2021
Cited by 4 | Viewed by 2039
Abstract
Deep low-frequency earthquakes (LFEs) are known to occur in dehydration phenomena from the subducting hydrous slab and in magmatic phenomena beneath Quaternary volcanoes in Japan. To realize the spatial and temporal characteristics of the magmatic deep low-frequency earthquakes, their hypocenters along with those [...] Read more.
Deep low-frequency earthquakes (LFEs) are known to occur in dehydration phenomena from the subducting hydrous slab and in magmatic phenomena beneath Quaternary volcanoes in Japan. To realize the spatial and temporal characteristics of the magmatic deep low-frequency earthquakes, their hypocenters along with those of ordinary overhead high-frequency earthquakes are analyzed beneath six volcanic fields in northeastern Japan. This trial clarifies the rising basaltic magma conduits and rheological profiles of the lithosphere. Deep low-frequency earthquakes tend to form three vertical clusters corresponding to the rheological strength peak of the peridotite upper mantle, gabbroic lower crust, and granitic upper crust. Interactive aseismic gaps between low- and high-frequency earthquakes reveal the brittle–plastic transition as an isothermal indicator in the lithosphere. This relationship provides a tool to monitor the thermal evolution of the lithosphere and to explore sustainable geothermal resources with basaltic magma replenishment systems. Full article
(This article belongs to the Section H: Geo-Energy)
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23 pages, 11845 KiB  
Article
Copernicus Sentinel-1 MT-InSAR, GNSS and Seismic Monitoring of Deformation Patterns and Trends at the Methana Volcano, Greece
by Theodoros Gatsios, Francesca Cigna, Deodato Tapete, Vassilis Sakkas, Kyriaki Pavlou and Issaak Parcharidis
Appl. Sci. 2020, 10(18), 6445; https://doi.org/10.3390/app10186445 - 16 Sep 2020
Cited by 24 | Viewed by 4990
Abstract
The Methana volcano in Greece belongs to the western part of the Hellenic Volcanic Arc, where the African and Eurasian tectonic plates converge at a rate of approximately 3 cm/year. While volcanic hazard in Methana is considered low, the neotectonic basin constituting the [...] Read more.
The Methana volcano in Greece belongs to the western part of the Hellenic Volcanic Arc, where the African and Eurasian tectonic plates converge at a rate of approximately 3 cm/year. While volcanic hazard in Methana is considered low, the neotectonic basin constituting the Saronic Gulf area is seismically active and there is evidence of local geothermal activity. Monitoring is therefore crucial to characterize any activity at the volcano that could impact the local population. This study aims to detect surface deformation in the whole Methana peninsula based on a long stack of 99 Sentinel-1 C-band Synthetic Aperture Radar (SAR) images in interferometric wide swath mode acquired in March 2015–August 2019. A Multi-Temporal Interferometric SAR (MT-InSAR) processing approach is exploited using the Interferometric Point Target Analysis (IPTA) method, involving the extraction of a network of targets including both Persistent Scatterers (PS) and Distributed Scatterers (DS) to augment the monitoring capability across the varied land cover of the peninsula. Satellite geodetic data from 2006–2019 Global Positioning System (GPS) benchmark surveying are used to calibrate and validate the MT-InSAR results. Deformation monitoring records from permanent Global Navigation Satellite System (GNSS) stations, two of which were installed within the peninsula in 2004 (METH) and 2019 (MTNA), are also exploited for interpretation of the regional deformation scenario. Geological, topographic, and 2006–2019 seismological data enable better understanding of the ground deformation observed. Line-of-sight displacement velocities of the over 4700 PS and 6200 DS within the peninsula are from −18.1 to +7.5 mm/year. The MT-InSAR data suggest a complex displacement pattern across the volcano edifice, including local-scale land surface processes. In Methana town, ground stability is found on volcanoclasts and limestone for the majority of the urban area footprint while some deformation is observed in the suburban zones. At the Mavri Petra andesitic dome, time series of the exceptionally dense PS/DS network across blocks of agglomerate and cinder reveal seasonal fluctuation (5 mm amplitude) overlapping the long-term stable trend. Given the steepness of the slopes along the eastern flank of the volcano, displacement patterns may indicate mass movements. The GNSS, seismological and MT-InSAR analyses lead to a first account of deformation processes and their temporal evolution over the last years for Methana, thus providing initial information to feed into the volcano baseline hazard assessment and monitoring system. Full article
(This article belongs to the Special Issue Data Processing and Modeling on Volcanic and Seismic Areas)
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26 pages, 11875 KiB  
Article
Monitoring Thermal Activity of the Beppu Geothermal Area in Japan Using Multisource Satellite Thermal Infrared Data
by Md. Bodruddoza Mia, Yasuhiro Fujimitsu and Jun Nishijima
Geosciences 2018, 8(8), 306; https://doi.org/10.3390/geosciences8080306 - 17 Aug 2018
Cited by 8 | Viewed by 5496
Abstract
The Beppu geothermal area, one of the largest spa resorts on the northeast Kyushu Island of Japan, is fed by hydrothermal fluids beneath the volcanic center of Mt. Garan and Mt. Tsurumi in the west. We explored the thermal status of the Beppu [...] Read more.
The Beppu geothermal area, one of the largest spa resorts on the northeast Kyushu Island of Japan, is fed by hydrothermal fluids beneath the volcanic center of Mt. Garan and Mt. Tsurumi in the west. We explored the thermal status of the Beppu geothermal area using nighttime multisource satellite thermal infrared data (TIR) from the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) and Landsat 8 thermal infrared scanner (TIRS) to monitor heat loss from 2009 to 2017. We also assessed heat loss from Mt. Garan fumaroles to investigate a relationship between them. The normalized differential vegetation index (NDVI) threshold method of spectral emissivity, the split-window algorithm for land surface temperature (LST), and the Stefan–Boltzmann equation for radiative heat flux (RHF) were used to estimate heat loss in this study. Total heat loss increased by about a 35% trend overall from 2009 to 2015 and then declined about 33–42% in 2017 in both the Beppu geothermal area and Mt. Garan fumaroles overall. The higher thermal anomalies were found in 2015 mostly in the southeastern coastal area of the Beppu geothermal region. The highest thermal anomaly was obtained in 2011 and the lowest in 2017 within the Mt. Garan fumaroles. The areas with a higher range of RHF values were recorded in 2015 in both study areas. Finally, the results show similar patterns of heat loss and thermal anomalies in both the Beppu geothermal area and Mt. Garan fumaroles, indicating a closely connected geothermal system overall. This suggests that nighttime TIR data are effective for monitoring the thermal status of the Beppu geothermal area. Full article
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17 pages, 6608 KiB  
Article
Preliminary Study of UAS Equipped with Thermal Camera for Volcanic Geothermal Monitoring in Taiwan
by Shih-Hong Chio and Cheng-Horng Lin
Sensors 2017, 17(7), 1649; https://doi.org/10.3390/s17071649 - 18 Jul 2017
Cited by 23 | Viewed by 6508
Abstract
Thermal infrared cameras sense the temperature information of sensed scenes. With the development of UASs (Unmanned Aircraft Systems), thermal infrared cameras can now be carried on a quadcopter UAV (Unmanned Aircraft Vehicle) to appropriately collect high-resolution thermal images for volcanic geothermal monitoring in [...] Read more.
Thermal infrared cameras sense the temperature information of sensed scenes. With the development of UASs (Unmanned Aircraft Systems), thermal infrared cameras can now be carried on a quadcopter UAV (Unmanned Aircraft Vehicle) to appropriately collect high-resolution thermal images for volcanic geothermal monitoring in a local area. Therefore, the quadcopter UAS used to acquire thermal images for volcanic geothermal monitoring has been developed in Taiwan as part of this study to overcome the difficult terrain with highly variable topography and extreme environmental conditions. An XM6 thermal infrared camera was employed in this thermal image collection system. The Trimble BD970 GNSS (Global Navigation Satellite System) OEM (Original Equipment Manufacturer) board was also carried on the quadcopter UAV to gather dual-frequency GNSS observations in order to determine the flying trajectory data by using the Post-Processed Kinematic (PPK) technique; this will be used to establish the position and orientation of collected thermal images with less ground control points (GCPs). The digital surface model (DSM) and thermal orthoimages were then produced from collected thermal images. Tests conducted in the Hsiaoyukeng area of Taiwan’s Yangmingshan National Park show that the difference between produced DSM and airborne LIDAR (Light Detection and Ranging) data are about 37% between −1 m and 1 m, and 66% between −2 m and 2 m in the area surrounded by GCPs. As the accuracy of thermal orthoimages is about 1.78 m, it is deemed sufficient for volcanic geothermal monitoring. In addition, the thermal orthoimages show some phenomena not only more globally than do the traditional methods for volcanic geothermal monitoring, but they also show that the developed system can be further employed in Taiwan in the future. Full article
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26 pages, 13912 KiB  
Article
Investigation of Potential Volcanic Risk from Mt. Baekdu by DInSAR Time Series Analysis and Atmospheric Correction
by Jung-Rack Kim, Shih-Yuan Lin, Hye-Won Yun, Ya-Lun Tsai, Hwa-Jung Seo, Sungwook Hong and YunSoo Choi
Remote Sens. 2017, 9(2), 138; https://doi.org/10.3390/rs9020138 - 7 Feb 2017
Cited by 23 | Viewed by 8664
Abstract
Mt. Baekdu is a volcano near the North Korea-Chinese border that experienced a few destructive eruptions over the course of its history, including the well-known 1702 A.D eruption. However, signals of unrest, including seismic activity, gas emission and intense geothermal activity, have been [...] Read more.
Mt. Baekdu is a volcano near the North Korea-Chinese border that experienced a few destructive eruptions over the course of its history, including the well-known 1702 A.D eruption. However, signals of unrest, including seismic activity, gas emission and intense geothermal activity, have been occurring with increasing frequency over the last few years. Due to its close vicinity to a densely populated area and the high magnitude of historical volcanic eruptions, its potential for destructive volcanic activity has drawn wide public attention. However, direct field surveying in the area is limited due to logistic challenges. In order to compensate for the limited coverage of ground observations, comprehensive measurements using remote sensing techniques are required. Among these techniques, Differential Interferometric SAR (DInSAR) analysis is the most effective method for monitoring surface deformation and is employed in this study. Through advanced atmospheric error correction and time series analysis, the accuracy of the detected displacements was improved. As a result, clear uplift up to 20 mm/year was identified around Mt. Baekdu and was further used to estimate the possible deformation source, which is considered as a consequence of magma and fault interaction. Since the method for tracing deformation was proved feasible, continuous DInSAR monitoring employing upcoming SAR missions and advanced error regulation algorithms will be of great value in monitoring comprehensive surface deformation over Mt. Baekdu and in general world-wide active volcanoes. Full article
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24 pages, 173 KiB  
Article
Origin and Distribution of Thiophenes and Furans in Gas Discharges from Active Volcanoes and Geothermal Systems
by Franco Tassi, Giordano Montegrossi, Francesco Capecchiacci and Orlando Vaselli
Int. J. Mol. Sci. 2010, 11(4), 1434-1457; https://doi.org/10.3390/ijms11041434 - 31 Mar 2010
Cited by 28 | Viewed by 13690
Abstract
The composition of non-methane organic volatile compounds (VOCs) determined in 139 thermal gas discharges from 18 different geothermal and volcanic systems in Italy and Latin America, consists of C2–C20 species pertaining to the alkanes, alkenes, aromatics and O-, S [...] Read more.
The composition of non-methane organic volatile compounds (VOCs) determined in 139 thermal gas discharges from 18 different geothermal and volcanic systems in Italy and Latin America, consists of C2–C20 species pertaining to the alkanes, alkenes, aromatics and O-, S- and N-bearing classes of compounds. Thiophenes and mono-aromatics, especially the methylated species, are strongly enriched in fluids emissions related to hydrothermal systems. Addition of hydrogen sulphide to dienes and electrophilic methylation involving halogenated radicals may be invoked for the formation of these species. On the contrary, the formation of furans, with the only exception of C4H8O, seems to be favoured at oxidizing conditions and relatively high temperatures, although mechanisms similar to those hypothesized for the production of thiophenes can be suggested. Such thermodynamic features are typical of fluid reservoirs feeding high-temperature thermal discharges of volcanoes characterised by strong degassing activity, which are likely affected by conspicuous contribution from a magmatic source. The composition of heteroaromatics in fluids naturally discharged from active volcanoes and geothermal areas can then be considered largely dependent on the interplay between hydrothermal vs. magmatic contributions. This implies that they can be used as useful geochemical tools to be successfully applied in both volcanic monitoring and geothermal prospection. Full article
(This article belongs to the Section Physical Chemistry, Theoretical and Computational Chemistry)
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