Search Results (26)

In this study, a chemometrics-assisted calibration method was developed for the Z-903 SciAps handheld Laser-Induced Breakdown Spectroscopy (h-LIBS) device. For this purpose, seventeen silica-based standard samples with known chemical composition were collected, pelleted, and analyzed using h-LIBS. Spectral data were pre-processed using a Whittaker filter and normalized via Standard Normal Variate (SNV). The dataset was divided into calibration and validation sets using the Kennard–Stone algorithm. Partial Least Square (PLS) regression was employed for multivariate regression analysis, and a variable selection method (i.e., Variable Importance in Projection, VIP) was applied to reduce the number of predictors. Results from the PLS-VIP approach demonstrated that this device is suitable for the quantitative measurement of nineteen chemical elements, including major and minor elements, achieving significant R² values for major elements including Na (R² = 0.91), Mg (R² = 0.95), and Si (R² = 0.89). The limits of detection reached are satisfying, being, for example, 0.24%, 0.41%, 0.43%, 1.5%, and 1.7% for Na, Al, Ca, Si, and Fe, respectively, among major elements, and 189 ppm, 165 ppm, 203 ppm, and 1 ppm for Ba, Cu, Mn, and Rb, respectively, among minor elements. Uncertainties in prediction of the element concentrations were compared with data from the literature, and the effect of another baseline pretreatment algorithm, airPLS (adaptive iteratively reweighted PLS), was also tested. The method was then applied to nine silica-based artifacts of different typologies sampled from the Archaeological Park of Tindari (Italy), including bricks from the theatre, archaeological glasses, and volcanic rocks. Full article

The Sierra de las Navajas is a Late Pliocene volcanic complex with a rhyolitic composition and peralkaline affinity. It is located on the northeastern edge of the Trans-Mexican Volcanic Belt in the state of Hidalgo. Within this rocky massif lies Cerro de las Navajas, the site of the most intensively exploited archaeological obsidian deposit in Mesoamerica. Obsidian extraction in this area has been carried out through open-pit mining and unique underground mining. The geological identity of the deposit encompasses the origin, distribution, and petrological characteristics of the obsidian from Cerro de las Navajas, determined through detailed geological mapping, petrographic study, and geochemical analysis. The results reveal the obsidian deposit’s style as well as its temporal and spatial position within the eruptive evolution of the region. The deposit originated from a local explosive eruptive mechanism associated with the partial collapse of a lava dome, forming a Block and Ash Flow Deposit (BAFD). The obsidian blocks, exploited by different cultures, correspond to the pyroclastic blocks within this deposit, which can reach up to 1 m in diameter and are embedded in a weakly consolidated ash matrix. The BAFD was later buried by (a) subsequent volcanic events, (b) structural adjustments of the volcanic edifice, and (c) soils derived from the erosion of other volcanic units. This obsidian deposit was mined underground from the Early Formative period to the Colonial era by the cultures of the Central Highlands and colonized societies. Interest in the vitreous quality and exotic nature of obsidian lithics from the BAFD led to the development of a complex exploitation system, which was generationally refined by the Teotihuacan, Toltec, and Aztec states. Full article

The “Gutâi-Maramureș” UNESCO Global Geopark project is to be realized in the Gutâi Volcanic Zone in the northwestern part of the East Carpathians (Romania), an area with long-lasting and complex Miocene volcanic activity and a centuries-long mining history. In order to identify the volcanism and mining-related patrimonial values, in combination with other natural and cultural assets able to support the establishment of a UNESCO geopark, and to develop a sustainable tourism in the area, this paper presents the main objectives of the adopted research methodology, namely to realize (1) a geological synthesis of the area, (2) an inventory and assessment of geological and mining heritage sites, (3) a synthesis of local biodiversity, and (4) documentation of the cultural, historical and archaeological values. Furthermore, we conducted a SWOT analysis to help define the optimal territory for the geopark, to establish the core values for a strong brand identity, and to develop educational and sustainable tourism activities. This paper presents all the significant heritage values located within the future geopark area: geosites of international scientific significance, sites related to centuries-long mining of precious metals, natural protected areas, including European Natura 2000 sites, important cultural heritage sites such as old wooden churches (five of them included in the UNESCO World Heritage List) and museums. The promotion of sustainable tourism in the area by harnessing all these patrimonial values could be realized by the implementation of the geoeducation and geotourism concepts during the project development based on previous experiences/activities in the area involving local people, NGOs and institutions. Full article

The present work describes the first results of the project “Lipari Obsidian and Neolithic Human Communities in the Aeolian Islands”, which aims to study the connection between obsidian sources on the island of Lipari and Neolithic populations on the Aeolian archipelago in Italy. Obsidian is a natural volcanic glass used to produce chipped tools; in the Neolithic period it was the sharpest known material and its trade played an important role in the Mediterranean area. It is thus of particular interest for tracing prehistoric trading patterns. Indeed, Lipari obsidian has a wide distribution and has been found even in southern France, Dalmatia, Sicily and mainland Italy. To reach the project goal, we considered both raw materials from different obsidian geological samples and artefacts from Neolithic settlements on the Aeolian islands, and performed fission-track dating (FT), a radiometric technique that can be used for uranium-bearing minerals and glasses. The preliminary results facilitated the age determination of geological samples, which we could relate to the different eruption phases. Archaeological samples were also dated; their link with the studied volcanic deposits and lava flows made it possible to shed some new light on raw material procurement and on the ability of the Neolithic populations to move from their locations, with particular attention to the consequences of environmental features on the first human settlements on the Aeolian islands. Full article

Many volcanological and geoarchaeological studies in the ancient city of Pompeii (Italy) have been devoted to the 79 CE Plinian eruption of Vesuvius, which sealed the city under a thick pyroclastic sequence. Only fragmentary information exists regarding the stratigraphy of the volcanic sediments sandwiched between the 79 CE street level and the volcanic rocks that form the geological framework of the hill on which Pompeii was built, which constitutes the “Pompeii bedrock”. The stratigraphic survey of twenty-one trenches throughout the city, coupled with a geochemical characterization, highlighted that the pre-79 CE stratigraphy includes at least eight late Pleistocene to Holocene tephra layers. Six eruptions were sourced from Somma–Vesuvius (Pomici di Base, Mercato, AP1 to AP4) and two originated from Campi Flegrei (Neapolitan Yellow Tuff and Soccavo 4). The Pompeii bedrock is the product of local vents, the last activity of which possibly shortly predates the 22 ka Pomici di Base eruption. From a geoarchaeological perspective, a relevant result is the absence of the 3.9 ka Avellino tephra in all trenches. This evidence, along with the reappraisal of the stratigraphy of the nearby archaeological site of S. Abbondio, suggests that the Avellino eruption possibly only marginally affected the Pompeii area during the Early Bronze Age. Full article

This work describes the effects of using neutron irradiation on cellulose and non-destructive methods to analyze linen fabrics of high heritage value. For this purpose, 8 samples were irradiated with increasing doses of neutrons and gamma rays up to 166 kGy of total dose. The samples were characterized by techniques such as ultraviolet luminescence, attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectroscopy, Raman spectroscopy, and the nuclear magnetic resonance (NMR) technique. The luminescence of linen fabrics in the ultraviolet range increases markedly with dosage. Some chemical changes were also perceived by the ATR-FTIR spectra in the linen samples. Similarly, the fluorescence background observed in Raman spectroscopy intensifies with dosage. Due to the heterogeneity of the textile cellulose, NMR offers limited applicability for detecting neutron doses in cultural heritage fabrics. Radiation is applied for preservation against microorganisms in cultural heritage objects where the damage is to be assessed. This radiation can occasionally be found after earthquakes or in volcanic archaeological sites, which could question its dating using carbon 14. Despite some limitations encountered due to working with commonly used linen fabrics, the techniques employed in this study have made it possible to observe trends between the responses obtained and the irradiation dose for each linen sample. Full article

The enigmatic major eruption in the late 16th century, believed to have originated from Raung, the most active stratovolcano in the Ijen UNESCO Global Geopark in East Java, Indonesia, has ignited significant debate among researchers and historians due to its profound impact on the region. This research aims to substantiate Raung as the likely source of the major eruption by integrating geological, archaeological, and historical data. This study synthesizes current findings and explores ongoing debates surrounding historical volcanic activities. Eruption parameters suggest that the late 16th century eruption exhibited a Plinian type, characterized by an explosive eruption column reaching the stratosphere, widespread pumiceous tephra fallout, and pyroclastic density current (PDC). Stratigraphic succession reveals that the eruption occurred in five phases, with deposits from 10 eruptive units. These deposits are mainly concentrated on the northwestern flank of Raung. Archaeological findings, historical records, and local legends converge to pinpoint the occurrence of this catastrophic event in the late 16th century. These diverse sources estimate that the eruption resulted in approximately 10,000 casualties, marking it as one of the most significant volcanic disasters in the past 500 years. The implications of this eruption extend beyond historical documentation, providing a critical case study for advancing disaster mitigation strategies through geotourism in the geopark area. Moreover, the eruption record outcrops identified in this study can be proposed as potential new geosites within the Ijen UNESCO Global Geopark, enhancing its educational and touristic value. We propose the Jebung Kidul, Alas Sumur, and Batu Sappar sites as potential disaster-based geosites, considering that these sites record the eruption process and preserve archaeological structures. This addition would not only commemorate the historical event but also promote awareness and preparedness for future volcanic activities in the region. Full article

A multidisciplinary study, including geomorphological, stratigraphic, paleontological and archaeological methods and techniques, allowed for a detailed exploration of coastal landforms and environments in front of the ancient city of Pompeii (southern Italy). The famous site of Pompeii sits on a small volcanic hill in the alluvial-coastal plain of the Sarno River, very close to the ancient paleoshoreline. When the Roman city was buried during the eruption of Vesuvius in 79 CE, pyroclastic fall and flow deposits covered the urban centres and ancient coastal landforms. In this study, 83 new boreholes were carried out up to a depth of 10 m. Some of them (15) were analysed for their sedimentological, stratigraphical and paleontological characterisation, in order to reconstruct the sedimentary environments in 79 CE. The data collected allow for new hypotheses to be formulated regarding the paleoshorelines, as well as the 79 CE coastal landforms and environments. In particular, litho-stratigraphic and fossil assemblages highlight the presence of shallow marine environments in a large back-ridge depression, named Masseria Curati, that is located just outside the city walls. This hypothesis opens new insights on the unknown location of the harbour of the Roman city. Full article

Archaeometry can help archaeologists in many ways, and one of the most common archaeometric objectives is provenance analysis. Volcanic rocks are often found in archaeological sites as materials used to make grinding tools such as millstones and mortars or as building materials. Petrographic characterization is commonly applied to identify their main mineralogical components. However, the provenance study of volcanic stones is usually undertaken by comparing geochemical data from reference outcrops using common descriptive statistical tools such as biplots of chemical elements, and occasionally, unsupervised multivariate data analysis like principal component analysis (PCA) is also used. Recently, the use of supervised classification methods has shown a superior performance in assigning provenance to archaeological samples. However, these methods require the use of reference databases for all the possible provenance classes in order to train the classification models. The existence of comprehensive collections of published geochemical analyses of igneous rocks enables the use of the supervised approach for the provenance determination of volcanic stones. In this paper, the provenance of volcanic grinding tools from two archaeological sites (Iulia Libica, Spain, and Sidi Zahruni, Tunisia) is attempted using data from the GEOROC database through unsupervised and supervised approaches. The materials from Sidi Zahruni have been identified as basalts from Pantelleria (Italy), and the agreement between the different supervised classification models tested is particularly conclusive. In contrast, the provenance of the materials from Iulia Libica remained undetermined. The results illustrate the advantages and limitations of all the examined methods. Full article

Archaeoseismological research often deals with two unresolved questions: the magnitude and level of damage caused by past earthquakes, and the precise location of the seismic source. We propose a comprehensive review of an integrated approach that combines site effects with the analysis of geochemical data in the field of archaeoseismology. This approach aims to identify active buried faults potentially related to the causative seismic source and provide insights into earthquake parameters. For each integrated method, we report the foundational principles, delineation of theoretical field procedures, and exemplification through two case studies. Site effects analysis in archaeoseismology assumes a pivotal role in unraveling historical seismic occurrences. It enables estimating the earthquake magnitude, assessing the seismotectonic patterns, and determining the resulting damage level. Valuable data related to earthquake parameters can be extracted by analyzing vibration frequencies and acceleration measurements from structures within archaeological sites. This information is instrumental in characterizing seismic events, evaluating their impact on ancient structures, and enhancing our understanding of earthquake hazards within the archaeological context. Geochemical investigations supply indispensable tools for identifying buried active faults. The analysis of fluids and gases vented in proximity to faults yields valuable insights into their nature, activity, and underlying mechanisms. Faults often manifest distinctive geochemical imprints, enabling the differentiation between tectonically active and volcanically related fault systems. The presence of specific gases can further serve as indicators of the environmental conditions surrounding these fault networks. Integrating site effects analysis and geochemical investigations within archaeoseismological research is crucial to improving our understanding of unknown past earthquakes. Moreover, it enhances the seismic hazard assessment of the region under study. Full article

Portable X-ray fluorescence (pXRF) is a useful geochemical technique employed to explore toolstone procurement strategies in the lithic record, commonly utilized in sourcing obsidians. Non-obsidian volcanic toolstones (e.g., dacites, rhyolites, basalts, and andesites) are abundant in interior Alaskan assemblages yet understudied compared to obsidian. Geochemical analyses of these non-obsidian materials offer the potential to gain new insights into ancient toolstone provisioning behaviors. This paper presents a synthesis of geochemical (pXRF) analyses of rhyolite artifacts, systematic regional raw material surveys, and lithic technological analyses collected from nineteen late Pleistocene and Holocene assemblages from the Nenana valley, interior Alaska. Previous research studies on archaeological rhyolites from the region are replicated, new rhyolite artifact groups are identified, and one new rhyolite source is reported and described here. Ultimately, this paper contributes to a growing body of geochemical research seeking to provide a more nuanced look at the complex late Pleistocene and Holocene record of eastern Beringia. Full article

Soils and agriculture are inextricably linked, in the past as well as today. The Pacific islands, which often represent organized gradients of the essential soil-forming factors of substrate age and rainfall, represent excellent study systems to understand interactions between people and soils. The relationship between soil characteristics and indigenous agricultural practices are well documented for some locations, but there is a paucity of data for much of the region. Given the extent of ecological adaptation that has been documented, specifically for Hawai‘i, new Pacific datasets are expected to provide important insights into indigenous agricultural practices. To contribute to this discussion, we analyzed patterns in soil chemistry and vegetation in the Manu‘a islands of American Samoa. Soils were sampled along transects that crossed through precontact settlement zones in the upland of Fiti‘uta on Ta‘ū island, a location characterized by young (<100 ky) volcanic substrates and very high (>3800 mm y⁻¹) annual rainfall. Soils were analyzed for several soil fertility properties that have been proposed as predictors of intensive rainfed tuber production in Hawai‘i and Rapa Nui. Surveys of remnant economic plants were conducted to assess patterns of past land use. Soils demonstrated moderate values of soil fertility as measured by pH, base saturation, exchangeable calcium, and total and exchangeable phosphorus, despite the high rainfall. Previously identified soil fertility indicators had some application to the distribution of traditional agriculture, but they also differed in important ways. In particular, low exchangeable calcium in the soils may have limited the agricultural form, especially the cultivation of tubers. Significant shifts in both soil parameters and remnant economic crops were documented, and alignment suggests cropping system adaptation to soil biochemistry. Archaeological samples combined with surveys of relict vegetation suggest that agroforestry and arboriculture were key components of past agricultural practices. Full article

Harrat Khaybar is an active monogenetic volcanic field in western Saudi Arabia that hosts spectacular monogenetic volcanoes and a Holocene volcanic cone with extensive lava fields. The volcanic region is a subject of intensive land use development, especially along tourism ventures, where the volcanic features are the key elements to utilize for increasing visitation rates to the region. The youngest eruption is suspected to be Holocene and occurred fewer than 5000 years ago based on the cross-cutting relationship between the youngest lava flows and archaeological sites. Lava flows are typical, from pāhoehoe to ‘a‘ā types with great diversity of transitional textural forms. Here, we recorded typical transitional lava flow surface textures from the youngest flows identified by digital-elevation-model-based terrain analysis, satellite imagery, and direct field observations. We performed lava flow simulations using the Q-LavHA plug-in within the QGIS environment. Lava flow simulations yielded satisfactory results if we applied eruptions along fissures, long simulation distances, and ~5 m lava flow thickness. In these simulations, the upper flow regimes were reconstructed well, but long individual lava flows were not possible to simulate, suggesting that morphological steps likely promoted lava ponding, inflation, and sudden deflation by releasing melts further along shallow syneruptive valley networks. Full article

Obsidian is a natural volcanic glass formed after eruptions if very rapid cooling of lava occurs. In particular conditions, the lava silicate ions cannot reach the crystalline lattice ordered formation and assume a chaotic arrangement, giving origin to obsidian flows. Obsidian has been used since the Paleolithic period to make tools because of its durability; in the Neolithic period, its trade played an important role in the Mediterranean area, and currently, obsidian is of particular interest for tracing prehistoric trading patterns. In this work, we present a semi-quantitative approach, exploiting energy-dispersive X-ray fluorescence (ED-XRF) coupled with principal component analysis. We consider geological samples from the five main collection sites of archaeological interest in the Mediterranean Basin (i.e., Pantelleria, Lipari, Palmarola, and Sardinia islands in Italy and Milos Island in Greece) and obtain a reliable classification of the fragments’ provenance, also comparing chemical fingerprints with data from the literature. Reported results show that this non-invasive semi-quantitative protocol could ease the application to archaeological samples, such as blades and splinters, permitting the classification of artifacts found in the archeological sites of the Mediterranean area even when relatively few samples are considered. Full article

Nisyros Geopark, an island geopark in the Southeastern Aegean Sea, Greece, is here presented as an official candidate for the UNESCO Global Geoparks designation, featuring outstanding geological, natural and cultural characteristics tightly connected to its volcanic origin. It covers a total area of 481 km² and includes Nisyros, an active volcano and the main island, the surrounding islets of Pachia, Strongyli, Pergousa, Kandeliousa and the marine region among them. It features 24 geosites and a network of well-established walking trails. Furthermore, there are two internationally designated Natura 2000 areas covering its entire surface and also exceptional archaeological and cultural sites, including fortresses, remnants of ancient habituations and numerous churches and monasteries. It is the only area in the broader region of the Eastern Mediterranean that hosts all these features within such a restricted area. The initial efforts of the management body of Nisyros Geopark and its scientific team to promote its unique geodiversity included the complete design, construction and launch of the official website, the mobile application “Nisyros Volcano App’’, a modern informative leaflet regarding the region of the hydrothermal craters (Lakki), a Geopark guidebook and a series of panels and signs for the geosites. Full article