Search Results (23)

Polymer flooding is a widely used enhanced oil recovery (EOR) method for improving energy efficiency and reducing the carbon footprint of oil production. Optimizing polymer concentration is critical for maximizing recovery while minimizing economic and environmental costs. Here, we present a systematic experimental study which shows that even very low concentrations of polymers yield relatively high recovery rates at adverse mobility ratios (230 cP oil). A series of core flood experiments were conducted on Bentheimer sandstone rock, with polymer concentrations ranging from 40 ppm (1.35 cP) to 600 ppm (10.0 cP). Beyond a mobility ratio threshold, increasing polymer concentration did not significantly enhance recovery. This plateau in performance was attributed to the persistence of viscous fingering and oil crossflow into pre-established water channels. The study suggests that low concentrations of polymer may mobilize oil at high mobility ratios by making use of the pre-established water channels as transport paths for the oil and that the rheology of the polymer enhances this effect. These findings enable reductions in the polymer concentration in fields with adverse mobility ratios, leading to substantial reductions in chemical usage, energy consumption, and environmental impact of the extraction process. Full article

Aiming at the problem that conventional friction reducers used in fracturing cannot simultaneously possess properties such as temperature resistance, salt resistance, shear resistance, rapid dissolution, and low damage. Under the design concept of “medium-low molecular weight, salt-resistant functional monomer, supramolecular physical crosslinking aggregation, and enhanced chain mechanical strength”, acrylamide, sulfonic acid salt-resistant monomer 2-acrylamide-2-methylpropanesulfonic acid, hydrophobic association monomer, and rigid skeleton functional monomer acryloyl morpholine were introduced into the friction reducer molecular chain by free radical polymerization, and combined with the compound suspension technology to develop a new type of multi-functional viscous friction reducer suspension (SAMD), the comprehensive performance of SAMD was investigated. The results indicated that the critical micelle concentration of SAMD was 0.33 wt%, SAMD could be dissolved in 80,000 mg/L brine within 3.0 min, and the viscosity loss of 0.5 wt% SAMD solution was 24.1% after 10 min of dissolution in 80,000 mg/L brine compared with that in deionized water, the drag reduction rate of 0.1 wt% SAMD solution could exceed 70% at 120 °C and still maintained good drag reduction performance in brine with a salinity of 100,000 mg/L. After three cycles of 170 s⁻¹ and 1022 s⁻¹ variable shear, the SAMD solution restored viscosity quickly and exhibited good shear resistance. The Tan δ (a parameter characterizing the viscoelasticity of the system) of 1.0 wt% SAMD solution was 0.52, which showed a good sand-carrying capacity, and the proppant settling velocity in it could be as low as 0.147 mm/s at 120 °C, achieving the function of high drag reduction at low concentrations and strong sand transportation at high concentrations. The viscosity of 1.4 wt% SAMD was 95.5 mPa s after shearing for 120 min at 140 °C and at 170 s⁻¹. After breaking a gel, the SAMD solution system had a core permeability harm rate of less than 15%, while the SAMD solution also possessed the performance of enhancing oil recovery. Compared with common friction reducers, SAMD simultaneously possessed the properties of temperature resistance, salt resistance, shear resistance, rapid dissolution, low damage, and enhanced oil recovery. Therefore, the use of this multi-effect friction reducer is suitable for the development of unconventional oil reservoirs with a temperature lower than 140 °C and a salinity of less than 100,000 mg/L. Full article

Anthropogenic activities have led to hydrocarbon spills, and while traditional bioremediation methods are costly and time-consuming, recent research has focused on engineered enzymes for managing pollutant. The potential of enzymes for resolving wax flow problems in the petroleum industry remains unexplored. This paper offers a comprehensive review of the current state of research activities related to the bioremediation of petroleum-polluted sites and the biodegradation of specific petroleum hydrocarbons. The assayed enzymes that took part in the degradation were discussed in detail. Lipase, laccase, alkane hydroxylase, alcohol dehydrogenase, esterase, AlkB homologs and cytochrome P450 monooxygenase are among the enzymes responsible for the degradation of more than 50% of the hydrocarbons in contaminated soil and wastewater and found to be active on carbon C8 to C40. The possible biodegradation mechanism of petroleum hydrocarbons was also elucidated. The enzymes’ primary metabolic pathways include terminal, subterminal, and ω-oxidation. Next, given the successful evidence of the hydrocarbon treatment efficiency, the authors analyzed the opportunity for the enzymatic degradation approach if it were to be applied to a different scenario: managing wax deposition in petroleum-production lines. With properties such as high transformation efficiency and high specificity, enzymes can be utilized for the treatment of viscous heavy oil for transportability, evidenced by the 20 to 99% removal of hydrocarbons. The challenges associated with the new approach are also discussed. The production cost of enzymes, the characteristics of hydrocarbons and the operating conditions of the production line may affect the biocatalysis reaction to some extent. However, the challenges can be overcome by the usage of extremophilic enzymes. The combination of technological advancement and deployment strategies such as the immobilization of a consortium of highly thermophilic and halotolerant enzymes is suggested. Recovering and reusing enzymes offers an excellent strategy to improve the economics of the technology. This paper provides insights into the opportunity for the enzymatic degradation approach to be expanded for wax deposition problems in pipelines. Full article

Considering the damage caused by conventional fracturing fluid in low-permeability reservoirs, a novel fracturing fluid (FNG) combining hydroxypropyl guar (HPG) and functionally modified nano-silica (FMNS) was prepared. The properties of heat/shear resistance, rheological property, proppant transportation, and formation damage were evaluated with systematic experiments. The results showed that the viscosities of FNG before and after the heat/resistance were 1323 mPa·s and 463 mPa·s, respectively, while that of conventional HPG gel was 350 mPa·s. FNG is a pseudoplastic strong gel with a yield stress of 12.9 Pa, a flow behavior index of 0.54, an elastic modulus of 16.2 Pa, and a viscous modulus of 6.2 Pa. As the proportions of proppant mass in further sections transported with FNG were higher than those transported with HPG gel, FNG could transport the proppant better than HPG gel at high temperatures. Because of the amphiphilic characteristics of FMNS, the surface/interface properties were improved by the FNG filtrate, resulting in a lower oil permeability loss rate of 10 percentage points in the matrix than with the filtrated HPG gel. Due to the considerable residual gel in broken HPG gel, the retained conductivity damaged with broken FNG was 9.5 percentage points higher than that damaged with broken HPG gel. FNG shows good potential for reducing formation damage during fracturing in low-permeability reservoirs in China. Full article

A possible method for fluid transportation of heavy oil through horizontal pipes is core annular flow (CAF), which is water-lubricated. In this study, a large eddy simulation (LES) and a sub-grid-scale (SGS) model are used to examine CAF. The behavior of heavy oil flow through turbulent CAF in horizontal pipes is numerically investigated. The Smagorinsky model is utilized to capture small-scale unstable turbulent flows. The transient flow of oil and water is first separated under the behavior of the core fluid. Two different conditions of the horizontal pipes, one with sudden expansion and the other with sudden contraction, are considered in the geometry to investigate the effects of different velocities of oil and water on the velocity distribution, pressure drop, and volume fraction. The model was created to predict the losses that occur due to fouling and wall friction. According to the model, increasing water flow can reduce fouling. Additionally, the water phase had an impact on the CAF’s behavior and pressure drop. Also, the increased stability in the CAF reduces the pressure drop to a level that is comparable to water flow. This study demonstrated that a very viscous fluid may be conveyed efficiently utilizing the CAF method. Full article

Marangoni bursting describes the spontaneous spread of a droplet of a binary mixture of alcohol/water deposited on a bath of oil, followed by its fast spontaneous fragmentation into a large number of smaller droplets in a self-similar way. Several papers have aimed to describe the physical phenomena underlying this spectacular phenomenon, in which two opposite effects, solutal and thermal Marangoni stresses, play competitive roles. We performed investigations of the Marangoni bursting phenomenon, paying attention to the surface temperature changes during bursting and after it. Fragmentation instabilities were monitored using a thermal camera for various initial alcohol/water compositions and at different stages of the process. We uncovered the role of thermocapillary Marangoni flows within the more viscous oil phase that are responsible for outward and inward shrinking of the periphery circle at the final stage of the phenomenon, enabling a more comprehensive understanding of the thermal Marangoni effect. Simulations of the Marangoni thermocapillary effect in an oil bath by solving coupled Navier–Stokes and heat transport equations using the COMSOL Multiphysics software platform support our experimental observations. Full article

Extensive research has been conducted over the past few decades on carbon-free hydrogen energy. Hydrogen, being an abundant energy source, requires high-pressure compression for storage and transportation due to its low volumetric density. Mechanical and electrochemical compression are two common methods used to compress hydrogen under high pressure. Mechanical compressors can potentially cause contamination due to the lubricating oil when compressing hydrogen, whereas electrochemical hydrogen compressors (EHCs) can produce high-purity, high-pressure hydrogen without any moving parts. A study was conducted using a 3D single-channel EHC model focusing on the water content and area-specific resistance of the membrane under various temperature, relative humidity, and gas diffusion layer (GDL) porosity conditions. Numerical analysis demonstrated that the higher the operating temperature, the higher the water content in the membrane. This is because the saturation vapor pressure increases with higher temperatures. When dry hydrogen is supplied to a sufficiently humidified membrane, the actual water vapor pressure decreases, leading to an increase in the membrane’s area-specific resistance. Furthermore, with a low GDL porosity, the viscous resistance increases, hindering the smooth supply of humidified hydrogen to the membrane. Through a transient analysis of an EHC, favorable operating conditions for rapidly hydrating membranes were identified. Full article

The transportation of highly viscous oil surrounded by water annulus has been recognized as a feasible option in terms of low-energy consumption and high efficiency. During the process of heavy oil delivery, the problem of pipe fittings is inevitably encountered, and the most common one is elbow assembly. In this present study, simulations for oil-water core annular flow (CAF) through a 90° elbow pipe were performed by computational fluid dynamics (CFD) based on VOF, standard k-ε, and CSF models. Simulation results were consistent with experimental data, which verifies the validity and practicability of the proposed model. The effects of inlet water fraction, superficial velocities of oil and water, oil properties (density and viscosity), and pipe geometry-related parameters (diameter ratio, wall roughness, and surface wettability) on the hydrodynamic performance and stability characteristics were explored. It is revealed that inlet water fraction, superficial velocities of oil and water, oil properties, and pipe geometric parameters do influence the volume fraction of oil and the stability of the water ring. Furthermore, the oil core may adhere to the downstream of the 90° elbow pipe under certain operational conditions. The results could provide a reference for the design of 90° elbow pipe structures and the optimization of operation parameters. Full article

Entropy generation in peristaltic transport of hybrid nanofluid possessing temperature-dependent thermal conductivity through a two-dimensional vertical channel is studied in this paper. The hybrid nanofluid consists of multi-walled carbon nanotubes mixed with zinc oxide suspended in engine oil. Flow is affected by a uniform external magnetic field, hence generating Lorentz force, Hall and heating effects. Given the vertical orientation of the channel, the analysis accounts for mixed convection. To study heat transfer in the current flow configuration, the model considers phenomena such as viscous dissipation, heat generation or absorption, and thermal radiation. The mathematical modeling process employs the lubrication approach and Galilean transformation for enhanced accuracy. The slip condition for the velocity and convective conditions for the temperature are considered at the boundaries. The study analyzes entropy generation using the Homotopy Analysis Method (HAM) and includes convergence curves for HAM solutions. Results are presented using graphs and bar charts. The analysis shows that higher Brinkman and thermal radiation parameters result in higher temperatures, while higher thermal conductivity parameters lead to reduced entropy generation and temperature profile. Additionally, higher Hall parameter values decrease entropy generation, while an increased Hartman number improves entropy generation. Full article

Centrifugal pumps are widely used in the oil and mining industries. In contrast to water pumps, the centrifugal pumps in the oil and mining industries are used for the transportation of drilling fluid, which is typically non-Newtonian fluid. Drilling fluids are usually modeled as power-law fluids with varying shear viscosity and imposed shear rates. In this paper, a numerical simulation of power-law fluid flow in a centrifugal pump was simulated, varying only in the flow-rate magnitude, using water flow as a comparison. The simulation results show that the pump used for drilling fluid presents a lower head and efficiency but a higher shaft power than that used for water. The flow patterns of both the water pump and the drilling fluid pump were investigated in terms of pressure fluctuation, turbulent kinetic energy, and radial force on the impeller. In contrast to the literature, this paper also analyzes the pressure pulsations in the individual blades of the impeller, as well as those in the volute path. In the case of drilling fluid, it was found that the viscous effect made the flow at the end of the blades highly irregular, and this could be attributed to the pressure generated by them. At the same time, the fluid flow at the small cross-section of the volute was more sensitive to the rotation of the impeller. In addition, the effects of the shear collision exerted on the outlet fluid of the impeller and the fluid in the volute, as well as the dynamic and static interferences, made the non-Newtonian power-law fluid consume more mechanical energy than the water. The results of this paper can be used as a reference for improving the design of centrifugal pumps using non-Newtonian fluids as media. Full article

Solar pyrolysis is a promising technology as it combines use of biomass and solar energy to generate transportable and storable fuels, as well as chemicals of interest. The most desired product of rapid pyrolysis of microalgae is bio-oil, a liquid and viscous mixture composed of hundreds of chemicals. Among these compounds are many oxygenates that usually bring some undesirable properties to bio-oil, e.g., instability. This study aimed to investigate the potential of Spirulina platensis to produce bio-oil from catalytic solar pyrolysis assisted by Fresnel lens. The performance of the mixed oxides derived from hydrocalumite was evaluated, aiming to improve the yield and quality of the liquid product. The effects of reaction time and percentage of catalyst on the product distribution and bio-oil composition were quantified. An optimization study was performed using the differential evolution (DE) algorithm in order to maximize the bio-oil yield. The results showed that the highest liquid yield (43.4%) was obtained in 23.4 min using a catalyst percentage of 58.6%. The mixed oxides derived from hydrocalumite contributed to the improvement in the bio-oil quality, which presented in its composition a low quantity of oxygenated compounds and a higher percentage of hydrocarbons. Full article

The importance of heavy oil in the world oil market has increased over the past twenty years as light oil reserves have declined steadily. The high viscosity of this kind of unconventional oil results in high energy consumption for its transportation, which significantly increases production costs. A cost-effective solution for the long-distance transport of viscous crudes could be water-lubricated flow technology. A water ring separates the viscous oil-core from the pipe wall in such a pipeline. The main challenge in using this kind of lubricated system is the need for a model that can provide reliable predictions of friction losses. An artificial neural network (ANN) was used in this study to model pressure losses based on 225 data sets from independent sources. The seven input variables used in the current ANN model are pipe diameter, average velocity, oil density, oil viscosity, water density, water viscosity, and water content. The ANN developed using the backpropagation technique with seven processing neurons or nodes in the hidden layer demonstrated to be the optimal architecture. A comparison of ANN with other artificial intelligence and parametric techniques shows the promising precision of the current model. After the model was validated, a sensitivity analysis determined the relative order of significance of the input parameters. Some of the input parameters had linear effects, while other parameters had polynomial effects of varying degrees on the friction losses. Full article

Fast pyrolysis of biomass is a well-known opportunity for sustainable alternative fuel production for transport and energy. However, bio-oils from biomass pyrolysis are viscous, acidic bio-crudes that need further steps of upgrading before being used either as fuels or chemicals. A process that is complementary to bio-oil hydrotreatment or co-processing consists of optimizing and tuning the upstream condensation steps of fast pyrolysis to separate and concentrate selected classes of compounds. This can be implemented by varying the condensation temperatures in a multi-step condensation unit. In this study, fractional condensation of fast pyrolysis vapors from pinewood has been applied to a bubbling fluidized bed reactor of 1 kg h⁻¹ feed. The reactor was operated at 500 °C and connected to a downstream interchangeable condensation unit. Tests were performed using two different condensing layouts: (1) a series of two spray condensers and a tube-in-tube water-jacketed condenser, referred to as an intensive cooler; (2) an electrostatic precipitator and the intensive cooler. Using the first configuration, which is the focus of this study, high boiling point compounds—such as sugars and lignin-derived oligomers—were condensed at higher temperatures in the first stage (100–170 °C), while water-soluble lighter compounds and most of the water was condensed at lower temperatures and thus largely removed from the bio-oil. In the first two condensing stages, the bio-oil water content remained below 7% in mass (and therefore, the oil’s high calorific content reached 22 MJ kg⁻¹) while achieving about 43% liquid yield, compared to 55% from the single-step condensation runs. Results were finally elaborated to perform a preliminary energy assessment of the whole system toward the potential upscaling of this fractional condensation approach. The proposed layout showed a significant potential for the upstream condensation step, simplifying the downstream upgrading stages for alternative fuel production from fast pyrolysis bio-oil. Full article

Nanofluids have better surface stability, thermal absorption, and distribution capacities are produced as heat transfer fluids. In current nanofluid-transport studies, together with the heat transfer mechanisms, entropy reduction in thermo- and non-Newtonian nanofluid models with changing thermophysical characteristics is heavily addressed. The entropy production is examined as thermodynamically stable first-grade viscoelastic nanofluid (FGVNF) flow over a flat penetrable, porous barrier. The uniform porous horizontal stretching of the surface in a Darcy type of pore media results in a fluid motion disturbance. In addition, this study also includes the effects of thermal radiation, viscous dissipation, and slip conditions at the border. Under boundary layer flow and Rosseland approximations, the governing mathematical equations defining the physical features of the FGVNF flow and heat transfer models are summarized. The governing nonlinear partial differential equation is transformed by similarity variables to achieve solutions in nonlinear ordinary differential equations. Approximative solutions for reduced ordinary differential equations are obtained by the Keller Box Scheme. Two distinct types of nanofluids, Copper-Engine Oil (Cu-EO) and Zirconium Dioxide-Engine Oil (ZrO₂-EO), are considered in this research. The graphs are produced to examine the effects of the different physical factors for the speed, temperature, and entropy distributions. The significant findings of this study are that the critical characteristics of (boundary layer) BL collectively promote temperature variation, including slip speed, diverse thermal conductivity, and non-Newtonian first-grade viscoelastic nanofluid, the concentration of nanoparticles as well as thermal radiation, and a high porous media. The other noteworthy observation of this study demonstrates that the (Cu-EO) FGVNF is a better conductor than (ZrO₂-EO) FGVNF transmission. The entropy of the system grows the Deborah number and volume fraction parameter. Full article

Water-lubricated flow technology is an environmentally friendly and economically beneficial means of transporting unconventional viscous crudes. The current research was initiated to investigate an engineering model suitable to estimate the frictional pressure losses in water-lubricated pipelines as a function of design/operating parameters such as flow rates, water content, pipe size, and liquid properties. The available models were reviewed and critically assessed for this purpose. As the reliability of the existing models was not found to be satisfactory, a new two-parameter model was developed based on a phenomenological analysis of the dataset available in the open literature. The experimental conditions for these data included pipe sizes and oil viscosities in the ranges of 25–260 mm and 1220–26,500 mPa·s, respectively. A similar range of water equivalent Reynolds numbers corresponding to the investigated flow conditions was 10³–10⁶. The predictions of the new model agreed well with the experimental results. The respective values of the coefficient of determination (R²) and the root mean square error (RMSE) were 0.90 and 0.46. The current model is more refined, easy-to-use, and adaptable compared to other existing models. Full article