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17 pages, 18471 KiB  
Article
Finite-Difference Analysis of Influence of Borehole Diameter and Spacing on Reduction in Rockburst Potential of Burst-Prone Coal Seams
by Mikhail O. Eremin, Artyom O. Chirkov, Albert Pazhin, Sergey A. Laptev and Dmitriy V. Chanov
Mining 2024, 4(4), 1058-1074; https://doi.org/10.3390/mining4040058 - 2 Dec 2024
Viewed by 911
Abstract
Decreasing the rockburst potential in longwall mining of burst-prone coal seams has been a longstanding challenge for geotechnical engineering worldwide. One of the effective approaches is drilling of relief boreholes in front of the coal seam face from the airways. This work presents [...] Read more.
Decreasing the rockburst potential in longwall mining of burst-prone coal seams has been a longstanding challenge for geotechnical engineering worldwide. One of the effective approaches is drilling of relief boreholes in front of the coal seam face from the airways. This work presents a novel approach based on the integral rockburst factor (KIrb) taking account of the length of the dynamic abutment stress influence zone and the ratio of the vertical stress to the remote field virgin stress. The geotechnical conditions of seam 3 of the Alardinskaya mine (Kuznetsky basin, Russia) are taken as a study site. An approach of the finite-difference continuum damage mechanics is employed to describe the processes of deformation and fracture of coal and host rocks using an in-house software. The results indicate that the abutment stress maximum shifts deep into the seam after drilling and that the stress distribution along the coal seam horizon is a superposition of the solutions similar to those of the elastoplastic Kirsch problem. The results also indicate that the curves of KIrb dependence on spacing between the boreholes and their diameter are nonlinear and non-monotonic functions, which allows for optimizing of the drilling technology. Full article
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18 pages, 1808 KiB  
Review
Progress in Solvent-Based Recycling of Polymers from Multilayer Packaging
by Tianmiao Li, George Theodosopoulos, Chris Lovell, Adamantini Loukodimou, Kranthi Kumar Maniam and Shiladitya Paul
Polymers 2024, 16(12), 1670; https://doi.org/10.3390/polym16121670 - 12 Jun 2024
Cited by 10 | Viewed by 4548
Abstract
Conversion of chemical feedstocks derived from fossil fuels to virgin polymer, manufacturing of plastics in coal-dependent economies, and increasing consumption of virgin polymers for plastics packaging contribute significantly to environmental issues and the challenges we face. Nowadays, promoting sustainable development has become the [...] Read more.
Conversion of chemical feedstocks derived from fossil fuels to virgin polymer, manufacturing of plastics in coal-dependent economies, and increasing consumption of virgin polymers for plastics packaging contribute significantly to environmental issues and the challenges we face. Nowadays, promoting sustainable development has become the consensus of more and more countries. Among them, the recycling of multilayer packaging is a huge challenge. Due to the complexity of its structure and materials, as well as the limitations of existing recycling frameworks, currently, multilayer packaging cannot be commercially recycled thus resulting in a series of circular economy challenges. It is undeniable that multilayer packaging offers many positive effects on products and consumers, so banning the use of such packaging would be unwise and unrealistic. Developing the appropriate processes to recycle multilayer packaging is the most feasible strategy. In recent years, there have been some studies devoted to the recycling process of multilayer packaging. Many of the processes being developed involve the use of solvents. Based on the recycled products, we categorised these recycling processes as solvent-based recycling, including physical dissolution and chemical depolymerisation. In physical dissolution, there are mainly two approaches named delamination and selective dissolution–precipitation. Focusing on these processes, this paper reviews the solvents developed and used in the last 20 years for the recycling of polymers from multilayer packaging waste and gives a summary of their advantages and disadvantages in terms of cost, product quality, ease of processing, and environmental impact. Based on existing research, one could conclude that solvent-based recycling methods have the potential to be commercialised and become part of a standard recycling process for polymer-based multilayer packaging. The combined use of multiple solvent-based recycling processes could be a breakthrough in achieving unified recycling of multilayer packaging with different components. Full article
(This article belongs to the Section Circular and Green Sustainable Polymer Science)
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33 pages, 1796 KiB  
Review
Remining for Renewable Energy Metals: A Review of Characterization Needs, Resource Estimates, and Potential Environmental Effects
by Ann S. Maest
Minerals 2023, 13(11), 1454; https://doi.org/10.3390/min13111454 - 18 Nov 2023
Cited by 6 | Viewed by 4441
Abstract
Remining has been researched for decades, but its potential to supplement virgin extraction is currently unknown. This review addresses the remining of tailings/waste rock, coal residues, and byproduct and primary production materials for renewable energy metals (e.g., Co, Ni, REEs, Mn, Li). Geochemical [...] Read more.
Remining has been researched for decades, but its potential to supplement virgin extraction is currently unknown. This review addresses the remining of tailings/waste rock, coal residues, and byproduct and primary production materials for renewable energy metals (e.g., Co, Ni, REEs, Mn, Li). Geochemical characterization methods for estimating pollution potential must be supplemented with mineral liberation analysis and process testing to reliably estimate remining’s economic potential. National and regional remining characterization efforts currently exist in the U.S., Europe, Australia, and China but will take years to produce viable operations at scale. Tailings hold the most promise due to their large amounts worldwide and the fact that they are already extracted and pre-processed, which reduces energy and water use. Of the processing approaches examined, bioleaching appears to offer the most benefits with the fewest potential downsides. The advantages and challenges of the processing methods and remining sources are presented. Best remining practices are urgently needed to improve resource estimates and avoid impacts such as the tailings dam failures that occurred at remining operations in Romania and South Africa. Interest in remining is booming because it can increase domestic supply. If properly conducted, remining can also improve circularity and environmental conditions in areas affected by existing and legacy mining activity. Full article
(This article belongs to the Special Issue Reutilization and Valorization of Mine Waste, Volume II)
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16 pages, 4688 KiB  
Article
Study on Surrounding Rock Failure Law of Gob-Side Entry Based on the Second Invariant of Deviatoric Stress
by Xiaozhou Liu, Hu Xu, Ben Li, Wenrui He, Xian Liang and Hongchun Xia
Sustainability 2023, 15(13), 10569; https://doi.org/10.3390/su151310569 - 5 Jul 2023
Cited by 3 | Viewed by 1187
Abstract
The second invariant of deviatoric stress of the coal and rock mass is closely related to the distortion energy driving the deformation and failure of the surrounding rock. Based on the second invariant of deviatoric stress, this study built a global model of [...] Read more.
The second invariant of deviatoric stress of the coal and rock mass is closely related to the distortion energy driving the deformation and failure of the surrounding rock. Based on the second invariant of deviatoric stress, this study built a global model of gob-side entry with different widths of the coal pillar through numerical analysis, and compared and analyzed the evolution law of the surrounding rock distortion energy, plastic location state, and roadway deformation with the width of the coal pillar. This study concluded that the peak distortion energy in the virgin coal rib and the roof and floor of the gob-side entry gradually increases with the reduction in the coal pillar width. When the coal pillar width is 5 m, the second invariant peak value of deviatoric stress in the virgin coal rib reaches the maximum of 294.8 MPa2. When the width of the coal pillar is reduced from 30 m to 5 m, the second invariant of the deviatoric stress in the side of the coal pillar and the roof and floor of the side presents the law of first increasing and then decreasing. The greater the damage degree of the coal pillar, the smaller the distortion energy it contains. The distortion energy is the key factor in driving the deformation and failure of the surrounding rock. The greater the distortion energy, the greater the deformation degree of the surrounding rock, the more vulnerable it is to external mining stress disturbance, and the greater the difficulty in controlling the stability of the roadway-surrounding rock. Full article
(This article belongs to the Special Issue Sustainability in Geology and Civil Engineering)
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36 pages, 7448 KiB  
Review
Potential of New Sustainable Green Geopolymer Metal Composite (GGMC) Material as Mould Insert for Rapid Tooling (RT) in Injection Moulding Process
by Allice Tan Mun Yin, Shayfull Zamree Abd Rahim, Mohd Mustafa Al Bakri Abdullah, Marcin Nabialek, Abdellah El-hadj Abdellah, Allan Rennie, Muhammad Faheem Mohd Tahir and Aurel Mihail Titu
Materials 2023, 16(4), 1724; https://doi.org/10.3390/ma16041724 - 19 Feb 2023
Cited by 4 | Viewed by 3338
Abstract
The investigation of mould inserts in the injection moulding process using metal epoxy composite (MEC) with pure metal filler particles is gaining popularity among researchers. Therefore, to attain zero emissions, the idea of recycling metal waste from industries and workshops must be investigated [...] Read more.
The investigation of mould inserts in the injection moulding process using metal epoxy composite (MEC) with pure metal filler particles is gaining popularity among researchers. Therefore, to attain zero emissions, the idea of recycling metal waste from industries and workshops must be investigated (waste free) because metal recycling conserves natural resources while requiring less energy to manufacture new products than virgin raw materials would. The utilisation of metal scrap for rapid tooling (RT) in the injection moulding industry is a fascinating and potentially viable approach. On the other hand, epoxy that can endure high temperatures (>220 °C) is challenging to find and expensive. Meanwhile, industrial scrap from coal-fired power plants can be a precursor to creating geopolymer materials with desired physical and mechanical qualities for RT applications. One intriguing attribute of geopolymer is its ability to endure temperatures up to 1000 °C. Nonetheless, geopolymer has a higher compressive strength of 60–80 MPa (8700–11,600 psi) than epoxy (68.95 MPa) (10,000 psi). Aside from its low cost, geopolymer offers superior resilience to harsh environments and high compressive and flexural strength. This research aims to investigate the possibility of generating a new sustainable material by integrating several types of metals in green geopolymer metal composite (GGMC) mould inserts for RT in the injection moulding process. It is necessary to examine and investigate the optimal formulation of GGMC as mould inserts for RT in the injection moulding process. With less expensive and more ecologically friendly components, the GGMC is expected to be a superior choice as a mould insert for RT. This research substantially impacts environmental preservation, cost reduction, and maintaining and sustaining the metal waste management system. As a result of the lower cost of recycled metals, sectors such as mould-making and machining will profit the most. Full article
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17 pages, 6042 KiB  
Article
Ground Response of Non-Coal Pillar Mining Panel
by Hengzhong Zhu and Huajun Wang
Sustainability 2023, 15(4), 3164; https://doi.org/10.3390/su15043164 - 9 Feb 2023
Cited by 2 | Viewed by 1433
Abstract
The mining-induced ground response (MIGR) has a critical impact on safety management, the mining plan, and entry support. A clear understanding of the characteristics is the foundation of the MIGRs scientific control. This study is the result of the MIGRs development of the [...] Read more.
The mining-induced ground response (MIGR) has a critical impact on safety management, the mining plan, and entry support. A clear understanding of the characteristics is the foundation of the MIGRs scientific control. This study is the result of the MIGRs development of the non-pillar mining panel with gob-side entry by roof cutting (GSERC). Comprehensive research of the in situ measurements, numerical simulation, and theoretical analysis to determine the ground response characteristics, including mining panel and GSERC, were implemented. The results indicate that the MIGR presents the characteristic of asymmetric development and that the ground response near the non-roof cutting side is more significant than that near the roof cutting side. The development stage of the entry convergence of GESRC can be divided into seven stages; the primary rapid development stage should be paid more attention to in the support process. The entry convergence rapidly increases to 275 mm, 380 mm, 410 mm, and 525 mm, respectively, for the roof cutting rib to the virgin coal rib, the roof near the virgin coal side, the roof of the middle section, and the roof near the cutting side. The hydraulic support end cycle resistance at the roof cutting side and the middle section of the mining panel with the value of more than 30.8 MPa is greater than that at the non-roof cutting side with the value of less than 26 MPa, which presents the asymmetric feature. The numerical simulation results regarding vertical stress development, vertical displacement, and horizontal displacement also presents the asymmetric feature. The MIGR division is divided into five divisions. Division II (the middle section of the panel) and division IV (the entry range near the roof cutting side) should be paid more attention to in the panel mining process. The results of this study can provide technical guidance and theoretical reference for similar engineering practices. Full article
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21 pages, 3499 KiB  
Article
Environmental Acceptability of Geotechnical Composites from Recycled Materials: Comparative Study of Laboratory and Field Investigations
by Marija Đurić, Vesna Zalar Serjun, Ana Mladenovič, Alenka Mauko Pranjić, Radmila Milačič, Janez Ščančar, Janko Urbanc, Nina Mali, Alenka Pavlin, Janez Turk and Primož Oprčkal
Int. J. Environ. Res. Public Health 2023, 20(3), 2014; https://doi.org/10.3390/ijerph20032014 - 21 Jan 2023
Cited by 2 | Viewed by 2365
Abstract
The environmental properties of three geotechnical composites made by recycling wastes were investigated on a laboratory scale and in the field with the use of lysimeters designated for the revitalization of degraded mining sites. Composites were prepared by combining the mine waste with [...] Read more.
The environmental properties of three geotechnical composites made by recycling wastes were investigated on a laboratory scale and in the field with the use of lysimeters designated for the revitalization of degraded mining sites. Composites were prepared by combining the mine waste with paper-mill sludge and foundry sand (Composite 1), with digestate from municipal waste and paper ash (Composite 2), and with coal ash, foundry slag and waste incineration bottom ash (Composite 3). The results of laboratory leaching tests proved that Composites 1 and 3 are environmentally acceptable, according to the legislative limits, as the potentially hazardous substances were immobilized, while in Composite 2, the legislative limits were exceeded. In the field lysimeters, the lowest rate of leaching was determined for optimally compacted Composites 1 and 3, while for Composite 2 the leaching of Cu was high. This study proved that optimally installed Composites 1 and 3 are environmentally acceptable for use in construction as an alternative to virgin materials, for the revitalization of degraded mining sites or, along with Composite 2, for closure operations with landfills. In this way, locally available waste streams are valorised and channelized into a beneficial and sustainable recycling practice. Full article
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15 pages, 2165 KiB  
Article
Thermal Insulation of Excavations and Its Effect on Climate Conditions
by Nikodem Szlązak, Dariusz Obracaj and Justyna Swolkień
Energies 2021, 14(14), 4170; https://doi.org/10.3390/en14144170 - 10 Jul 2021
Cited by 7 | Viewed by 1857
Abstract
The article compares the climate conditions in an excavation with thermally insulated roof and sidewalls to the conditions when such insulation is absent. The analysis of the temperatures presented in the article consisted of limiting the heat transfer from the rock mass to [...] Read more.
The article compares the climate conditions in an excavation with thermally insulated roof and sidewalls to the conditions when such insulation is absent. The analysis of the temperatures presented in the article consisted of limiting the heat transfer from the rock mass to the heading in one of the Polish coal mines. It is widely believed that the thermal insulation of heading sidewalls, through which fresh air is supplied, can substantially improve climate conditions. The article’s objective is to evaluate the impact of thermal insulation on the surface of the roof and sidewalls on the reduction in heat transfer from the strata with a high virgin temperature to mine air. Preventing the existing climate hazard involves higher costs of coal extraction, whereas the consequences of inadequate prevention threaten the health or life of the miners. Full article
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20 pages, 4637 KiB  
Review
Agricultural Solid Waste as Source of Supplementary Cementitious Materials in Developing Countries
by Suvash Chandra Paul, Peter B.K. Mbewe, Sih Ying Kong and Branko Šavija
Materials 2019, 12(7), 1112; https://doi.org/10.3390/ma12071112 - 3 Apr 2019
Cited by 122 | Viewed by 11355
Abstract
Concrete production utilizes cement as its major ingredient. Cement production is an important consumer of natural resources and energy. Furthermore, the cement industry is a significant CO2 producer. To reduce the environmental impact of concrete production, supplementary cementitious materials such as fly [...] Read more.
Concrete production utilizes cement as its major ingredient. Cement production is an important consumer of natural resources and energy. Furthermore, the cement industry is a significant CO2 producer. To reduce the environmental impact of concrete production, supplementary cementitious materials such as fly ash, blast furnace slag, and silica fume are commonly used as (partial) cement replacement materials. However, these materials are industrial by-products and their availability is expected to decrease in the future due to, e.g., closing of coal power plants. In addition, these materials are not available everywhere, for example, in developing countries. In these countries, industrial and agricultural wastes with pozzolanic behavior offer opportunities for use in concrete production. This paper summarizes the engineering properties of concrete produced using widespread agricultural wastes such as palm oil fuel ash, rice husk ash, sugarcane bagasse ash, and bamboo leaf ash. Research on cement replacement containing agricultural wastes has shown that there is great potential for their utilization as partial replacement for cement and aggregates in concrete production. When properly designed, concretes containing these wastes have similar or slightly better mechanical and durability properties compared to ordinary Portland cement (OPC) concrete. Thus, successful use of these wastes in concrete offers novel sustainable materials and contributes to greener construction as it reduces the amount of waste, while also minimizing the use of virgin raw materials for cement production. This paper will help the concrete industry choose relevant waste products and their optimum content for concrete production. Furthermore, this study identifies research gaps which may help researchers in further studying concrete based on agricultural waste materials. Full article
(This article belongs to the Special Issue Sustainability in Construction and Building Materials)
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36 pages, 5117 KiB  
Review
Plastics—Villain or Hero? Polymers and Recycled Polymers in Mineral and Metallurgical Processing—A Review
by Sheila Devasahayam, R. K. Singh Raman, K. Chennakesavulu and Sankar Bhattacharya
Materials 2019, 12(4), 655; https://doi.org/10.3390/ma12040655 - 21 Feb 2019
Cited by 41 | Viewed by 12513
Abstract
This review focusses on the use of recycled and virgin polymers in mineral and metallurgical processing, both high and ambient temperature processes, including novel applications. End of life applications of polymers as well as the utilisation of polymers during its life time in [...] Read more.
This review focusses on the use of recycled and virgin polymers in mineral and metallurgical processing, both high and ambient temperature processes, including novel applications. End of life applications of polymers as well as the utilisation of polymers during its life time in various applications are explored. The discussion includes applications in cleaner coal production, iron and steel production, iron ore palletisation, iron alloy manufacturing, manganese processing, E-wastes processing and carbon sequestration. The underlying principles of these applications are also explained. Advantages and disadvantages of using these polymers in terms of energy and emission reductions, reduction in non-renewables and dematerialisation are discussed. Influence of the polymers on controlling the evolution of micro and nanostructures in alloys and advanced materials is also considered. Full article
(This article belongs to the Section Carbon Materials)
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17 pages, 3450 KiB  
Article
Experimental Investigation of the Adsorption Characteristics of Mixed Coal and Variations of Specific Surface Areas before and after CH4 Adsorption
by Pengxiang Zhao, Hui Liu, Shugang Li, Haifei Lin, Yongyong Jia, Min Yan, Meiqi Yuan and Jia Lin
Appl. Sci. 2019, 9(3), 524; https://doi.org/10.3390/app9030524 - 4 Feb 2019
Cited by 19 | Viewed by 3221
Abstract
Tectonic coal is a kind of soft coal that is generated during tectonic movement. Gas outbursts usually occur in seams containing both virgin coal and tectonic coal. To reveal the adsorption characteristics of this type of coal seam (containing both virgin coal and [...] Read more.
Tectonic coal is a kind of soft coal that is generated during tectonic movement. Gas outbursts usually occur in seams containing both virgin coal and tectonic coal. To reveal the adsorption characteristics of this type of coal seam (containing both virgin coal and tectonic coal), both tectonic coal and virgin coal were collected from the same longwall face and a series of laboratory tests were conducted, including coal sorption tests and pore specific surface measurements. Both the tectonic coal and virgin coal were crushed into coal powder (0.18–0.25 mm) for the coal sorption tests. In these laboratory tests, different mass ratios between tectonic coal and virgin coal were tested. We found that with the increase of the percentage of tectonic coal, the adsorption volume showed a rising trend, reached its maximum value, and then decreased. The specific surface areas of the mixed coal samples had the same evolution trends as those of the adsorption volume. From the laboratory tests, we found that when the mass ratio of virgin coal to tectonic coal was 1:1, both the adsorption volume and the specific surface areas reached their maximum values. Due to the percentage variation of the tectonic coal in the panel with the advancement of the longwall face, when the tectonic coal accounted for 50% of the total coal, the gas content would rise. Thus, proper measures should be adopted for outburst hazards control. The mathematical model between the change of specific surface area and the stress and strain of pore expansion before and after gas adsorption was established, and the relationship between the change of pore structure and gas emission before and after gas adsorption was obtained. It provides a theoretical basis for further research on coal and gas outburst mechanisms. Full article
(This article belongs to the Section Chemical and Molecular Sciences)
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20 pages, 3583 KiB  
Review
New Trends in the Application of Carbon-Bearing Materials in Blast Furnace Iron-Making
by Hesham Ahmed
Minerals 2018, 8(12), 561; https://doi.org/10.3390/min8120561 - 1 Dec 2018
Cited by 53 | Viewed by 10412
Abstract
The iron and steel industry is still dependent on fossil coking coal. About 70% of the total steel production relies directly on fossil coal and coke inputs. Therefore, steel production contributes by ~7% of the global CO2 emission. The reduction of CO [...] Read more.
The iron and steel industry is still dependent on fossil coking coal. About 70% of the total steel production relies directly on fossil coal and coke inputs. Therefore, steel production contributes by ~7% of the global CO2 emission. The reduction of CO2 emission has been given highest priority by the iron- and steel-making sector due to the commitment of governments to mitigate CO2 emission according to Kyoto protocol. Utilization of auxiliary carbonaceous materials in the blast furnace and other iron-making technologies is one of the most efficient options to reduce the coke consumption and, consequently, the CO2 emission. The present review gives an insight of the trends in the applications of auxiliary carbon-bearing material in iron-making processes. Partial substitution of top charged coke by nut coke, lump charcoal, or carbon composite agglomerates were found to not only decrease the dependency on virgin fossil carbon, but also improve the blast furnace performance and increase the productivity. Partial or complete substitution of pulverized coal by waste plastics or renewable carbon-bearing materials like waste plastics or biomass help in mitigating the CO2 emission due to its high H2 content compared to fossil carbon. Injecting such reactive materials results in improved combustion and reduced coke consumption. Moreover, utilization of integrated steel plant fines and gases becomes necessary to achieve profitability to steel mill operation from both economic and environmental aspects. Recycling of such results in recovering the valuable components and thereby decrease the energy consumption and the need of landfills at the steel plants as well as reduce the consumption of virgin materials and reduce CO2 emission. On the other hand, developed technologies for iron-making rather than blast furnace opens a window and provide a good opportunity to utilize auxiliary carbon-bearing materials that are difficult to utilize in conventional blast furnace iron-making. Full article
(This article belongs to the Special Issue Towards Sustainability in Extractive Metallurgy)
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13 pages, 1919 KiB  
Article
Production of Torrefied Solid Bio-Fuel from Pulp Industry Waste
by Michael Huang, Chia-Chi Chang, Min-Hao Yuan, Ching-Yuan Chang, Chao-Hsiung Wu, Je-Lueng Shie, Yen-Hau Chen, Yi-Hung Chen, Chungfang Ho, Wei-Ren Chang, Tzu-Yi Yang and Far-Ching Lin
Energies 2017, 10(7), 910; https://doi.org/10.3390/en10070910 - 3 Jul 2017
Cited by 17 | Viewed by 4698
Abstract
The pulp industry in Taiwan discharges tons of wood waste and pulp sludge (i.e., wastewater-derived secondary sludge) per year. The mixture of these two bio-wastes, denoted as wood waste with pulp sludge (WPS), has been commonly converted to organic fertilizers for agriculture application [...] Read more.
The pulp industry in Taiwan discharges tons of wood waste and pulp sludge (i.e., wastewater-derived secondary sludge) per year. The mixture of these two bio-wastes, denoted as wood waste with pulp sludge (WPS), has been commonly converted to organic fertilizers for agriculture application or to soil conditioners. However, due to energy demand, the WPS can be utilized in a beneficial way to mitigate an energy shortage. This study elucidated the performance of applying torrefaction, a bio-waste to energy method, to transform the WPS into solid bio-fuel. Two batches of the tested WPS (i.e., WPS1 and WPS2) were generated from a virgin pulp factory in eastern Taiwan. The WPS1 and WPS2 samples contained a large amount of organics and had high heating values (HHV) on a dry-basis (HHD) of 18.30 and 15.72 MJ/kg, respectively, exhibiting a potential for their use as a solid bio-fuel. However, the wet WPS as received bears high water and volatile matter content and required de-watering, drying, and upgrading. After a 20 min torrefaction time (tT), the HHD of torrefied WPS1 (WPST1) can be enhanced to 27.49 MJ/kg at a torrefaction temperature (TT) of 573 K, while that of torrefied WPS2 (WPST2) increased to 19.74 MJ/kg at a TT of 593 K. The corresponding values of the energy densification ratio of torrefied solid bio-fuels of WPST1 and WPST2 can respectively rise to 1.50 and 1.25 times that of the raw bio-waste. The HHD of WPST1 of 27.49 MJ/kg is within the range of 24–35 MJ/kg for bituminous coal. In addition, the wet-basis HHV of WPST1 with an equilibrium moisture content of 5.91 wt % is 25.87 MJ/kg, which satisfies the Quality D coal specification of the Taiwan Power Co. requiring a value of above 20.92 MJ/kg. Full article
(This article belongs to the Collection Bioenergy and Biofuel)
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18 pages, 6954 KiB  
Article
Characteristics of Microbial Coalbed Gas during Production; Example from Pennsylvanian Coals in Indiana, USA
by Maria Mastalerz, Agnieszka Drobniak and Arndt Schimmelmann
Geosciences 2017, 7(2), 26; https://doi.org/10.3390/geosciences7020026 - 13 Apr 2017
Cited by 6 | Viewed by 4665
Abstract
Coalbed gases from 11 wells producing from the Springfield and Seelyville Coal Members (Pennsylvanian) were analyzed for composition and carbon and hydrogen stable isotope ratios in four sampling events to investigate short-term variation trends. Nine wells in the Seelyville Coal Member produce coalbed [...] Read more.
Coalbed gases from 11 wells producing from the Springfield and Seelyville Coal Members (Pennsylvanian) were analyzed for composition and carbon and hydrogen stable isotope ratios in four sampling events to investigate short-term variation trends. Nine wells in the Seelyville Coal Member produce coalbed gases from the virgin seam, whereas two wells in the Springfield Coal Member produce gas from mine voids. Methane dominates gas composition in all wells, and its content ranges from ~94% to almost 98%, with ethane typically accounting for less than 0.01%. Carbon dioxide content in most samples is below 1%, whereas N2 content ranges from less than 2% to 4.8%. Methane δ13C values range from −55.3‰ to −61.1‰, and δ2H values range from −201‰ to −219‰. Isotopic values of methane and C1/(C2 + C3) ratios indicate a biogenic origin along the CO2-reduction pathway, consistent with previous studies in this area. Our results demonstrate that gas properties may change significantly during a period of one year of production history. Compositional trends (e.g., C1/(C2 + C3), CH4/CO2 ratios) are specific for each well and often irregular. These changes result from a combined influence of numerous factors and, therefore, are difficult to predict. Full article
(This article belongs to the Special Issue Natural Gas Origin, Migration, Alteration and Seepage)
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