Search Results (236)

Photovoltaic–thermal (PVT) technology has attracted considerable attention for its ability to significantly improve solar energy conversion efficiency by simultaneously providing electricity and heat during the day. PVT technology serves a purpose in condensers and subcoolers for passive cooling in refrigeration systems at night. In our previous work, we proposed a switchable film-insulated photovoltaic–thermal–passive cooling (PVT-PC) module to address the structural incompatibility between diurnal and nocturnal modes. However, the performance of the proposed module strongly depends on two key design parameters: the structural height and the vacuum level of the air cushion. In this study, a numerical model of the proposed module is developed to examine the impact of design and meteorological parameters on its all-day performance. The results show that diurnal performance remains stable across different structural heights, while nocturnal passive cooling power shows strong dependence on vacuum level and structural height, achieving up to 103.73 W/m² at 10 mm height and 1500 Pa vacuum, which is comparable to unglazed PVT modules. Convective heat transfer enhancement, induced by changes in air cushion shape, is identified as the primary contributor to improved nocturnal cooling performance. Wind speed has minimal impact on electrical output but significantly enhances thermal efficiency and nocturnal convective cooling power, with a passive cooling power increase of up to 31.61%. In contrast, higher sky temperatures degrade nocturnal cooling performance due to diminished radiative exchange, despite improving diurnal thermal efficiency. These findings provide fundamental insights for optimizing the structural design and operational strategies of PVT-PC systems under varying environmental conditions. Full article

Background/Objectives: The industrial extraction and purification processes of Cannabis sativa L. compounds are critical steps in creating formulations with reliable and reproducible therapeutic and sensorial attributes. Methods: For this study, standardized preparations of chemotype I were chemically analyzed, and the sensory attributes were studied to characterize the extraction and purification processes, ensuring the maximum retention of cannabinoids and minimization of other secondary metabolites. The industrial process used deep-cooled ethanol for selective extraction. Results: Taking into consideration that decarboxylation occurs in the process, the cannabinoid profile composition was preserved from the herbal substance to the herbal preparations, with wiped-film distillation under deep vacuum conditions below 0.2 mbar, as a final purification step. The profiles of the terpenes and cannabinoids in crude and purified Full-spectrum Extract Cannabis Oil (FECO) were analyzed at different stages to evaluate compositional changes that occurred throughout processing. Subjective intensity and acceptance ratings were received for taste, color, overall appearance, smell, and mouthfeel of FECO preparations. Conclusions: According to sensory analysis, purified FECO was more accepted than crude FECO, which had a stronger and more polarizing taste, and received higher ratings for color and overall acceptance. In contrast, a full cannabis extract in the market resulted in lower acceptance due to taste imbalance. The purification process effectively removed non-cannabinoids, improving sensory quality while maintaining therapeutic potency. Terpene markers of the flower were remarkably preserved in SOMAÍ’s preparations’ fingerprint, highlighting a major qualitative profile reproducibility and the opportunity for their previous separation and/or controlled reintroduction. The study underscores the importance of monitoring the extraction and purification processes to optimize the cannabinoid content and sensory characteristics in cannabis preparations. Full article

This study presents the design, optimization, and experimental validation of a large-air-gap voice coil motor (LAG-VCM) for high-precision magnetic levitation vibration isolation in vacuum environments. Key challenges arising from a large air gap, including pronounced leakage flux and a reduced flux density, were addressed by employing the equivalent magnetic charge method and the image method for the modeling of permanent magnets. Finite element analysis was applied to refine the motor geometry and obtain high thrust, low ripple, and strong linearity. To mitigate the severe thermal conditions of a vacuum, a heat pipe-based cooling strategy was introduced to efficiently dissipate heat from the coil windings. The experimental results demonstrate that the optimized LAG-VCM delivers a thrust of 277 N with low ripple while effectively maintaining coil temperatures below critical limits for prolonged operation. These findings confirm the suitability of the proposed LAG-VCM for vacuum applications with stringent requirements for both a large travel range and stable, high-force output. Full article

CoCrMo alloys are interesting materials for implantable devices due to their favorable mechanical properties, high wear resistance, and good biocompatibility with the human body. Recent studies have demonstrated the possibility to further increase their wear resistance with an innovative approach consisting of nitriding treatments by the High-Power Impulse Magnetron Sputtering (HiPIMS) technique. Given the novelty of this treatment, it is relevant to develop a preliminary sustainability analysis of the processes to highlight the total environmental impact and to evaluate possible strategies to decrease it. Here, a Life Cycle Assessment (LCA) of HiPIMS nitriding treatments of CoCrMo alloys using a tantalum or molybdenum target is presented. The main impact driver in all impact categories was the electrical consumption of the vacuum apparatus and cooling system of HiPIMS instrumentation with a 45–47% and 37–39% contribution for Ta-based, and 39–40% and 41–42% for Mo-based treatments, respectively. Climate Change was found to be the most impacted category, followed by Resource Use both for Mo and Ta nitriding targets. Therefore, some perspectives to enhance the environmental sustainability of the synthesis process have been considered by means of a sensitivity analysis. Moreover, a Critical Raw Material (CRM) assessment is discussed, providing a complete sustainability evaluation of the proposed HiPIMS treatments. Full article

In the context of global warming, building transformation takes on a dual responsibility to be more energy-efficient and sustainable for climate change mitigation and to be more climate-resilient for occupants’ comfort. The building energy retrofitting is an urgent need due to the large amount of existing building stock. Especially in high-rise and high-density cities under a subtropical climate, like Hong Kong, existing buildings with large glazed façades face the challenges of high energy consumption and overheating risks. An advanced glazing system, namely the vacuum insulating glazing (VIG), shows the potential for effective building envelope retrofitting due to its excellent thermal insulation ability. Yet, its performance for practical applications in the subtropical region has not been investigated. To enhance the energy performance and thermal comfort of existing high-rise buildings, this study proposed a novel retrofitting approach by integrating the VIG into the existing window system as secondary glazing. Field experiments were conducted in a commercial building in Hong Kong to investigate the thermal performance of the VIG retrofit application under real-world conditions. Furthermore, the energy-saving potential and thermal comfort performance of the VIG retrofit were evaluated by building energy simulations. The experimental results indicate that the VIG retrofit can effectively stabilize the fluctuation of the inside glass surface temperature and significantly reduce the heat gain by up to 85.3%. The simulation work shows the significant energy-saving potential of the VIG retrofit in Hong Kong. For the VIG retrofit cases under different scenarios, the energy-saving potential varies from 12.5% to 29.7%. In terms of occupants’ thermal comfort, the VIG retrofit can significantly reduce the overheating risk and improve thermal satisfaction by 9.2%. Due to the thermal comfort improvement, the cooling setpoint could be reset to 1 °C higher without compromising the overall thermal comfort. The average payback period for the VIG application is 5.8 years and 8.6 years for the clear glass retrofit and the coated glass retrofit, respectively. Therefore, the VIG retrofit approach provides a promising solution for building envelope retrofits under subtropical climate conditions. It not only benefits building owners and occupants but also contributes to achieving long-term climate resilience and the carbon neutrality of urban areas. Full article

Quantum field theory (QFT) and general relativity (GR) are pillars of modern physics, each supported by extensive experimental evidence. QFT operates within Lorentzian spacetime, while GR ensures local Lorentzian geometry. Despite their successes, these frameworks diverge significantly in their estimations of vacuum energy density, leading to the cosmological constant problem—a discrepancy where QFT estimates exceed observed values by 123 orders of magnitude. This paper addresses this inconsistency by tracing the cooling evolution of the universe’s gauge symmetries—from $SU\left(3\right)\times SU\left(2\right)\times U\left(1\right)$ at high temperatures to $SU\left(3\right)$ alone near absolute zero—motivated by the experimental Meissner effect. This symmetry reduction posits that $SU\left(3\right)$ forms the fundamental “atoms” of vacuum energy. Our analysis demonstrates that the calculated number of $SU\left(3\right)$ vacuum atoms reconciles QFT’s predictions with empirical observations, effectively resolving the cosmological constant problem. The third law of thermodynamics, by preventing the attainment of absolute zero, ensures the stability of $SU\left(3\right)$ vacuum atoms, providing a thermodynamic foundation for quark confinement. This stability guarantees a strictly positive mass gap defined by the vacuum energy density and implies a Lorentzian quantum structure of spacetime. Moreover, it offers insights into the origins of both gravity/gauge duality and gravity/superconductor duality. Full article

Building facade insulation technologies have evolved from primitive thermal barriers to high-performance, multifunctional systems that enhance energy efficiency and indoor comfort. Historical insulation methods, such as thick masonry walls and timber-based construction, have gradually been replaced by advanced materials and innovative facade designs. Studies indicate that a significant proportion of a building’s heat loss occurs through its external walls and windows, highlighting the need for effective insulation strategies. The development of double-skin facades (D-SFSs), adaptive facades (AFs), and green facades has enabled substantial reductions in heating and cooling energy demands. Materials such as vacuum insulation panels (VIPs), aerogels, and phase change materials (PCMs) have demonstrated superior thermal resistance, contributing to improved thermal regulation and reduced carbon emissions. Green facades offer additional benefits by lowering surface temperatures and mitigating urban heat island effects, while D-SF configurations can reduce cooling loads by over 20% in warm climates. Despite these advancements, challenges remain regarding the initial investment costs, durability, and material sustainability. The future of facade insulation technologies is expected to focus on bio-based and recyclable insulation materials, enhanced thermal performance, and climate-responsive facade designs. This study provides a comprehensive review of historical and modern facade insulation technologies, examining their impact on energy efficiency, sustainability, and future trends in architectural design. Full article

In-plane thermoelectric thin-film cooling devices are considered a promising solution for thermal management in electronic systems. However, the actual cooling performance is far below that of regular bulk cooling devices, making the design of thin-film devices much more difficult. In this work, a numerical analysis of the cooling performance of single-leg thin-film devices and multi-stage cascaded thin-film devices was conducted to understand the depressed cooling performance. The effects of input current, operating environment, substrate, and contact resistance on cooling performance were investigated and compared with the experimental data. The results show that under ideal conditions, including vacuum environment, absence of substrate, and no contact resistance, the maximum cooling temperature difference simulated by the finite element method (105.4 K) closely matches the theoretical value estimated from the ZT-based calculation (96.6 K). Under practical conditions, such as within atmosphere and with substrate and contact resistance, the simulated maximum temperature difference (2.1 K) fits well with the experimental value (1.1 K). These findings demonstrate that substrate effects, contact resistance, and operating environment can significantly impair the cooling performance of in-plane film thermoelectric devices, although high-performance thermoelectric materials were used. This study provides a guidance for the design and parameter optimization of thermoelectric thin-film cooling modules. Full article

Background/Objectives: Lipid-based formulations (LBFs) are enabling formulations for poorly water-soluble, mostly lipophilic drugs. In LBFs, the drug is pre-dissolved in the formulation which can consist of lipids, surfactants, and/or cosolvents. In cases where the administration of high amounts of a drug is required, exceeding the drug solubility in the lipidic vehicle at the administration temperature, supersaturated LBFs are an option. The standard method described in the literature for inducing supersaturation in LBFs is to dissolve the drug substance in the lipidic vehicle at an elevated temperature, e.g., at 60 °C, and then subsequently let the formulation cool to ambient temperature before administration (heat-based approach). In this work, an alternative approach to induce supersaturation in LBFs was investigated in order to evaluate if higher drug loads, i.e., the concentration of drug dissolved in the vehicle, could be reached compared to the loading obtainable via heating. Methods: A volatile solvent that is miscible with the lipid matrix and in which the compound has a high solubility is added to the lipid matrix, after which the solvent is evaporated. Both approaches were compared in this work investigating two different LBFs loaded with the BCS-class II drugs celecoxib and fenofibrate. Results: When inducing supersaturation by heat, drug loads of 238% for celecoxib and 278% for fenofibrate could be achieved relative to the solubility at ambient temperature. Using the solvent-based approach, drug loads of up to 475% for celecoxib and 557% for fenofibrate could be prepared in the LBFs using dichloromethane (DCM) as the volatile solvent. However, those highly supersaturated preparations showed suboptimal physical stability and quickly led to precipitation when the LBFs were stored at ambient temperature. In addition, selected formulations were analyzed with GC-headspace to determine the residual DCM after solvent evaporation using a vacuum evaporator. This analysis revealed that the DCM content exceeded regulatory requirements, with up to 21,883 ppm DCM in the formulations. Conclusions: Overall, the relatively high residual DCM concentration and the suboptimal physical stability do not make the approach easily usable for generating supersaturated lipid-based formulations. Full article

The critical consequence of climate change resulting from global warming is the increase in temperature. In combined cycle power plants (CCPPs), the Electric Power Output (PE) is affected by changes in both Ambient Temperature (AT) and Sea Surface Temperature (SST), particularly in plants utilizing seawater cooling systems. As AT increases, air density decreases, leading to a reduction in the mass of air absorbed by the gas turbine. This change alters the fuel–air mixture in the combustion chamber, resulting in decreased turbine power. Similarly, as SST increases, cooling efficiency declines, causing a loss of vacuum in the condenser. A lower vacuum reduces the steam expansion ratio, thereby decreasing the Steam Turbine Power Output. In this study, the effects of increases in these two parameters (AT and SST) due to global warming on the PE of CCPPs are investigated using various regression analysis techniques, Artificial Neural Networks (ANNs) and a hybrid model. The target variables are condenser vacuum (V), Steam Turbine Power Output (ST Power Output), and PE. The relationship of V with three input variables—SST, AT, and ST Power Output—was examined. ST Power Output was analyzed with four input variables: V, SST, AT, and relative humidity (RH). PE was analyzed with five input variables: V, SST, AT, RH, and atmospheric pressure (AP) using regression methods on an hourly basis. These models were compared based on the Coefficient of Determination (R²), Mean Absolute Error (MAE), Mean Absolute Percentage Error (MAPE), Mean Square Error (MSE), and Root Mean Square Error (RMSE). The best results for V, ST Power Output, and PE were obtained using the hybrid (LightGBM + DNN) model, with MAE values of 0.00051, 1.0490, and 2.1942, respectively. As a result, a 1 °C increase in AT leads to a decrease of 4.04681 MWh in the total electricity production of the plant. Furthermore, it was determined that a 1 °C increase in SST leads to a vacuum loss of up to 0.001836 bar_a. Due to this vacuum loss, the steam turbine experiences a power loss of 0.6426 MWh. Considering other associated losses (such as generator efficiency loss due to cooling), the decreases in ST Power Output and PE are calculated as 0.7269 MWh and 0.7642 MWh, respectively. Consequently, the combined effect of a 1 °C increase in both AT and SST results in a 4.8110 MWh production loss in the CCPP. As a result of a 1 °C increase in both AT and SST due to global warming, if the lost energy is to be compensated by an average-efficiency natural gas power plant, an imported coal power plant, or a lignite power plant, then an additional 610 tCO₂e, 11,184 tCO₂e, and 19,913 tCO₂e of greenhouse gases, respectively, would be released into the atmosphere. Full article

The exploitation of fusion energy in tokamak reactors relies on efficient and reliable tritium management. The tritium needed to sustain the deuterium–tritium fusion reaction is produced in the Li-based blanket surrounding the plasma chamber, and, therefore, the effective extraction and purification of the tritium bred in the Li-blankets is needed to guarantee the tritium self-sufficiency of future fusion plants. This work introduces a new technology for the extraction of tritium from the Pb–Li eutectic alloy used in liquid blankets. Process units based on the concept of Membrane Gas–Liquid Contactor (MGLC) have been studied for the extraction of tritium from the Pb–Li in the Water Cooled Lithium Lead blankets of the DEMO reactor. MGLC units have been preliminarily designed and then compared in terms of the permeation areas and sizes with the tritium extraction technologies presently under study, namely the Permeator Against Vacuum (PAV) and the Gas–Liquid Contactors (GLCs). The results of this study show that the DEMO WCLL tritium extraction systems using MGLC require smaller permeation areas and quicker permeation kinetics than those based on PAV (Permeator Against Vacuum) devices. Accordingly, the MGLC extraction unit exhibits volumes smaller than those of both PAV and GLC. Full article

In this paper, a new TaMoNbTiZr multielement alloy has been designed, using chemical elements that exhibit extremely low bio-toxicity for the human body. The alloy was obtained by melting in vacuum arc remelting (VAR) equipment MRF ABJ 900 from high-purity chemical elements (99.5%) as mini-ingots having about 40 g weight each. The biocompatible alloys underwent changes in hardness after performing the annealing at 900 °C for 2 h, followed by cooling in water. The new alloy had an average hardness in the cast state of 545 HV0.5, and after heat treatment, it hardened to a value of 984 HV0.5, over 40% higher than that in the casting state, which ensures a longer working period. To use them as materials for medical instruments, their biocompatibility was highlighted through specific laboratory tests. For this, mesenchymal stem cells isolated from bone tissue and a human fibroblast cell line were cultured in vitro on the TaMoNbTiZr alloy’s surface. The biocompatibility of the alloy with the biological environment was evaluated by analyzing cell viability, adhesion, and proliferation, and in parallel, the cytolysis effects manifested by the increase in lactate dehydrogenase activity in the culture media were analyzed. Full article

Organic phase change materials (PCMs) have been widely studied for thermal management applications, such as the passive cooling of silicon photovoltaic (PV) cells, whose efficiency is negatively affected by rising temperature. The aim of the present study is to investigate the shape stabilization of PCMs by using expanded graphite (EG) as a highly conductive supporting matrix, leading to the development of novel PCM/EG composites with melting temperatures in the range 30–50 °C. Different organic PCMs were selected and compared, i.e., two paraffins and a eutectic mixture of fatty acids (myristic and palmitic acid). The EG was vacuum-impregnated with organic PCMs, and, subsequently, powdery composites were cold-compacted to obtain dense heat-absorbing panels. The thermal conductivity was enhanced up to 6 W/m·K, guaranteeing composites with a melting enthalpy of 160 to 220 J/g. This study found that the EG vacuum impregnation method is suitable for PCM shape stabilization, and cold compaction allows for the formation of solid panels with improved thermal response. The obtained PCM/EG composites were utilized to produce panels of about 6 × 6 × 2 cm³, suitable for the thermal management of silicon PV. Full article

The Er-Zr-Sc-modified Al-Mg alloys produced by additive manufacturing (AM) exhibit good formability and excellent mechanical properties, and present great potential for applications in the fields of aerospace and automotive fields. In this work, the preparation process of Al-4.5Mg-0.7Er-0.5Zr-0.3Sc high-strength aluminum alloy powder for additive manufacturing by vacuum induction melting gas atomization (VIGA) was investigated. With the goal of obtaining excellent sphericity and higher powder yield in the particle size range of 15~53 μm, a new type atomizer with optimized convergence angle and tube extension length was designed based on finite element numerical simulation and experimental research, and the optimal atomization processing parameters were determined. The results revealed that when the convergence angle was 32° and the extension length was 5 mm, the large negative pressure and suction force at the tube outlet could facilitate the smooth flow of the melt and a refined powder particle size; when the melt temperature was 800 °C and the atomization pressure was 3.25 Mpa, the melt had low viscosity and the atomization gas could fully interact with the melt. Meanwhile, the melt droplets had suitable cooling conditions, avoiding the generation of irregular powders and improving the powder sphericity. Under the above optimal processing parameters, the prepared powders were spherical or nearly spherical with fine particle size and a high yield of about 39.45%. Full article

Porous 316L stainless steel has a low density and high specific surface area, and is easy to process due to the large number of pores within it, making it ideal for applications such as piping in the chemical and food industries, as a medical tool, or as a fuel cell pole plate material. Nitriding treatment can further improve the hardness and strength of porous stainless steel. In this paper, a method combining vacuum sintering and nitriding treatment was proposed, i.e., 316L stainless steel powder was used as the raw material, and porous 316L was sintered in a vacuum tube furnace, in which the porous stainless steel was nitrided with nitrogen gas during the cooling process. In the research process, thermodynamic calculation and differential thermal analysis were used to determine the optimum nitriding temperature range of 700 °C~850 °C and nitriding pressure of 0.4 MPa~0.8 MPa. With the increase in nitriding temperature and pressure, the nitrogen content in the sample increased, and the nitrogen content of porous 316L stainless steel after nitriding was 0.03%~0.86%. The results show that nitrogen exists exclusively in solid solution at nitriding temperatures of 700 °C and 750 °C. At nitriding temperatures of 800 °C and 850 °C, the nitrogen existed in both solid solution and chromium nitride (CrN), and the Vickers hardness at 0.08 MPa and 850 °C was 135 HV, which was 2.82 times higher than that before nitriding. The compressive strength of the specimens was maximum at a nitriding pressure of 0.04 MPa and 850 °C. The corrosion resistance of the specimens is optimized when the nitriding pressure is 0.04 MPa and the temperature is 800 °C. Full article