Search Results (71)

Land-use changes cause disturbance to sediment dynamics, increasing downstream sediment loads discharged into ecosystems and provoking impacts on stream quality and damage to current stormwater infrastructures. Wastewater nature-based solutions (NBSWT) are bioretention techniques that alleviate downstream degradation caused by runoff sediment accumulation and are projected as an off-line street device that enhances treatment of runoff contaminant loads. This research assesses the economic, social, and environmental benefits from sediment load reduction in runoff by designing a new NBSWT in a selected urban area of the Mantiqueira Mountain Range (São Paulo, Brazil), considered an irreplaceable protected area for biodiversity and urban water supply. To achieve this quantification, the shadow prices methodology has been used. The results obtained here show the adaptive capacity that NBSWT have according to the territory and its climatic particularities, quantified at USD 40,475,255. This value demonstrates that the retention of runoff sediment generates a direct environmental benefit related to the ecosystem improvement of the river system located downstream, preserving its environmental and social importance. Hence, this study demonstrates the potential of using shadow prices methodology as a management tool for quantifying the environmental benefit of removing runoff solids by using NBSWT in developing urban areas. Full article

In response to the European Union’s revised Urban Wastewater Treatment Directive, which mandates enhanced monitoring and advanced treatment of micropollutants, this study was conducted. It took place within the Coastal Landscape Park (CLP), a Natura 2000 protected area in northern Poland. The focus was on the municipal wastewater treatment plant in Jastrzębia Góra, located in a region exposed to seasonal tourist pressure and discharging effluent into the Czarna Wda River. A total of 90 wastewater samples were collected during five monitoring campaigns (July, September 2021; February, May, July 2022) and analysed for 13 pharmaceuticals and personal care products (PPCPs) using ultra-high-performance liquid chromatography tandem mass spectrometry with electrospray ionisation (UHPLC-ESI-MS/MS). The monitoring included both untreated (UTWW) and treated wastewater (TWW) to assess the PPCP removal efficiency and persistence. The highest concentrations in the treated wastewater were observed for metoprolol (up to 472.9 ng/L), diclofenac (up to 3030 ng/L), trimethoprim (up to 603.6 ng/L) and carbamazepine (up to 2221 ng/L). A risk quotient (RQ) analysis identified diclofenac and LI-CBZ as priority substances for monitoring. Multivariate analyses (PCA, HCA) revealed co-occurrence patterns and seasonal trends. The results underline the need for advanced treatment solutions and targeted monitoring, especially in sensitive coastal catchments with variable micropollutant presence. Full article

The escalating global demand for fresh water, driven by urbanization and industrial growth, underscores the need for sustainable water management, particularly in the water-intensive construction sector. Although prior studies have primarily concentrated on treated wastewater, the practical viability of utilizing untreated wastewater has not been thoroughly investigated—especially in developing nations where treatment expenses frequently impede actual implementation, even for non-structural uses. While prior research has focused on treated wastewater, the potential of untreated or partially treated wastewater from diverse industrial sources remains underexplored. This study investigates the feasibility of incorporating wastewater from textile, sugar mill, service station, sewage, and fertilizer industries into concrete paver block production. The novelty lies in a dual approach, combining experimental analysis with XGBoost-based machine learning (ML) models to predict the impact of key physicochemical parameters—such as Biochemical Oxygen Demand (BOD), Chemical Oxygen Demand (COD), and Hardness—on mechanical properties like compressive strength (CS), water absorption (WA), ultrasonic pulse velocity (UPV), and dynamic modulus of elasticity (DME). The ML models showed high predictive accuracy for CS (R² = 0.92) and UPV (R² = 0.97 direct, 0.99 indirect), aligning closely with experimental data. Notably, concrete pavers produced with textile (CP-TXW) and sugar mill wastewater (CP-SUW) attained 28-day compressive strengths of 47.95 MPa and exceeding 48 MPa, respectively, conforming to ASTM C936 standards and demonstrating the potential to substitute fresh water for non-structural applications. These findings demonstrate the viability of using untreated wastewater in concrete production with minimal treatment, offering a cost-effective, sustainable solution that reduces fresh water dependency while supporting environmentally responsible construction practices aligned with SDG 6 (Clean Water and Sanitation) and SDG 12 (Responsible Consumption and Production). Additionally, the model serves as a practical screening tool for identifying and prioritizing viable wastewater sources in concrete production, complementing mandatory laboratory testing in industrial applications. Full article

The recent Directive EU/2024/3019, a recast of the previous 1991 Directive 91/271/EEC concerning urban wastewater treatment, introduces new obligations concerning effluents requirements and overall energy management in urban wastewater systems. In addition to increased levels of treatment (including extended tertiary and quaternary pollutants removal), the Directive introduces the obligation for treatment facilities to become “energy neutral” at the national sectoral level, increasing reliance on energy optimization and recovery from internal processes and external renewable energy sources. In order to achieve this objective, an obligation to periodically conduct energy audits is introduced; however, while this practice is commonly carried out in residential and industrial buildings, guidelines for its implementation in treatment facilities are currently not precisely defined. The paper summarizes current issues on wastewater sector energy audits, discussing the current state-of-the-art and the expected requirements to conduct such audits. It then discusses the causes of possible facility inefficiencies and their possible solutions from both permanent and transient perspectives. Finally, it addresses the issue of energy neutrality requirement, and the role of renewable energy sources contribution, both natural and internal (process-related) to the sector’s energy efficiency. Full article

Drug removal from urban wastewater (UW) is a topic of growing interest. The new European Directive addresses this problem by introducing quaternary treatment by 2045, as part of the “Zero Pollution” plan from a One Health perspective. In this context, the role of microalgae remains very promising in achieving clean and safe effluents, although its cost–benefit ratio needs to be carefully evaluated. The purpose of this review is to disclose the latest approaches to drug removal and energy recovery from UWs adopting different algae (Chlorella spp., Galdieria spp., and Scenedesmus spp.), to provide a detailed background for further research towards the development of new effective strategies on UW remediation while producing clean energy. We examined the most recent studies, considering most drugs found in wastewater, their management, as well as strategies used to recover energy while being mindful of a circular economy. There is growing interest in algae-based systems. The latest findings on algae–bacteria consortia show that it could be a better alternative to suspended biomass and represent a way to manage drug waste. This finding suggests that large-scale experiments should be conducted to confirm the potential benefits of such waste treatments. Full article

This study proposes and evaluates a two-step phosphorus (P) recovery strategy that combines chemical precipitation with adsorption to comply with the updated EU Urban Wastewater Treatment Directive (Directive (EU) 2024/3019), which sets stricter limits on nutrient discharge and promotes resource recovery. The objective was to enhance the P removal efficiency beyond that achieved by conventional precipitation. A laboratory-scale design of experiments was conducted using real wastewater with an initial P concentration of 10 mg P/L post-precipitation and was extended to 1 and 40 mg P/L to assess broader applicability. The optimal lab-scale conditions (30 cm bed height and 5 mL/min flow rate) resulted in a saturated bed fraction (FSB) of 0.425 and a breakthrough time of 126 min. The process was successfully scaled up to a column with a height of 60 cm and a diameter of 4 cm, achieving a higher FSB (0.764), improved adsorption capacity (84.1 mg P/kg), and reduced unused bed (40%). The integrated system maintained effluent P levels below 0.5–0.7 mg P/L for over 400 min, demonstrating regulatory compliance and operational reliability. These findings confirmed the feasibility and scalability of combining precipitation with adsorption for enhanced P recovery in wastewater treatment systems. Full article

Anthropogenic pollution of watersheds significantly threatens aquatic ecosystems, biodiversity, and human health. The present review examines the primary sources of contamination in river catchments, including industrial effluents, agricultural runoff, and urban wastewater discharge. The presence of pollutants degrades water quality, disrupting aquatic habitats and leading to adverse outcomes, including biodiversity loss, eutrophication, and declining fish populations. It also focuses on strategic mitigation approaches, including implementing stricter waste management regulations, adopting sustainable agricultural practices, improving wastewater treatment infrastructure, and public education initiatives. The article summarizes several biotechnological techniques developed to decrease the impact of farming activities on water quality. It also emphasises directions that could be followed concerning specific water chemical indicators, such as the residual quantity of heavy metals. Emphasis is placed on the need for integrated policy frameworks and cross-sector collaboration to safeguard freshwater systems and ensure long-term environmental sustainability. Full article

Pharmaceutical residues are emerging contaminants of growing concern due to their persistence and poor removal efficiency in conventional wastewater treatment plants. This study evaluates UVC photolysis with type C ultraviolet radiation (UVC) and UVC/TiO₂ photocatalysis of a mixture of four pharmaceuticals—atenolol (ATL), acetaminophen (ACM), clofibric acid (CLA), and antipyrine (ANT)—commonly found in treated urban wastewater. A comprehensive kinetic model was developed to describe their degradation, taking into account the generation of reactive oxygen species (ROS): hydroxyl (HO^●), superoxide ion (O₂^●−) radicals, and singlet oxygen (¹O₂), along with their reactions with both the pharmaceuticals and dissolved organic matter. Direct quantum yields were determined as 8.05 × 10⁻³ mol·Einstein⁻¹ for ATL, 1.93 × 10⁻³ for ACM, 3.12 × 10⁻¹ for CLA, and 5.12 × 10⁻² for ANT. In addition, rate constants of the reactions between singlet oxygen and pharmaceuticals were 9.93, 1.3 × 10⁶, 1.18 × 10², and 1.14 × 10⁴ M⁻¹s⁻¹ for ATL, ACM, CLA, and ANT, respectively. Scavenger experiments confirmed the key role of the ROS involved. The model reproduces the inhibitory effect of natural organic matter in secondary effluent and, in most cases, treated, accurately predicts the concentration profiles of the pharmaceuticals. Under photocatalytic conditions (0.10 g·L⁻¹ TiO₂), all compounds were completely degraded in less than 15 min. This validated model provides a useful tool for understanding the degradation mechanisms of pharmaceutical mixtures and for supporting the design of effective water strategies based on photochemical processes. Full article

Contaminants of emerging concern (CECs) comprise a diverse group of substances whose presence in the environment is of increasing concern due to their potential negative effects on human health and the environment. Multiple studies have concluded that nanofiltration (NF) and reverse osmosis (RO) membrane separation mechanisms are effective barriers for organic pollutants, showing generally high removal efficiency. In this study, nine indicator CECs included in the Directive (EU) 2024/3019 concerning urban wastewater treatment were selected and used as a reference to calculate the removal percentage of all micropollutants present in the influent of wastewater treatment plants (WWTPs). According to the regulations, a minimum average removal percentage of 80% of the influent load must be achieved by analyzing at least six out of a set of twelve micropollutants, including those considered in this study. The treatments were conducted using three commercial RO membranes and one commercial NF membrane. Our findings indicate that membrane technology alone can remove over 80% of the micropollutants studied, except benzotriazole. An analysis of the separation mechanisms was carried out to understand the performance of each CEC in relation to each membrane type, taking into account pollutant physicochemical properties and observed removal efficiencies. Full article

The reuse of reclaimed water is essential for sustainable water management in arid regions. However, despite advancements in Wastewater Treatment Plants (WWTPs), certain micropollutants may persist. To address these challenges, the recently enacted European Urban Wastewater Treatment Directive (UWWTD) has established strict standards focused on monitoring twelve specific indicator compounds. In line with this, the present study aims to evaluate the concentrations and potential risks of these twelve UWWTD-designated compounds across various water sources, including surface water, groundwater, and effluents from a WWTP in the southeast of Spain. Although none of the evaluated water sources are, as expected, intended for human consumption, risks were assessed based on worst-case scenarios that could amplify their impact. The study assessed potential risks to human health across different age groups and ecosystems, focusing on key organisms such as fish, daphnia, and algae, using empirical assessment approaches. The risk assessment identified a low risk for most compounds regarding human health, except for citalopram (HRQ = 19.116) and irbesartan (HRQ = 1.104), which showed high human risk quotients (HQR > 1) in babies, particularly in reclaimed water. In terms of ecotoxicological risk, irbesartan presented the highest ecological risk quotient (ERQ = 3.500) in fish, followed by clarithromycin, with algae (ERQ = 1.500) being the most vulnerable organism. Furthermore, compounds like citalopram, venlafaxine, and benzotriazole exhibited moderate ecological risks (ERQ between 0.1 and 1) in the reclaimed water, and their risk was reduced in surface water and groundwater. Finally, this study discussed the potential impacts of elevated concentrations of these emerging compounds, emphasizing the need for rigorous wastewater monitoring to protect human health and ecosystem integrity. It also revealed notable differences in risk assessment outcomes when comparing two distinct evaluation approaches, further highlighting the complexities of accurately assessing these risks. Full article

Illicit or inappropriate inflows into urban drainage systems cause significant operational issues, impacting utilities, communities, and the environment. The continued deterioration of system assets increases these inflows. Groundwater infiltration, rain-derived inflows, and misconnections contribute to reduced system performance, amongst other detrimental inflows. Climate change effects and the revised EU Wastewater Treatment Directive put pressure on utilities to reduce combined sewage and polluted stormwater discharges and overflows while promoting carbon neutrality. The effective management of undue inflows requires identifying cause–effect relationships and quantifying their consequences. This paper proposes a performance-based methodology with metrics and reference values to assess and categorise various undue inflows in wastewater, stormwater, or combined systems. This approach allows the tracking of performance over time, the comparing of systems, and requires data commonly available to utilities. The reliable quantification of inflows depends on the availability and accuracy of flow data from relevant system locations, rainfall data, and pertinent contextual information. This paper uses data from eight utilities and the Portuguese regulator to validate its approach, calculate metrics, refine reference values and enable better-targeted control measures. The results enhance the value of a unified approach to this problem in making better decisions to improve the urban water drainage system’s performance, enhance pollution control, and promote sustainable water management. Full article

This research focuses on the removal of emerging contaminants (CEC) present in synthetic aqueous matrices. Azole compounds were selected as CEC of interest due to their persistence and toxicity, particularly the triazole and oxazole groups. These compounds are also trace contaminants listed in the proposed revision of Directive 91/271/EEC on urban wastewater treatment and the 3rd European Union Observation List (Implementing Decision EU 2020/116), highlighting their regulatory importance. The draft Directive includes the implementation of quaternary treatments to achieve the highest possible removal rates of micropollutants. Among the technologies used on a large scale are some advanced oxidation processes (AOP), often combined with adsorption on activated carbon (AC). Laboratory-scale pilot plants have been designed and operated in this research, including UV photolysis and oxidation with H₂O₂ and adsorption with GAC. The results demonstrate that UV photolysis is able to remove all the selected CECs except fluconazole, reaching eliminations higher than 86% at high doses of 31.000 J/m². Treatment by H₂O₂ achieved removals of 4 to 55%, proving to be ineffective in the degradation of persistent compounds when acting as a single technology. Adsorption by AC is improved with longer contact times, reaching removals above 80% for benzotriazole and methyl benzotriazole at short contact times, followed by sulfamethoxazole and tebuconazole. Fluconazole had a mean adsorption capacity at low contact times, while metconazole and penconazole showed low adsorption capacities. Full article

Ensuring sustainable consumption of water, which is essential for human development, is not sufficient, therefore, there is an urgent need to improve reuse of treated wastewater. This paper reviews the newest EU legislation related to reclaimed water reuse, which is the main driver for change. While there are some positive developments in the EU, the paper argues that the current EU legislation does not sufficiently encourage circular solutions, especially on how to deal with any bottleneck effects, which prevent to fully utilise wastewater. This reflection is noted based on the national and regional developments in Italy with some comparison with other Southern countries, such as Greece and Spain in attempt to identify good practices as well as any barriers for the reclaimed water to be reused. Full article

With the rapid development of urbanization and the widespread adoption of wastewater treatment facilities, the volume of sludge produced has steadily increased. Hydrothermal oxidation (HTO) technology offers an effective solution for sludge reduction, harmless disposal, and resource recovery, making it a highly promising method for sludge treatment. In recent years, HTO has attracted significant attention due to its efficiency and environmental benefits. This paper provides a detailed explanation of the fundamental principles of HTO in sludge treatment, with a focus on the removal of organic pollutants, nitrogen transformation, and phosphorus recovery. The influence of key operational parameters, such as reaction temperature, time, initial oxygen pressure, and pH, on the performance of HTO treatment is also explored. In addition, the research status of HTO sludge treatment and an example of product recovery after treatment are also discussed. It examines the challenges associated with scaling up HTO for large-scale sludge treatment, along with potential research directions for future work. Special attention is given to the innovation of catalysts, with the goal of achieving self-catalysis in sludge treatment. Moreover, considering that ammonia nitrogen (NH₃-N) is a major intermediate product in HTO, its removal, as well as the prediction and planning of other unintended products, remains a key issue. Further areas of interest include improving sludge dewatering performance and enhancing the production of valuable single carboxylic acids, which can boost resource recovery efficiency. This paper also highlights the diversification of sludge applications after HTO treatment. By providing insights into future development trends, this review offers valuable references for further research and practical applications. The ultimate goal is to support the development of HTO as a sustainable and efficient solution for sludge treatment, addressing environmental concerns while maximizing resource recovery opportunities. Full article

Antibiotics, widely used pharmaceuticals, enter wastewater treatment systems and ultimately the aquatic environment through the discharge of wastewater from residential areas, hospitals, breeding farms, and pharmaceutical factories, posing potential ecological and health risks. Due to the misuse and discharge of antibiotics, the spread of antibiotic resistance genes (ARGs) in water bodies and significant changes in microbial community structure have direct toxic effects on aquatic ecosystems and human health. This paper summarizes the occurrence of antibiotics in wastewater treatment systems and their ecological and health risks, focusing on the impact of antibiotics on aquatic microorganisms, aquatic plants and animals, and human health. It points out that existing wastewater treatment processes have poor removal capabilities for antibiotics and even become an important pathway for the spread of some antibiotics. In terms of detection technology, the article discusses the application of immunoassays, instrumental analysis, and emerging sensor technologies in detecting antibiotics in sewage, each with its advantages and limitations. Future efforts should combine multiple technologies to improve detection accuracy. Regarding the removal methods of antibiotics, the paper categorizes physical, chemical, and biodegradation methods, introducing various advanced technologies including membrane separation, adsorption, electrochemical oxidation, photocatalytic oxidation, and membrane bioreactors. Although these methods have shown good removal effects in the laboratory, there are still many limitations in large-scale practical applications. This paper innovatively takes urban wastewater treatment systems as the entry point, systematically integrating the sources of antibiotics, environmental risks, detection technologies, and treatment methods, providing targeted and practical theoretical support and technical guidance, especially in the removal of antibiotics in wastewater treatment, on a scientific basis. Future efforts should strengthen the control of antibiotic sources, improve the efficiency of wastewater treatment, optimize detection technologies, and promote the formulation and implementation of relevant laws and standards to more effectively manage and control antibiotic pollution in the aquatic environment. Full article