Search Results (97)

Polyimide, a class of high-performance polymers, is renowned for its exceptional thermal stability, mechanical strength, and chemical resistance. However, in the context of high-integration and high-frequency electronic packaging, polyimides face critical challenges including relatively high dielectric constants, inadequate thermal conductivity, and mechanical brittleness. Recent advances have focused on molecular design and composite engineering strategies to address these limitations. This review first summarizes the intrinsic properties of polyimides, followed by a systematic discussion of chemical synthesis, surface modification approaches, molecular design principles, and composite fabrication methods. We comprehensively examine both conventional polymerization synthetic routes and emerging techniques such as microwave-assisted thermal imidization and chemical vapor deposition. Special emphasis is placed on porous structure engineering via solid-template and liquid-template methods. Three key modification strategies are highlighted: (1) surface modifications for enhanced hydrophobicity, chemical stability, and tribological properties; (2) molecular design for optimized dielectric performance and thermal stability; and (3) composite engineering for developing high-thermal-conductivity materials with improved mechanical strength and electromagnetic interference (EMI) shielding capabilities. The dielectric constant of polyimide is reduced while chemical stability and wear resistance can be enhanced through the introduction of fluorine groups. Ultra-low dielectric constant and high-temperature resistance can be achieved by employing rigid monomers and porous structures. Furthermore, the incorporation of fillers such as graphene and boron nitride can endow the composite materials with high thermal conductivity, excellent EMI shielding efficiency, and improved mechanical properties. Finally, we discuss representative applications of polyimide and composites in electronic device packaging, EMI shielding, and thermal management systems, providing insights into future development directions. Full article

Hydrogenated amorphous carbon (a-C:H) films are widely valued for their excellent mechanical strength and low friction, but their performance significantly degrades at elevated temperatures, limiting practical applications in aerospace environments. In this work, we aimed to enhance the high-temperature tribological behavior of a-C:H films through controlled silicon (Si) doping. A series of a-C:H:Si films with varying Si contents were fabricated via direct current magnetron sputtering, and their microstructure, mechanical properties, and friction behavior were systematically evaluated from room temperature up to 400 °C. Results show that moderate Si doping (8.3 at.%) substantially enhances hardness and wear resistance, while enabling ultralow friction (as low as 0.0034) at 400 °C. This superior performance is attributed to the synergistic effects of transfer layer formation, preferential Si oxidation, and tribo-induced graphitization. This study provides new insights into the high-temperature lubrication mechanisms of Si-doped a-C:H films and demonstrates the critical role of Si content optimization, highlighting a viable strategy for extending the thermal stability and lifespan of solid-lubricating films. Full article

This study develops novel superhydrophobic UHMWPE/PTFE/PVA composites via hot-pressing sintering to achieve ultra-low friction and enhanced wear resistance. The ternary system synergistically combines UHMWPE’s mechanical stability, PTFE’s lubricity, and PVA’s dispersion/binding capability. Results show PTFE disrupts UHMWPE crystallization, reducing melting temperature by 2.77 °C and enabling energy dissipation. All composites exhibit hydrophobicity, with optimal formulations (UPP3/UPP4) reaching superhydrophobicity. Tribological testing under varied loads and frequencies reveals low friction, where UPP1 achieves a COF of 0.043 and wear rate below 1.5 × 10⁻⁵ mm³/(N·m) under low-load conditions. UHMWPE oxidative degradation forming carboxylic acids at the interface (C=O at 289 eV, C–O at 286 eV). Formation of tungsten oxides (WO₃/WO₂), carbides (WC), and transfer films on steel counterparts. A four-step tribochemical reaction pathway is established. PVA promotes uniform transfer films, while PTFE lamellar peeling and UHMWPE chain stability enable sustained lubrication. Carbon-rich stratified accumulations under high-load/speed increase COF via abrasive effects. The composites demonstrate exceptional biocompatibility and provide a scalable solution for biomedical and industrial tribological applications. Full article

Diamond-like carbon (DLC) coatings have emerged as a focal point in advanced carbon materials research due to exceptional tribological properties, including ultralow friction coefficient, exceptional wear resistance, ultrahigh hardness, and chemical inertness. Deposition of DLC coatings on metal components represents an innovative solution to enhance wear resistance in engineering applications. However, suboptimal adhesion strength between coatings and substrates, coupled with inherent material limitations, critically compromises the tribological performance. This review systematically examines recent advances in improving the wear resistance of DLC-coated metal components. First, the fundamental wear mechanisms governing both metallic substrates and DLC coatings under service conditions are elucidated. Next, three pivotal technologies, substrate material treatment/strengthening, coating structure design, and elemental doping, all demonstrating significant efficacy in wear resistance enhancement, are critically analyzed. Furthermore, a comparative assessment of these techniques reveals the synergistic potential in hybrid approaches. Finally, a concise summary of the outlook is presented. Full article

This work studies the fabrication of CoCrFeNiMo high-entropy alloy (HEA) coatings via coaxial powder-fed laser cladding, addressing porosity and impurity issues in conventional methods. The HEA coatings exhibited eutectic/hypereutectic microstructures under all laser power conditions. A systematic investigation of laser power effects (1750–2500 W) reveals that 2250 W optimizes microstructure and performance, yielding a dual-phase structure with FCC matrix and dispersed σ phases (Fe-Cr/Mo-rich). The coating achieves exceptional hardness (738.3 HV_0.2, 3.8× substrate), ultralow wear rate (4.55 × 10⁻⁵ mm³/N·m), and minimized corrosion current (2.31 × 10⁻⁴ A/cm²) in 3.5 wt.% NaCl. The friction mechanism of the CoCrFeNiMo HEA coating is that in high-speed friction and wear, the oxide film is formed on the surface of the coating, and then the rupture of the oxide film leads to adhesive wear and abrasive wear. The corrosion mechanism is the galvanic corrosion caused by the potential difference between the FCC phase and the σ phase. Full article

Silicon-doped tetrahedral amorphous carbon (ta-C:Si) coatings are promising materials for achieving ultralow friction in water-lubricated environments, attributed to the formation of Si(OH)_x-based tribofilms. However, the deposition process via filtered cathodic vacuum arc (FCVA) often introduces large particles into the film, increasing surface roughness and causing accelerated wear during the initial sliding phase, despite the high hardness of the coating. In this study, ball-on-disk tribological tests were performed to investigate the wear behavior of ta-C:Si coatings under water lubrication. Friction coefficients, wear volume, and surface roughness were analyzed over various sliding durations. The Archard wear equation and the plasticity index were used to analyze wear and contact behavior. The friction coefficient decreased from 0.14 to 0.04 within the initial 100 m section, and the surface roughness of ta-C:Si decreased sharply from 0.35 μm to 0.01 μm based on the Rpk parameter during 10 h. Following this period, the plasticity index decreased from an initial value of 1.1 to below 0.6, transitioning to a fully elastic contact stage, marking the onset of steady-state wear after 10 h. These results indicate that the reduction in surface roughness plays a crucial role in stabilizing wear behavior and provide insights into optimizing the long-term performance of ta-C:Si coatings in aqueous environments. Full article

Uncontrolled wear in complex multiphysics systems can cause catastrophic failures, prompting the development of empirical methods and numerical prediction models for managing system lifetimes. This study introduces a novel approach for predicting wear on lubricated sliding surfaces by integrating rough contact mechanics into a nonlocal function with a non-uniform distribution. The model considers the sliding speed, contact area, fluid pressures, lubricant properties, and surface roughness. It employs a mixed elastohydrodynamic lubrication (mixed EHL) model to simulate lubrication and wear, using a multiscale roughness model to adjust the parameters based on the wear evolution. Validated against journal bearing data, the model accurately predicted wear rates and depths, revealing distinct roughness variations depending on the lubricant viscosity. Full article

The tribological behavior of molybdenum disulfide (MoS₂) coatings was systematically investigated under various controlled gas environments in a vacuum chamber. A hemispherical steel pin was slid cyclically over a MoS₂-coated steel disk, prepared via high-speed powder spraying. The study measured both dynamic and static friction coefficients under different gaseous atmospheres, including high vacuum, helium, argon, dry air, and water vapor. In high vacuum (10⁻⁵ Pa), an ultra-low dynamic friction coefficient (µ ≈ 0.01) was observed, while increasing values were recorded with helium (µ ≈ 0.03), argon (µ ≈ 0.04), dry air (µ ≈ 0.17), and water vapor (µ ≈ 0.30). Static friction coefficients followed a similar trend, decreasing significantly upon evacuation of water vapor or injection of inert gases. Surface analyses revealed that friction in vacuum or inert gases promoted smooth wear tracks and basal plane alignment of MoS₂ crystallites, while exposure to water vapor led to rougher, more disordered wear surfaces. Mass spectrometry and energetic modeling of physisorption interactions provided further insights into gas–solid interfacial mechanisms. These results demonstrate that the tribological performance of MoS₂ coatings is highly sensitive to the surrounding gas environment, with inert and vacuum conditions favoring low friction through enhanced basal plane orientation and minimal gas–surface interactions. In contrast, water vapor disrupts this structure, increasing friction and surface degradation. Understanding these interactions is crucial for optimizing MoS₂-based lubrication systems in varying atmospheric or sealed environments. Full article

The automotive industry faces increasing challenges due to fuel scarcity and pollutant emissions, necessitating the implementation of strategies that optimize engine performance while minimizing the environmental impact. This study aimed to analyze the influence of oil viscosity and fuel quality on the engine performance and pollutant emissions in an internal combustion engine. A Response Surface Methodology (RSM)-based experimental design was employed. Three oil viscosity levels (SAE 5W-30, 10W-30, and 20W-50) and three fuel quality levels (87, 92, and 95 octane) were evaluated using a Chevrolet Grand Vitara 2.0L (General Motors, Quito, Ecuador) tested on a dynamometer. The oil grades were selected to represent a practical range of viscosities commonly used in commercial vehicles operating under local conditions. The results indicate that using lower-viscosity oil (SAE 5W-30) increased the engine power by up to 6.25% compared to when using SAE 20W-50. Additionally, using higher-octane fuel led to an average power increase of 1.49%, attributed to improved combustion stability and the ability to operate at a more advanced ignition timing without knocking. The emissions analysis revealed that high-viscosity oil at high RPMs increased CO₂ emissions to 14.4% vol, whereas low-viscosity oil at low RPMs reduced CO₂ emissions to 13.4% vol. Statistical analysis confirmed that the engine speed (RPM) was the most influential factor in emissions (F = 163.11 and p < 0.0001 for CO₂; F = 247.02 and p < 0.0001 for NOx), while fuel quality also played a significant role. These findings suggest that optimizing the oil viscosity and selecting the appropriate fuel can enhance engine efficiency and reduce emissions, thereby contributing to the development of more sustainable automotive technologies. Future research should explore the use of ultra-low-viscosity lubricants (SAE 0W-20) and assess their long-term effects on engine wear. Full article

Ultra-high molecular weight polyethylene (UHMWPE) fiber-reinforced concrete (UHMWPE-FRC) is a hard–soft multiphase hybrid composite with exceptional toughness and impact resistance compared to conventional concrete. However, its cutting characteristics and processing performance have not been sufficiently investigated, potentially causing accelerated saw blade wear, higher energy consumption, and poor cutting quality, thus increasing project costs and duration. In order to intelligently evaluate the performance of diamond saw blades when cutting UHMWPE-FRC, a feature extraction method, based on feature classification and an improved Hilbert–Huang transform (HHT), is proposed, which consider Improved Complete Ensemble Empirical Mode Decomposition with Adaptive Noise (ICEEMDAN) and wavelet threshold de-noising. By conducting the cutting experiments, the cutting force was analyzed by the improved HHT, in terms of noise reduction and time-frequency. Five types of characteristics were preliminarily screened, including depth of cut (a_p), cutting speed (V_c), feed rate (V_f), concrete strength, and the type of concrete. A feature correlation analysis method for UHMWPE-FRC cutting, based on feature classification, is proposed. The five features were classified into continuous variable features and unordered categorical variable features; correlation analyses were carried out by Spearman correlation coefficient testing and Kruskal–Wallis and Dunn’s testing, respectively. It was found that the a_p and concrete strength exhibited a strong positive correlation with cutting force, making them the primary influencing factors. Meanwhile, the influence of aggregates on cutting force can be identified in the low-frequency range, while the influence of fibers can be identified in the high-frequency range. The feature classification-based correlation analysis effectively distinguishes the influence of V_c on cutting force. Full article

The impact of ice and snow in seasonally frozen regions has led to a significant decline in the flatness and skid resistance of highway pavements, creating severe traffic safety hazards. With economic development driving the transition from road construction to maintenance, this study proposes enhancing Ultra-Thin Wearing Course (UTWC) maintenance materials with anti-icing performance and snow-melting properties. The study first employed the Marshall mix design method to develop gradations for two common types of UTWC asphalt mixtures: the dense-graded GT-8 and the open-graded NovaChip^® Type-B. Using the volume substitution method, aggregates were replaced with equivalent volumes of ceramic grains. The optimal asphalt–aggregate ratios for the mixtures with varying ceramic grain contents were determined, and the influence of ceramic grains content on the asphalt–aggregate ratio was analyzed. The results indicate that the optimal asphalt–aggregate ratio increases with higher ceramic grains content. Subsequently, the high-temperature performance, low-temperature performance, and water stability of UTWC with varying ceramic grain contents were evaluated. Overall, NovaChip^® gradation mixtures demonstrated superior road performance compared to GT-8 gradation mixtures. Moreover, an increase in ceramic grains content enhanced the high-temperature performance of UTWC but moderately reduced its low-temperature performance and water stability. Finally, the effects of different ceramic grain contents and snowmelt agent types on the anti-icing and snowmelt properties of UTWC were examined. The results revealed that higher ceramic grains content improved snowmelt effectiveness. Considering the road performance of the specimens, a ceramic grains content of 40% was recommended. Furthermore, calcium chloride (CaCl₂) exhibited superior anti-icing performance compared to other snowmelt agents. Full article

The water-lubricated bearing plays a crucial role in the ship propulsion system, significantly impacting vessel safety. However, under the harsh working conditions of low-speed and heavy-load, the lubrication state of water-lubricated bearings is usually poor, leading to serious friction and wear. To improve the tribological performance of composites and reduce friction, three short fibers (ultra-high-molecular-weight polyethylene fibers, basalt fibers, and bamboo fibers) with the same mass fraction (5%) were added into the melted thermoplastic polyurethane (TPU). The tribological behavior of these three composites under different loads and rotation speeds was investigated using the CBZ-1 friction and wear tester. Through the comprehensive analysis of the friction coefficient, the wear mass loss, and the surface morphology, it was confirmed that the filled fiber positively affected the tribological performance of thermoplastic polyurethane materials. The experimental results indicated that basalt fiber significantly improved the tribological performance of TPU, and the friction coefficient of the sample was only 0.088 under the working conditions of 0.5 MPa and 250 r/min, which was 70.57% lower than that of pure TPU material. And in all the tests, the minimum wear of the basalt fiber-reinforced composite is only 0.4 mg, which is also the smallest of all the materials under all conditions, and a decrease of 98.69% compared to TPU. Under high loads, ultra-high-molecular-weight polyethylene fiber and bamboo fiber-reinforced composites have smoother surfaces and exhibit better tribological properties. This study provides an experimental foundation for tribological performance enhancement for environmentally friendly, water-lubricated bearing composites. Full article

42CrMo is an ultra-high-strength, low-alloy structural steel. To enhance its surface wear resistance and prolong the service life of components, surface strengthening techniques are commonly applied. In this study, a numerical model for the laser phase transformation hardening of 42CrMo was established. The temperature field and metallurgical transformations during the laser phase transformation hardening process were investigated through numerical simulation, and the morphology of the hardened layer after laser surface treatment was predicted. The effects of key process parameters on the temperature field and the characteristics of the hardened layer were identified. The optimal parameters for single-pass laser phase transformation hardening were found to be a laser power of 1200 W, a scanning speed of 20 mm/s, and a spot diameter of 6 mm. The accuracy of the simulation results was validated through laser phase transformation hardening experiments. The results indicate that under these optimal conditions—laser power of 1200 W and a scanning speed of 20 mm/s—the hardening effect is maximized. The surface hardness reaches a maximum of 782 HV_0.2, with a cross-sectional hardness peaking at 875 HV_0.2, which is three to four times higher than the base material’s hardness, with an average surface hardness of 745 HV_0.2. Full article

In the field of industrial lubrication, solid–liquid composite lubrication (SLCL) techniques based on diamond-like carbon (DLC) coatings and lubricating oils are emerging recently, which may be applied in many fields in the near future, especially automotive industries. The tribological behaviors of SLCL systems depend strongly on the compatibility between DLC coatings and oils. This review describes the advantages of SLCL techniques by pointing out the synergistic effects between DLC coatings and lubricating oils. Then the main factors determining the tribological performance of SLCL systems are discussed in detail. Finally, a conclusion about the characteristics of reported SLCL systems is made, and a prospect about the potential development of SLCL technology is proposed. On the basis of the relevant literature, it could be found that the tribological properties of SLCL systems were influenced by many more factors compared with individual DLC lubrication or individual oil lubrication due to the complicated tribo-chemical reactions involving DLC and oil during friction. And under some optimized working conditions, the tribological performances of SLCL systems (friction and wear reduction) are superior to individual DLC lubrication and individual oil lubrication. However, the tribological performance of SLCL systems needs to be further improved (for example, to achieve superlubricity and ultra-low wear simultaneously) by adjusting the structures of DLC coatings, regulating the compositions of oils, and most importantly, enhancing the physicochemical and tribological synergies between DLC coatings and oils. This review provides a comprehensive understanding of the SLCL technology, which may be very helpful for the researchers and engineers in the field of industrial lubrication and tribology. Full article

The low viscosity of water-lubricated films compromises their load-bearing capacity, posing challenges for practical application. Enhancing the lubrication stability of these films under load is critical for the successful use of seawater-lubricated bearings in engineering. Polydopamine (PDA) shows great potential to address this issue due to its strong bio-inspired adhesion and hydration lubrication properties. Thus, PDA nanoparticles and seawater suspensions were synthesized to promote adhesive lubricating film formation under dynamic friction. The lubrication properties of PDA suspensions were evaluated on Cu ball and ultra-high molecular weight polyethylene (UHMWPE) tribo-pairs, with a detailed comparison to seawater. The results show PDA nanoparticles provide excellent adhesion and lubrication, enhancing the formation of lubricating films during friction with seawater. Under identical conditions, PDA suspensions demonstrated the lowest friction coefficient and minimal wear. At 3 N, friction decreased by 56% and wear by 47% compared to distilled water. These findings suggest a novel strategy for using PDA as a lubricant in seawater for engineering applications. Full article