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Keywords = time-varying conditions

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27 pages, 405 KiB  
Article
Comparative Analysis of Centralized and Distributed Multi-UAV Task Allocation Algorithms: A Unified Evaluation Framework
by Yunze Song, Zhexuan Ma, Nuo Chen, Shenghao Zhou and Sutthiphong Srigrarom
Drones 2025, 9(8), 530; https://doi.org/10.3390/drones9080530 - 28 Jul 2025
Abstract
Unmanned aerial vehicles (UAVs), commonly known as drones, offer unprecedented flexibility for complex missions such as area surveillance, search and rescue, and cooperative inspection. This paper presents a unified evaluation framework for the comparison of centralized and distributed task allocation algorithms specifically tailored [...] Read more.
Unmanned aerial vehicles (UAVs), commonly known as drones, offer unprecedented flexibility for complex missions such as area surveillance, search and rescue, and cooperative inspection. This paper presents a unified evaluation framework for the comparison of centralized and distributed task allocation algorithms specifically tailored to multi-UAV operations. We first contextualize the classical assignment problem (AP) under UAV mission constraints, including the flight time, propulsion energy capacity, and communication range, and evaluate optimal one-to-one solvers including the Hungarian algorithm, the Bertsekas ϵ-auction algorithm, and a minimum cost maximum flow formulation. To reflect the dynamic, uncertain environments that UAV fleets encounter, we extend our analysis to distributed multi-UAV task allocation (MUTA) methods. In particular, we examine the consensus-based bundle algorithm (CBBA) and a distributed auction 2-opt refinement strategy, both of which iteratively negotiate task bundles across UAVs to accommodate real-time task arrivals and intermittent connectivity. Finally, we outline how reinforcement learning (RL) can be incorporated to learn adaptive policies that balance energy efficiency and mission success under varying wind conditions and obstacle fields. Through simulations incorporating UAV-specific cost models and communication topologies, we assess each algorithm’s mission completion time, total energy expenditure, communication overhead, and resilience to UAV failures. Our results highlight the trade-off between strict optimality, which is suitable for small fleets in static scenarios, and scalable, robust coordination, necessary for large, dynamic multi-UAV deployments. Full article
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26 pages, 666 KiB  
Article
Sensor Fault Detection and Reliable Control of Singular Stochastic Systems with Time-Varying Delays
by Yunling Shi, Haosen Yang, Gang Liu, Xiaolin He and Jajun Wang
Sensors 2025, 25(15), 4667; https://doi.org/10.3390/s25154667 - 28 Jul 2025
Abstract
In unmanned systems, especially in large-scale and complex ones, sensor and communication failures occur from time to time and are hard to avoid. Therefore, this paper studies the fault detection problem of a class of unknown nonlinear singular uncertain time-varying delay Markov jump [...] Read more.
In unmanned systems, especially in large-scale and complex ones, sensor and communication failures occur from time to time and are hard to avoid. Therefore, this paper studies the fault detection problem of a class of unknown nonlinear singular uncertain time-varying delay Markov jump systems (UNSUTVDMJSs). Firstly, the corresponding sliding mode controller (SMC) is designed by using the equivalent control principle, and the unknown nonlinearity is equivalently replaced by changing the system input. Then, a fault detection filter adapted to this system is designed, thereby obtaining the unknown nonlinear stochastic singular uncertain Augmented filter residual system (UNSSUAFRS) model. To obtain the sufficient conditions for the random admissibility of this augmented system, a weak infinitesimal generator was used to design the required Lyapunov-Krasovskii functional. With the help of the Lyapunov principle and H performance analysis method, the sufficient conditions for the random admissibility of UNSSUAFRS under the H performance index γ were derived. Finally, with the aid of the designed residual evaluation function and threshold, simulation analysis was conducted on the examples of DC servo motors and numerical calculation examples to verify the effectiveness and practicability of this fault detection filter. Full article
(This article belongs to the Special Issue Smart Sensing and Control for Autonomous Intelligent Unmanned Systems)
15 pages, 1641 KiB  
Article
Optimization of TEMPO-Mediated Oxidation of Chitosan to Enhance Its Antibacterial and Antioxidant Activities
by Abdellah Mourak, Aziz Ait-Karra, Mourad Ouhammou, Abdoussadeq Ouamnina, Abderrahim Boutasknit, Mohamed El Hassan Bouchari, Najat Elhadiri and Abdelhakim Alagui
Polysaccharides 2025, 6(3), 65; https://doi.org/10.3390/polysaccharides6030065 - 28 Jul 2025
Abstract
This study systematically investigated the oxidation of chitosan using the TEMPO/NaClO/NaBr catalytic system under varying experimental conditions, namely temperature, reaction time, and pH, in order to optimize the oxidation process. Response surface methodology (RSM) was employed to determine the optimal parameters for maximizing [...] Read more.
This study systematically investigated the oxidation of chitosan using the TEMPO/NaClO/NaBr catalytic system under varying experimental conditions, namely temperature, reaction time, and pH, in order to optimize the oxidation process. Response surface methodology (RSM) was employed to determine the optimal parameters for maximizing the efficiency of the reaction. The structural modifications to the chitosan following oxidation were confirmed using Fourier-transform infrared spectroscopy (FTIR), alongside additional analytical techniques, which validated the successful introduction of carbonyl and carboxyl functional groups. Solvent-cast films were prepared from both native and oxidized chitosan in order to evaluate their functional performance. The antibacterial activity of these films was assessed against Gram-negative (Salmonella) and Gram-positive (Streptococcus faecalis) bacterial strains. The oxidized chitosan films exhibited significantly enhanced antibacterial effects, particularly at shorter incubation periods. In addition, antioxidant activity was evaluated using DPPH radical scavenging and ferrous ion chelation assays, which both revealed a marked improvement in radical scavenging ability and metal ion binding capacity in oxidized chitosan. These findings confirm that TEMPO-mediated oxidation effectively enhances the physicochemical and bioactive properties of chitosan, highlighting its potential for biomedical and environmental applications. Full article
30 pages, 6739 KiB  
Article
Linear Dependence of Sublimation Enthalpy on Young’s Elastic Modulus: Implications for Thermodynamics of Solids
by Anne M. Hofmeister
Materials 2025, 18(15), 3535; https://doi.org/10.3390/ma18153535 - 28 Jul 2025
Abstract
Classical thermodynamics omits rigidity, which property distinguishes solids from gases and liquids. By accounting for rigidity (i.e., Young’s elastic modulus, ϒ), we recently amended historical formulae and moreover linked heat capacity, thermal expansivity, and ϒ. Further exploration is motivation by the importance of [...] Read more.
Classical thermodynamics omits rigidity, which property distinguishes solids from gases and liquids. By accounting for rigidity (i.e., Young’s elastic modulus, ϒ), we recently amended historical formulae and moreover linked heat capacity, thermal expansivity, and ϒ. Further exploration is motivation by the importance of classical thermodynamics to various applied sciences. Based on heat performing work, we show here, theoretically, that density times sublimation enthalpy divided by the molar mass (ρΔHsub/M, energy per volume), depends linearly on ϒ (1 GPa = 109 J m−3). Data on diverse metals, non-metallic elements, chalcogenides, simple oxides, alkali halides, and fluorides with cubic structures validate this relationship at ambient conditions. Furthermore, data on hcp metals and molecular solids show that ρΔHsub/M is proportional to ϒ for anisotropic materials. Proportionality constants vary only from 0.1 to 0.7 among these different material types (>100 substances), which shows that the elastic energy reservoir of solids is large. Proportionality constants depend on whether molecules or atoms are sublimated and are somewhat affected by structure. We show that ductility of refractory, high-ϒ metals affect high-temperature determinations of their ΔHsub. Our results provide information on sublimation processes and subsequent gas phase reactions, while showing that elasticity of solids is the key parameter needed to assessing their energetics. Implications are highlighted. Full article
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20 pages, 300 KiB  
Review
Nighttime Primary Headaches in Children: Beyond Hypnic Headache, a Comprehensive Review
by Beatrice Baldo, Ilaria Bonemazzi, Antonella Morea, Roberta Rossi, Alessandro Ferretti, Vittorio Sciruicchio, Alessia Raffagnato, Vincenzo Raieli, Antonia Versace and Irene Toldo
Life 2025, 15(8), 1198; https://doi.org/10.3390/life15081198 - 28 Jul 2025
Abstract
Many headaches at night arise due to primary headache disorders, which occur independently of other symptoms and are not caused by another medical condition. Primary headache disorders with nighttime attacks can include tension-type headaches, migraines, hypnic headaches, and cluster headaches. A hypnic headache [...] Read more.
Many headaches at night arise due to primary headache disorders, which occur independently of other symptoms and are not caused by another medical condition. Primary headache disorders with nighttime attacks can include tension-type headaches, migraines, hypnic headaches, and cluster headaches. A hypnic headache is sometimes called an “alarm clock headache” because symptoms tend to arise at the same time of night. Apart from considering primary headaches, secondary causes of nighttime headaches should be considered and ruled out, in particular headaches secondary to intracranial hypertension, temporomandibular joint issues (like bruxism) and sleep apnea. Treatments vary based on headache type but often include a combination of medications and prevention strategies. This review article covers the basics of nighttime primary headaches in children, including pathophysiology, etiology, clinical features of the different forms and their treatment. It will also discuss the differences in headache features between children and adults. Full article
(This article belongs to the Section Medical Research)
17 pages, 6326 KiB  
Article
Dynamic Stress Wave Response of Thin-Walled Circular Cylindrical Shell Under Thermal Effects and Axial Harmonic Compression Boundary Condition
by Desejo Filipeson Sozinando, Patrick Nziu, Bernard Xavier Tchomeni and Alfayo Anyika Alugongo
Appl. Mech. 2025, 6(3), 55; https://doi.org/10.3390/applmech6030055 - 28 Jul 2025
Abstract
The interaction between thermal fields and mechanical loads in thin-walled cylindrical shells introduces complex dynamic behaviors relevant to aerospace and mechanical engineering applications. This study investigates the axial stress wave propagation in a circular cylindrical shell subjected to combined thermal gradients and time-dependent [...] Read more.
The interaction between thermal fields and mechanical loads in thin-walled cylindrical shells introduces complex dynamic behaviors relevant to aerospace and mechanical engineering applications. This study investigates the axial stress wave propagation in a circular cylindrical shell subjected to combined thermal gradients and time-dependent harmonic compression. A semi-analytical model based on Donnell–Mushtari–Vlasov (DMV) shells theory is developed to derive the governing equations, incorporating elastic, inertial, and thermal expansion effects. Modal solutions are obtained to evaluate displacement and stress distributions across varying thermal and mechanical excitation conditions. Empirical Mode Decomposition (EMD) and Instantaneous Frequency (IF) analysis are employed to extract time–frequency characteristics of the dynamic response. Complementary Finite Element Analysis (FEA) is conducted to assess modal deformations, stress wave amplification, and the influence of thermal softening on resonance frequencies. Results reveal that increasing thermal gradients leads to significant reductions in natural frequencies and amplifies stress responses at critical excitation frequencies. The combination of analytical and numerical approaches captures the coupled thermomechanical effects on shell dynamics, providing an understanding of resonance amplification, modal energy distribution, and thermal-induced stiffness variation under axial harmonic excitation across thin-walled cylindrical structures. Full article
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26 pages, 4687 KiB  
Article
Geant4-Based Logging-While-Drilling Gamma Gas Detection for Quantitative Inversion of Downhole Gas Content
by Xingming Wang, Xiangyu Wang, Qiaozhu Wang, Yuanyuan Yang, Xiong Han, Zhipeng Xu and Luqing Li
Processes 2025, 13(8), 2392; https://doi.org/10.3390/pr13082392 - 28 Jul 2025
Abstract
Downhole kick is one of the most severe safety hazards in deep and ultra-deep well drilling operations. Traditional monitoring methods, which rely on surface flow rate and fluid level changes, are limited by their delayed response and insufficient sensitivity, making them inadequate for [...] Read more.
Downhole kick is one of the most severe safety hazards in deep and ultra-deep well drilling operations. Traditional monitoring methods, which rely on surface flow rate and fluid level changes, are limited by their delayed response and insufficient sensitivity, making them inadequate for early warning. This study proposes a real-time monitoring technique for gas content in drilling fluid based on the attenuation principle of Ba-133 γ-rays. By integrating laboratory static/dynamic experiments and Geant4-11.2 Monte Carlo simulations, the influence mechanism of gas–liquid two-phase media on γ-ray transmission characteristics is systematically elucidated. Firstly, through a comparative analysis of radioactive source parameters such as Am-241 and Cs-137, Ba-133 (main peak at 356 keV, half-life of 10.6 years) is identified as the optimal downhole nuclear measurement source based on a comparative analysis of penetration capability, detection efficiency, and regulatory compliance. Compared to alternative sources, Ba-133 provides an optimal energy range for detecting drilling fluid density variations, while also meeting exemption activity limits (1 × 106 Bq) for field deployment. Subsequently, an experimental setup with drilling fluids of varying densities (1.2–1.8 g/cm3) is constructed to quantify the inverse square attenuation relationship between source-to-detector distance and counting rate, and to acquire counting data over the full gas content range (0–100%). The Monte Carlo simulation results exhibit a mean relative error of 5.01% compared to the experimental data, validating the physical correctness of the model. On this basis, a nonlinear inversion model coupling a first-order density term with a cubic gas content term is proposed, achieving a mean absolute percentage error of 2.3% across the full range and R2 = 0.999. Geant4-based simulation validation demonstrates that this technique can achieve a measurement accuracy of ±2.5% for gas content within the range of 0–100% (at a 95% confidence interval). The anticipated field accuracy of ±5% is estimated by accounting for additional uncertainties due to temperature effects, vibration, and mud composition variations under downhole conditions, significantly outperforming current surface monitoring methods. This enables the high-frequency, high-precision early detection of kick events during the shut-in period. The present study provides both theoretical and technical support for the engineering application of nuclear measurement techniques in well control safety. Full article
(This article belongs to the Section Chemical Processes and Systems)
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18 pages, 5492 KiB  
Article
A Novel Variable Stiffness Torque Sensor with Adjustable Resolution
by Zhongyuan Mao, Yuanchang Zhong, Xuehui Zhao, Tengfei He and Sike Duan
Micromachines 2025, 16(8), 868; https://doi.org/10.3390/mi16080868 - 27 Jul 2025
Abstract
In rotating machinery, the demands for torque sensor resolution and range in various torque measurements are becoming increasingly stringent. This paper presents a novel variable stiffness torque sensor designed to meet the demands for high resolution or a large range under varying measurement [...] Read more.
In rotating machinery, the demands for torque sensor resolution and range in various torque measurements are becoming increasingly stringent. This paper presents a novel variable stiffness torque sensor designed to meet the demands for high resolution or a large range under varying measurement conditions. Unlike traditional strain gauge-based torque sensors, this sensor combines the advantages of torsion springs and magnetorheological fluid (MRF) to achieve dynamic adjustments in both resolution and range. Specifically, the stiffness of the elastic element is adjusted by altering the shear stress of the MRF via an applied magnetic field while simultaneously harnessing the high sensitivity of the torsion spring. The stiffness model is established and validated for accuracy through finite element analysis. A screw modulation-based angle measurement method is proposed for the first time, offering high non-contact angle measurement accuracy and resolving eccentricity issues. The performance of the sensor prototype is evaluated using a self-developed power-closed torque test bench. The experimental results demonstrate that the sensor exhibits excellent linearity, hysteresis, and repeatability while effectively achieving dynamic continuous adjustment of resolution and range. Full article
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17 pages, 4621 KiB  
Article
ANN-Enhanced Modulated Model Predictive Control for AC-DC Converters in Grid-Connected Battery Systems
by Andrea Volpini, Samuela Rokocakau, Giulia Tresca, Filippo Gemma and Pericle Zanchetta
Energies 2025, 18(15), 3996; https://doi.org/10.3390/en18153996 - 27 Jul 2025
Abstract
With the increasing integration of renewable energy sources (RESs) into power systems, batteries are playing a critical role in ensuring grid reliability and flexibility. Among them, vanadium redox flow batteries (VRFBs) have emerged as a promising solution for large-scale storage due to their [...] Read more.
With the increasing integration of renewable energy sources (RESs) into power systems, batteries are playing a critical role in ensuring grid reliability and flexibility. Among them, vanadium redox flow batteries (VRFBs) have emerged as a promising solution for large-scale storage due to their long cycle life, scalability, and deep discharge capability. However, achieving optimal control and system-level integration of VRFBs requires accurate, real-time modeling and parameter estimation, challenging tasks given the multi-physics nature and time-varying dynamics of such systems. This paper presents a lightweight physics-informed neural network (PINN) framework tailored for VRFBs, which directly embeds the discrete-time state-space dynamics into the network architecture. The model simultaneously predicts terminal voltage and estimates five discrete-time physical parameters associated with RC dynamics and internal resistance, while avoiding hidden layers to enhance interpretability and computational efficiency. The resulting PINN model is integrated into a modulated model predictive control (MMPC) scheme for a dual-stage DC-AC converter interfacing the VRFB with low-voltage AC grids. Simulation and hardware-in-the-loop results demonstrate that adaptive tuning of the PINN-estimated parameters enables precise tracking of battery parameter variations, thereby improving the robustness and performance of the MMPC controller under varying operating conditions. Full article
16 pages, 8118 KiB  
Article
The Influence of Long-Term Service on the Mechanical Properties and Energy Dissipation Capacity of Flexible Anti-Collision Rings
by Junhong Zhou, Jia Lu, Wei Jiang, Ang Li, Hancong Shao, Zixiao Huang, Fei Wang and Qiuwei Yang
Coatings 2025, 15(8), 880; https://doi.org/10.3390/coatings15080880 - 27 Jul 2025
Abstract
This study investigates the long-term performance of flexible anti-collision rings after 12 years of service on the Xiangshan Port Highway Bridge. Stepwise loading–unloading tests at multiple loading rates (0.8–80 mm/s) were performed on the anti-collision rings, with full-field strain measurement via digital image [...] Read more.
This study investigates the long-term performance of flexible anti-collision rings after 12 years of service on the Xiangshan Port Highway Bridge. Stepwise loading–unloading tests at multiple loading rates (0.8–80 mm/s) were performed on the anti-collision rings, with full-field strain measurement via digital image correlation (DIC) technology. The results show that: The mechanical response of the anti-collision ring shows significant asymmetric tension–compression, with the tensile peak force being 6.8 times that of compression. A modified Johnson–Cook model was developed to accurately characterize the tension–compression force–displacement behavior across varying strain rates (0.001–0.1 s−1). The DIC full-field strain analysis reveals that the clamping fixture significantly influences the tensile deformation mode of the anti-collision ring by constraining its inner wall movement, thereby altering strain distribution patterns. Despite exhibiting a corrosion gradient from severe underwater degradation to minimal surface weathering, all tested rings demonstrated consistent mechanical performance, verifying the robust protective capability of the rubber coating in marine service conditions. Full article
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21 pages, 3802 KiB  
Article
Parameter Identification and Speed Control of a Small-Scale BLDC Motor: Experimental Validation and Real-Time PI Control with Low-Pass Filtering
by Ayman Ibrahim Abouseda, Resat Ozgur Doruk and Ali Amini
Machines 2025, 13(8), 656; https://doi.org/10.3390/machines13080656 - 27 Jul 2025
Abstract
This paper presents a structured and experimentally validated approach to the parameter identification, modeling, and real-time speed control of a brushless DC (BLDC) motor. Electrical parameters, including resistance and inductance, were measured through DC and AC testing under controlled conditions, respectively, while mechanical [...] Read more.
This paper presents a structured and experimentally validated approach to the parameter identification, modeling, and real-time speed control of a brushless DC (BLDC) motor. Electrical parameters, including resistance and inductance, were measured through DC and AC testing under controlled conditions, respectively, while mechanical and electromagnetic parameters such as the back electromotive force (EMF) constant and rotor inertia were determined experimentally using an AVL dynamometer. The back EMF was obtained by operating the motor as a generator under varying speeds, and inertia was identified using a deceleration method based on the relationship between angular acceleration and torque. The identified parameters were used to construct a transfer function model of the motor, which was implemented in MATLAB/Simulink R2024b and validated against real-time experimental data using sinusoidal and exponential input signals. The comparison between simulated and measured speed responses showed strong agreement, confirming the accuracy of the model. A proportional–integral (PI) controller was developed and implemented for speed regulation, using a low-cost National Instruments (NI) USB-6009 data acquisition (DAQ) and a Kelly controller. A first-order low-pass filter was integrated into the control loop to suppress high-frequency disturbances and improve transient performance. Experimental tests using a stepwise reference speed profile demonstrated accurate tracking, minimal overshoot, and robust operation. Although the modeling and control techniques applied are well known, the novelty of this work lies in its integration of experimental parameter identification, real-time validation, and practical hardware implementation within a unified and replicable framework. This approach provides a solid foundation for further studies involving more advanced or adaptive control strategies for BLDC motors. Full article
(This article belongs to the Section Electrical Machines and Drives)
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20 pages, 1940 KiB  
Article
Linkages Between Sorghum bicolor Root System Architectural Traits and Grain Yield Performance Under Combined Drought and Heat Stress Conditions
by Alec Magaisa, Elizabeth Ngadze, Tshifhiwa P. Mamphogoro, Martin P. Moyo and Casper N. Kamutando
Agronomy 2025, 15(8), 1815; https://doi.org/10.3390/agronomy15081815 - 26 Jul 2025
Viewed by 50
Abstract
Breeding programs often overlook the use of root traits. Therefore, we investigated the relevance of sorghum root traits in explaining its adaptation to combined drought and heat stress (CDHS). Six (i.e., three pre-release lines + three checks) sorghum genotypes were established at two [...] Read more.
Breeding programs often overlook the use of root traits. Therefore, we investigated the relevance of sorghum root traits in explaining its adaptation to combined drought and heat stress (CDHS). Six (i.e., three pre-release lines + three checks) sorghum genotypes were established at two low-altitude (i.e., <600 masl) locations with a long-term history of averagely very high temperatures in the beginning of the summer season, under two management (i.e., CDHS and well-watered (WW)) regimes. At each location, the genotypes were laid out in the field using a randomized complete block design (RCBD) replicated two times. Root trait data, namely root diameter (RD), number of roots (NR), number of root tips (NRT), total root length (TRL), root depth (RDP), root width (RW), width–depth ratio (WDR), root network area (RNA), root solidity (RS), lower root area (LRA), root perimeter (RP), root volume (RV), surface area (SA), root holes (RH) and root angle (RA) were gathered using the RhizoVision Explorer software during the pre- and post-flowering stage of growth. RSA traits differentially showed significant (p < 0.05) correlations with grain yield (GY) at pre- and post-flowering growth stages and under CDHS and WW conditions also revealing genotypic variation estimates exceeding 50% for all the traits. Regression models varied between pre-flowering (p = 0.013, R2 = 47.15%, R2 Predicted = 29.32%) and post-flowering (p = 0.000, R2 = 85.64%, R2 Predicted = 73.30%) growth stages, indicating post-flowering as the optimal stage to relate root traits to yield performance. RD contributed most to the regression model at post-flowering, explaining 51.79% of the 85.64% total variation. The Smith–Hazel index identified ICSV111IN and ASAREACA12-3-1 as superior pre-release lines, suitable for commercialization as new varieties. The study demonstrated that root traits (in particular, RD, RW, and RP) are linked to crop performance under CDHS conditions and should be incorporated in breeding programs. This approach may accelerate genetic gains not only in sorghum breeding programs, but for other crops, while offering a nature-based breeding strategy for stress adaptation in crops. Full article
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10 pages, 380 KiB  
Article
High Social Motivation Can Promote Time-Based Prospective Memory Performance
by Yadong Zhou, Mingyuan Wang, Yu Tian and Yunfei Guo
Behav. Sci. 2025, 15(8), 1015; https://doi.org/10.3390/bs15081015 - 26 Jul 2025
Viewed by 47
Abstract
Prospective memory, the ability to remember to execute a preplanned activity, is important in social interactions, insofar as such interactions frequently involve preplanned activities. The importance of prospective memory varies across different social contexts and individuals generally make greater efforts to ensure the [...] Read more.
Prospective memory, the ability to remember to execute a preplanned activity, is important in social interactions, insofar as such interactions frequently involve preplanned activities. The importance of prospective memory varies across different social contexts and individuals generally make greater efforts to ensure the completion of prospective memory tasks under high social motivation conditions compared to low social motivation conditions. We aimed to investigate the effects of various levels of social motivation on prospective memory. A single-factor between-subjects experimental design was implemented to explore the influence of social motivation intensity on time-based prospective memory and its processing mechanism. We found that only the high social motivation group demonstrated superior prospective memory performance compared to the control group. The high social motivation group also had slower response speeds in response to the ongoing tasks than both the control group and the low social motivation group, but the number of strategies used was not different among the three groups. Moreover, in comparison with the control group, the high social motivation group monitored time more frequently. The results suggest that only high-intensity social motivation can promote time-based prospective memory performance, and increased attention consumption is necessary for the occurrence of this effect. Full article
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13 pages, 609 KiB  
Article
Leaching of Potentially Toxic Elements from Paper and Plastic Cups in Hot Water and Their Health Risk Assessment
by Mahmoud Mohery, Kholoud Ahmed Hamam, Sheldon Landsberger, Israa J. Hakeem and Mohamed Soliman
Toxics 2025, 13(8), 626; https://doi.org/10.3390/toxics13080626 - 26 Jul 2025
Viewed by 89
Abstract
This study aims to investigate the release of potentially toxic elements from disposable paper and plastic cups when exposed to hot water, simulating the scenario of their use in hot beverage consumption, and to assess the associated health risks. By using ICP-MS, twelve [...] Read more.
This study aims to investigate the release of potentially toxic elements from disposable paper and plastic cups when exposed to hot water, simulating the scenario of their use in hot beverage consumption, and to assess the associated health risks. By using ICP-MS, twelve potentially toxic elements, namely As, Ba, Cd, Co, Cr, Cu, Mn, Mo, Pb, Sb, V, and Zn, were determined in leachates, revealing significant variability in mass fractions between paper and plastic cups, with plastic cups demonstrating greater leaching potential. Health risk assessments, including hazard quotient (HQ) and excess lifetime cancer risk (ELCR), indicated minimal non-carcinogenic and carcinogenic risks for most elements, except Pb, which posed elevated non-carcinogenic risk, especially in plastic cups. Children showed higher relative exposure levels compared to adults due to their lower body weights (the HQ in children is two times greater than in adults). Overall, the findings of the current study underscore the need for stricter monitoring and regulation of materials used in disposable cups, especially plastic ones, to mitigate potential health risks. Future investigations should assess the leaching behavior of potentially toxic elements under conditions that accurately mimic real-world usage. Such investigations ought to incorporate a systematic evaluation of diverse temperature regimes, varying exposure durations, and different beverage types. Full article
(This article belongs to the Section Exposome Analysis and Risk Assessment)
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16 pages, 1859 KiB  
Article
Simulation of Effect on Charge Accumulation Distribution in Laminar Oil Flow with Bubbles in Oil Passage of Converter Transformer
by Wen Si, Haibo Li, Hongshun Liu and Xiaotian Gu
Energies 2025, 18(15), 3992; https://doi.org/10.3390/en18153992 - 26 Jul 2025
Viewed by 111
Abstract
The converter transformer is subjected to AC/DC composite voltage during operation, and the sealed and time-varying internal state makes its electric field distribution and charge accumulation unable to be monitored in real-time experiments. In this paper, aiming at the influence of bubbles in [...] Read more.
The converter transformer is subjected to AC/DC composite voltage during operation, and the sealed and time-varying internal state makes its electric field distribution and charge accumulation unable to be monitored in real-time experiments. In this paper, aiming at the influence of bubbles in the oil passage of the converter transformer on charge accumulation before discharge, a simulation model in a laminar flow environment is established, and four different calculation conditions are set to simulate the charge accumulation in 1 s. It is found that under laminar flow conditions, the trapped bubbles on the insulation paper wall play an obvious role in intensifying the charge accumulation in transformer oil, and the extreme range of charge density will increase by about 104 times. Bubbles aggravate the electric field distortion, and the insulation strength of bubbles is lower, which becomes the weak link of insulation. In the laminar flow environment, the oil flow will take away part of the accumulated charge in the oil, but in the case of trapped bubbles, the charge accumulation in the insulating paper will increase from the order of 10−2 to 10−1. In the case of no bubbles, the transformer oil layer flow will increase the charge accumulation in the insulation paper by 4–5 orders of magnitude. Therefore, it can be seen that the flow of transformer oil will increase the deterioration level of insulation paper. And when the transformer oil is already in the laminar flow state, the influence of laminar flow velocity on charge accumulation is not obvious. The research results in this paper provide a time-varying simulation reference state for the charge accumulation problem that cannot be measured experimentally under normal charged operation conditions, and we obtain quantitative numerical results, which can provide a valuable reference for the study of transformer operation and insulation discharge characteristics. Full article
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