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25 pages, 7269 KB  
Article
Wearable PPG Multi-Sensor for Skin Humidity, Temperature, and Contact Pressure Measurement in Weak Magnetic Field Environment: First-Step Experiments
by Jiří Přibil, Anna Přibilová and Tomáš Dermek
Bioengineering 2025, 12(12), 1361; https://doi.org/10.3390/bioengineering12121361 - 14 Dec 2025
Viewed by 772
Abstract
This study describes the developed special prototype of a wearable measuring device based on a photoplethysmography (PPG) sensor. It contains also a humidity sensor and a thermometer to measure skin moisture and temperature, and a force-sensitive (FSR) element to sense a contact pressure [...] Read more.
This study describes the developed special prototype of a wearable measuring device based on a photoplethysmography (PPG) sensor. It contains also a humidity sensor and a thermometer to measure skin moisture and temperature, and a force-sensitive (FSR) element to sense a contact pressure between the measuring probe and the skin surface. All parts of the multi-sensor are shielded, to be applicable in a weak magnetic field environment. After the basic sensor’s functionality verification inside the magnetic resonance imaging tomograph, a set of experiments was performed. Comparative measurements by an oximeter confirm good correspondence with heart rate values determined from PPG (HRPPG) and FSR (HRFSR) signals—the mean absolute error lies below 0.5 min−1 for both types. The sensing of PPG signals on wrists was realized for Normal, Dry, and Wet skin. In comparison with normal skin conditions, drying decreases the PPG signal range by 7% and the systolic pulse width by 8%, while moistening increases the signal ripple by 3% and decreases the correlation between HRPPG and HRFSR values by 5%. The detailed analysis per hand and gender types yields differences between male and female subjects, while the results for left and right hands differ less. Full article
(This article belongs to the Special Issue Advanced Biomedical Signal Communication Technology)
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20 pages, 5699 KB  
Article
Application of Fiber-Optic Sensors to Monitor Concrete Dams: A Case Study
by Douglas Moser, Araceli Martin-Candilejo, Luis Cueto-Felgueroso and David Santillan
Appl. Sci. 2025, 15(23), 12397; https://doi.org/10.3390/app152312397 - 21 Nov 2025
Viewed by 574
Abstract
Fiber-Optic Sensors (FOSs) offer unprecedented performance for Structural Health Monitoring (SHM) of concrete dams, addressing the critical need for robust instrumentation. This study evaluates the capabilities of Raman-type Distributed Fiber-Optic Sensors (DFOSs) and Bragg grating-type Localized Fiber-Optic Sensors (LFOSs) for concrete temperature monitoring [...] Read more.
Fiber-Optic Sensors (FOSs) offer unprecedented performance for Structural Health Monitoring (SHM) of concrete dams, addressing the critical need for robust instrumentation. This study evaluates the capabilities of Raman-type Distributed Fiber-Optic Sensors (DFOSs) and Bragg grating-type Localized Fiber-Optic Sensors (LFOSs) for concrete temperature monitoring in a case study. Raman-type DFOSs offer superior spatial resolution and comprehensive thermal mapping, enabling the detection of detailed thermal phenomena, such as the cooling effects of dam galleries and significant thermal gradients, that conventional technologies cannot capture. They are also easier and faster to install, as they do not require trench construction. However, monitoring data acquisition can be more expensive with Raman-type DFOSs. Bragg-type LFOSs offer reliable localized measurements analogous to conventional thermometers. A key benefit is their multiplexing capability, which significantly reduces the total number of cables needed, making a complete LFOS-based monitoring system easier and potentially cheaper to install than an equivalent conventional system, even though individual LFOS installation still requires trenches. Overall, both FOS technologies are effective and reliable for concrete dam temperature monitoring, providing data quality comparable to conventional sensors and representing a significant advancement for SHM systems. Full article
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3474 KB  
Proceeding Paper
A Wearable PPG Multi-Sensor for Measurement of Skin Humidity, Temperature, and Contact Pressure
by Jiří Přibil, Anna Přibilová and Tomáš Dermek
Eng. Proc. 2025, 118(1), 71; https://doi.org/10.3390/ECSA-12-26558 - 7 Nov 2025
Viewed by 207
Abstract
The aim of our work was to analyze the influence of changes in humidity and temperature on temporal features of sensed photoplethysmography (PPG) waves. This paper describes a special prototype of a wearable PPG multi-sensor with an integrated I2C humidity sensor and a [...] Read more.
The aim of our work was to analyze the influence of changes in humidity and temperature on temporal features of sensed photoplethysmography (PPG) waves. This paper describes a special prototype of a wearable PPG multi-sensor with an integrated I2C humidity sensor and a thermometer to carry out measurements at three skin moisture levels. This sensor is supplemented with a force-sensitive resistor for the measurement of the physical contact pressure between the measuring probe and the skin surface, which can be used to sense heart pulsation in the wrist radial artery. The experiments conducted show that the performed skin manipulation (skin drying, moistening) was always detectable; the PPG signal range is mainly affected, while changes in signal ripple and heart rate variance are smaller. The detailed analysis per hand and gender type yielded differences between male and female subjects, and the results for left and right hands differed less. Full article
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28 pages, 5701 KB  
Article
Temperature and Pressure Observations by Tommaso Temanza from 1751 to 1769 in Venice, Italy
by Dario Camuffo, Antonio della Valle and Francesca Becherini
Climate 2025, 13(10), 217; https://doi.org/10.3390/cli13100217 - 18 Oct 2025
Viewed by 1051
Abstract
The study aims to recover, interpret, and analyze the daily meteorological observations made in Venice by Tommaso Temanza from 1751 to 1769. These records are relevant because they provide direct information about the climate of the Little Ice Age. Temanza used a barometer, [...] Read more.
The study aims to recover, interpret, and analyze the daily meteorological observations made in Venice by Tommaso Temanza from 1751 to 1769. These records are relevant because they provide direct information about the climate of the Little Ice Age. Temanza used a barometer, an air thermometer of Amontons’ type, and an additional mercury thermometer, i.e., Réaumur’s thermometer. These early instruments are presented and discussed in this study. The barometer readings needed standard corrections, which were unknown at that time. The scale of the air thermometer was arbitrary, and temperatures were measured in inches of mercury. For the Amontons thermometer, Temanza missed the calibration points and used a particular scale with the zero-point in the middle of the range. He gave two contradictory explanations for this choice, both of which are discussed in this paper. In the 18th century, the use of a singular value to represent the average temperature, called “Temperate”, was promoted by Michieli du Crest in Geneva and Toaldo in Padua. This work reconstructs the unknown scale, using contemporary observations by Giovanni Poleni and Giuseppe Toaldo in Padua (30 km west of Venice) and snowfall reported in the weather notes to determine the temperature point at 0 °C. A discussion is made about the calibration, validation, and conversion of readings from the original to modern units of pressure and temperature, i.e., hPa and °C, respectively. The recovered record of Venice is presented in comparison with Padua, Bologna, and Milan. The paper provides and analyzes the new dataset, and improves knowledge about the climate, history of science, instruments, and observations made in the mid-18th century. Full article
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21 pages, 1488 KB  
Article
Comparative Evaluation and Optimization of Auxin Type and Concentration on Rooting Efficiency of Photinia × fraseri Dress: Stem Cuttings Using Response Surface Methodology
by Gülcay Ercan Oğuztürk, Müberra Pulatkan, Cem Alparslan and Türker Oğuztürk
Plants 2025, 14(15), 2420; https://doi.org/10.3390/plants14152420 - 4 Aug 2025
Cited by 2 | Viewed by 1201
Abstract
This study aimed to evaluate and optimize the effects of three auxin types—indole-3-butyric acid (IBA), naphthaleneacetic acid (NAA), and indole-3-acetic acid (IAA)—applied at four concentrations (1000, 3000, 5000, and 8000 ppm) on the rooting performance of Photinia × fraseri Dress. stem cuttings. The [...] Read more.
This study aimed to evaluate and optimize the effects of three auxin types—indole-3-butyric acid (IBA), naphthaleneacetic acid (NAA), and indole-3-acetic acid (IAA)—applied at four concentrations (1000, 3000, 5000, and 8000 ppm) on the rooting performance of Photinia × fraseri Dress. stem cuttings. The experiment was conducted under controlled greenhouse conditions using a sterile perlite medium. Rooting trays were placed on bottom-heated propagation benches maintained at a set temperature of 25 ± 2 °C to stimulate root formation. However, the actual rooting medium temperature—measured manually every four days from the perlite zone using a calibrated thermometer—ranged between 18 °C and 22 °C, with an overall average of approximately 20 ± 2 °C. The average values of these root-zone temperatures were used in the statistical analyses. Rooting percentage, root number, root length, callus formation, and mortality rate were recorded after 120 days. In addition to classical one-way ANOVA, response surface methodology (RSM) was employed to model and optimize the interactions between auxin type, concentration, and temperature. The results revealed that 5000 ppm IBA significantly enhanced rooting performance, yielding the highest rooting percentage (85%), average root number (5.80), and root length (6.30 cm). RSM-based regression models demonstrated strong predictive power, with the model for rooting percentage explaining up to 92.79% of the total variance. Temperature and auxin concentration were identified as the most influential linear factors, while second-order and interaction terms—particularly T·ppm—contributed substantially to root length variation. These findings validate IBA as the most effective exogenous auxin for the vegetative propagation of Photinia × fraseri Dress. and provide practical recommendations for optimizing hormone treatments. Moreover, the study offers a robust statistical modeling framework that can be applied to similar propagation systems in woody ornamental plants. Full article
(This article belongs to the Section Horticultural Science and Ornamental Plants)
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19 pages, 2312 KB  
Article
Improvement of Blood Flow and Epidermal Temperature in Cold Feet Using Far-Infrared Rays Emitted from Loess Balls Manufactured by Low-Temperature Wet Drying Method: A Randomized Trial
by Yong Il Shin, Min Seok Kim, Yeong Ae Yang, Yun Jeong Lee, Gye Rok Jeon, Jae Ho Kim, Yeon Jin Choi, Woo Cheol Choi and Jae Hyung Kim
Biomedicines 2025, 13(7), 1759; https://doi.org/10.3390/biomedicines13071759 - 18 Jul 2025
Viewed by 4320
Abstract
Background: Cold feet syndrome is characterized by hypersensitivity of sympathetic nerves to cold stimuli, resulting in vasoconstriction and reduced peripheral blood flow. This condition causes an intense cold sensation, particularly in the extremities. Although hormonal changes (e.g., during childbirth or menopause) and psychological [...] Read more.
Background: Cold feet syndrome is characterized by hypersensitivity of sympathetic nerves to cold stimuli, resulting in vasoconstriction and reduced peripheral blood flow. This condition causes an intense cold sensation, particularly in the extremities. Although hormonal changes (e.g., during childbirth or menopause) and psychological stress have been implicated, the mechanisms and effective treatments remain unclear. Methods: Ninety adult volunteers were randomized into three groups based on the type of heating mat applied to the feet, with surface temperatures gradually increased from 20 °C to 50 °C. Group A (control) used non-FIR electric mats, Group B used carbon FIR mats, and Group C used loess bio-ball FIR mats. Blood flow (mL/min/100 g) and epidermal temperature (°C) in the left big toe (LBT) and right big toe (RBT) were measured before and after heating or FIR exposure using laser Doppler flowmetry and infrared thermometers. Results: No significant changes in blood flow or skin temperature were observed in Group A. In Group B, blood flow increased by 15.07 mL/min/100 g in the LBT (from 4.12 ± 2.22 to 19.19 ± 5.44) and by 14.55 mL/min/100 g in the RBT (from 4.26 ± 2.29 to 18.81 ± 4.29). In Group C, blood flow increased by 32.86 mL/min/100 g in the LBT (from 4.23 ± 1.64 to 37.09 ± 6.04) and by 32.63 mL/min/100 g in the RBT (from 4.20 ± 1.61 to 36.83 ± 6.48). Epidermal temperature also increased significantly in Group C. All changes in Groups B and C were statistically significant (p < 0.05), with Group C showing the most prominent enhancement. Conclusions: The loess bio-ball mat significantly increased both peripheral blood flow and epidermal temperature compared to the electric and carbon mats. These findings suggest that FIR emitted from loess bio-balls may enhance peripheral circulation through hypothalamus thermogenic response and nitric oxide (NO)-dependent pathways and could serve as a complementary and non-invasive intervention for individuals with poor blood flow. Full article
(This article belongs to the Section Biomedical Engineering and Materials)
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16 pages, 10425 KB  
Article
Pressure and Temperature Observations in Venice by Bernardino Zendrini from 1738 to 1743
by Dario Camuffo, Antonio della Valle and Francesca Becherini
Atmosphere 2025, 16(7), 759; https://doi.org/10.3390/atmos16070759 - 20 Jun 2025
Cited by 1 | Viewed by 785
Abstract
This study aims to recover, interpret and analyse the early meteorological observations made in Venice by Bernardino Zendrini from 1738 to 1743. Zendrini used a cistern barometer, an Amontons-type air thermometer and an additional mercury thermometer, i.e., a de l’Isle one. By comparing [...] Read more.
This study aims to recover, interpret and analyse the early meteorological observations made in Venice by Bernardino Zendrini from 1738 to 1743. Zendrini used a cistern barometer, an Amontons-type air thermometer and an additional mercury thermometer, i.e., a de l’Isle one. By comparing and interpreting the existing details, the instruments have been re-imagined, interpreted and discussed; finally their unknown scale and calibration points have been calculated. The barometer readings needed standard corrections, which were not known at that time. The scale of the air thermometers was in inches of mercury. Zendrini used a reversed scale, with boiling water set to 0, but neglected the second calibration point and the length of the tube. In addition, he gave the thermoscopic readings without the corresponding pressures. The methodology for the calibration, validation and transformation of the readings into modern units, i.e., hPa and °C, is carefully discussed. This paper provides and analyses new data, and improves our knowledge about the history of science, meteorological measurements, instruments and observations in the first half of the 18th century. Full article
(This article belongs to the Section Atmospheric Techniques, Instruments, and Modeling)
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14 pages, 242 KB  
Article
Associations Between Chemotherapy-Induced Peripheral Neuropathy and Distress in Patients Assigned to Adjuvant Irradiation for Non-Metastatic Breast Cancer
by Dirk Rades, Tobias Bartscht, Achim Rody and Martin Ballegaard
J. Pers. Med. 2025, 15(6), 248; https://doi.org/10.3390/jpm15060248 - 13 Jun 2025
Cited by 1 | Viewed by 1296
Abstract
Background/Objectives: Many patients assigned to adjuvant radiotherapy for non-metastatic breast cancer already received taxane-based chemotherapy, which can cause peripheral neuropathy (PNP). This study investigated potential associations between moderate-to-severe or mild PNP and distress. Methods: Ninety-eight breast cancer patients who received taxane-based chemotherapy and [...] Read more.
Background/Objectives: Many patients assigned to adjuvant radiotherapy for non-metastatic breast cancer already received taxane-based chemotherapy, which can cause peripheral neuropathy (PNP). This study investigated potential associations between moderate-to-severe or mild PNP and distress. Methods: Ninety-eight breast cancer patients who received taxane-based chemotherapy and completed the National Comprehensive Cancer Network Distress Thermometer were included in this retrospective study. The severity of PNP plus 17 factors were evaluated for associations with distress. Results: Mean distress scores (higher scores representing higher levels of distress) were 6.17 (SD ± 2.41) in patients with moderate-to-severe PNP, 4.21 (SD ± 2.54) in patients with mild PNP and 4.04 (SD ± 2.24) in patients without PNP. On univariable analyses, higher distress scores were significantly associated with moderate-to-severe PNP (vs. mild or no PNP, p < 0.001), Karnofsky performance score ≤ 80 (p = 0.001), history of autoimmune disease (p = 0.035), and hypertension (p = 0.002). Trends were found for age ≥65 years (p = 0.056), type of chemotherapy (p = 0.078), and beta-blocker medication (p = 0.072). On multivariable analysis, moderate-to-severe PNP (p = 0.036), Karnofsky performance score ≤ 80 (p = 0.013), and hypertension (p = 0.045) were significant. Conclusions: Since moderate-to-severe chemotherapy-induced PNP was associated with a significantly higher level of distress when compared to mild or nor PNP, these patients should be offered early psychological support and personalized monitoring. Full article
(This article belongs to the Special Issue Advances in Personalized Treatment of Breast Cancer)
16 pages, 3480 KB  
Case Report
Navigating Rarity: Pathological Challenges and Diagnostic Ambiguity in Rare Gliomas—A Case Series with a Focus on Personalized Treatment and Quality of Life
by Nadja Grübel, Anika Wickert, Felix Sahm, Bernd Schmitz, Anja Osterloh, Rebecca Kassubek, Ralph König, Christian Rainer Wirtz, Jens Engelke, Andrej Pala and Mona Laible
Onco 2025, 5(2), 28; https://doi.org/10.3390/onco5020028 - 10 Jun 2025
Viewed by 1690
Abstract
Gliomas are incurable, heterogeneous brain tumors, with rare forms often constituting diagnostic and treatment challenges. Molecular diagnostics, mainly implemented through the World Health Organization (WHO) 2021 guidelines, have refined the classification, but highlight difficulties in diagnosing rare gliomas remain. This case series analyzes [...] Read more.
Gliomas are incurable, heterogeneous brain tumors, with rare forms often constituting diagnostic and treatment challenges. Molecular diagnostics, mainly implemented through the World Health Organization (WHO) 2021 guidelines, have refined the classification, but highlight difficulties in diagnosing rare gliomas remain. This case series analyzes four patients with rare gliomas treated at the University Hospital, Ulm, between 2002 and 2024. Patients were selected based on unique histopathological features and long-term clinical follow-up. Clinical records, imaging, and histological data were reviewed. Molecular diagnostics followed WHO 2021 guidelines. Quality of life was assessed using standardized tools including the EQ-5D-5L, EQ VAS, the Distress Thermometer, and the Montreal Cognitive Assessment (MoCA). In the first case, a 51-year-old male’s diagnosis evolved from pleomorphic xanthoastrocytoma to a high-grade glioma with pleomorphic and pseudopapillary features, later identified as a neuroepithelial tumor with a PATZ1 fusion over 12 years. Despite multiple recurrences, extensive surgical interventions led to excellent outcomes. The second case involved a young female with long-term survival of astroblastoma, demonstrating significant improvements in both longevity and quality of life through personalized care. The third case involved a patient with oligodendroglioma, later transforming into glioblastoma, emphasizing the importance of continuous diagnostic reevaluation and adaptive treatment strategies, contributing to prolonged survival and quality of life improvements. Remarkably, the patient has achieved over 20 years of survival, including 10 years of being both therapy- and progression-free. The fourth case presents a young woman with neurofibromatosis type 1, initially misdiagnosed with glioblastoma based on histopathological findings. Subsequent molecular diagnostics revealed a subependymal giant cell astrocytoma-like astrocytoma, highlighting the critical role of early advanced diagnostic techniques. These cases underscore the importance of precise molecular diagnostics, individualized treatments, and ongoing diagnostic reevaluation to optimize outcomes. They also address the psychological impact of evolving diagnoses, stressing the need for comprehensive patient support. Even in complex cases, extensive surgical interventions can yield favorable results, reinforcing the value of adaptive, multidisciplinary strategies based on evolving tumor characteristics. Full article
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18 pages, 7058 KB  
Article
In-Depth Thermal Analysis of Different Pin Configurations in Friction Stir Spot Welding of Similar and Dissimilar Alloys
by Sajad N. Alasdi and Raheem Al-Sabur
J. Manuf. Mater. Process. 2025, 9(6), 184; https://doi.org/10.3390/jmmp9060184 - 1 Jun 2025
Viewed by 1432
Abstract
Over the past decade, friction stir spot welding (FSSW) has gained increasing attention, making it a competitor to conventional welding methods such as resistance welding, rivets, and screws. This type of welding is environmentally friendly because it does not require welding tools and [...] Read more.
Over the past decade, friction stir spot welding (FSSW) has gained increasing attention, making it a competitor to conventional welding methods such as resistance welding, rivets, and screws. This type of welding is environmentally friendly because it does not require welding tools and is solid-state welding. This study attempts to demonstrate the importance of pin geometry on temperature distribution and joint quality by using threaded and non-threaded pins for similar and dissimilar alloys. To this end, thermal analysis of the welded joints was conducted using real-time monitoring from a thermal camera and an infrared thermometer, in addition to finite element method (FEM) simulations. The thermal analysis showed that the generated temperatures were higher in dissimilar alloys (Al-Cu) than in similar ones (Al-Al), reaching about 350 °C. In addition, dissimilar alloys show more pronounced FSSW stages through extended periods for each plunging, dwelling, and drawing-out time. The FEM simulation results are consistent with those obtained from thermal imaging cameras and infrared thermometers. The dwelling time was influential, as the higher it was, the more heat was generated, which could be close to the melting point, especially in aluminum alloys. This study provides an in-depth experimental and numerical investigation of temperature distribution throughout the welding cycle, utilizing different pin geometries for both similar and dissimilar non-ferrous alloy joints, offering valuable insights for advanced industrial welding applications. Full article
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18 pages, 2080 KB  
Article
In Situ Evaluation of the Self-Heating Effect in Resistance Temperature Sensors
by Przemysław Otomański, Eligiusz Pawłowski and Anna Szlachta
Sensors 2025, 25(11), 3374; https://doi.org/10.3390/s25113374 - 27 May 2025
Cited by 6 | Viewed by 2171
Abstract
This paper discusses the issue of the self-heating effect of resistance sensors during temperature measurement. The self-heating effect causes temperature measurement errors. The aim of this work was to develop a method for in situ assessment of the thermal resistance between a self-heating [...] Read more.
This paper discusses the issue of the self-heating effect of resistance sensors during temperature measurement. The self-heating effect causes temperature measurement errors. The aim of this work was to develop a method for in situ assessment of the thermal resistance between a self-heating thermometer and its surrounding environment, the temperature of which is measured. The proposed method is used to assess the uncertainty resulting from the heat transfer from the thermometer to the surrounding environment, which allows increased measurement accuracy. The proposed method consists of experimental determination of the sensor’s temperature characteristics in relation to the heating power for different values of the measuring current. Sample measurements were carried out on a representative group of resistance temperature sensors. The relationship of the internal thermal resistance to the type of sensor design and the relationship of the external resistance to the ambient conditions were demonstrated. The developed method allows the appropriate measuring current of the resistance temperature sensor to be selected according to its design, the mounting method, and the environmental conditions, which ensures that measurement errors are maintained at an appropriately low level. Full article
(This article belongs to the Section Physical Sensors)
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22 pages, 5346 KB  
Article
The Effect of Green Areas on Urban Microclimate: A University Campus Model Case
by Gülcay Ercan Oğuztürk, Sude Sünbül and Cem Alparslan
Appl. Sci. 2025, 15(8), 4358; https://doi.org/10.3390/app15084358 - 15 Apr 2025
Cited by 10 | Viewed by 3104
Abstract
Urbanization and the reduction of green spaces have significantly contributed to problems such as rising temperatures and declining air quality in urban areas. This study examines the impact of different types of green areas—broadleaved trees, coniferous trees, shrubs, and vines—on urban temperature regulation [...] Read more.
Urbanization and the reduction of green spaces have significantly contributed to problems such as rising temperatures and declining air quality in urban areas. This study examines the impact of different types of green areas—broadleaved trees, coniferous trees, shrubs, and vines—on urban temperature regulation at the Recep Tayyip Erdoğan University Zihni Derin Campus. Surface temperature, humidity, ambient temperature, and wind speed measurements were collected using an infrared thermometer over a one-year period under various climatic conditions (August, October, January, and April) and at different times of the day (09:00 AM, 01:00 PM, and 05:00 PM). To quantitatively assess the cooling effect of each type of green area, a Response Surface Methodology (RSM) was applied, and a predictive formula was developed to estimate the cooling impact of various green areas under different environmental conditions. These formulated models enable the estimation of the temperature reduction provided by these four plant types based on different input parameters, achieving an accuracy of approximately 92% or higher without requiring direct measurements. The findings of this study provide a robust methodological framework and a practical tool for optimizing green space designs, mitigating urban heat island effects, and enhancing urban living comfort under various climatic conditions. Full article
(This article belongs to the Section Ecology Science and Engineering)
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52 pages, 17724 KB  
Article
Thermal Influence of Volcanic Tephra on Maximum Soil Temperatures: Geoecological Implications for Germination and Distribution of Argyroxiphium sandwicense (Haleakalā, Maui, Hawai’i)
by Francisco Luis Pérez
Geographies 2025, 5(1), 13; https://doi.org/10.3390/geographies5010013 - 11 Mar 2025
Viewed by 3245
Abstract
Mid-day maximum soil temperatures were measured at 10 study plots during different hot summer days in Haleakalā Crater, Maui, with thermocouple thermometers on five adjacent microsite types: bare surface soils, soils under black tephra, soils under reddish tephra, soils shaded by silverswords, and [...] Read more.
Mid-day maximum soil temperatures were measured at 10 study plots during different hot summer days in Haleakalā Crater, Maui, with thermocouple thermometers on five adjacent microsite types: bare surface soils, soils under black tephra, soils under reddish tephra, soils shaded by silverswords, and soils under plant litter. The main tephra morphologies and geomorphic environments, as well as their geoecological association with silversword rosettes (Argyroxiphium sandwicense), were also assessed; silversword density was substantially greater on reddish tephra-covered areas than under black tephra fragments. Silversword seeds are extremely sensitive to high temperatures and fail to germinate after a short exposure to soil temperatures ≥35 °C. Thermal data sets were statistically compared with parallel box plots; the ability of various microsites to provide safe sites for silversword growth was also assessed. Bare soils and black tephra reached the highest median temperatures, up to 48.7 °C and 40.3 °C, respectively; reddish tephra remained much cooler, with all median temperatures ≤30.8 °C. Rosette-shaded soils and soils under silversword litter were the coolest, with temperatures below 18.7 °C and 18.5 °C, respectively. Temperatures in all microsites, except those under black tephra, were significantly lower (p < 0.0001) than on contiguous bare ground. It was concluded that reddish tephra provides the ideal conditions for silversword regeneration. Full article
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21 pages, 320 KB  
Review
Stripping Voltammetry in Trace Ga(III) Analysis Using Different Working Electrodes: A Review
by Malgorzata Grabarczyk, Edyta Wlazlowska and Marzena Fialek
Materials 2025, 18(4), 769; https://doi.org/10.3390/ma18040769 - 10 Feb 2025
Cited by 1 | Viewed by 1813
Abstract
Heavy metal contamination of water has become a global environmental problem in recent years, which is caused by the rapid development of economies and industries. Gallium is of enduring interest because of its wide range of applications in technology and industry. In its [...] Read more.
Heavy metal contamination of water has become a global environmental problem in recent years, which is caused by the rapid development of economies and industries. Gallium is of enduring interest because of its wide range of applications in technology and industry. In its pure form or as a component of alloys, gallium is used in devices such as high-current switches, pressure gauges, and thermometers. Gallium compounds also play an important role in electronics and optoelectronics, particularly in devices that operate in the infrared range. Gallium isotopes are also used in medical diagnostics. The increasing demand for gallium emphasizes the need for accurate methods for its determination in different matrices. One method used for this purpose is stripping voltammetry. The working electrodes, complexing agents, and the influence of interferences on the accuracy of the measurement are discussed in detail, highlighting their crucial role in obtaining the analytical signal of gallium in procedures based on stripping voltammetry. Voltammetric procedures for the simultaneous determination of gallium and other metal ions are also described. The application of the developed procedures to the analysis of real samples is emphasized as crucial for environmental monitoring and the accurate determination of trace concentrations of gallium. A summary of the results is presented in the form of a table which provides detailed information on the stripping voltammetry methods, including the types of working electrodes, characteristics of the substrate electrolytes used, complexing agents, linear ranges, and detection limits. The table also includes accumulation times, interferences investigated, and practical applications of the methods discussed, making it a valuable resource for researchers and analysts involved in environmental analysis. The review highlights the importance of this technique as an accurate and sensitive tool for the analysis of gallium in environmental samples. Full article
18 pages, 2358 KB  
Article
Graphene Oxide Nanoparticles for Photothermal Treatment of Hepatocellular Carcinoma Using Low-Intensity Femtosecond Laser Irradiation
by Charilaos Xenodochidis, Kamelia Hristova-Panusheva, Trayana Kamenska, Poornima Budime Santhosh, Todor Petrov, Lyubomir Stoychev, Julia Genova and Natalia Krasteva
Molecules 2024, 29(23), 5650; https://doi.org/10.3390/molecules29235650 - 28 Nov 2024
Cited by 7 | Viewed by 2658
Abstract
Graphene oxide-mediated photothermal therapy using femtosecond lasers has recently shown promise in treating hepatocellular carcinoma. However, significant work remains to optimize irradiation parameters for specific nanoparticle types and cancer cells to improve nanomaterial-mediated photothermal anticancer therapy. This study investigated the photothermal potential of [...] Read more.
Graphene oxide-mediated photothermal therapy using femtosecond lasers has recently shown promise in treating hepatocellular carcinoma. However, significant work remains to optimize irradiation parameters for specific nanoparticle types and cancer cells to improve nanomaterial-mediated photothermal anticancer therapy. This study investigated the photothermal potential of nGO and nGO-PEG nanoparticles (NPs) combined with femtosecond laser irradiation at 515 nm and 1030 nm wavelengths, with varying power (0.1 and 0.2 W/cm2) and duration (5 and 10 min), to optimize photothermal therapy for hepatocellular carcinoma. Conversion efficiency of NPs, morphology and viability of HepG2 and normal MDCK cells after treatments were evaluated using an electronic thermometer, phase-contrast microscopy, and WST-1 assay. The results revealed that nGO-PEG NPs exhibited better photothermal efficiency than nGO, with 515 nm of irradiation inducing a temperature increase up to 19.1 °C compared to 4.7 °C with 1030 nm of light. Laser exposure to 515 nm significantly reduced HepG2 cell viability, with the most intense conditions (10 min at 0.2 W/cm2) causing a decrease of up to 58.2% with nGO and 43.51% with nGO-PEG. Normal MDCK cells showed minimal impact or a slight viability increase, especially with nGO-PEG. Combined treatment with laser irradiation and NPs induced significant morphological changes in HepG2 cells, including cell detachment and apoptotic-like characteristics, particularly with 1030 nm of irradiation. MDCK cells exhibited minimal morphological changes, with some recovery observed under lower energy conditions. These findings suggest that low-energy lasers and engineered nanomaterials could provide a minimally invasive approach to photothermal cancer therapy with reduced side effects. Full article
(This article belongs to the Special Issue New Nanomaterials for Diagnostic and Drug Delivery)
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