Sign in to use this feature.

Years

Between: -

Subjects

remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline

Journals

remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline

Article Types

Countries / Regions

remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline

Search Results (648)

Search Parameters:
Keywords = thermal infrared region

Order results
Result details
Results per page
Select all
Export citation of selected articles as:
17 pages, 1893 KiB  
Article
Tracking Heat Stress in Broilers: A Thermographic Analysis of Anatomical Sensitivity Across Growth Stages
by Rimena do Amaral Vercellino, Irenilza de Alencar Nääs and Daniella Jorge de Moura
Animals 2025, 15(15), 2233; https://doi.org/10.3390/ani15152233 - 29 Jul 2025
Viewed by 224
Abstract
This study aimed to identify anatomical regions and developmental stages in broiler chickens that serve as reliable thermographic indicators of acute heat stress. Broilers aged 14, 21, 35, and 39 days were exposed to controlled heat stress, and surface temperatures across 12 anatomical [...] Read more.
This study aimed to identify anatomical regions and developmental stages in broiler chickens that serve as reliable thermographic indicators of acute heat stress. Broilers aged 14, 21, 35, and 39 days were exposed to controlled heat stress, and surface temperatures across 12 anatomical regions were recorded using infrared thermography. Thermal response metrics (maximum, minimum, and mean peak variation) were analyzed with repeated-measures ANOVA and eta squared (η2) to quantify the strength of physiological responses. Principal component and cluster analyses grouped body regions based on their thermal sensitivity. The comb and wattle consistently showed the highest temperature increases (ΔT = 2.3–4.1 °C) and strongest effect sizes (η2 ≥ 0.70), establishing them as primary thermoregulatory markers. As age increased, more body regions—especially peripheral zones like the drumstick and tail—exhibited strong responses (η2 > 0.40), indicating an expansion of thermoregulatory activity. Cluster analysis identified three distinct sensitivity groups, confirming anatomical differences in thermal regulation. Thermographic responses to heat stress in broilers depend on age and region. The comb and wattle are the most reliable biomarkers, while peripheral responses grow more prominent with maturity. These findings support the use of targeted, age-specific infrared thermography for monitoring poultry welfare. Full article
Show Figures

Graphical abstract

22 pages, 3083 KiB  
Article
Evaluating the Effect of Thermal Treatment on Phenolic Compounds in Functional Flours Using Vis–NIR–SWIR Spectroscopy: A Machine Learning Approach
by Achilleas Panagiotis Zalidis, Nikolaos Tsakiridis, George Zalidis, Ioannis Mourtzinos and Konstantinos Gkatzionis
Foods 2025, 14(15), 2663; https://doi.org/10.3390/foods14152663 - 29 Jul 2025
Viewed by 355
Abstract
Functional flours, high in bioactive compounds, have garnered increasing attention, driven by consumer demand for alternative ingredients and the nutritional limitations of wheat flour. This study explores the thermal stability of phenolic compounds in various functional flours using visible, near and shortwave-infrared (Vis–NIR–SWIR) [...] Read more.
Functional flours, high in bioactive compounds, have garnered increasing attention, driven by consumer demand for alternative ingredients and the nutritional limitations of wheat flour. This study explores the thermal stability of phenolic compounds in various functional flours using visible, near and shortwave-infrared (Vis–NIR–SWIR) spectroscopy (350–2500 nm), integrated with machine learning (ML) algorithms. Random Forest models were employed to classify samples based on flour type, baking temperature, and phenolic concentration. The full spectral range yielded high classification accuracy (0.98, 0.98, and 0.99, respectively), and an explainability framework revealed the wavelengths most relevant for each class. To address concerns regarding color as a confounding factor, a targeted spectral refinement was implemented by sequentially excluding the visible region. Models trained on the 1000–2500 nm and 1400–2500 nm ranges showed minor reductions in accuracy, suggesting that classification is not solely driven by visible characteristics. Results indicated that legume and wheat flours retain higher total phenolic content (TPC) under mild thermal conditions, whereas grape seed flour (GSF) and olive stone flour (OSF) exhibited notable thermal stability of TPC even at elevated temperatures. These first findings suggest that the proposed non-destructive spectroscopic approach enables rapid classification and quality assessment of functional flours, supporting future applications in precision food formulation and quality control. Full article
Show Figures

Figure 1

21 pages, 2965 KiB  
Article
Inspection Method Enabled by Lightweight Self-Attention for Multi-Fault Detection in Photovoltaic Modules
by Shufeng Meng and Tianxu Xu
Electronics 2025, 14(15), 3019; https://doi.org/10.3390/electronics14153019 - 29 Jul 2025
Viewed by 270
Abstract
Bird-dropping fouling and hotspot anomalies remain the most prevalent and detrimental defects in utility-scale photovoltaic (PV) plants; their co-occurrence on a single module markedly curbs energy yield and accelerates irreversible cell degradation. However, markedly disparate visual–thermal signatures of the two phenomena impede high-fidelity [...] Read more.
Bird-dropping fouling and hotspot anomalies remain the most prevalent and detrimental defects in utility-scale photovoltaic (PV) plants; their co-occurrence on a single module markedly curbs energy yield and accelerates irreversible cell degradation. However, markedly disparate visual–thermal signatures of the two phenomena impede high-fidelity concurrent detection in existing robotic inspection systems, while stringent onboard compute budgets also preclude the adoption of bulky detectors. To resolve this accuracy–efficiency trade-off for dual-defect detection, we present YOLOv8-SG, a lightweight yet powerful framework engineered for mobile PV inspectors. First, a rigorously curated multi-modal dataset—RGB for stains and long-wave infrared for hotspots—is assembled to enforce robust cross-domain representation learning. Second, the HSV color space is leveraged to disentangle chromatic and luminance cues, thereby stabilizing appearance variations across sensors. Third, a single-head self-attention (SHSA) block is embedded in the backbone to harvest long-range dependencies at negligible parameter cost, while a global context (GC) module is grafted onto the detection head to amplify fine-grained semantic cues. Finally, an auxiliary bounding box refinement term is appended to the loss to hasten convergence and tighten localization. Extensive field experiments demonstrate that YOLOv8-SG attains 86.8% mAP@0.5, surpassing the vanilla YOLOv8 by 2.7 pp while trimming 12.6% of parameters (18.8 MB). Grad-CAM saliency maps corroborate that the model’s attention consistently coincides with defect regions, underscoring its interpretability. The proposed method, therefore, furnishes PV operators with a practical low-latency solution for concurrent bird-dropping and hotspot surveillance. Full article
Show Figures

Figure 1

11 pages, 2547 KiB  
Article
Simultaneous Remote Non-Invasive Blood Glucose and Lactate Measurements by Mid-Infrared Passive Spectroscopic Imaging
by Ruka Kobashi, Daichi Anabuki, Hibiki Yano, Yuto Mukaihara, Akira Nishiyama, Kenji Wada, Akiko Nishimura and Ichiro Ishimaru
Sensors 2025, 25(15), 4537; https://doi.org/10.3390/s25154537 - 22 Jul 2025
Viewed by 307
Abstract
Mid-infrared passive spectroscopic imaging is a novel non-invasive and remote sensing method based on Planck’s law. It enables the acquisition of component-specific information from the human body by measuring naturally emitted thermal radiation in the mid-infrared region. Unlike active methods that require an [...] Read more.
Mid-infrared passive spectroscopic imaging is a novel non-invasive and remote sensing method based on Planck’s law. It enables the acquisition of component-specific information from the human body by measuring naturally emitted thermal radiation in the mid-infrared region. Unlike active methods that require an external light source, our passive approach harnesses the body’s own emission, thereby enabling safe, long-term monitoring. In this study, we successfully demonstrated the simultaneous, non-invasive measurements of blood glucose and lactate levels of the human body using this method. The measurements, conducted over approximately 80 min, provided emittance data derived from mid-infrared passive spectroscopy that showed a temporal correlation with values obtained using conventional blood collection sensors. Furthermore, to evaluate localized metabolic changes, we performed k-means clustering analysis of the spectral data obtained from the upper arm. This enabled visualization of time-dependent lactate responses with spatial resolution. These results demonstrate the feasibility of multi-component monitoring without physical contact or biological sampling. The proposed technique holds promise for translation to medical diagnostics, continuous health monitoring, and sports medicine, in addition to facilitating the development of next-generation healthcare technologies. Full article
(This article belongs to the Special Issue Feature Papers in Sensing and Imaging 2025)
Show Figures

Figure 1

25 pages, 11642 KiB  
Article
Non-Invasive Estimation of Crop Water Stress Index and Irrigation Management with Upscaling from Field to Regional Level Using Remote Sensing and Agrometeorological Data
by Emmanouil Psomiadis, Panos I. Philippopoulos and George Kakaletris
Remote Sens. 2025, 17(14), 2522; https://doi.org/10.3390/rs17142522 - 20 Jul 2025
Viewed by 448
Abstract
Precision irrigation plays a crucial role in managing crop production in a sustainable and environmentally friendly manner. This study builds on the results of the GreenWaterDrone project, aiming to estimate, in real time, the actual water requirements of crop fields using the crop [...] Read more.
Precision irrigation plays a crucial role in managing crop production in a sustainable and environmentally friendly manner. This study builds on the results of the GreenWaterDrone project, aiming to estimate, in real time, the actual water requirements of crop fields using the crop water stress index, integrating infrared canopy temperature, air temperature, relative humidity, and thermal and near-infrared imagery. To achieve this, a state-of-the-art aerial micrometeorological station (AMMS), equipped with an infrared thermal sensor, temperature–humidity sensor, and advanced multispectral and thermal cameras is mounted on an unmanned aerial system (UAS), thus minimizing crop field intervention and permanently installed equipment maintenance. Additionally, data from satellite systems and ground micrometeorological stations (GMMS) are integrated to enhance and upscale system results from the local field to the regional level. The research was conducted over two years of pilot testing in the municipality of Trifilia (Peloponnese, Greece) on pilot potato and watermelon crops, which are primary cultivations in the region. Results revealed that empirical irrigation applied to the rhizosphere significantly exceeded crop water needs, with over-irrigation exceeding by 390% the maximum requirement in the case of potato. Furthermore, correlations between high-resolution remote and proximal sensors were strong, while associations with coarser Landsat 8 satellite data, to upscale the local pilot field experimental results, were moderate. By applying a comprehensive model for upscaling pilot field results, to the overall Trifilia region, project findings proved adequate for supporting sustainable irrigation planning through simulation scenarios. The results of this study, in the context of the overall services introduced by the project, provide valuable insights for farmers, agricultural scientists, and local/regional authorities and stakeholders, facilitating improved regional water management and sustainable agricultural policies. Full article
Show Figures

Figure 1

23 pages, 4267 KiB  
Article
Proof of Concept of an Integrated Laser Irradiation and Thermal/Visible Imaging System for Optimized Photothermal Therapy in Skin Cancer
by Diogo Novas, Alessandro Fortes, Pedro Vieira and João M. P. Coelho
Sensors 2025, 25(14), 4495; https://doi.org/10.3390/s25144495 - 19 Jul 2025
Viewed by 390
Abstract
Laser energy is widely used as a selective photothermal heating agent in cancer treatment, standing out for not relying on ionizing radiation. However, in vivo tests have highlighted the need to develop irradiation techniques that allow precise control over the illuminated area, adapting [...] Read more.
Laser energy is widely used as a selective photothermal heating agent in cancer treatment, standing out for not relying on ionizing radiation. However, in vivo tests have highlighted the need to develop irradiation techniques that allow precise control over the illuminated area, adapting it to the tumor size to further minimize damage to surrounding healthy tissue. To address this challenge, a proof of concept based on a laser irradiation system has been designed, enabling control over energy, exposure time, and irradiated area, using galvanometric mirrors. The control software, implemented in Python, employs a set of cameras (visible and infrared) to detect and monitor real-time thermal distributions in the region of interest, transmitting this information to a microcontroller responsible for adjusting the laser power and controlling the scanning process. Image alignment procedures, tunning of the controller’s gain parameters and the impact of the different engineering parameters are illustrated on a dedicated setup. As proof of concept, this approach has demonstrated the ability to irradiate a phantom of black modeling clay within an area of up to 5 cm × 5 cm, from 15 cm away, as well as to monitor and regulate the temperature over time (5 min). Full article
Show Figures

Graphical abstract

22 pages, 10488 KiB  
Article
Morphological and Functional Evolution of Amorphous AlN Thin Films Deposited by RF-Magnetron Sputtering
by Maria-Iulia Zai, Ioana Lalau, Marina Manica, Lucia Chiriacescu, Vlad-Andrei Antohe, Cristina C. Gheorghiu, Sorina Iftimie, Ovidiu Toma, Mirela Petruta Suchea and Ștefan Antohe
Surfaces 2025, 8(3), 51; https://doi.org/10.3390/surfaces8030051 - 17 Jul 2025
Viewed by 320
Abstract
Aluminum nitride (AlN) thin films were deposited on SiO2 substrates by RF-magnetron sputtering at varying powers (110–140 W) and subsequently subjected to thermal annealing at 450 °C under nitrogen atmosphere. A comprehensive multi-technique investigation—including X-ray reflectometry (XRR), X-ray diffraction (XRD), scanning electron [...] Read more.
Aluminum nitride (AlN) thin films were deposited on SiO2 substrates by RF-magnetron sputtering at varying powers (110–140 W) and subsequently subjected to thermal annealing at 450 °C under nitrogen atmosphere. A comprehensive multi-technique investigation—including X-ray reflectometry (XRR), X-ray diffraction (XRD), scanning electron microscopy (SEM), atomic force microscopy (AFM), optical profilometry, spectroscopic ellipsometry (SE), and electrical measurements—was performed to explore the physical structure, morphology, and optical and electrical properties of the films. The analysis of the film structure by XRR revealed that increasing sputtering power resulted in thicker, denser AlN layers, while thermal treatment promoted densification by reducing density gradients but also induced surface roughening and the formation of island-like morphologies. Optical studies confirmed excellent transparency (>80% transmittance in the near-infrared region) and demonstrated the tunability of the refractive index with sputtering power, critical for optoelectronic applications. The electrical characterization of Au/AlN/Al sandwich structures revealed a transition from Ohmic to trap-controlled space charge limited current (SCLC) behavior under forward bias—a transport mechanism frequently present in a material with very low mobility, such as AlN—while Schottky conduction dominated under reverse bias. The systematic correlation between deposition parameters, thermal treatment, and the resulting physical properties offers valuable pathways to engineer AlN thin films for next-generation optoelectronic and high-frequency device applications. Full article
(This article belongs to the Special Issue Surface Engineering of Thin Films)
Show Figures

Graphical abstract

13 pages, 4656 KiB  
Article
High-Speed and Hysteresis-Free Near-Infrared Optical Hydrogen Sensor Based on Ti/Pd Bilayer Thin Films
by Ashwin Thapa Magar, Tu Anh Ngo, Hoang Mai Luong, Thi Thu Trinh Phan, Minh Tuan Trinh, Yiping Zhao and Tho Duc Nguyen
Nanomaterials 2025, 15(14), 1105; https://doi.org/10.3390/nano15141105 - 16 Jul 2025
Viewed by 503
Abstract
Palladium (Pd) and titanium (Ti) exhibit opposite dielectric responses upon hydrogenation, with stronger effects observed in the near-infrared (NIR) region. Leveraging this contrast, we investigated Ti/Pd bilayer thin films as a platform for NIR hydrogen sensing—particularly at telecommunication-relevant wavelengths, where such devices have [...] Read more.
Palladium (Pd) and titanium (Ti) exhibit opposite dielectric responses upon hydrogenation, with stronger effects observed in the near-infrared (NIR) region. Leveraging this contrast, we investigated Ti/Pd bilayer thin films as a platform for NIR hydrogen sensing—particularly at telecommunication-relevant wavelengths, where such devices have remained largely unexplored. Ti/Pd bilayers coated with Teflon AF (TAF) and fabricated via sequential electron-beam and thermal evaporation were characterized using optical transmission measurements under repeated hydrogenation cycles. The Ti (5 nm)/Pd (x = 2.5 nm)/TAF (30 nm) architecture showed a 2.7-fold enhancement in the hydrogen-induced optical contrast at 1550 nm compared to Pd/TAF reference films, attributed to the hydrogen ion exchange between the Ti and Pd layers. The optimized structure, with a Pd thickness of x = 1.9 nm, exhibited hysteresis-free sensing behavior, a rapid response time (t90 < 0.35 s at 4% H2), and a detection limit below 10 ppm. It also demonstrated excellent selectivity with negligible cross-sensitivity to CO2, CH4, and CO, as well as high durability, showing less than 6% signal degradation over 135 hydrogenation cycles. These findings establish a scalable, room-temperature NIR hydrogen sensing platform with strong potential for deployment in automotive, environmental, and industrial applications. Full article
Show Figures

Figure 1

23 pages, 4200 KiB  
Article
Thermal Multi-Sensor Assessment of the Spatial Sampling Behavior of Urban Landscapes Using 2D Turbulence Indicators
by Gabriel I. Cotlier, Drazen Skokovic, Juan Carlos Jimenez and José Antonio Sobrino
Remote Sens. 2025, 17(14), 2349; https://doi.org/10.3390/rs17142349 - 9 Jul 2025
Viewed by 284
Abstract
Understanding spatial variations in land surface temperature (LST) is critical for analyzing urban climate dynamics, especially within the framework of two-dimensional (2D) turbulence theory. This study assesses the spatial sampling behavior of urban thermal fields across eight metropolitan areas, encompassing diverse morphologies, surface [...] Read more.
Understanding spatial variations in land surface temperature (LST) is critical for analyzing urban climate dynamics, especially within the framework of two-dimensional (2D) turbulence theory. This study assesses the spatial sampling behavior of urban thermal fields across eight metropolitan areas, encompassing diverse morphologies, surface materials, and Köppen–Geiger climate zones. We analyzed thermal infrared (TIR) imagery from two remote sensing platforms—MODIS (1 km) and Landsat (30 m)—to evaluate resolution-dependent turbulence indicators such as spectral slopes and breakpoints. Power spectral analysis revealed systematic divergences across spatial scales. Landsat exhibited more negative breakpoint values, indicating a greater ability to capture fine-scale thermal heterogeneity tied to vegetation, buildings, and surface cover. MODIS, in contrast, emphasized broader thermal gradients, suitable for regional-scale assessments. Seasonal differences reinforced the turbulence framework: summer spectra displayed steeper, more variable slopes, reflecting increased thermal activity and surface–atmosphere decoupling. Despite occasional agreement between sensors, spectral metrics remain inherently resolution-dependent. MODIS is better suited for macro-scale thermal structures, while Landsat provides detailed insights into intra-urban processes. Our findings confirm that 2D turbulence indicators are not fully scale-invariant and vary with sensor resolution, season, and urban form. This multi-sensor comparison offers a framework for interpreting LST data in support of climate adaptation, urban design, and remote sensing integration. Full article
Show Figures

Figure 1

20 pages, 5206 KiB  
Article
Self-Powered Photodetectors with Ultra-Broad Spectral Response and Thermal Stability for Broadband, Energy Efficient Wearable Sensing and Optoelectronics
by Peter X. Feng, Elluz Pacheco Cabrera, Jin Chu, Badi Zhou, Soraya Y. Flores, Xiaoyan Peng, Yiming Li, Liz M. Diaz-Vazquez and Andrew F. Zhou
Molecules 2025, 30(14), 2897; https://doi.org/10.3390/molecules30142897 - 8 Jul 2025
Viewed by 391
Abstract
This work presents a high-performance novel photodetector based on two-dimensional boron nitride (BN) nanosheets functionalized with gold nanoparticles (Au NPs), offering ultra-broadband photoresponse from 0.25 to 5.9 μm. Operating in both photovoltaic and photoconductive modes, the device features rapid response times (<0.5 ms), [...] Read more.
This work presents a high-performance novel photodetector based on two-dimensional boron nitride (BN) nanosheets functionalized with gold nanoparticles (Au NPs), offering ultra-broadband photoresponse from 0.25 to 5.9 μm. Operating in both photovoltaic and photoconductive modes, the device features rapid response times (<0.5 ms), high responsivity (up to 1015 mA/W at 250 nm and 2.5 V bias), and thermal stability up to 100 °C. The synthesis process involved CO2 laser exfoliation of hexagonal boron nitride, followed by gold NP deposition via RF sputtering and thermal annealing. Structural and compositional analyses confirmed the formation of a three-dimensional network of atomically thin BN nanosheets decorated with uniformly distributed gold nanoparticles. This architecture facilitates plasmon-enhanced absorption and efficient charge separation via heterojunction interfaces, significantly boosting photocurrent generation across the deep ultraviolet (DUV), visible, near-infrared (NIR), and mid-infrared (MIR) spectral regions. First-principles calculations support the observed broadband response, confirming bandgap narrowing induced by defects in h-BN and functionalization by gold nanoparticles. The device’s self-driven operation, wide spectral response, and durability under elevated temperatures underscore its strong potential for next-generation broadband, self-powered, and wearable sensing and optoelectronic applications. Full article
(This article belongs to the Special Issue Novel Nanomaterials: Sensing Development and Applications)
Show Figures

Figure 1

12 pages, 3441 KiB  
Article
Mechanical Strength and Hydration Characteristic of Multiple Common Waste-Blended Cement-Based Materials Cured by Electric-Induced Heating Curing Under Severely Cold Environments
by Lei Zhang, Ruisen Li, Sheng Li, Han Wang and Qiang Fu
Materials 2025, 18(14), 3220; https://doi.org/10.3390/ma18143220 - 8 Jul 2025
Viewed by 305
Abstract
To address the challenges of concrete construction in polar regions, this study investigates the feasibility of fabricating cement-based materials under severely low temperatures using electric-induced heating curing methods. Cement mortars incorporating fly ash (FA-CM), ground granulated blast furnace slag (GGBS-CM), and metakaolin (MK-CM) [...] Read more.
To address the challenges of concrete construction in polar regions, this study investigates the feasibility of fabricating cement-based materials under severely low temperatures using electric-induced heating curing methods. Cement mortars incorporating fly ash (FA-CM), ground granulated blast furnace slag (GGBS-CM), and metakaolin (MK-CM) were cured at environmental temperatures of −20 °C, −40 °C, and −60 °C. The optimal carbon fiber (CF) contents were determined using the initial electric resistivity to ensure a consistent electric-induced heating curing process. The thermal profiles during curing were monitored, and mechanical strength development was systematically evaluated. Hydration characteristics were elucidated through thermogravimetric analysis (TG), X-ray diffraction (XRD), and Fourier-transform infrared spectroscopy (FTIR) to identify phase compositions and reaction products. Results demonstrate that electric-induced heating effectively mitigates the adverse effect caused by the ultra-low temperature constraints, with distinct differences in the strength performance and hydration kinetics among supplementary cementitious materials. MK-CM exhibited superior early strength development with strength increasing rates above 10% compared to the Ref. specimen, which was attributed to the accelerated pozzolanic reactions. Microstructural analyses further verified the macroscopic strength test results that showed that electric-induced heating curing can effectively promote the performance development even under severely cold environments with a higher hydration degree and refined micro-pore structure. This work proposes a viable strategy for polar construction applications. Full article
Show Figures

Figure 1

18 pages, 4181 KiB  
Article
Crystal Structure Features, Spectroscopic Characteristics and Thermal Conversions of Sulfur-Bearing Groups: New Natural Commensurately Modulated Haüyne Analogue, Na6Ca2−x(Si6Al6O24)(SO42−,HS,S2●−,S4,S3●−,S52−)2−y
by Nikita V. Chukanov, Natalia V. Zubkova, Roman Yu. Shendrik, Anatoly N. Sapozhnikov, Igor V. Pekov, Marina F. Vigasina, Nadezhda A. Chervonnaya, Dmitry A. Varlamov, Nadezhda B. Bolotina, Dmitry A. Ksenofontov and Dmitry Yu. Pushcharovsky
Minerals 2025, 15(7), 709; https://doi.org/10.3390/min15070709 - 3 Jul 2025
Viewed by 345
Abstract
A multimethodic approach based on infrared, Raman, electron spin resonance and photoluminescence spectroscopy, absorption spectroscopy in near infrared, visible and ultraviolet regions, single-crystal X-ray diffraction as well as electron microprobe analyses was applied to the characterization of a new commensurately modulated cubic haüyne [...] Read more.
A multimethodic approach based on infrared, Raman, electron spin resonance and photoluminescence spectroscopy, absorption spectroscopy in near infrared, visible and ultraviolet regions, single-crystal X-ray diffraction as well as electron microprobe analyses was applied to the characterization of a new commensurately modulated cubic haüyne analogue with the modulation parameter of 0.2 and unit-cell parameter of 45.3629(3) Å (designated as haüyne-45Å) from the Malobystrinskoe lazurite deposit, in the Baikal Lake area, Siberia, Russia, as well as associated SO32−-bearing afghanite. Haüyne-45Å is the second member, after vladimirivanovite, of the sodalite group with a commensurately modulated structure. The average structure is based on the tetrahedral aluminosilicate sodalite-type framework with sodalite cages of different sizes. The simplified formula of haüyne-45Å is Na6Ca2−x(Si6Al6O24)(SO42−,HS,S2●−,S4,S3●−,S52−)2−y. The structural modulations of the haüyne-45Å framework are presumably related to the regular alternation of SO42− anions with polysulfide S2●−, S3●−, S4, and S52− groups detected by the spectroscopic methods. Mechanisms of thermal conversions of S-bearing groups in haüyne-45Å under oxidizing and reducing conditions at temperatures up to 800 °C are studied, and their geochemical importance is discussed. Full article
(This article belongs to the Special Issue Crystal Chemistry of Sulfate Minerals and Synthetic Compounds)
Show Figures

Figure 1

13 pages, 3753 KiB  
Article
Highly Transparent Yb:Y2O3 Laser Ceramics with High Thermal Conductivity Obtained via a Sintering-Additive-Free Strategy
by Zhongchao Fu, Qiang Wu, Nan Wu, Haibo Long, Jinsheng Li, Yi Ren and Zhaoxia Hou
Inorganics 2025, 13(7), 217; https://doi.org/10.3390/inorganics13070217 - 27 Jun 2025
Viewed by 532
Abstract
Fine-grained Yb:Y2O3 laser ceramics with excellent transmittance and thermal conductivity were fabricated from commercial powders. The process involved aqueous colloidal forming, additive-free air pre-sintering at 1400 °C, and hot isostatic pressing at 1550 °C. Suspensions were prepared with a deionization [...] Read more.
Fine-grained Yb:Y2O3 laser ceramics with excellent transmittance and thermal conductivity were fabricated from commercial powders. The process involved aqueous colloidal forming, additive-free air pre-sintering at 1400 °C, and hot isostatic pressing at 1550 °C. Suspensions were prepared with a deionization process to alleviate the hydrolysis issue, which optimizes the microstructure uniformity and enhances the green compacts’ density after consolidation. The microstructure, in-line transmittance, microhardness, and fracture toughness of the Yb3+-doped Y2O3 ceramics with different concentrations were measured. The 5.0 at% Yb3+-doped Y2O3 ceramic yielded a superior transmittance of 80.1% at 1100 nm and 83.0% in the mid-infrared region. The average grain size was 752 nm. The sample exhibited a thermal conductivity of 9.94 W·m−1·K−1 while achieving a 1076 nm laser output with a 42 mW peak power and 4.3% slope efficiency. Full article
(This article belongs to the Special Issue Preparation and Application of Transparent Ceramics)
Show Figures

Figure 1

22 pages, 11262 KiB  
Article
Toward Aerosol-Aware Thermal Infrared Radiance Data Assimilation
by Shih-Wei Wei, Cheng-Hsuan (Sarah) Lu, Emily Liu, Andrew Collard, Benjamin Johnson, Cheng Dang and Patrick Stegmann
Atmosphere 2025, 16(7), 766; https://doi.org/10.3390/atmos16070766 - 22 Jun 2025
Viewed by 355
Abstract
Aerosols considerably reduce the upwelling radiance in the thermal infrared (IR) window; thus, it is worthwhile to understand the effects and challenges of assimilating aerosol-affected (i.e., hazy-sky) IR observations for all-sky data assimilation (DA). This study introduces an aerosol-aware DA framework for the [...] Read more.
Aerosols considerably reduce the upwelling radiance in the thermal infrared (IR) window; thus, it is worthwhile to understand the effects and challenges of assimilating aerosol-affected (i.e., hazy-sky) IR observations for all-sky data assimilation (DA). This study introduces an aerosol-aware DA framework for the Infrared Atmospheric Sounder Interferometer (IASI) to exploit hazy-sky IR observations and investigate the impact of assimilating hazy-sky IR observations on analyses and subsequent forecasts. The DA framework consists of the detection of hazy-sky pixels and an observation error model as the function of the aerosol effect. Compared to the baseline experiment, the experiment utilized an aerosol-aware framework that reduces biases in the sea surface temperature in the tropical region, particularly over the areas affected by heavy dust plumes. There are no significant differences in the evaluation of the analyses and the 7-day forecasts between the experiments. To further improve the aerosol-aware framework, the enhancements in quality control (e.g., aerosol detection) and bias correction need to be addressed in the future. Full article
Show Figures

Figure 1

17 pages, 4602 KiB  
Article
Dual-Plasma Discharge Tube for Synergistic Glioblastoma Treatment
by William Murphy, Alex Horkowitz, Vikas Soni, Camil Walkiewicz-Yvon and Michael Keidar
Cancers 2025, 17(12), 2036; https://doi.org/10.3390/cancers17122036 - 18 Jun 2025
Viewed by 495
Abstract
Background: Glioblastoma (GBM) resists current therapies due to its rapid proliferation, diffuse invasion, and heterogeneous cell populations. We previously showed that a single cold atmospheric plasma discharge tube (DT) reduces GBM viability via broad-spectrum electromagnetic (EM) emissions. Here, we tested whether two DTs [...] Read more.
Background: Glioblastoma (GBM) resists current therapies due to its rapid proliferation, diffuse invasion, and heterogeneous cell populations. We previously showed that a single cold atmospheric plasma discharge tube (DT) reduces GBM viability via broad-spectrum electromagnetic (EM) emissions. Here, we tested whether two DTs arranged in a helmet configuration could generate overlapping EM fields to amplify the anti-tumor effects without thermal injury. Methods: The physical outputs of the single- and dual-DT setups were characterized by infrared thermography, broadband EM field probes, and oscilloscope analysis. Human U87-MG cells were exposed under the single or dual configurations. The viability was quantified with WST-8 assays mapped across 96-well plates; the intracellular reactive oxygen species (ROS), membrane integrity, apoptosis, and mitochondrial potential were assessed by multiparametric flow cytometry. Our additivity models compared the predicted versus observed dual-DT cytotoxicity. Results: The dual-DT operation produced constructive EM interference, elevating electric and magnetic field amplitudes over a broader area than either tube alone, while temperatures remained <39 °C. The single-DT exposure lowered the cell viability by ~40%; the dual-DT treatment reduced the viability by ~60%, exceeding the additive predictions. The regions of greatest cytotoxicity co-localized with the zones of highest EM field overlap. The dual-DT exposure doubled the intracellular ROS compared with single-DT and Annexin V positivity, confirming oxidative stress-driven cell death. The out-of-phase operation of the discharge tubes enabled the localized control of the treatment regions, which can guide future treatment planning. Conclusions: Two synchronously operated plasma discharge tubes synergistically enhanced GBM cell killing through non-thermal mechanisms that coupled intensified overlapping EM fields with elevated oxidative stress. This positions modular multi-DT arrays as a potential non-invasive adjunct or alternative to existing electric-field-based therapies for glioblastoma. Full article
(This article belongs to the Special Issue Plasma and Cancer Treatment)
Show Figures

Figure 1

Back to TopTop