Search Results (1,363)

Photovoltaic (PV) performance in desert environments is significantly hindered by soiling and partial shading. To bridge the gap in empirical data for extreme Saharan conditions, this study presents a novel techno-economic assessment of uniform horizontal shading (UHS) specifically conducted in Mauritania. Controlled outdoor experiments were performed using a 250 W crystalline silicon PV module and a PVPM 2540C I–V curve tracer, applying progressive shading levels from 2.5% to 20%. The novelty of this work lies in the integration of high-resolution experimental I–V/P–V characterization with a localized techno-economic model for five pre-commercial PV plants. It was observed that PV modules are exceptionally sensitive to shading; specifically, a mere 10% shaded area leads to a catastrophic 90% drop in power and current, while the voltage remains remarkably stable. Thermographic analysis further validates the thermal gradients and bypass diode functionality. By quantifying the financial impacts, this research highlights that cumulative economic losses across the five real-world sites reached 87.95%, exceeding 55,000 MRU. These findings provide a strategic framework for optimizing PV systems in arid terrains and offer a robust tool for enhancing the design and operation of large-scale solar applications in desert environments. Full article

The objective of this study was to evaluate the impact of seasonal changes in the chemical and structural composition of giant miscanthus (Miscanthus × giganteus) biomass on the performance, kinetics, and efficiency of anaerobic digestion (AD), as well as on the overall energy and techno-economic balance of the conversion chain. The AD performance was assessed using batch biochemical methane potential (BMP) assays conducted for eight harvest dates (June–January). Comprehensive characterization included fundamental physicochemical properties of the biomass, lignocellulosic fraction composition, AD kinetics, and methane production yield. A statistically significant (p < 0.05) increase in structural fiber fractions was observed with advancing plant maturity, accompanied by a progressive decline in specific methane yield from 281 ± 32 mL CH₄/g VS in June to 170 ± 11–172 ± 13 mL CH₄/g VS in winter harvests. Despite a relatively stable theoretical biochemical methane potential (TBMP) ranging from 425 to 443 mL CH₄/g VS, the conversion efficiency (BMP/TBMP) decreased from approximately 66% to below 40%, indicating increasing structural and kinetic limitations to substrate biodegradability. Kinetic parameters deteriorated systematically in late harvests, as reflected by a reduction in the first-order rate constant k_CH₄ from 0.115 to approximately 0.072 1/d and an extension of the lag phase λ from 2.19 to over 4 days. Regression analysis revealed strong negative correlations between lignocellulosic complex content and both BMP and k_CH₄, whereas the C/N ratio exhibited a positive association with process performance under the experimental conditions applied. The highest methane production per hectare (3904 ± 720 m³CH₄/ha) and the most favorable economic outcome (1979 ± 465 EUR/ha) were achieved for the September harvest. The results demonstrate that harvest timing constitutes a critical optimization parameter in lignocellulosic biogas systems, governing not only methane yield and process kinetics but also the overall energy output and economic viability of the bioenergy production chain. Full article

The transition from petrochemical plastics to sustainable biopolymers has created a critical demand for functional materials that do not compromise on performance. Starch and zein, due to their abundance and complementary nature, represent not just a chemical pair, but a techno-economic symbiosis: zein provides the hydrophobic shield, while starch offers the cost-effective structural volume. This review adopts a “Puzzle Theory” framework to synthesize over 80 peer-reviewed studies published between 2014 and 2025, categorizing the literature into established structural knowledge and unresolved functional limitations. Our analysis reveals that while fabrication protocols and molecular synergy are well-defined in approximately 65% of the surveyed literature, critical functional data remain largely absent. Specifically, fewer than 15% of studies investigate hydro-stability in high-humidity environments or bio-interface behavior, creating a disconnect between laboratory success and industrial application. We identify that current research disproportionately prioritizes dry-state morphology over wet-state mechanical integrity. To bridge the gap between academic prototypes and industrial reality, this article moves beyond general recommendations to propose concrete experimental benchmarks, including specific targets for wet mechanical integrity (>1 MPa), regulatory solvent compliance (<50 ppm), and scalable throughput. This article concludes by providing a strategic roadmap to bridge these gaps, arguing that future research must pivot from simple morphological characterization to developing “smart response” mechanisms and “green manufacturing” protocols to ensure commercial viability. Full article

Carbon capture and storage technologies are widely adopted, primarily in conventional power plants. Maritime transport must align with the 2050 targets and sharply reduce its environmental footprint. Onboard Carbon Capture and Storage (OCCS) appear to be an immediately feasible solution until alternative fuels are adopted and fully implemented. This study presents a regulatory compliance assessment and a techno-economic analysis of the implementation of OCCS. An LNG tanker was selected as a case study due to the inherent compatibility between LNG storage systems and CO₂ storage on board. The examined regulation includes the calculation of the corresponding penalties arising from the enforcement of the EU ETS, FuelEU Maritime, and the IMO NZF framework. The cost of installing the OCCS is also considered when evaluating the proposal’s sustainability. The results demonstrate that OCCS shows real promise in the fight against maritime transport emissions, but at present, it is not economically viable. Its viability depends mainly on clear regulatory guidelines and effective incentives that encourage its adoption, while offsetting investment and operating costs. Finally, the current study also seeks to resolve an ambiguity in the existing legislation that renders the OCCS a viable option. Full article

The upscaling of turbines in the offshore wind industry has been unprecedented, as compared to 5–6 MW rated turbines 10 years ago. A typical 20–26 MW rated turbine in modern commercial applications (MingYang MySE 18.X-20 MW installed in 2025 and 26 MW prototype by Dongfang Electric tested in 2025) has been demonstrated. This scaling has been made possible by increasing rotor diameters (>250 m) and hub heights (>150–180 m) to achieve capacity factors of up to 55–65%, annual energy generation of more than 80 GWh/turbine, and significant decreases in levelised cost of energy (LCOE) to current values of up to 63–65 USD 2023/MWh globally averaged in 2023 (with minor variability in 2024 due to market changes and new regional areas). The paper analyses turbine upscaling over three levels of hierarchy, including turbine scale—rated capacity and physical aspect, project scale—multi-gigawatts of farms, and market scale—the global pipeline > 1500 GW level, and combines techno-economic evaluation, structural evaluation of loads, and infrastructure needs assessment. The upscaling has the advantage of reducing the number of turbines dramatically (e.g., 500 to 67 turbines in a 1 GW farm, as turbine size is increased to 15 MW) and balancing-of-plant (BoP) CAPEX (turbine-to-turbine foundations and cables) by some 20 to 30 percent per unit of capacity, and serial production learning rates of between 15 and 18% per doubling of capacity. But the problems that come with the increase in ultra-large designs are nonlinear increments in mass and load (i.e., blade-root and tower-bending moments), logistical constraints (blades > 120 m, nacelle up to 800–1000 tonnes demanding special vessels and ports), supply-chain issues (rare-earth materials, vessel shortages increase day rates by 30–50%), and technology limitations (aeroelastic compounded by numerical differences between reference 5 MW, 10 MW, and 15 MW models), it becomes evident that there is a significant increase in deflections of the tower and blades and platform surge/pitch responses with continued increases in power levels, but without a correspondingly mature infrastructure. The regional differences (mature ports of Europe vs. U.S. Jones Act restrictions vs. scale-up of vessels/manufacturing in China) lead to the necessity of optimisation depending on the context. The analysis concludes that, to the extent of mature markets with adapted logistics, continuous upscaling is an effective business strategy and can result in 5 to 12 percent further reductions in LCOE, but beyond that point, gains become marginal or even negative, as risks and costs increase. The competitiveness of the future depends on multi-scale/multi-market-based approaches—modular-based families of turbines, programmatic standardisation, vibration control innovations, and industry coordination towards supply-chain alignment and standards. Its major strength is that it transcends mere size–cost relationships and shows how nonlinear structural processes, aero-hydro-servo-elastic interactions, and bottlenecks in logistical systems are becoming more determinant of the efficiency of ultra-large turbines. The study demonstrates that upscaling turbines has LCOE benefits through the support of associated improvements in installation facility, supply-chain preparedness, and structural vibration control potential, based on the comparisons of quantitative loads, techno-economic scaling trends, and regional market differentiation. Full article

Power-to-X technologies play a crucial role in accelerating the energy and material transition. A key opportunity lies in integrating these systems with existing bio-based infrastructures such as anaerobic digesters, providing a reliable source of biogenic carbon. Developing effective Power-to-Methanol (PtM) pathways requires a comprehensive understanding of process behavior through detailed simulation, including technical performance, economic feasibility, and environmental consequences. Despite growing interest, substantial variation remains in published levelized methanol costs, and many assessments insufficiently account for the full environmental footprint of production routes. This study evaluates the potential of PtM deployment in the Netherlands by comparing two pathways that utilize biogenic carbon sources: (i) hydrogenation of captured CO₂ using green hydrogen and (ii) dry methane reforming (DMR) of biogas, followed by catalytic syngas conversion to methanol. Results indicate that operational expenses—mainly driven by renewable electricity consumption—far outweigh capital investment. Both routes yield an LCoMeOH of approximately €2630 per tonne, about five times the cost of fossil-based methanol. Life cycle analysis shows that DMR performs more favorably overall, although elevated freshwater ecotoxicity and eutrophication result from digestate application as fertilizer. Continued improvements in renewable energy integration and nutrient recovery technologies are essential for enhancing future economic and environmental performance. Full article

The transportation sector’s decarbonization represents one of the most critical challenges in achieving global climate targets. This study presents a comprehensive analysis of an integrated renewable energy system that produces green hydrogen through a hybrid solar photovoltaic (PV) and wind power configuration. The proposed system combines a 1.2 MWp solar array with 800 kW wind turbines, feeding a 1 MW proton exchange membrane (PEM) electrolyzer for hydrogen production. The hydrogen is subsequently compressed, stored at 350 (for trucks and buses) and 700 bar (for cars), and then utilized either directly for fuel cell electric vehicles (FCEVs) or reconverted to electricity via a 250 kW stationary PEM fuel cell to support electric vehicle (EV) charging infrastructure. Through detailed techno-economic simulation using HOMER Pro and MATLAB/Simulink 2022a, we demonstrate that the hybrid configuration achieves a 71% electrolyzer capacity factor, producing 55.8 tonnes of hydrogen annually with a levelized cost of 5.82 €/kg. The system ensures over 60 h of grid-independent operation while reducing CO₂ emissions by 1656 tones annually compared to conventional grid-powered alternatives. Results indicate that hybrid renewable hydrogen systems can provide economically viable solutions for sustainable mobility infrastructure, with projected cost reductions making them competitive with fossil fuel alternatives by 2030. Full article

Chile stands out for its renewable energy resources and its commitment to developing green hydrogen. However, achieving cost parity with gray hydrogen remains an obstacle, mainly due to high capital costs and sensitivity to scale. This study assesses the technical and economic feasibility of green hydrogen production, using five different plants located in the Magallanes region in the south of the country as a reference. The model integrates a detailed framework of wind generation, PEM electrolysis, compression, and high-pressure storage subsystems, as well as a stochastic economic layer that combines the CAPEX, NPV, and LCOH assessments using Monte Carlo simulations. It also incorporates real-world capacity distributions and probabilistic fluctuations in systems. A sensitivity analysis confirms production scale as the main factor affecting profitability, with a break-even threshold of 0.5 MW. The results show that the LCOH decreases from 7.1 USD to 3.4 USD/kgH₂ as capacity increases. The analysis reveals that only 23.88% of small-scale configurations yield positive NPV, underscoring the need for scaling to achieve economic viability. Full article

Ulaanbaatar, the capital of Mongolia, operates one of the world’s largest district heating (DH) systems in the coldest national capital (heating degree-days ~5800). Despite serving over 60% of the city’s 1.6 million residents, the current 3rd generation DH system suffers from high thermal losses (~17–18%) and relies on coal-fired combined heat and power plants. Transitioning to 4th generation district heating (4GDH) with lower supply temperatures could reduce these losses while enabling future low-temperature renewable energy integration. A geographic information system (GIS)-based spatial heat load density (HLD) analysis uses operational data from the Ulaanbaatar District Heating Company, encompassing 13,500 buildings with a total connected capacity of 3924 MW. Grid-based spatial analysis was performed at two resolutions (1 km² and 2 km²). Threshold sensitivity analysis was conducted across HLD criteria of 1–5 MW/km². Results indicate that median HLD values exceed the European reference threshold of 3 MW/km², with log-normal distributions confirmed by Shapiro–Wilk tests. Three candidate pilot zones were identified. A hybrid temperature strategy (65/35 °C above −25 °C; 90/60 °C below) further contextualizes the findings. These results suggest spatially favorable conditions for 4GDH development, providing a quantitative foundation for subsequent techno-economic feasibility studies. Full article

Plastic waste gasification offers a dual-benefit pathway for hydrogen production and waste management in emerging economies. However, existing hydrogen infrastructure planning focuses predominantly on blue and green pathways, with limited integration of waste-derived hydrogen or spatially distributed waste availability constraints. This study determines optimal waste-to-hydrogen infrastructure deployment in Oman through 2040 using mixed-integer linear programming with verified techno-economic parameters. Results indicate that plastic waste can produce 21,997 tonnes H₂ annually at a levelised cost of $2.88/kg, competitive with blue hydrogen ($1.80–2.50/kg) and significantly cheaper than current green hydrogen ($4–6/kg). The optimal network comprises four facilities at Muscat (500 TPD), Sohar (128 TPD), Salalah (192 TPD), and Nizwa (67 TPD), processing 275,000 tonnes of plastic waste whilst avoiding 137,000 tonnes of CO₂-eq through landfill diversion. However, feedstock availability constrains production to 24% of base case demand (90,000 tonnes), positioning waste-to-H₂ as a complementary pathway requiring integration with steam methane reforming for industrial hubs and electrolysis for the transport sector. Sensitivity analysis reveals hydrogen yield (±29% cost impact) and CAPEX (±20%) as critical parameters, with cost reduction pathways targeting $2.00–2.30/kg by 2035 through technology learning and co-benefit monetisation. Policy recommendations include extended producer responsibility schemes, government fleet procurement mandates, and regional waste trade agreements across the GCC. Waste-to-hydrogen demonstrates techno-economic viability as a guaranteed baseload contributor within diversified hydrogen strategies for Gulf economies. Full article

This study quantitatively evaluates the effect of solid-phase pre-reduction of chromite concentrate on the energy efficiency and techno-economic performance of high-carbon ferrochrome (HC FeCr) smelting. Laboratory pre-reduction experiments were conducted at 1200–1400 °C using Shubarkol coal, metallurgical coke, and special coke as carbonaceous reducing agents. Structural and phase transformations were characterized by X-ray diffraction (XRD) and scanning electron microscopy with energy-dispersive spectroscopy (SEM-EDS). At 1200 °C, the degree of metallization remained low (<5%), whereas at 1400 °C it increased to 41.3% under laboratory conditions and up to 65% in pilot-scale tests due to the decomposition of the spinel matrix and the formation of metallic and carbide phases. The application of pre-reduced feedstock in a submerged arc furnace reduced specific electricity consumption by up to 33.5% compared with conventional smelting and increased chromium recovery to 89.71%. Industrial-scale extrapolation indicates the potential to decrease power consumption to approximately 3190 kWh/t of alloy. Techno-economic analysis demonstrates that the use of pre-reduced feedstock reduces the production cost by approximately 10–23%, depending on the type of carbonaceous reducing agent (Shubarkol coal, metallurgical coke, or special coke). Special coke provided the highest energy efficiency, whereas Shubarkol coal ensured the greatest direct economic benefit. The integrated microstructural, energetic, and economic assessment confirms the industrial applicability of the proposed pre-reduction approach. Full article

Many countries rely on coal for energy security during renewable transitions. This study conducts a technical, economic, and environmental analysis of hybridizing a supercritical coal-fired power unit with photovoltaics (PV) to create a sustainable hybrid system at a plant in Silesian Voivodeship, Poland. The goal is to assess costs and optimal operating conditions for a coal–PV hybrid under varying scenarios, using a decision-support model that integrates fuel prices, CO₂ emission charges (EUA), and technical parameters. Two main scenarios are modeled. In auxiliary-only PV (112 MW system), real-time power supplies pumps and fans, cutting coal consumption without storage; LCOE decreases with annual hours (2800–7000), outperforming conventional coal across EUA prices (20–50 EUR/t). In PV surplus export, excess generation (1300 h/year) is grid-fed for revenue, amplifying LCOE reductions—hybrid superiority emerges above 34 EUR/t EUA, per equivalence thresholds. Results show coal electricity exceeds low-emission costs above 34 EUR/t CO₂, with maximum disparity at 50 EUR/Mg. The hybrid leverages existing infrastructure, mitigates solar intermittency via auxiliary supply, ensures baseload continuity, boosts flexibility, and prolongs asset life—reducing >123,000 EUA/year at 145,000 MWh PV output. This sustainable hybrid promotes energy transition, reduces fossil fuel dependence, and aligns with global sustainability goals. Full article

The integration of microalgal cultivation with wastewater streams offers a promising pathway to enhance resource efficiency within circular bioeconomy frameworks. However, the suitability of clarified aquaponics sedimentation effluent for producing carbohydrate-rich microalgal biomass remains insufficiently evaluated, particularly with respect to nutrient recovery and bioethanol-relevant feedstock potential. In this study, clarified aquaponics sedimentation effluent was assessed as a cultivation medium for Chlorella sp. under controlled laboratory conditions. Biomass productivity, nutrient removal performance, and carbohydrate accumulation were systematically evaluated and compared with conventional synthetic medium. Chlorella sp. cultivated in clarified aquaponic effluent achieved a maximum biomass concentration of approximately 2.05 g L⁻¹, exceeding that obtained in Bold’s Basal Medium. Carbohydrate content exceeded 40% of dry weight, indicating suitability for fermentable sugar production. Nitrate and phosphate removal efficiencies greater than 95% were achieved, with mass balance analysis confirming biological assimilation as the primary removal mechanism (~87.4%). This confirms the dual functionality of the system. The effective nutrient assimilation and confirmed the dual functionality of the system as both a biomass production and nutrient recovery process. Comparable performance under diluted and undiluted effluent conditions further indicated that freshwater dilution is not required following clarification. Light saturation was observed at 180–190 μmol m⁻² s⁻¹, providing guidance for energy-efficient operation. These findings demonstrate that clarified aquaponics effluent can serve as an effective alternative growth medium for producing carbohydrate-rich Chlorella sp. biomass while enabling nutrient recovery. The estimated bioethanol potential is theoretical, based on stoichiometric conversion assumptions, and experimental fermentation was not conducted. This work provides quantitative evidence supporting the integration of microalgae into aquaponic systems and establishes a foundation for future pilot-scale, techno-economic, and life-cycle assessments. Full article

The European Environment Agency believes that circular economy strategies could substantially contribute to CO₂ emissions reduction. Therefore, it is necessary that the agro-industrial sector identifies sustainable technologies for side-stream management. The scope of this review was to compare the sustainability of available biological treatments for by-product biomasses and organic waste. A total of 147 studies, all Life Cycle Assessments (LCAs) and Techno-Economic Analyses (TEAs), were selected through PRISMA-ScR methodology, on Scopus and Web of Science, and were bibliographically mapped on VOSviewer (Version 1.6.20) Anaerobic digestion and integrated energy recovery systems were found to be the most environmentally robust options. Integrated biorefineries and multi-product systems have emerged as the highest long-term sustainability potential, especially when process integration and co-product recovery were also implemented. Importantly, the most sustainable systems were found to have required considerable start-up investments. Thus, sustainable deployment of biological treatment technologies was clearly dependent on time-consistent policy frameworks that have been fertile to capital-intensive infrastructures via incentives and fiscal measures and that have embraced circular bioeconomy systems. Finally, this paper has demonstrated that the sustainability of biological treatments has resulted from optimal relationships between biomass characteristics, system boundaries, process integration, and market value of co-product, while no single technology has been sufficient in isolation. Full article

Produced-water (PW) management in the Permian Basin faces tightening injection constraints, induced seismicity concerns, and volatile saltwater disposal (SWD) costs. At the same time, chemistry-rich PW contains dissolved constituents (e.g., Li, B, and Sr) that may be valorized if SWD recovery performance and market conditions support favorable techno-economics. Here, we develop an integrated decision-support framework that couples (i) chemistry-informed surrogate models for unit process performance (recovery, effluent quality, and energy/chemical intensity) with (ii) a network-based allocation model that routes PW from sources through pretreatment, optional treatment and mineral-recovery modules (e.g., desalination and direct lithium extraction), and end-use nodes (beneficial reuse, hydraulic fracturing reuse, mineral recovery/valorization, or Class II disposal). This is a screening-level demonstration using publicly available chemistry percentiles and representative pilot-reported performance windows; it is not a site-specific facility design or a bankable TEA for a particular operator. The optimization is posed as a tri-objective problem—to maximize expected net present value, minimize SWD, and minimize an injection-risk indicator R—subject to mass balance, capacity, quality, and regulatory constraints. Uncertainty in commodity prices, recovery fractions, and operating costs is propagated via Monte Carlo scenario sampling, yielding PARETO-efficient portfolios that quantify trade-offs between profitability and risk mitigation. Using the PW chemistry percentiles reported by the Texas Produced Water Consortium for the Delaware and Midland Basins, we derive screening-level break-even lithium concentrations and illustrate how lithium-carbonate-equivalent price and recovery govern the extent to which mineral revenue can offset SWD expenditures. Comparative brine benchmarks (Smackover Formation and Salton Sea geothermal systems) contextualize the Permian’s generally lower-Li PW and highlight transferability of the workflow across brine types. The proposed framework provides a transparent, extensible basis for design matrix planning under evolving injection limits, enabling risk-aware PW management strategies that reduce disposal dependence while improving water resilience. Full article