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Keywords = tailings-based green concrete

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39 pages, 8719 KB  
Article
Life Cycle Environmental Evaluation Framework for Mining Waste Concrete: Insights from Molybdenum Tailings Concrete in China
by Shan Gao, Jicheng Xu, Zhenhua Huang, Tomoya Nishiwaki and Chuanxin Rong
Buildings 2025, 15(20), 3755; https://doi.org/10.3390/buildings15203755 - 17 Oct 2025
Cited by 4 | Viewed by 1367
Abstract
This study uses the case of substituting natural river sand with molybdenum tailings in concrete production in China to propose a methodological framework for evaluating the life cycle environmental impact of concrete materials. This approach addresses the mechanical performance adaptability and environmental friendliness, [...] Read more.
This study uses the case of substituting natural river sand with molybdenum tailings in concrete production in China to propose a methodological framework for evaluating the life cycle environmental impact of concrete materials. This approach addresses the mechanical performance adaptability and environmental friendliness, as well as the resource utilization of solid waste. The resource consumption, environmental impact, and economic costs are systematically analyzed using a life cycle assessment (LCA) approach, and the circular economy potential of tailings-based concrete is explored. A three-dimensional evaluation framework is constructed, encompassing raw material production, transportation, and construction stages. The environmental impacts of concrete with different molybdenum tailings replacement rates and strength grades are quantified using a willingness-to-pay (WTP) model. The results indicate that increasing the dosage of molybdenum tailings can significantly reduce environmental indicators such as global warming potential and acidification potential value. Specifically, C30 concrete with a 100% replacement rate shows an 8.5% reduction in total WTP compared to ordinary concrete, with a 2.85% reduction in energy consumption during the production stage. High-strength concrete further optimizes the environmental cost per unit strength through the “strength dilution effect,” with a 44.9% reduction in carbon footprint for 60 MPa concrete compared to 30 MPa concrete. Regional analysis reveals that the environmental contribution of the production stage dominates in short-distance transportation scenarios, while logistics optimization has a significant emission reduction effect in long-distance transportation scenarios. The study demonstrates that the proposed LCA methodology provides a scientific approach for the development of green building materials and the sustainable resource utilization of solid waste through case-informed generalization. Full article
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15 pages, 15832 KB  
Article
Study on Carbonization Performance of Metakaolin on Tailings- and Recycled-Concrete-Based Green Concrete
by Tao Li, Xiuyun Chen, Wanying Yang, Meng Zhan, Lyv Hao, Liufeng Zhang and Yan Yang
Buildings 2025, 15(13), 2262; https://doi.org/10.3390/buildings15132262 - 27 Jun 2025
Cited by 2 | Viewed by 945
Abstract
As a highly active mineral admixture, metakaolin is often used as an efficient performance-enhancing material for concrete, but its performance in long-term complex service environments still needs to be verified. This article presents a composite green concrete with a substitution rate of 30% [...] Read more.
As a highly active mineral admixture, metakaolin is often used as an efficient performance-enhancing material for concrete, but its performance in long-term complex service environments still needs to be verified. This article presents a composite green concrete with a substitution rate of 30% for recycled coarse aggregates (RCAs) and iron tailings (IOTs) and a waste polypropylene fiber (WPF) content of 0.6%. Concrete with different mixing conditions of metakaolin was prepared, and its carbonization resistance was studied with macro- and micro-experimental methods. The results indicated that when the content of metakaolin was less than 10%, its mechanical and deformation properties gradually improved, resulting in a maximum increase of 70% in its cubic compressive strength. Overall, carbonization improved the corresponding mechanical properties. For example, when carbonized for 14 days, the compressive strength growth rate increased by nearly 30%, and the elastic modulus did not change significantly. Through microscopic testing, it could be seen that when the content of metakaolin reached 10%, an appropriate amount of metakaolin (10%) promoted the hydration of cement, with the least number of pores and the best compaction performance, resulting in the best overall performance. But when added excessively, the coupling effect of secondary hydration and carbonization reactions could lead to the emergence of new harmful pores in the matrix structure. In future engineering applications of metakaolin, it is recommended that its mixing ratio be less than 10% to achieve better concrete performance. Full article
(This article belongs to the Special Issue Recycled Aggregate Concrete as Building Materials)
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28 pages, 4963 KB  
Review
Recent Advances in Properties and Application Progress of Cement-Based Materials with Iron Tailing
by Xianlei Chao, Chang Han, Cheng Shao, Chenxu Wang, Penghui Wen and Chaohui Wang
Sustainability 2024, 16(23), 10631; https://doi.org/10.3390/su162310631 - 4 Dec 2024
Cited by 10 | Viewed by 2362
Abstract
In the context of the comprehensive green transformation of infrastructure construction, utilizing bulk waste tailings materials, such as iron tailing, in cement-based materials commonly used in the infrastructure sector holds significant practical importance. However, there are differences in the range of iron tailings [...] Read more.
In the context of the comprehensive green transformation of infrastructure construction, utilizing bulk waste tailings materials, such as iron tailing, in cement-based materials commonly used in the infrastructure sector holds significant practical importance. However, there are differences in the range of iron tailings content used in previous studies, and the research results are quite scattered. There has not yet been a recommendation for a reasonable material ratio, which severely restricts the resource utilization of iron tailings in cement-based materials. To effectively guide the design and performance optimization of cement-based materials using iron tailing, recent advances related to iron tailing cement-based materials have been reviewed systematically. The previous studies on the composition design of iron tailing in cement-based materials were summarized, and the effect of iron tailing and cement on the mechanical properties and durability of various cement-based materials were highlighted. The results show that the recommended content of iron tailing sand in concrete is 25–50%. Under this content, the mechanical properties of iron tailing sand concrete increase the most, and it has better drying shrinkage performance and carbonation resistance. For cement stabilized base materials, the recommended content of iron tailing sand is 11–20%. Under this content, its mechanical properties increase significantly, and it also has excellent drying shrinkage and temperature shrinkage performance. The increase in the content of iron tailing stones reduces the mechanical properties of cement stabilized materials. Cement stabilized iron tailing stones can be applied to the roadbase by adjusting the cement content and the content of iron tailing stones. Full article
(This article belongs to the Special Issue Sustainability of Pavement Engineering and Road Materials)
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25 pages, 771 KB  
Review
Eco-Concrete in High Temperatures
by Marcin Sundin, Hans Hedlund and Andrzej Cwirzen
Materials 2023, 16(12), 4212; https://doi.org/10.3390/ma16124212 - 6 Jun 2023
Cited by 19 | Viewed by 3037
Abstract
Concrete technology is becoming more and more sustainable and ecological following more extensive and focused research. The usage of industrial waste and by-products, such as steel ground granulated blast-furnace slag (GGBFS), mine tailing, fly ash, and recycled fibers, is a very important step [...] Read more.
Concrete technology is becoming more and more sustainable and ecological following more extensive and focused research. The usage of industrial waste and by-products, such as steel ground granulated blast-furnace slag (GGBFS), mine tailing, fly ash, and recycled fibers, is a very important step toward a good transition of concrete into a “green” future and significant improvement in waste management in the world. However, there are also several known durability-related problems with some types of eco-concretes, including exposure to fire. The general mechanism occurring in fire and high-temperature scenarios is broadly known. There are many variables that weightily influence the performance of this material. This literature review has gathered information and results regarding more sustainable and fire-resistant binders, fire-resistant aggregates, and testing methods. Mixes that utilize industrial waste as a total or partial cement replacement have been consistently achieving favorable and frequently superior outcomes when compared to conventional ordinary Portland cement (OPC)-based mixes, especially at a temperature exposure up to 400 °C. However, the primary emphasis is placed on examining the impact of the matrix components, with less attention given to other factors such as sample treatment during and following exposure to high temperatures. Furthermore, there is a shortage of established standards that could be utilized in small-scale testing. Full article
(This article belongs to the Section Construction and Building Materials)
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15 pages, 6051 KB  
Article
Resourceful Utilization of Cow Hair in the Preparation of Iron Tailing-Based Foam Concrete
by Leipeng Liu, Junjie Yang, Yinfei She, Shenghua Lv, Zheng Yang and Jia Zhang
Materials 2022, 15(16), 5739; https://doi.org/10.3390/ma15165739 - 19 Aug 2022
Cited by 11 | Viewed by 3181
Abstract
Cow hair, a by-product of tannery waste, is usually stockpiled on a large scale as waste, which leads to serious environmental impacts. In this paper, cow hair was used as a reinforcement fiber to improve the mechanical strength of iron tailing-based foam concrete. [...] Read more.
Cow hair, a by-product of tannery waste, is usually stockpiled on a large scale as waste, which leads to serious environmental impacts. In this paper, cow hair was used as a reinforcement fiber to improve the mechanical strength of iron tailing-based foam concrete. The effects of the amount of cow hair fiber on the apparent density, compressive strength, and flexural strength of foam concrete were investigated by a series of characterization methods. Meanwhile, Image-Pro Plus software was used to analyze the porosity, average pore size, roundness, and other parameters of the specimens with different amounts of cow hair fiber. Results revealed that a proper amount of cow hair fiber can form a stable three-dimensional network structure inside the foam concrete and promote a uniform distribution and size of the pore structure inside the test piece. This could effectively improve the compressive strength, flexural strength, and crack resistance of the foam concrete, and when the fiber content was 0.2 wt%, the foam concrete exhibited the best mechanical properties, with a compressive strength of 11.19 MPa and a flexural strength of 3.58 MPa. The present work was in agreement with the strategic objective of resource recycling and solid waste utilization, which was conducive to the development of the circular and green economy. Full article
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12 pages, 3467 KB  
Article
Gel Evolution of Copper Tailing-Based Green Geopolymers in Marine Related Environments
by Jing Li, Lang Yang, Feng Rao and Xiang Tian
Materials 2022, 15(13), 4599; https://doi.org/10.3390/ma15134599 - 30 Jun 2022
Cited by 9 | Viewed by 2599
Abstract
Geopolymers have attracted extensive attention in the marine environment because of its special reticulate nanostructure. Gel evolutions of copper tailing-based green geopolymers were studied under air, deionized water, seawater, freeze–thaw cycle and carbonization environments. Their mechanical properties and microstructures were characterized by compressive [...] Read more.
Geopolymers have attracted extensive attention in the marine environment because of its special reticulate nanostructure. Gel evolutions of copper tailing-based green geopolymers were studied under air, deionized water, seawater, freeze–thaw cycle and carbonization environments. Their mechanical properties and microstructures were characterized by compressive strength measurement, X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), nuclear magnetic resonance (NMR) and scanning electron microscopy (SEM). It was found that the deionized water and natural marine water exposure promoted the evolution degree of geopolymers and improved their compressive strength, while exposure to the carbonization environment weakened the gel evolution and decreased the cross-linking degree of the Sodium aluminosilicate hydrate (N-A-S-H)gel structure, resulting in a decline of compressive strength. The geopolymer exposed in the freeze–thaw cycle exhibited the worst deterioration due to the expansion caused by the crystallization in the geopolymer. These results are essential and beneficial to further understanding the gel formation process in various marine environments and could promote the investigation of green concrete. Full article
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17 pages, 5316 KB  
Article
Application of Iron Tailings-Based Composite Supplementary Cementitious Materials (SCMs) in Green Concrete
by Yannian Zhang, Daokui Yang, Xiaowei Gu, Hao Chen and Zhijun Li
Materials 2022, 15(11), 3866; https://doi.org/10.3390/ma15113866 - 28 May 2022
Cited by 24 | Viewed by 3440
Abstract
How to treat the iron tailings of mining solid waste with high value is an urgent problem on a global scale. In recent years, the application of iron tailings in the building materials industry has attracted the attention of many scholars. The conversion [...] Read more.
How to treat the iron tailings of mining solid waste with high value is an urgent problem on a global scale. In recent years, the application of iron tailings in the building materials industry has attracted the attention of many scholars. The conversion of iron tailings into green building materials helps achieve carbon neutrality and high-value utilization of solid waste, and promotes sustainable development. Although iron tailings have been extensively studied as supplementary cementitious materials, the performance of concrete is not ideal due to its low activity. In this study, the hybrid supplementary cementitious materials system was prepared by iron tailings, phosphorus slag, and steel slag, and the effects of supplementary cementitious materials type, iron tailings content, iron tailings grinding time, and supplementary cementitious materials content on concrete performance were studied. The compressive properties, iron tailings properties, pore structure, interfacial transition zone, and element distribution of hydration products of concrete were tested by compressive strength tests, X-ray Diffractometer (XRD), X-ray Photoelectron Spectroscopy (XPS), Mercury Intrusion Porosimetry (MIP), Backscattering Electron Tests (BSE), and Energy Dispersive Spectrometer (EDS). The results show that further grinding improves the iron tailings activity. There is a synergistic mechanism between steel slag and phosphorus slag in the composite supplementary cementitious materials, which overcomes the low activity defect of iron tailings and produces concrete with a compressive strength exceeding 40 MPa. The composite supplementary cementitious materials can optimize the interfacial transition zone of the concrete interface and reduce the calcium–silicon ratio of the hydration products. However, it will deteriorate the pore structure of the concrete matrix, cause part of the concrete matrix to be damaged and lead to a loss of compressive strength, and the loss is acceptable. This work broadens the methods of comprehensive utilization of iron tailings and also provides a reference for a more detailed understanding of the properties of iron tailings-based concrete. Full article
(This article belongs to the Topic Innovative Construction and Building Materials)
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17 pages, 3361 KB  
Article
Characterisation of Industrial Side Streams and Their Application for the Production of Geopolymer Composites
by Mehmet Emin Küçük, Teemu Kinnarinen, Juha Timonen, Olli Mulari and Antti Häkkinen
Minerals 2021, 11(6), 593; https://doi.org/10.3390/min11060593 - 31 May 2021
Cited by 7 | Viewed by 3863
Abstract
This study focuses on characterisation of side streams including biomass fly ash, biomass bottom ash, coal fly ash, green liquor dregs, limestone mine tailings, and electric arc furnace steel slag from different industrial locations in Finland. It was found that the fly ash [...] Read more.
This study focuses on characterisation of side streams including biomass fly ash, biomass bottom ash, coal fly ash, green liquor dregs, limestone mine tailings, and electric arc furnace steel slag from different industrial locations in Finland. It was found that the fly ash samples contained the highest Al2O3 and SiO2 concentrations, a large number of spherical particles of small sizes and high specific surface areas. Fly ashes and steel slag were observed to contain higher amounts of amorphous phases compared to the other side streams. The high loss on ignition value of the coal fly ash and green liquor dregs was found to exceed the limitations for their application in geopolymer composites. Despite their relatively high concentrations in ashes and steel slag, the leaching tests have shown that no hazardous metal leached out from the streams. Finally, test specimens of geopolymer composites (GP2) were prepared by the application of biomass fly ash, bottom ash, and limestone mine tailings without any pre-treatment process, in addition to the ordinary Portland cement-(R) and metakaolin-based geopolymer composites (GP1). The measured compressive (14.1 MPa) and flexural strength (3.5 MPa) of GP2 suggest that it could be used in concrete kerbs and paving flags. The data has also shown that over 500% of the compressive strength was developed between 7 and 28 days in GP2, whereas in the case of reference concrete (R) and the metakaolin-based geopolymer composite (GP1) it was developed in the first 7 days. Full article
(This article belongs to the Section Environmental Mineralogy and Biogeochemistry)
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