Study on Carbonization Performance of Metakaolin on Tailings- and Recycled-Concrete-Based Green Concrete
Abstract
1. Introduction
2. Test Material Properties
3. Design of Test Parameters
3.1. Mix Design
3.2. Rapid Carbonization Test Design
3.3. Block Size and Test Method Design
4. Mechanical Property Test Results
4.1. Cube Compressive Strength
4.2. Splitting Tensile Strength
4.3. Axial Compressive Strength
4.4. Stress–Strain Constitutive Curve
4.5. Deformation Properties
5. Durability
5.1. Relative Dynamic Elasticity Modulus
5.2. Carbonization Depth
6. Micro-Morphology
6.1. Nuclear Magnetic Resonance (NMR)
6.2. Scanning Electron Microscope (SEM)
7. Conclusions
- (1)
- The compressive strength and splitting tensile strength presented a similar regular pattern, showing a trend of first increasing and then decreasing, with an optimal dosage of 5–10%.
- (2)
- The peak strain increased slightly, and the elastic modulus fluctuated with a low content of metakaolin (≤10%). With a high content (>10%), it gradually tended to decrease, and its brittleness was further strengthened. Carbonization could improve effects caused by differences in metakaolin content and made the correlation value become gentle and regular.
- (3)
- At the same carbonization age, the RDEM of RAC was the lowest, the metakaolin addition made the value fluctuate a little, and the peak point was approximately at a content ranging from 0% and 10%. As the content increased, its carbonization depth showed a trend of first decreasing and then increasing. When the content of metakaolin was 10%, the carbonization depth was minimal, indicating that its carbonization resistance was the strongest.
- (4)
- Through an NMR analysis, the peak amplitude could be reduced by adding the proper amount of metakaolin, but the number of pores rose again when the content was large, and the porosity reached its minimum when the content was 10%.
- (5)
- The SEM analysis indicated that a small MK amount could greatly promote the hydration of cement, improve its compactness, and greatly increase its mechanical properties. When the content was high (>10%), the secondary hydration promotion effect was large and increased the demand for free water and alkaline substances. With the progress of the carbonization reaction, harmful pores appeared in the matrix structure, resulting in a decline in relevant properties.
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
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Water Requirement for Normal Consistency/% | Initial Setting Time/min | Final Setting Time/min | Fineness Modulus (45 μm) | Stability | Flexural Strength/MPa | Compressive Strength/MPa | ||
---|---|---|---|---|---|---|---|---|
3 d | 28 d | 3 d | 28 d | |||||
28 | 160 | 280 | 2.8 | Qualified | 5.2 | 6.8 | 19.5 | 42.2 |
Performance Criteria | Apparent Density kg/m3 | Bulk Density kg/m3 | Fragmentation Index/% | Water Absorption/% | Mud Content/% | Water Content/% | Organic Matter Content | Alkali-Aggregate Reaction |
---|---|---|---|---|---|---|---|---|
NCA | 2941 | 1749 | 10.3 | 1.33 | 0.72 | 0.8 | Qualified | Qualified |
RCA | 2536 | 1467 | 14.8 | 7 | 1.86 | 3.02 | Qualified | Qualified |
Norm value | ≥2500 | ≥1300 | ≤16 | - | ≤1.0 | - | Qualified | Qualified |
Sand | 2764 | 1830 | 12 | 2.12 | 1.2 | 4.1 | Qualified | Qualified |
IOT | 2745 | 1824 | 19.53 | 8.7 | 2.9 | 1.45 | Qualified | Qualified |
Norm value | - | - | ≤10 | - | ≤3.0 | - | Qualified | Qualified |
Density (kg/cm3) | Length (mm) | Equivalent Diameter (mm) | Tensile Strength (MPa) | Breaking Elongation (%) | Elastic Modulus (MPa) | Retention Rate of Alkali Resistant (%) |
---|---|---|---|---|---|---|
1.12 | 22 | 0.08 | >350 | 12–40 | >4000 | >94.4 |
Whiteness | Screenings of 325 Mesh | Refractive Index | Water Content | PH Value of Aqueous Suspension | Oil Absorption |
---|---|---|---|---|---|
95.5 | 0.01 | 1.65 | 0.145 | 7 | 65 |
Serial Number | Binding Materials | Coarse Aggregate | Fine Aggregate | Water | WPF | Water Reducing Agent | |||
---|---|---|---|---|---|---|---|---|---|
Cement | MK | NCA | RCA | Sand | IOT | ||||
NAC-21 | 538 | 0 | 1063 | 0 | 572 | 0 | 215 | 0 | 0 |
RAC-21 | 538 | 0 | 735 | 315 | 566 | 0 | 215 | 0 | 0 |
PE-RAC-3 | 538 | 0 | 748 | 320 | 403 | 172 | 215 | 6.416 | 8.07 |
PE-RAC-6 | 511 | 26.7 | 748 | 320 | 403 | 172 | 215 | 6.416 | 8.07 |
PE-RAC-7 | 484 | 53.8 | 748 | 320 | 403 | 172 | 215 | 6.416 | 8.07 |
PE-RAC-8 | 457 | 80.6 | 748 | 320 | 403 | 172 | 215 | 6.416 | 8.07 |
PE-RAC-9 | 430 | 107.5 | 748 | 320 | 403 | 172 | 215 | 6.416 | 8.07 |
Block Number | T1,S/ms | T1,F/ms | T1,P/ms | A1/a.u. | S1 | ST | αS1/% |
---|---|---|---|---|---|---|---|
NAC | 0.013 | 4.199 | 0.74 | 504.711 | 15,539.854 | 17,035.959 | 91.218 |
RAC-1 | 0.013 | 4.824 | 0.823 | 597.940 | 18,708.792 | 19,911.785 | 93.958 |
PE-RAC-3 | 0.013 | 7.317 | 0.744 | 334.515 | 10,843.064 | 11,868.871 | 91.357 |
PE-RAC-6 | 0.013 | 9.011 | 0.793 | 302.676 | 10,249.873 | 11,365.371 | 90.185 |
PE-RAC-7 | 0.013 | 9.011 | 0.74 | 191.635 | 7093.927 | 7904.976 | 89.732 |
PE-RAC-8 | 0.013 | 7.843 | 0.74 | 282.078 | 9739.373 | 11,011.676 | 88.446 |
PE-RAC-9 | 0.013 | 10.353 | 0.793 | 332.513 | 10,956.861 | 12,694.481 | 86.312 |
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Li, T.; Chen, X.; Yang, W.; Zhan, M.; Hao, L.; Zhang, L.; Yang, Y. Study on Carbonization Performance of Metakaolin on Tailings- and Recycled-Concrete-Based Green Concrete. Buildings 2025, 15, 2262. https://doi.org/10.3390/buildings15132262
Li T, Chen X, Yang W, Zhan M, Hao L, Zhang L, Yang Y. Study on Carbonization Performance of Metakaolin on Tailings- and Recycled-Concrete-Based Green Concrete. Buildings. 2025; 15(13):2262. https://doi.org/10.3390/buildings15132262
Chicago/Turabian StyleLi, Tao, Xiuyun Chen, Wanying Yang, Meng Zhan, Lyv Hao, Liufeng Zhang, and Yan Yang. 2025. "Study on Carbonization Performance of Metakaolin on Tailings- and Recycled-Concrete-Based Green Concrete" Buildings 15, no. 13: 2262. https://doi.org/10.3390/buildings15132262
APA StyleLi, T., Chen, X., Yang, W., Zhan, M., Hao, L., Zhang, L., & Yang, Y. (2025). Study on Carbonization Performance of Metakaolin on Tailings- and Recycled-Concrete-Based Green Concrete. Buildings, 15(13), 2262. https://doi.org/10.3390/buildings15132262