Search Results (34)

This research presents the development of a type-2 fuzzy-controlled autonomous mobile robot specifically designed for monitoring and actively maintaining indoor air quality. The core of this system is the proposed type-2 fuzzy PID dual-mode controller used for stably patrolling rooms along the walls of the environment. The design method ingeniously merges the fast error correction capability of PID control with the robust adaptability of type-2 fuzzy logic control, which utilizes interval type-2 fuzzy sets. Furthermore, the type-2 fuzzy rule table of the right wall-following controller can be extended from the first designed fuzzy left wall-following controller in a symmetrical design manner. As a result, this study eliminates the drawbacks of excessive oscillations arising from PID control and sluggish response to large initial errors in typical traditional fuzzy control. The following of the stable wall and obstacle is facilitated with ensured accuracy and easy implementation so that effective air quality monitoring and active PM2.5 filtering are achieved in a movable manner. Furthermore, the augmented reality (AR) interface overlays real-time PM2.5 data directly onto a user’s visual field, enhancing situational awareness and enabling an immediate and intuitive assessment of air quality. As this type of control is different from that used in traditional fixed sensor networks, both broader area coverage and efficient air filtering are achieved. Finally, the experimental results demonstrate the controller’s superior performance and its potential to significantly improve indoor air quality. Full article

Large storage tanks situated in coastal areas are vulnerable to environmental hazards, with earthquakes being one of the most destructive forces threatening their structural safety. Additionally, differential settlement can significantly alter conditions in the tank, including the inclination, thereby changing the direction of external applied excitation forces and affecting the liquid sloshing response. To investigate the coupled effects of structural settlement and external excitation, model tests were conducted in series to analyze liquid sloshing behavior in a tilted tank subjected to harmonic excitation. The results revealed that the liquid response under combined environmental loads displayed distinct characteristics compared with that under single excitation. While the inclination angle had minimal influence during the unstable sloshing stage, it became crucial during the stable stage, particularly for third-order resonant responses, leading to intensified sloshing. More specifically, as the tilt angle of the storage tank from 0° to 8°, the steady-state wave height at third-order resonance increased by approximately 69%. This highlights the amplified risks to the structural stability and safety posed by differential settlement. Furthermore, variations in steady-state wave heights due to differential settlement conditions were investigated. The water level elevation along the tank walls varies as the inclination angles increase, which leads to potential risks to the stability of liquid storage under forced motion, especially under symmetric structural designs, and increases the likelihood of structural instability, oil spills, and other coastal disasters. These results provide valuable insights into the safety risks and sustainable utilization of coastal infrastructure, serving a basis for assessing and mitigating the risks associated with structural settlement and seismic excitations. Full article

The study of energy savings in ventilation systems within buildings is crucial. Impinging jet ventilation (IJV) systems have garnered significant interest from researchers. The identification of the appropriate location for the IJV reveals a gap in the existing literature. This research was conducted to address the existing gap by examining the impact of IJV location on energy savings and thermal comfort. A comprehensive three-dimensional CFD model is examined to accurately simulate the real environment of an office room (3 × 3 × 2.9 m³) during cooling mode, without the application of symmetrical plans. Four locations have been selected: two at the corners and two along the midwalls, designated for fixed-person positions. The return vent height is analyzed utilizing seven measurements: 2.9, 2.6, 2.3, 1.7, 1.1, 0.8, and 0.5 m. The RNG k–ε turbulence model is implemented alongside enhanced wall treatment. The findings indicated that the optimal range for the return vent height is between 1.7 and 0.8 m. It is advisable to utilize the IJV midwall 1 location, positioned behind the seated individual and away from the exterior hot wall. It is characterized by low vortex formation in the local working zone that contributes to a more comfortable sensation while providing recognized energy-saving potential. Full article

Background/Objectives: Gynecomastia is a common condition characterized by the benign enlargement of male breast tissue, often resulting from hormonal imbalances. A rare variant, unilateral pseudogynecomastia, involves enlargement due to adipose tissue accumulation without glandular proliferation and can be associated with occupational factors. Methods: We report the case of a 45-year-old male mechanic presenting with unilateral enlargement of the left breast. The patient reported daily microtrauma on his left axilla and chest wall. The clinical evaluation and imaging revealed lipomatosis with pronounced fibrous tissue and no glandular tissue involvement. The hormonal assays were within the normal limits. The patient underwent surgical excision of excess adipose tissue using the Kornstein technique, preserving the nipple–areola complex. Results: The histopathological examination confirmed the absence of malignancy. The postoperative recovery was uneventful, and the follow-up examination at 12 months demonstrated a symmetrical breast appearance with no recurrence. This case underscores the importance of differentiating pseudogynecomastia from true gynecomastia and recognizing potential occupational risks. Surgical management using techniques that preserve the nipple–areola complex can achieve excellent cosmetic outcomes. Full article

The problem of submerged body motion in a frozen channel is considered. The fluid in the channel is assumed to be inviscid and incompressible. Fluid flow is the potential. The ice cover has non-uniform compression along the principal coordinates. The damping of hydroelastic waves generated by the motion of submerged body is modeled by taking into account porosity of ice. The submerged body is modeled as a dipole, the potential of which is determined using mirror images from the channel walls. The main problem of the submerged body motion at constant speed along the central line of the channel is considered. Two subproblems are addressed: comparison of damping effects of the porosity and viscosity of ice and investigation of effects of symmetrically variable ice thickness relative to the central line of the channel. It was found that the most important compressive stress is the stress in the direction of the motion of the submerged body. The speed of the body, which was subcritical for uncompressed ice, may become critical or supercritical. Compressive stresses perpendicular to the direction of motion do not qualitatively change the character of the ice response. These stresses, in combination with compressive stresses along the direction of motion, strengthen the effect of the latter, making the transition from subcritical to supercritical regime faster. Full article

The sedimentation of a soft particle composed of an uncharged hard sphere core and a charged porous surface layer inside a concentric charged spherical cavity full of a symmetric electrolyte solution is analyzed in a quasi-steady state. By using a regular perturbation method with small fixed charge densities of the soft sphere and cavity wall, a set of linearized electrokinetic equations relevant to the fluid velocity field, electrical potential profile, and ionic electrochemical potential energy distributions are solved. A closed-form formula for the sedimentation velocity of the soft sphere is obtained as a function of the ratios of core-to-particle radii, particle-to-cavity radii, particle radius-to-Debye screening length, and particle radius-to-porous layer permeation length. The existence of the surface charge on the cavity wall increases the settling velocity of the charged soft sphere, principally because of the electroosmotic enhancement of fluid recirculation within the cavity induced by the sedimentation potential gradient. When the porous layer space charge and cavity wall surface charge have the same sign, the particle velocity is generally enhanced by the presence of the cavity. When these fixed charges have opposite signs, the particle velocity will be enhanced/reduced by the presence of the cavity if the wall surface charge density is sufficiently large/small relative to the porous layer space charge density in magnitude. The effect of the wall surface charge on the sedimentation of the soft sphere increases with decreases in the ratios of core-to-particle radii, particle-to-cavity radii, and particle radius-to-porous layer permeation length but is not a monotonic function of the ratio of particle radius-to-Debye length. Full article

Lithium niobate (LiNbO₃) single-crystal nanodevices featuring elevated readout domain wall currents exhibit significant potential for integrated circuits in memory computing applications. Nevertheless, challenges stem from suboptimal electrode–LiNbO₃ single crystal contact characteristics, which impact the stability of high currents within these devices. In this work, we concentrate on augmenting the domain wall current by refining the fabrication processes of domain wall random access memory (DWRAM). Each LiNbO₃ domain wall nanodevice was fabricated using a self-aligned process. Device performance was significantly enhanced by introducing a 10 nm interlayer between the LiNbO₃ and Cu electrodes. A comparative analysis of electrical properties was conducted on devices with interlayers made of chromium (Cr) and titanium (Ti), as well as devices without interlayers. After the introduction of the Ti interlayer, the device’s coercive voltage demonstrated an 82% reduction, while the current density showed a remarkable 94-fold increase. A 100 nm sized device with the Ti interlayer underwent positive down–negative up pulse testing, demonstrating a writing time of 82 ns at 8 V and an erasing time of 12 μs at −9 V. These operating speeds are significantly faster than those of devices without interlayers. Moreover, the enhanced devices exhibited symmetrical domain switching hysteresis loops with retention times exceeding 10⁶ s. Notably, the coercive voltage (V_c) dispersion remained narrow after more than 1000 switching cycles. At an elevated temperature of 400 K, the device’s on/off ratio was maintained at 10⁵. The device’s embedded selector demonstrated an ultrahigh selectivity (>10⁶) across various reading voltages. These results underscore the viability of high-density nanoscale integration of ferroelectric domain wall memory. Full article

The quasi-steady diffusiophoresis of a soft particle composed of an uncharged hard sphere core and a uniformly charged porous surface layer in a concentric charged spherical cavity full of a symmetric electrolyte solution with a concentration gradient is analyzed. By using a regular perturbation method with small fixed charge densities of the soft particle and cavity wall, the linearized electrokinetic equations relevant to the fluid velocity field, electric potential profile, and ionic concentration distributions are solved. A closed-form formula for the diffusiophoretic (electrophoretic and chemiphoretic) velocity of the soft particle is obtained as a function of the ratios of the core-to-particle radii, particle-to-cavity radii, particle radius to the Debye screening length, and particle radius to the permeation length in the porous layer. In typical cases, the confining charged cavity wall significantly influences the diffusiophoresis of the soft particle. The fluid flow caused by the diffusioosmosis (electroosmosis and chemiosmosis) along the cavity wall can considerably change the diffusiophoretic velocity of the particle and even reverse its direction. In general, the diffusiophoretic velocity decreases with increasing core-to-particle radius ratios, particle-to-cavity radius ratios, and the ratio of the particle radius to the permeation length in the porous layer, but increases with increasing ratios of the particle radius to the Debye length. Full article

The design of well-defined hierarchical free-standing electrodes for robust high-performance energy storage is challenging. We report herein that azo-linkage redox metal–organic frameworks (MOFs) incorporate single-walled carbon nanotubes (CNTs) as flexible electrodes. The in situ-guided growth, crystallinity and morphology of UiO-66-NO₂ MOFs were finely controlled in the presence of CNTs. The MOFs’ covalent anchoring to CNTs and solvothermal grafting anthraquinone (AQ) pendants endow the hybrid (denoted as CNT@UiO-66-AQ) with greatly improved conductivity, charge storage pathways and electrochemical dynamics. The flexible CNT@UiO-66-AQ displays a highest areal specific capacitance of 302.3 mF cm⁻² (at 1 mA cm⁻²) in −0.4~0.9 V potential window, together with 100% capacitance retention over 5000 cycles at 5 mA cm⁻². Its assembled symmetrical supercapacitor (SSC) achieves a maximum energy density of 0.037 mWh cm⁻² and a maximum power density of 10.4 mW cm⁻², outperforming many MOFs-hybrids-based SSCs in the literature. Our work may open a new avenue for preparing azo-coupled redox MOFs hybrids with carbaneous substrates for high-performance robust aqueous energy storage. Full article

In subjects with functionally bicuspid aortic valves (BAVs) with fusion between the coronary leaflets, there is a natural variation of the commissural angle. What is not fully understood is how this variation influences the hemodynamics and tissue biomechanics. These variables may influence valvar durability and function, both in the native valve and following repair, and influence ongoing aortic dilation. A 3D aortic valvar model was reconstructed from a patient with a normal trileaflet aortic valve using cardiac magnetic resonance (CMR) imaging. Fluid–structure interaction (FSI) simulations were used to compare the effects of the varying commissural angles between the non-coronary with its adjacent coronary leaflet. The results showed that the BAV with very asymmetric commissures (${120}^{\circ }$ degree commissural angle) reduces the aortic opening area during peak systole and with a jet that impacts on the right posterior wall proximally of the ascending aorta, giving rise to elevated wall shear stress. This manifests in a shear layer with a retrograde flow and strong swirling towards the fused leaflet side. In contrast, a more symmetrical commissural angle (${180}^{\circ }$ degree commissural angle) reduces the jet impact on the posterior wall and leads to a linear decrease in stress and strain levels in the non-fused non-coronary leaflet. These findings highlight the importance of considering the commissural angle in the progression of aortic valvar stenosis, the regional distribution of stresses and strain levels experienced by the leaflets which may predispose to valvar deterioration, and progression in thoracic aortic dilation in patients with functionally bicuspid aortic valves. Understanding the hemodynamics and biomechanics of the functionally bicuspid aortic valve and its variation in structure may provide insight into predicting the risk of aortic valve dysfunction and thoracic aortic dilation, which could inform clinical decision making and potentially lead to improved aortic valvar surgical outcomes. Full article

Subjects with bicuspid aortic valves (BAV) are at risk of developing valve dysfunction and need regular clinical imaging surveillance. Management of BAV involves manual and time-consuming segmentation of the aorta for assessing left ventricular function, jet velocity, gradient, shear stress, and valve area with aortic valve stenosis. This paper aims to employ machine learning-based (ML) segmentation as a potential for improved BAV assessment and reducing manual bias. The focus is on quantifying the relationship between valve morphology and vortical structures, and analyzing how valve morphology influences the aorta’s susceptibility to shear stress that may lead to valve incompetence. The ML-based segmentation that is employed is trained on whole-body Computed Tomography (CT). Magnetic Resonance Imaging (MRI) is acquired from six subjects, three with tricuspid aortic valves (TAV) and three functionally BAV, with right–left leaflet fusion. These are used for segmentation of the cardiovascular system and delineation of four-dimensional phase-contrast magnetic resonance imaging (4D-PCMRI) for quantification of vortical structures and wall shear stress. The ML-based segmentation model exhibits a high Dice score (0.86) for the heart organ, indicating a robust segmentation. However, the Dice score for the thoracic aorta is comparatively poor (0.72). It is found that wall shear stress is predominantly symmetric in TAVs. BAVs exhibit highly asymmetric wall shear stress, with the region opposite the fused coronary leaflets experiencing elevated tangential wall shear stress. This is due to the higher tangential velocity explained by helical flow, proximally of the sinutubal junction of the ascending aorta. ML-based segmentation not only reduces the runtime of assessing the hemodynamic effectiveness, but also identifies the significance of the tangential wall shear stress in addition to the axial wall shear stress that may lead to the progression of valve incompetence in BAVs, which could guide potential adjustments in surgical interventions. Full article

Incremental sheet forming (ISF) is an emerging technology that has shown great potential in forming customized three-dimensional (3D) parts without the use of product-specific dies. The forming force is reduced in ISF due to the localized nature of deformation and successive forming. Forming force plays an important role in modeling the process accurately, so it needs to be evaluated accurately. Some attempts have been made earlier to calculate the forming force; however, they are mostly limited to empirical formulae for evaluating the average forming force and its different components. The current work presents a mathematical model for force prediction during ISF in a 3D polar coordinate system. The model can be used to predict forces for axis-symmetric cones of different wall angles and also for incremental hole flanging. Axial force component, resultant force in the r-θ plane, and total force have been calculated using the developed mathematical model appearing at different forming depths. The cone with the same geometrical parameters and experimental conditions was modeled and simulated on ABAQUS, and finally, experiments were carried out using a six-axis industrial robot. The mathematical model can be used to calculate forces for any wall angle, but for comparison purposes, a 45° wall angle cone has been used for analytical, numerical, and experimental validation. The total force calculated from the mathematical model had a very high level of accuracy with the force measured experimentally, and the maximum error was 4.25%. The result obtained from the FEA model also had a good level of accuracy for calculating total force, and the maximum error was 4.89%. Full article

The paper considers the visco-elastic response of the ice cover in a channel under an external load moving with constant speed along the center line. The channel has a rectangular cross-section with a finite depth and width. The fluid in the channel is inviscid and incompressible and its motion is potential. The fluid is covered by a thin sheet of ice frozen to the channel walls. The ice thickness varies linearly symmetrically across the channel, being lowest at the center of the channel and highest at the channel walls. Ice deflections and strains in the ice cover are independent of time in the coordinate system moving with the load. The problem is solved numerically using Fourier transform along the channel and the method of normal modes across the channel. The series coefficients for normal modes are determined by truncation for the resulting infinite systems of linear algebraic equations. The ice deflections and strains in the ice plate are investigated and compared to the case of constant mean ice thickness. It is shown that even a small variation of the ice thickness significantly changes the characteristics of the hydroelastic waves in the channel. Full article

The energy storage performances of supercapacitors are expected to be enhanced by the use of nanostructured hierarchically micro/mesoporous hollow carbon materials based on their ultra-high specific surface areas and rapid diffusion of electrolyte ions through the interconnected channels of their mesoporous structures. In this work, we report the electrochemical supercapacitance properties of hollow carbon spheres prepared by high-temperature carbonization of self-assembled fullerene-ethylenediamine hollow spheres (FE-HS). FE-HS, having an average external diameter of 290 nm, an internal diameter of 65 nm, and a wall thickness of 225 nm, were prepared by using the dynamic liquid-liquid interfacial precipitation (DLLIP) method at ambient conditions of temperature and pressure. High temperature carbonization (at 700, 900, and 1100 °C) of the FE-HS yielded nanoporous (micro/mesoporous) hollow carbon spheres with large surface areas (612 to 1616 m² g⁻¹) and large pore volumes (0.925 to 1.346 cm³ g⁻¹) dependent on the temperature applied. The sample obtained by carbonization of FE-HS at 900 °C (FE-HS_900) displayed optimum surface area and exhibited remarkable electrochemical electrical double-layer capacitance properties in aq. 1 M sulfuric acid due to its well-developed porosity, interconnected pore structure, and large surface area. For a three-electrode cell setup, a specific capacitance of 293 F g⁻¹ at a 1 A g⁻¹ current density, which is approximately 4 times greater than the specific capacitance of the starting material, FE-HS. The symmetric supercapacitor cell was assembled using FE-HS_900 and attained 164 F g⁻¹ at 1 A g⁻¹ with sustained 50% capacitance at 10 A g⁻¹ accompanied by 96% cycle life and 98% coulombic efficiency after 10,000 consecutive charge/discharge cycles. The results demonstrate the excellent potential of these fullerene assemblies in the fabrication of nanoporous carbon materials with the extensive surface areas required for high-performance energy storage supercapacitor applications. Full article

A novel symmetric tetra-imidazolium-bis-heterocycle, called C7, was designed and synthesized in a quick two-step pathway, with the objective to synthesize biologically active supramolecular assembly. The synthesized compound was then analyzed for its photophysical properties, for a potential application in theragnostic (fluorescence) or phototherapy (photodynamic therapy, with the production of reactive oxygen species, such as singlet oxygen ¹O₂). C7 was thus screened for its biological activity, in particular against important human pathogens of viral origin (respiratory viruses such as adenovirus type 2 and human coronavirus 229E) and of fungal and bacterial origin. The compound showed limited antiviral activity, combined with very good antiproliferative activity against breast cancer, and head and neck squamous cell carcinoma models. Interestingly, the selected compound showed excellent antibacterial activity against a large array of Gram-positive and Gram-negative clinically isolated pathogenic bacteria, with a possible inhibitory mechanism on the bacterial cell wall synthesis studied with electron microscopy and molecular docking tools. Collectively, the newly synthesized compound C7 could be considered as a potential lead for the development of new antibacterial treatment, endowed with basic photophysical properties, opening the door towards the future development of phototherapy approaches. Full article