Search Results (43)

A superconducting high-entropy alloy (HEA) Nb_0.67(TiZrHf)_0.33 powder was successfully synthesized via mechanical alloying for the first time. X-ray diffraction, scanning electron microscopy, energy dispersive X-ray spectroscopy, magnetic measurements, and specific heat were used to investigate its structural and physical properties. The alloy was crystallized in a single-phase body-centered cubic structure with a small amount of non-magnetic impurities coming from ball milling. Specific heat data confirms the presence of bulk superconductivity in the as-synthesized state, with the broadness of the thermodynamic anomaly reflecting the significant chemical disorder and distribution of critical temperatures typical of HEAs. $T_c$ is in the range 6–7.5 K, and the upper critical field $\mu 0H_{\mathrm{c}2}$ is in the range 6.4–7.6 T. These results demonstrate that mechanical synthesis is a viable route for producing superconducting HEA powders, which are promising candidates for consolidation via sintering and provide a robust platform for investigating superconductivity in highly disordered systems. Full article

The superconducting transition temperature, $T_c$, of the graphite intercalation compound, Ca${\mathrm{C}}_6$, was calculated using the Roeser–Huber (RH) formalism. This method was adapted to alloys with complex crystal structures by identifying symmetric paths for the superconducting charge carriers (Cooper pairs) and incorporating interactions with neighboring atoms through phonon coupling. The evaluation of the lowest energy levels, ${\Delta }_{\left(0\right)}$, along all relevant crystallographic directions reveals a slight anisotropy between the in-plane and out-of-plane directions, consistent with the experimental observation of the gap anisotropy by point contact spectroscopy. The $T_c$ values obtained for Ca${\mathrm{C}}_6$, Ca${\mathrm{C}}_6$ with applied high pressure, and Yb${\mathrm{C}}_6$ show good agreement with experimental data, thereby supporting both the validity of the RH approach and its predictive capability in describing superconductivity within complex crystal structures. Full article

Recent achievements in ultrafast spin physics have enabled the use of heterostructures composed of ferromagnetic (FM)/non-magnetic (NM) thin layers for terahertz (THz) generation. The mechanism of THz emission from FM/NM multilayers has been typically ascribed to the inverse spin Hall effect (ISHE). In this work, we probe the mechanism of the ISHE by inserting a second ferromagnetic layer in the form of an alloy between the FM/NM system. In particular, by utilizing the co-sputtering technique, we fabricate Fe/L1₀-FePt/Pt ultra-thin heterostructures. We successfully grow the tetragonal phase of FePt (L1₀-phase) as revealed by X-ray diffraction and reflection techniques. We show the strong magnetic coupling between Fe and L1₀-FePt using magneto-optical and Superconducting Quantum Interference Device (SQUID) magnetometry. Subsequently, by utilizing THz time domain spectroscopy technique, we record the THz emission and thus we the reveal the efficiency of spin-to-charge conversion in Fe/L1₀-FePt/Pt. We establish that Fe/L1₀-FePt/Pt configuration is significantly superior to the Fe/Pt bilayer structure, regarding THz emission amplitude. The unique trilayer structure opens new perspectives in terms of material choices for the future spintronic THz sources. Full article

In this work we revisit a vast amount of existing data on physical properties of Ti-Zr-Nb-(Cu,Ni,Co) glassy alloys over a broad range of concentrations (from the high-entropy range to that of conventional Cu-, Ni- or Co-rich alloys). By using our new approach based on the total content of late transition metal(s), we derive a number of physical parameters of a hypothetical amorphous TiZrNb alloy: lattice parameter $a=(3.42\pm 0.02)$ Å, Sommerfeld coefficient $\gamma =6.2\mathrm{mJ/mol}$${\mathrm{K}}^2$, density of states at $N\left(E_F\right)=2.6{\left(\mathrm{at}\mathrm{eV}\right)}^{-1}$, magnetic susceptibility $(2.00\pm 0.05)$mJ/${\mathrm{T}}^2$mol, superconducting transition temperature $T_c=(8\pm 1)$K, upper critical field ${\mathrm{\mu }}_0{H}_{c2}\left(0\right)=(20\pm 5)$T, and coherence length $\xi \left(0\right)=(40\pm 3)$Å. We show that our extrapolated results for the amorphous TiZrNb alloy would be similar to that of crystalline TiZrNb, except for superconducting properties (most notably the upper critical field $H_{c2}\left(0\right)$), which might be attributed to the strong topological disorder of the amorphous phase. Also, we offer an explanation of the discrepancy between the variations in $T_c$ with the average number of valency electrons in neighboring alloys of 4d transition metals and some high-entropy alloys. Overall, we find that our novel method of systematic analysis of results is rather general, as it can provide reliable estimates of the properties of any alloy which has not been prepared as yet. Full article

The Volumetric Neutron Source (VNS) is a pivotal facility proposed for advancing fusion nuclear technology, particularly for the qualification of breeding blanket systems, a key component of DEMO and future fusion reactors. This study focuses on the design and optimisation of the VNS Thermal Shield, adopting a multidisciplinary approach to address its thermal and structural behaviours. The Thermal Shield plays a crucial role in protecting superconducting magnets and other cryogenic components by limiting heat transfer from higher-temperature regions of the tokamak to the cryostat, which operates at temperatures between 4 K and 20 K. To ensure both thermal insulation and structural integrity, multiple design iterations were conducted. These iterations aimed to reduce electromagnetic (EM) forces induced during magnet charge and discharge cycles by introducing strategic cuts and reinforcements in the shield design. The optimisation process included the evaluation of various aluminium alloys and composite materials to achieve a balance between rigidity and weight while maintaining structural integrity under EM and mechanical loads. Additionally, an integrated thermal study was performed to ensure effective temperature management, maintaining the shield at an operational temperature of around 80 K. Cooling channels were incorporated to homogenise temperature distribution, improving thermal stability and reducing thermal gradients. This comprehensive approach demonstrates the viability of advanced material solutions and design strategies for thermal and structural optimisation. The findings reinforce the importance of the VNS as a dedicated platform for testing and validating critical fusion technologies under operationally relevant conditions. Full article

Superconducting alloy containing terbium (Tb) and its reference without the lanthanide were synthesized. X-ray diffraction, scanning electron microscopy, energy dispersive X-ray spectroscopy, specific heat, and magnetic measurements were used to investigate their structural and physical properties. Both alloys crystallized in body-centered cubic structure, and the presence of small amounts of Tb and Tb₂O₃ phases was detected. The critical temperature $T_{\mathrm{c}}$ of alloys was in the 4.6–5.2 K range, and the upper critical field ${\mu }_0{H}_{\mathrm{c}2}$ was 6.1–6.8 T. The comparison with the reference determined the effect of Tb on the alloy’s critical parameters and phase stability connected to the high-entropy alloys’ core effects. Overall, Tb addition did not have a beneficial effect on the superconducting properties of this alloy. Full article

The active and passive components of transformer electrical equipment have reached their limits regarding modernization and optimization, leading to the implementation of innovative approaches. This is particularly relevant for mobile and autonomous energy complexes due to the introduction of increased frequency, which can be advantageous, especially in geoengineering, where the energy efficiency of electrical equipment is crucial. The new design of transformer equipment utilizing cryogenic technologies incorporates high-temperature superconducting (HTS) windings, a dielectric filler made of liquid nitrogen, and a three-dimensional magnetic system based on amorphous alloys. The finite element method showed that the skin effect does not impact HTS windings compared to conventional designs when the frequency increases. The analysis and synthesis of the parameters of the magnetic system made from amorphous iron and HTS windings in an HTS transformer with a dielectric medium of liquid nitrogen at a temperature of 77 K were performed, significantly reducing the mass and size characteristics of the HTS transformer compared to traditional counterparts while eliminating environmental and fire hazards. Based on these studies, an experimental prototype of an industrial HTS transformer with a capacity of 25 kVA was designed and manufactured. Full article

The present report focuses on the close interplay between condensed matter physics and solid-state chemistry in Nb-based binary intermetallic compounds. Over the recent four decades, these materials have been widely used in the development of a number of superconducting applications and various superconducting devices, including non-standard engineering solutions in the design of large magnets. However, since the 1980s, when it became apparent that the mechanical and superior superconducting properties of ordered intermetallic alloys such as Nb₃Sn were largely due to their unique structural features, much of the research interest in the science of superconducting intermetallic alloys has been redirected to the development of necessary engineering applications in high magnetic field technology. Accordingly, the important role of crystal chemistry in understanding the fundamental aspects of the material properties of the Nb₃Sn family of intermetallics has not been extensively explored. In this paper, we try to fill this gap by investigating the relationships between composition, microstructure and properties, highlighting their relevance to technological applications. Our goal is to combine aspects of crystal chemistry with physical and material application issues. We shed light on the atomic assembly mechanisms and processes in terms of changes in the chemical environment, lattice structure, crystallization pathway, and macroscale phase textures, which can help in interpreting and explaining the prospects and limitations of the superconducting properties of Nb₃Sn. In the context of past and present prospects and limitations, we briefly overview most important technological applications and discuss the various inter-relations between superconductivity and structural properties of Nb-based A-15 intermetallic alloys. We argue that these inter-relations can be used to find Nb-based superconductors with more superior properties and stronger technological usability. Full article

The influence of dispersed ZrO₂ particles on the microstructure evolution and the superconducting properties of a Nb-Ti alloy was investigated. The studied materials were prepared by different methods including mechanical alloying (MA) and arc-melting. The obtained samples were studied by X-ray diffraction (XRD) and vibrating-sample magnetometer (VSM). It was found that ZrO₂ particles can be successively introduced into an Fe-Nb matrix by MA. However, among all prepared samples with a nominal composition of Nb-47wt%Ti-5 wt% ZrO₂, only the powders, which were prepared by MA of Nb-47wt%Ti and ZrO₂ powders, exhibit superconductivity with critical parameters comparable to those observed in pristine Nb-47wt%Ti alloy. In particular, the determined upper critical field at 0 K ${\mu }_0{H}_{\mathrm{c}2}\left(0\right)$ is close to 15.6(1) T. This value is slightly higher than 15.3(3) T obtained for Nb-47wt%Ti and it can be ascribed to the presence of introduced ZrO₂ particles in the Nb-Ti matrix. Full article

The impact of the interface phenomena on the properties of nanostructured materials is the focus of modern physics. We studied the magnetic properties of the nanostructured In–Ag alloy confined within a porous glass. The alloy composition was close to the eutectic point in the indium-rich range of the phase diagram. Temperature dependences of DC magnetization evidenced two superconducting transitions at 4.05 and 3.38 K. The magnetization isotherms demonstrated the superposition of two hysteresis loops with low and high critical fields below the second transition, a single hysteresis between the transitions and ferromagnetism with weak remanence in the normal state of the alloy. The shape of the loop seen below the second transition, which closes at a low magnetic field, corresponded to the intermediate state of the type-I superconductor. It was ascribed to strongly linked indium segregates. The loop observed below the first transition is referred to as type-II superconductivity. The secondary and tertiary magnetization branches measured at decreasing and increasing fields were shifted relative to each other, revealing the proximity of superconducting and ferromagnetic phases at the nanometer scale. This phenomenon was observed for the first time in the alloy, whose components were not magnetic in bulk. The sign of the shift shows the dominant role of the stray fields of ferromagnetic regions. Ferromagnetism was suggested to emerge at the interface between the In and AgIn₂ segregates. Full article

In contrast to the observed high-temperature superconductivity in monolayer $\mathrm{FeSe}/{\mathrm{SrTiO}}_3$ films, akin to ${\mathrm{CoS}\mathrm{b}/\mathrm{SrTiO}}_3$, the bulk counterpart, FeSe, does not exhibit superconductivity even under elevated pressure, and its magnetic characteristics remain subject to debate. This investigation delves into the electrical and magnetic attributes, alongside X-ray photoelectron spectroscopy (XPS) analysis, of FeSe mono-crystal. Magnetic and electrical transport assessments indicate that FeSe demonstrates characteristics of a Pauli paramagnetic metal within non-Fermi liquid traits. XPS analysis further reveals that the Fe and Se pair in FeSe exist in a zero-valence state, forming a predominantly metallic-bonded alloy. The Pauli paramagnetism observed in FeSe is ascribed to its itinerant electrons. The comprehension of the electronic states in FeSe mono-crystal not only clarifies its lack of magnetic characteristics but also paves the way for exploring potential high-temperature superconductivity. Full article

A comparison of the results of studies on the influence of structural defects on the critical parameters of superconductivity has been made for the high-entropy alloy (NbTa)${}_{0.67}$(MoHfW)${}_{0.33}$ and for the conventional superconducting magnet material Nb-47wt%Ti. Positron annihilation lifetime spectroscopy (PALS), electrical resistivity, magnetization and magnetic susceptibility measurements were used. In addition, X-ray powder diffraction studies were performed on the high-entropy alloy (NbTa)${}_{0.67}$(MoHfW)${}_{0.33}$. Due to the rapid cooling of the materials after melting in the arc furnace, they contain a higher concentration of structural defects compared to the heat-treated materials. Magnetic property measurements showed that both the critical temperatures $T_{\mathrm{c}}$ and the upper critical fields ${\mu }_0{H}_{\mathrm{c}2}$ of bulk superconductivity-related materials are improved in the presence of structural defects. Full article

Material innovation plays a very important role in technological progress and industrial development. Traditional experimental exploration and numerical simulation often require considerable time and resources. A new approach is urgently needed to accelerate the discovery and exploration of new materials. Machine learning can greatly reduce computational costs, shorten the development cycle, and improve computational accuracy. It has become one of the most promising research approaches in the process of novel material screening and material property prediction. In recent years, machine learning has been widely used in many fields of research, such as superconductivity, thermoelectrics, photovoltaics, catalysis, and high-entropy alloys. In this review, the basic principles of machine learning are briefly outlined. Several commonly used algorithms in machine learning models and their primary applications are then introduced. The research progress of machine learning in predicting material properties and guiding material synthesis is discussed. Finally, a future outlook on machine learning in the materials science field is presented. Full article

The structural and physical properties of the new titanium- and niobium-rich type-A high-entropy alloy (HEA) superconductor Nb${}_{0.34}$Ti${}_{0.33}$Zr${}_{0.14}$Ta${}_{0.11}$Hf${}_{0.08}$ (in at.%) were studied by X-ray powder diffraction, energy dispersive X-ray spectroscopy, magnetization, electrical resistivity, and specific heat measurements. In addition, electronic structure calculations were performed using two complementary methods: the Korringa–Kohn–Rostoker Coherent Potential Approximation (KKR-CPA) and the Projector Augmented Wave (PAW) within Density Functional Theory (DFT). The results obtained indicate that the alloy exhibits type II superconductivity with a critical temperature close to 7.5 K, an intermediate electron–phonon coupling, and an upper critical field of 12.2(1) T. This finding indicates that Nb${}_{0.34}$Ti${}_{0.33}$Zr${}_{0.14}$Ta${}_{0.11}$Hf${}_{0.08}$ has one of the highest upper critical fields among all known HEA superconductors. Full article

The phase transition process of Nb₃Sn during heat treatment exerts important influences on Nb₃Sn formation and the superconducting characteristics of Nb₃Sn superconductors. A simple method for quickly preparing Nb₃Sn was studied. First, Nb, Sn, and Cu powders were mechanically alloyed to prepare the precursor. Then, the precursor was heat treated at different times to form Nb₃Sn. During the first stage, the morphology and crystal structure of the products were analyzed after different milling times. The results of the transmission electron microscopy showed the poor crystallinity of the products compared with the original materials. During the second stage, heat treatment was performed at different temperatures ranging from room temperature to 1073 K. After treatment, the products were studied via X-ray diffraction analysis to determine how the structure changed with increasing temperature. Only the Nb diffraction peaks in the precursor were observed after high-energy ball milling for more than 3 h. When the heat treatment temperature was above 773 K and heat treatment time was 15 min, Nb₃Sn began to form. When the temperature was above 973 K, some impurities, such as Nb₂O₅, appeared. After 5 h of ball milling, the precursor was heat treated at different times in a vacuum heat treatment furnace. The crystal structure of the product exhibited evident diffraction peaks of Nb₃Sn. The critical temperatures of the samples that were heat treated at different times were between 17 K and 18 K. The magnetic critical current density of the sample versus the applied magnetic field at 4.2 K indicated that the magnetic J_c was approximately 30,000 A/cm². Full article