Search Results (33)

Fiber optic distributed acoustic sensing (DAS) technology can monitor vibrational strain of vast areas with fine spatial resolution at high sampling rates. The fiber optic cable portion of DAS may directly monitor, measure, and map potentially unsafe areas such as thin ice sheets. Once the fiber optic cable is emplaced, DAS can provide “rapid-response” information along the cable’s length through remote sampling. A field campaign was performed to test the sensitivity of DAS to spatial variations within thin ice sheets. A pilot field study was conducted in the northeastern United States in which fiber-optic cable was deployed on the surface of a freshwater pond. Phase velocity transformations were used to analyze the DAS response to strike testing on the thin ice sheet. The study results indicated that the ice sheet was about 5 cm thick generally, tapering to about 3.5 cm within 2 m of the pond’s edge and then disappearing at the margins. After validation of the pilot study’s methodology, a follow-up experiment using DAS to collect on a rapidly deployed, surface-laid cable atop a larger freshwater pond was conducted. Using phase velocity transformations, the ice thickness along the fiber optic cable was estimated to be between 25.5 and 28 cm and confirmed via ice auger measurements along the fiber optic cable. This field campaign demonstrates the feasibility of employing DAS systems to remotely assess spatially variable properties on thin freshwater ice sheets. Full article

Numerous strategies have been demonstrated to enhance the mechanical stretchability of electromechanical sensors for widespread applications in wearable electronics. However, ranging from composite to microstructural materials, their electromechanical sensing performances are usually vulnerable to large stretching deformations due to the low-ductility of the infilled conductive components and the modulus mismatch between the flexible polymer substrate and conductive fillers. Here, a novel design strategy is proposed to fabricate ultra-stretchable electromechanical composites constructed by a triple-level interaction conductive network (Tri-LICN) in buckled-TPU microfibers for strain sensors. The Tri-LICN is established by bridging one-dimensional cellulose nanocrystals (CNC) with zero-dimensional gold-nanoparticles (AuNPs) and two-dimensional MXene sheets using interface self-assembly and ultrasound-assisted anchoring to eliminate the modulus mismatching between the conductive material and polymer substrate. The buckled-TPU microfibers are introduced to improve the mechanical stretchability of composites by the external-stimuli-induced imbalance of the stretching conformation of TPU macromolecules. The Tri-LICN MXene/CNC/AuNPs@TPU composite sensor displays an enhanced strain sensitivity (GF~2514) with a fast response time (~150 ms) over a wide operational strain up to 200% and excellent durability over 1000 tensile cycles. Our finding offers a promising approach to enhancing the performance of stretchable sensors based on polymer materials, providing new opportunities for the development of next-generation electronics. Full article

The development of functional textiles has become a key focus in recent years, aiming to meet the diverse requirements of modern society. MXene has excellent conductivity, hydrophilicity, and UV resistance, and is widely used in electromagnetic shielding, sensors, energy storage, and photothermal conversion. Tussah silk (TS) is a unique natural textile raw material and has a unique jewelry luster, natural luxury, and a smooth and comfortable feel. However, there are relatively few studies on the functional finishing of TS fabric with Ti₃C₂T_x MXene. Here, we developed a multifunctional MXene/tussah silk (MXene/TS) fabric by the deposition of Ti₃C₂T_x MXene sheets on the surface of TS fabric through a simple padding–drying–curing process. The obtained MXene/TS fabric (five cycles) exhibited excellent conductivity (4.8 S/m), air permeability (313.6 mm/s), ultraviolet resistance (ultraviolet protection factor, UPF = 186.3), photothermal conversion (temperature increase of 11 °C), and strain sensing. Thanks to these superior properties, the MXene/TS fabric has broad application prospects in motion monitoring, smart clothing, flexible wearables, and artificial intelligence. Full article

Water-stable proteins may offer a new field of applications in smart materials for buildings and infrastructures where hydraulic reactions are involved. In this study, cement mortars modified through water-soluble silk fibroin (SF) are proposed. Water-soluble SF obtained by redissolving SF films in phosphate buffer solution (PBS) showed the formation of a gel with the $\beta$ sheet features of silk II. Electrical measurements of SF indicate that calcium ions are primarily involved in the conductivity mechanism. By exploiting the water solubility properties of silk II and Ca²⁺ ion transport phenomena as well as their trapping effect on water molecules, SF provides piezoresistive and piezocapacitive properties to cement mortars, thus enabling self-sensing of mechanical strain, which is quite attractive in structural health monitoring applications. The SF/cement-based composite introduces a capacitive gauge factor which surpasses the traditional resistive gauge factor reported in the literature by threefold. Cyclic voltammetry measurements demonstrated that the SF/cement mortars possessed memcapacitive behavior for positive potentials near +5 V, which was attributed to an interfacial charge build-up modulated by the SF concentration and the working electrode. Electrical square-biphasic excitation combined with cyclic compressive loads revealed memristive behavior during the unloading stages. These findings, along with the availability and sustainability of SF, pave the way for the design of novel multifunctional materials, particularly for applications in masonry and concrete structures. Full article

AlGaN-based LEDs are promising for many applications in deep ultraviolet fields, especially for water-purification projects, air sterilization, fluorescence sensing, etc. However, in order to realize these potentials, it is critical to understand the factors that influence the optical and electrical properties of the device. In this work, Al_xGa_1−xN (x = 0.24, 0.34, 0.47) epilayers grown on c-plane patterned sapphire substrate with GaN template by the metal organic chemical vapor deposition (MOCVD). It is demonstrated that the increase of the aluminum content leads to the deterioration of the surface morphology and crystal quality of the AlGaN epitaxial layer. The dislocation densities of Al_xGa_1−xN epilayers were determined from symmetric and asymmetric planes of the ω-scan rocking curve and the minimum value is 1.01 × 10⁹ cm⁻². The $\left(10\overline{1}5\right)$ plane reciprocal space mapping was employed to measure the in-plane strain of the Al_xGa_1−xN layers grown on GaN. The surface barrier heights of the Al_xGa_1−xN samples derived from XPS are 1.57, 1.65, and 1.75 eV, respectively. The results of the bandgap obtained by PL spectroscopy are in good accordance with those of XRD. The Hall mobility and sheet electron concentration of the samples are successfully determined by preparing simple indium sphere electrodes. Full article

Fiber-based flexible sensors have promising application potential in human motion and healthcare monitoring, owing to their merits of being lightweight, flexible, and easy to process. Now, high-performance elastic fiber-based strain sensors with high sensitivity, a large working range, and excellent durability are in great demand. Herein, we have easily and quickly prepared a highly sensitive and durable fiber-based strain sensor by dip coating a highly stretchable polyurethane (PU) elastic fiber in an MXene/waterborne polyurethane (WPU) dispersion solution. Benefiting from the electrostatic repulsion force between the negatively charged WPU and MXene sheets in the mixed solution, very homogeneous and stable MXene/WPU dispersion was successfully obtained, and the interconnected conducting networks were correspondingly formed in a coated MXene/WPU shell layer, which makes the as-prepared strain sensor exhibit a gauge factor of over 960, a large sensing range of over 90%, and a detection limit as low as 0.5% strain. As elastic fiber and mixed solution have the same polymer constitute, and tight bonding of the MXene/WPU conductive composite on PU fibers was achieved, enabling the as-prepared strain sensor to endure over 2500 stretching–releasing cycles and thus show good durability. Full-scale human motion detection was also performed by the strain sensor, and a body posture monitoring, analysis, and correction prototype system were developed via embedding the fiber-based strain sensors into sweaters, strongly indicating great application prospects in exercise, sports, and healthcare. Full article

SPIRA Coil actuators are formed from thin sheets of PET plastic laminated into a coil shape that unfurls like a “party horn” when inflated, while many soft actuators require large pressures to create only modest strains, SPIRA Coils can easily be designed and fabricated to extend over dramatic distances with relatively low working pressures. Internal metalized PET strips separate in the extended portion of the actuator, creating an electrical circuit with a resistance that corresponds to the actuator length. This paper presents and experimentally validates easy-to-use design models for the actuators’ self-retracting spring stiffness, its pneumatic extension force, and its internal length-sensing electrical resistance. Testing of the self-sensing capabilities demonstrates that the embedded sensor can be used to determine the actuator length with virtually no hysteresis. Feedback control with the resistance-based sensing resulted in length-control errors within 5% of the extended actuator length (i.e., 3 cm of 60 cm). Full article

Metal–organic frameworks (MOFs) are a class of crystalline porous materials with outstanding physical and chemical properties that make them suitable candidates in many fields, such as catalysis, sensing, energy production, and drug delivery. By combining MOFs with polymeric substrates, advanced functional materials are devised with excellent potential for biomedical applications. In this research, Zeolitic Imidazolate Framework 8 (ZIF-8), a zinc-based MOF, was selected together with cellulose, an almost inexhaustible polymeric raw material produced by nature, to prepare cellulose/ZIF-8 composite flat sheets via an in-situ growing single-step method in aqueous media. The composite materials were characterized by several techniques (IR, XRD, SEM, TGA, ICP, and BET) and their antibacterial activity as well as their biocompatibility in a mammalian model system were investigated. The cellulose/ZIF-8 samples remarkably inhibited the growth of Gram-positive and Gram-negative reference strains, and, notably, they proved to be effective against clinical isolates of Staphylococcus epidermidis and Pseudomonas aeruginosa presenting different antibiotic resistance profiles. As these pathogens are of primary importance in skin diseases and in the delayed healing of wounds, and the cellulose/ZIF-8 composites met the requirements of biological safety, the herein materials reveal a great potential for use as gauze pads in the management of wound infections. Full article

Flexible photonic devices based on soft polymers enable real-time sensing of environmental conditions in various industrial applications. A myriad of fabrication techniques have been established for producing optical devices, including photo and electron-beam lithography, nano/femtosecond laser writing, and surface imprinting or embossing. However, among these techniques, surface imprinting/embossing is simple, scalable, convenient to implement, can produce nanoscale resolutions, and is cost-effective. Herein, we utilize the surface imprinting method to replicate rigid micro/nanostructures onto a commonly available PDMS substrate, enabling the transfer of rigid nanostructures into flexible forms for sensing at a nanometric scale. The sensing nanopatterned sheets were mechanically extended, and the extension was remotely monitored via optical methods. Monochromatic light (450, 532, and 650 nm) was transmitted through the imprinted sensor under various force/stress levels. The optical response was recorded on an image screen and correlated with the strain created by the applied stress levels. The optical response was obtained in diffraction pattern form from the flexible grating-based sensor and in an optical-diffusion field form from the diffuser-based sensor. The calculated Young’s modulus in response to the applied stress, measured through the novel optical method, was found in a reasonable range compared to the reported range of PDMS (360–870 kPa) in the literature. Full article

This paper proposes a fiber optic Fabry-Perot (F-P) strain sensing system using non-scan correlation demodulation applied to the health monitoring of the pressurized water reactor’s fuel assembly structures. The structural design and sensing mechanism analysis of the sensor were carried out, and the strain transfer model from the fuel sheet to the strain gauge was established. After the sensor fabrication and installation, the static tests have been conducted, and the results indicate that the sensing system can accurately measure the microstrain with a sensitivity of up to 12.6 nm/με at a high temperature (300 °C). The dynamic testing shows that the sensing system has a good frequency adaptation at 10–500 Hz. Thermal-hydraulic experiments show that the sensing system can run stably in a nuclear reactor, with high temperature, high pressure, and high-velocity flow flushing; additionally, the consistency deviation of the measured data is less than 1.5%. Full article

Motion sensing, aimed at detecting and monitoring mechanical deformation, has received significant attention in various industrial and research fields. In particular, fiber-structured mechanical strain sensors with carbon-based materials have emerged as promising alternatives for wearable applications owing to their wearability and adaptability to the human body. Various materials, structures, sensing mechanisms, and fabrication methods have been used to fabricate high-performance fiber strain sensors. Nevertheless, developing multi-modal strain sensors that can monitor multiple deformations remains to be accomplished. This study established core/sheath fiber multi-modal strain sensors using polymer and carbon nanotubes (CNTs). Specifically, a flexible and conductive CNT sheet was wrapped onto the elastomeric core fiber at a certain angle. This wrapping angle allowed the CNTs to mechanically deform under tensile and torsional deformations without fatal structural damage. The CNTs could sense both tensile and torsional strains through reversible structural changes during deformations. The fiber strain sensor exhibited an increase of 124.9% and 9.6% in the resistance during tensile and torsional deformations of 100% and 1250 rad/m, respectively. Full article

Within the paradigm of smart mobility, the development of innovative materials aimed at improving resilience against structural failure in lightweight vehicles and electromagnetic interferences (EMI) due to wireless communications in guidance systems is of crucial relevance to improve safety, sustainability, and reliability in both aeronautical and automotive applications. In particular, the integration of intelligent structural health monitoring and electromagnetic (EM) shielding systems with radio frequency absorbing properties into a polymer composite laminate is still a challenge. In this paper, we present an innovative system consisting of a multi-layered thin panel which integrates nanostructured coatings to combine EM disturbance suppression and low-energy impact monitoring ability. Specifically, it is composed of a stack of dielectric and conductive layers constituting the sensing and EM-absorbing laminate (SEAL). The conductive layers are made of a polyurethane paint filled with graphene nanoplatelets (GNPs) at different concentrations to tailor the effective electrical conductivity and the functionality of the material. Basically, the panel includes a piezoresistive grid, obtained by selectively spraying onto mylar a low-conductive paint with 4.5 wt.% of GNPs and an EM-absorbing lossy sheet made of the same polyurethane paint but properly modified with a higher weight fraction (8 wt.%) of graphene. The responses of the grid’s strain sensors were analyzed through quasi-static mechanical bending tests, whereas the absorbing properties were evaluated through free-space and waveguide-based measurement techniques in the X, Ku, K, and Ka bands. The experimental results were also validated by numerical simulations. Full article

This study uses near-field electrospinning (NFES) technology to make a novel self-powered strain sensor and applies it to the real-time monitoring of a bending structure, so that the measurement equipment can be reduced in volume. A self-powered strain sensor consists of polyvinylidene difluoride (PVDF) fibers, a PDMS fixed substrate, and an aluminum electrode. PVDF fibers are spun with DMSO and acetone using NFES technology, with a diameter of about 8 μm, Young’s modulus of 1.1 GPa, and piezoelectric effect of up to 230 mV. The fixed substrate is a film made of PDMS by thermal curing, then adhered to the PDMS film surface of the sheet Al metal as an Al electrode, and then combined with PVDF fiber film, to become a self-powered strain sensor. As a result, the XRD β value of the self-powered strain sensor reaches 2112 and the sensitivity is increased by 20% over a traditional strain sensor. The cumulative angle algorithm can be applied to measure the angular change of the object over a unit of time or the cumulative displacement of the object over the entire period of motion. The experimental results demonstrate that the self-powered strain sensor combined with the angle accumulation algorithm may be applied to monitor the bending structure, thereby achieving continuous measurements of bending structure changes, and improving on traditional piezoelectric sensors, which can only be sensed once. In the future, self-powered strain sensors will have the ability to continuously measure in real-time, enabling the use of piezoelectric sensors for long-term monitoring of structural techniques. Full article

Harnessing surface wrinkle surfaces in various functional devices has been a hot topic. However, rapidly creating wrinkled surfaces on elastomers of arbitrary shape (especially curved surfaces) is still a great challenge. In this work, an ultrasonic-assisted deposition method has been proposed to achieve nanomodification of the robust layer (e.g., carbon nanotubes (CNTs)) with a labyrinth wrinkle pattern on polydimethylsiloxane (PDMS) fiber, sheet, and porous sponge. It is found that the swelling effect of the dispersion and the ultrasonic treatment play vital roles in the surface wrinkling. As a demonstration, the conductive wrinkled CNTs@PDMS fibers were assembled as stretchable strain sensors. The initial conductivity and the strain-sensing performances could be well tuned by simply adjusting the ultrasonic treatment time. The wrinkled CNTs@PDMS fiber strain sensor exhibited remarkable stretchability (ca. 300%) and good sensitivity, which can be applied in various human motion detection, voice recognition, and air-flow monitoring. It is also expected that the facile ultrasonic-assisted deposition method for surface wrinkling can be extended to fabricate various smart devices with promoted performances. Full article

Strain is one of the most frequently monitored parameters in civil structural health monitoring (SHM) applications, and strain-based approaches were among the first to be explored and applied in SHM. There are multiple reasons why strain plays such an important role in SHM: strain is directly related to stress and deflection, which reflect structural performance, safety, and serviceability. Strain field anomalies are frequently indicators of unusual structural behaviors (e.g., damage or deterioration). Hence, the earliest concepts of strain sensing were explored in the mid-XIX century, the first effective strain sensor appeared in 1919, and the first onsite applications followed in the 1920′s. Today, one hundred years after the first developments, two generations of strain sensors, based on electrical and fiber-optic principles, firmly reached market maturity and established themselves as reliable tools applied in strain-based SHM. Along with sensor developments, the application methods evolved: the first generation of discrete sensors featured a short gauge length and provided a basis for local material monitoring; the second generation greatly extended the applicability and effectiveness of strain-based SHM by providing long gauge and one-dimensional (1D) distributed sensing, thus enabling global structural and integrity monitoring. Current research focuses on a third generation of strain sensors for two-dimensional (2D) distributed and quasi-distributed sensing, based on new advanced technologies. On the occasion of strain sensing centenary, and as an homage to all researchers, practitioners, and educators who contributed to strain-based SHM, this paper presents an overview of the first one hundred years of strain sensing technological progress, with the objective to identify relevant transformative milestones and indicate possible future research directions. Full article