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Keywords = squeezed pore-water

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24 pages, 7584 KB  
Article
Influence of the Soil Squeezing Effect on the Peripile Soil of Pre-Tensioned H-Type Prestressed Concrete Revetment Pile Construction Based on Field Tests
by Yuedong Wu, Yu Xiao and Jian Liu
Buildings 2024, 14(12), 3816; https://doi.org/10.3390/buildings14123816 - 28 Nov 2024
Cited by 2 | Viewed by 1513
Abstract
Pre-tensioned H-type prestressed concrete revetment piles are a newly developed product dedicated to the protection of river, lake, and sea bank embankments, and their cross-section is H-shaped. In this study, a field test of H-type pile soil’s squeezing effect is carried out based [...] Read more.
Pre-tensioned H-type prestressed concrete revetment piles are a newly developed product dedicated to the protection of river, lake, and sea bank embankments, and their cross-section is H-shaped. In this study, a field test of H-type pile soil’s squeezing effect is carried out based on the second phase project of the HujiaShen Line. Pore water pressure, soil displacement, and other parameters of the H-type pile-driving process are monitored in real time. The test results show the following: (1) The influence range of the excess pore water pressure caused by the soil squeezing effect in the horizontal direction is about 14–15D, and in the vertical direction, the pore water pressure within a depth range of about 7D below the pile bottom increases rapidly. Its dissipation rate is fast at first and then slows down, and it completely dissipates 20 days after piling. (2) The excess pore water pressure caused by the soil squeezing effect does not decrease linearly in the radial direction. The soil around the construction pile can be divided into four areas: A, B, C, and D. Among them, A and B belong to the plastic zone, and C and D belong to the elastic zone. (3) The horizontal displacement of the soil occurs within the depth range of 5D from the surface of the pile to the bottom of the pile at the piling location, and the radial influence range is about 8–12D. From a vertical perspective, the main horizontal displacement of the soil occurs in the long section of the pile driven into the soil, showing a “U”-shaped distribution. (4) The dividing point between the vertical displacement uplift and the settlement of the soil appears within the range of 2–3 m from the construction pile, that is, between 5 and 7D. Settlement occurs after the piling is completed, and the settlement rate is fast at first and then slows down. The final settlement of the soil is stable on the 20th day. This research and experiment provide a design reference for the engineering application of pre-tensioned H-type prestressed concrete bank protection piles. Full article
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17 pages, 5930 KB  
Article
Field Test Study on Construction Disturbances of Driven Pile and PGP Pile
by Feiyu Shao, Yuebao Deng, Shuaijiong Chen, Rongyue Zheng and Rihong Zhang
Appl. Sci. 2023, 13(21), 11887; https://doi.org/10.3390/app132111887 - 30 Oct 2023
Cited by 8 | Viewed by 2850
Abstract
The pre-bored grouted planted (PGP) pile has been more and more used in recent years, but its precise disturbance effect in soft soil areas has not been studied deeply. Therefore, a comparative field test for the disturbances by PGP pile and driven pile [...] Read more.
The pre-bored grouted planted (PGP) pile has been more and more used in recent years, but its precise disturbance effect in soft soil areas has not been studied deeply. Therefore, a comparative field test for the disturbances by PGP pile and driven pile construction in deep soft ground was carried out. It revealed that the excess pore pressure caused by the two kinds of piles decreases with the increase of radial distance, and the influence range is less than 7.5 d (d is pile diameter). The maximum excess pore pressure generated by PGP pile construction is about 100 kPa smaller than that generated by driven pile construction. The comparison of the soil pressure and lateral displacement between the two piles is related to the depth and soil type. The typical result is that the soil pressure caused by PGP pile construction is half that of the driven pile, and the maximum lateral displacement of the PGP pile is 50.7~53.8% of that of the driven pile. The noise generated during PGP construction was lower but continuous, and the maximum value at the same distance was reduced by 8 to 15% than the driven pile. The test results reveal the construction disturbance effect of PGP pile and provide a reference for the selection of pile construction method in soft soil areas. Full article
(This article belongs to the Section Civil Engineering)
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14 pages, 4253 KB  
Article
NMR-Based Analysis of Fluid Occurrence Space and Imbibition Oil Recovery in Gulong Shale
by Fei Xu, Hanqiao Jiang, Ming Liu, Shuai Jiang, Yong Wang and Junjian Li
Processes 2023, 11(6), 1678; https://doi.org/10.3390/pr11061678 - 31 May 2023
Cited by 12 | Viewed by 2739
Abstract
The Gulong shale oil reservoir is situated in freshwater to slightly saline lacustrine basins mainly consisting of a pure shale geological structure, which is quite different from other shale reservoirs around the world. Currently, the development of Gulong shale oil mainly relies on [...] Read more.
The Gulong shale oil reservoir is situated in freshwater to slightly saline lacustrine basins mainly consisting of a pure shale geological structure, which is quite different from other shale reservoirs around the world. Currently, the development of Gulong shale oil mainly relies on hydraulic fracturing, while the subsequent shut-in period for imbibition has been proven to be an effective method for enhancing shale oil recovery. To clarify the characteristics of the fluid occurrence space and the variation in the fluid occurrence during saltwater imbibition in Gulong shale, this paper carried out porosity and permeability tests on Gulong shale cores and analyzed the fluid occurrence space characteristics and imbibition oil recovery based on nuclear magnetic resonance (NMR). In the porosity and permeability tests, T2 distributions were used to correct the porosity measured by the saturation method to obtain the NMR porosity. Combined with the identification of fractures in shale cores using micro-CT and the analysis of porosity and permeability parameters, it was found that the permeability of the shale cores was related to the development of fractures in the shale cores. Through the testing and analysis of T1-T2 maps of the shale cores before and after saturation with oil, it was found that the shale mainly contained heavy oil, light oil, and clay-bound water, and they were distributed in different regions in the T1-T2 maps. Finally, the T1-T2 maps of the shale cores at different imbibition stages were analyzed, and it was found that saltwater mainly entered the minuscule inorganic pores of clay minerals during the imbibition process and squeezed the larger-sized inorganic pores containing light oil through the hydration expansion effect, thus expelling the light oil from the shale core and achieving the purpose of enhanced oil recovery. Full article
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19 pages, 5947 KB  
Article
Development of Innovative Plate Load Testing Equipment for In-Situ Saturated Clays Soils
by Ibrahim Umaru, Mustapha Mohammed Alhaji, Musa Alhassan, Taiye Elisha Adejumo, Babawuya Alkali, Abdullahi Haruna Birniwa and Ahmad Hussaini Jagaba
Geotechnics 2023, 3(2), 142-160; https://doi.org/10.3390/geotechnics3020009 - 27 Mar 2023
Cited by 10 | Viewed by 4712
Abstract
This study proposes a method of gradually loading plate load on-site using lever arms to squeeze out pore water from clayey soils, allowing the soil to settle. Several types of tests were conducted, including a conventional field plate load test (CFPLT), a numerical [...] Read more.
This study proposes a method of gradually loading plate load on-site using lever arms to squeeze out pore water from clayey soils, allowing the soil to settle. Several types of tests were conducted, including a conventional field plate load test (CFPLT), a numerical field plate load test (NFPLT) and an innovative field plate load test (IFPLT) proposed in this study. Three trial pits with soils of varied engineering properties were studied using CFPLT, which employed the use of a heavy jack for load application, the NFPLT test using PLAXIS and an IFPLT, which employed a lever arm to magnify the applied static load. Disturbed soil samples collected from these trial pits were tested for index properties while the undisturbed soil samples were tested using the undrained triaxial compression test (UTCT) and laboratory consolidation tests. The results of the index properties classified these three clay soils as silt of low plasticity (ML) for clay from site 1, and clay of low plasticity (CL) for clay from site 2 and 3. The cohesion and angle of internal friction from the UTCT recorded cohesion values were 28, 29 and 37 kN/m2 for sites 1, 2 and 3, respectively, while the angle of internal friction values were 13, 8 and 6° for sites 1, 2 and 3, respectively. The plate load testing using the three methods showed similar graph pattern except that the allowable load occurred at approximately 350 kN/m2 for the CFPLT and 150 kN/m2 for the IFPLT. The high value of bearing capacity in CFPLT is due to the short period of time taken to load from a jack, which allowed the test to be completed within a short period of time. The ultimate bearing capacities computed from the laboratory test have values of 315.0, 231.0 and 270.0 kN/m2 for sites 1, 2 and 3, respectively. These values agree closely with the bearing capacities obtained for CFPLT but higher than the values recorded for the IFPLT. This is probably due to the long period of sustained loading during testing, which allowed for dissipation of pore water during each loading. Settlements obtained using the IFPLT were close to 25 mm, which is recommended as minimum settlements for building structures BS 8004, 1986. Full article
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17 pages, 9430 KB  
Article
Numerical Investigation of the Upside-Down Hanging Well Combined with Curtain Grouting for Strengthening a Flood Control Ancient Levee
by Zipeng Qin, Yan Tian, Siyuan Gao, Jianfen Zhou, Haitao Zhao, Zhizhuo Guo, Tannong Chen and Zhiping Hua
Sustainability 2023, 15(5), 4287; https://doi.org/10.3390/su15054287 - 28 Feb 2023
Cited by 4 | Viewed by 2478
Abstract
The ancient levees used for flood control generally exist in the rainy areas of southern China. After years of operation, the levees have lots of problems, such as leakage, swelling, and cracking, which need to be reinforced. In this paper, combined with the [...] Read more.
The ancient levees used for flood control generally exist in the rainy areas of southern China. After years of operation, the levees have lots of problems, such as leakage, swelling, and cracking, which need to be reinforced. In this paper, combined with the characteristics of river water level fluctuations, the effect of the upside-down hanging well and curtain grouting reinforcement of the ancient levee is analyzed by a numerical method, and the variation law of the levee’s stability in the flooding process before and after reinforcement is explored. The study results show that the flooding process significantly affects the pore water pressure of the filling soil between the ancient levee and the well, and has a weak impact on that behind the well, which is conducive to the levee’s stability. The horizontal displacements of the levee and the fill present the opposite change law before and after reinforcement. Before reinforcement, the maximum horizontal displacement reached 2.75 cm, and the displacement was toward the Lan River. This was caused by the deformation of the soil squeezing the levee after the water level rose, which was extremely unfavorable to the levee’s stability. After reinforcement, the levee and fill shifted away from the river, mainly due to the hydrostatic pressures caused by the rising water level. The change in the stability safety factors of the reinforced levee is basically consistent with the flood fluctuation. The minimum value of the safety factors is 1.727, the maximum value is 2.273, and the safety factor only decreases by 24.02%, which is half of the change range of the safety factors before reinforcement. The stability of the reinforced ancient levee is largely improved. Full article
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10 pages, 1621 KB  
Communication
A Novel Approach to Water Softening Based on Graphene Oxide-Activated Open Cell Foams
by Riccardo Balzarotti, Alessandro Migliavacca, Andrea Basso Peressut, Alessandro Mansutti and Saverio Latorrata
C 2023, 9(1), 6; https://doi.org/10.3390/c9010006 - 7 Jan 2023
Cited by 3 | Viewed by 3432
Abstract
This work focuses on exploring a new configuration for the reduction of water hardness based on the surface modification of polyurethane (PU) open cell foams by the deposition of thin graphene oxide (GO) washcoat layers. GO was deposited by the dip–squeeze coating procedure [...] Read more.
This work focuses on exploring a new configuration for the reduction of water hardness based on the surface modification of polyurethane (PU) open cell foams by the deposition of thin graphene oxide (GO) washcoat layers. GO was deposited by the dip–squeeze coating procedure and consolidated by thermal treatment. The final washcoat load was controlled by performing consecutive depositions, after three of which, a GO inventory up to 27 wt% was obtained onto PU foams of 60 pores per inch (PPI). The GO-coated PU foams were assembled into a filter, and the performance of the system was tested by continuously feeding water with hardness in the 190–270 mgCa2+,eq·L−1 range. Remarkable results were demonstrated in terms of total adsorbing capacity, which was evaluated by measuring the outlet total hardness by titration and exhibited values up to 63 mgCa2+,eq·gGO−1 at a specific filtered water volume of 650 mLH2O·gGO−1, outperforming the actual state-of-the-art adsorbing capacity of similar GO-based materials. Full article
(This article belongs to the Special Issue Carbons for Health and Environmental Protection)
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22 pages, 6839 KB  
Article
Experimental Investigation of the Coupling Effect of Jackup Offshore Platforms, Towers, and Seabed Foundations under Waves of Large Wave Height
by Hailin Ye, Feng Zu, Chuwei Jiang, Wenjing Bai and Yaojiang Fan
Water 2023, 15(1), 24; https://doi.org/10.3390/w15010024 - 21 Dec 2022
Cited by 2 | Viewed by 2937
Abstract
A large number of jackup offshore platforms with towers are widely applied in ocean engineering. The dynamic response of the platforms to waves of large wave height is critical, as such waves may cause platform accidents, property damage, and casualties. Therefore, it is [...] Read more.
A large number of jackup offshore platforms with towers are widely applied in ocean engineering. The dynamic response of the platforms to waves of large wave height is critical, as such waves may cause platform accidents, property damage, and casualties. Therefore, it is important to investigate the coupling effect of jackup offshore platform, towers and seabed foundations under waves of large wave height. In this study, the coupling effect of offshore platforms, tower structures, and seabed foundations under the impact of waves of large wave height was studied via a physical flume model test. The experimental results show that the impact of waves of large wave height on the platforms is significant when the wave is blocked by the platform surface as the water body gathers under the platform surface, causing a pile group effect that results in the onshore piles being subjected to larger pressures than the front ones. The combined action of wave impact and pile leg squeezing force leads to an increase in the pore pressure of the foundation bed near the pile leg, and the soil near the pile leg becomes soft, revealing the mechanism of instability of the offshore platform’s pile foundation under waves of large wave height. The acceleration of the longitudinal movement of the platform increases under waves of large wave height, and the vortex-induced vibration of the platform includes the vibration along the direction of the wave and perpendicular to it. A coupled vibration effect between the tower structure and the platform occurs under waves of large wave height, reducing the vibration of the platform itself. Furthermore, damping members are installed on the tower structure, greatly reducing the natural vibration period and the motion response of the tower structure. This study provides significant enlightenment for the design of offshore platforms with towers to protect against waves of large wave height. Full article
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16 pages, 4096 KB  
Article
Test Study of Seepage Characteristics of Coal Rock under Various Thermal, Hydraulic, and Mechanical Conditions
by Yanlin Zhao, Qiang Liu, Liming Tang, Jian Liao, Le Chang, Xiaguang Wang, Yang Li and Sheng Ren
Machines 2022, 10(11), 1012; https://doi.org/10.3390/machines10111012 - 2 Nov 2022
Cited by 10 | Viewed by 2323
Abstract
The seepage characteristics of rocks under conditions of multi-field activity have always been important in the field of rock mechanics. This study used the MTS815 multi-functional electro-hydraulic servo rock testing machine to conduct seepage tests on long-flame coal specimens under different confining pressures, [...] Read more.
The seepage characteristics of rocks under conditions of multi-field activity have always been important in the field of rock mechanics. This study used the MTS815 multi-functional electro-hydraulic servo rock testing machine to conduct seepage tests on long-flame coal specimens under different confining pressures, water pressures, and temperatures. This paper presents and discusses the seepage characteristics of coal specimens under the action of thermal hydraulic mechanical multi-field combinations. Considering parameters such as volumetric strain, temperature, thermal expansion coefficient, and initial porosity, the relationships of each parameter with porosity were obtained. The test results revealed that the volumetric strain of coal specimens increased gradually with the increase of temperature. The dynamic viscosity of water decreased with the increase of temperature, which accelerated the movement and circulation of water molecules. The increase in temperature caused the volume of the coal specimen to expand, the pores in the coal specimen squeezed against each other, the pore volume decreased, and the size of the seepage channel slowly decreased, which inhibited the seepage process. Furthermore, permeability gradually decreased with the increase of temperature. This inhibited the occurrence of seepage, and the higher the confining pressure, the lower was the permeability. The porosity of coal specimens decreased with the increase in temperature, which had an inhibitory effect on the seepage behavior. The results of this study provide experimental and theoretical support for the safe mining of coal and rock in underground mines. Full article
(This article belongs to the Special Issue Advances in Fracture Mechanics for Structural Integrity Assessment)
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11 pages, 13216 KB  
Article
Synthesis of Poly(styrene-vinyl sodium sulfonate-butyl acrylate-ethyl methacrylate) and Its Blocking Mechanism as a Nanometer Material in Water-Based Drilling Fluid
by Jiantao Yu, Yu Chen, Jingying Li, Chen Sheng, Jiaxun Sheng, Zhengtian Wu, Ye Zhou, Xiaodong Li and Gang Xie
Sustainability 2022, 14(21), 13861; https://doi.org/10.3390/su142113861 - 25 Oct 2022
Cited by 1 | Viewed by 2126
Abstract
Nano-blocking technology has become a key to overcoming a prominent bottleneck in shale gas development. In this paper, poly(ST-VS-B-E) was synthesized by Michael addition reaction using styrene, vinyl sodium sulfonate, ethyl methacrylate, and butyl acrylate. Poly(ST-VS-B-E) was characterized by infrared spectroscopy analysis, laser [...] Read more.
Nano-blocking technology has become a key to overcoming a prominent bottleneck in shale gas development. In this paper, poly(ST-VS-B-E) was synthesized by Michael addition reaction using styrene, vinyl sodium sulfonate, ethyl methacrylate, and butyl acrylate. Poly(ST-VS-B-E) was characterized by infrared spectroscopy analysis, laser scattering analysis, and thermogravimetric analysis. The rheological properties of drilling fluid with poly(ST-VS-B-E) were studied by testing the drilling fluid’s properties. The results showed that the median particle size of poly(ST-VS-B-E) was 79.15 nm and it resisted a 359.25 °C high temperature. The yield point of the water-based drilling fluid with 2.5 wt% poly(ST-VS-B-E) added was 27 Pa, and the fluid loss was 3.1 mL, with good drilling fluid performance. Further test results from simulated mud cake filtration and the simulated core penetration showed that when the mass concentration of poly(ST-VS-B-E) was 2.5 wt%, the blocking rates were 66.67% and 93.33%, respectively, and the blocking performance increased gradually with the addition of poly(ST-VS-B-E). Poly(ST-VS-B-E) can be squeezed into the nano-pores of a shale formation under the action of pressure difference, so as to block the formation and prevent the entry of water-based drilling fluid filtrate. Poly(ST-VS-B-E) can serve as a potential nano-blocking material in water-based drilling fluids. Full article
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16 pages, 7806 KB  
Article
Respiratory Adsorption of Organic Pollutants in Wastewater by Superhydrophobic Phenolic Xerogels
by Yinchun Li, Depeng Gong, Youliang Zhou, Chaocan Zhang, Chunyang Zhang, Yitian Sheng and Shu Peng
Polymers 2022, 14(8), 1596; https://doi.org/10.3390/polym14081596 - 14 Apr 2022
Cited by 6 | Viewed by 2626
Abstract
Organogel adsorbents are widely used for the adsorption of hard-to-degrade organic pollutants in wastewater due to their natural affinity to the organic phase in water. In this study, phenolic xerogels (PF) synthesised in the ethylene glycol inorganic acid system are used as a [...] Read more.
Organogel adsorbents are widely used for the adsorption of hard-to-degrade organic pollutants in wastewater due to their natural affinity to the organic phase in water. In this study, phenolic xerogels (PF) synthesised in the ethylene glycol inorganic acid system are used as a backbone and superhydrophobic phenolic xerogels (ASO-PF) are obtained by grafting aminosilanes onto the PF backbone via the Mannich reaction. The modified ASO-PF not only retains the pore structure of the original PF (up to 90% porosity), but also has excellent superhydrophobic properties (water contact angle up to 153°). Owing to the unique pore structure, ASO-PF has excellent compression properties, cycling 50% compression deformation more than 10 times without being damaged, with a maximum compression deformation of up to 80%. A squeeze–suction–squeeze approach is proposed for selective adsorption of organic pollutants in homogeneous solutions based on the recyclable compression properties of ASO-PF. The ASO-PF is put under negative pressure by squeezing, and when the pressure is released, the adsorbed liquid enters the ASO-PF, where the organic pollutants are retained by the adsorption sites in the skeleton, and then the remaining water is discharged by squeezing. This breathing ASO-PF holds great promise for organic pollutant adsorption and recovery applications. Full article
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13 pages, 4436 KB  
Article
Highly Stretchable and Rapid Self-Recoverable Cryogels Based on Butyl Rubber as Reusable Sorbent
by Sevil Muslumova, Berkant Yetiskin and Oguz Okay
Gels 2019, 5(1), 1; https://doi.org/10.3390/gels5010001 - 7 Jan 2019
Cited by 21 | Viewed by 7090
Abstract
Cryogels based on hydrophobic polymers combining good mechanical properties with fast responsivity are attractive materials for many applications, such as oil spill removal from water and passive sampler for organic pollutants. We present, here, cryogels based on butyl rubber (BR) with a high [...] Read more.
Cryogels based on hydrophobic polymers combining good mechanical properties with fast responsivity are attractive materials for many applications, such as oil spill removal from water and passive sampler for organic pollutants. We present, here, cryogels based on butyl rubber (BR) with a high stretchability, rapid self-recoverability, and excellent reusability for organic solvents. BR cryogels were prepared at subzero temperatures in cyclohexane and benzene at various BR concentrations in the presence of sulfur monochloride (S2Cl2) as a crosslinker. Although the properties of BR cryogels are independent of the amount of the crosslinker above a critical value, the type of the solvent, the cryogelation temperature, as well as the rubber content significantly affect their properties. It was found that benzene produces larger pore volumes as compared to cyclohexane due to the phase separation of BR from benzene at low temperatures, producing additional pores. Increasing cryogelation temperature from −18 to −2 °C leads to the formation of more ordered and aligned pores in the cryogels. Increasing BR content decreases the amount of unfrozen microphase of the frozen reaction solution, leading to a decrease in the total porosity of the cryogels and the average diameter of pores. Cryogels formed at −2 °C and at 5% (w/v) BR in cyclohexane sustain up to around 1400% stretch ratios. Cryogels swollen in toluene can completely be squeezed under strain during which toluene is released from their pores, whereas addition of toluene to the squeezed cryogels leads to recovery of their original shapes. Full article
(This article belongs to the Special Issue Cryogelation and Cryogels)
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13 pages, 12245 KB  
Article
Influence of Rice Straw Fibers on Concrete Strength and Drying Shrinkage
by Feraidon Ataie
Sustainability 2018, 10(7), 2445; https://doi.org/10.3390/su10072445 - 13 Jul 2018
Cited by 45 | Viewed by 11526
Abstract
Fibers have been used in construction materials for centuries. This study investigated the impact of the addition of rice straw fibers (RSF) on the compressive and flexural strengths of concrete, drying shrinkage, and on the heat of cement hydration. RSF was saturated before [...] Read more.
Fibers have been used in construction materials for centuries. This study investigated the impact of the addition of rice straw fibers (RSF) on the compressive and flexural strengths of concrete, drying shrinkage, and on the heat of cement hydration. RSF was saturated before being added to concrete. Addition of RSF in concrete reduced concrete strength, increased concrete drying shrinkage, and increased the induction period of cement hydration. It was suggested that water squeezed out of RSF during mixing and sample consolidation increased effective water-to-cement ratios (w/c) and resulted in reduction of concrete strength and increase of concrete drying shrinkage. The increase of retardation time was attributed to leaching of organic and inorganic compounds out of RSF into the pore solution. It was shown that samples containing washed RSF did not have noticeable improvement in compressive strength over samples containing unwashed (as received) RSF. However, samples containing washed RSF had lower drying shrinkage and shorter induction period compared to those containing unwashed RSF. Full article
(This article belongs to the Special Issue Sustainable Cementitious Materials for the Construction Industry)
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12 pages, 6043 KB  
Article
Polymerizable Microsphere-Induced High Mechanical Strength of Hydrogel Composed of Acrylamide
by Zhiyong Wang, Meiqin Lin, Menghan Wang, Xia Song, Chuqiao Zhang, Zhaoxia Dong, Juan Zhang and Zihao Yang
Materials 2018, 11(6), 880; https://doi.org/10.3390/ma11060880 - 24 May 2018
Cited by 15 | Viewed by 4361
Abstract
Polymerizable microspheres are introduced into acrylamide to prepare the high mechanical strength hydrogels with a novel three-dimensional pore structure. Rheological properties, compressive stress–strain, tensile property, and compression strength of three different types of hydrogels were investigated. Moreover, a scanning electron microscope (SEM) was [...] Read more.
Polymerizable microspheres are introduced into acrylamide to prepare the high mechanical strength hydrogels with a novel three-dimensional pore structure. Rheological properties, compressive stress–strain, tensile property, and compression strength of three different types of hydrogels were investigated. Moreover, a scanning electron microscope (SEM) was adopted to observe the three-dimension network structure of three different types of hydrogels. The test results illustrated that viscous moduli (G″) and elastic moduli (G′) of a hydrogel containing polymerizable microspheres (P) reached maximum values, compared to the normal hydrogel (N) and the composite hydrogel containing ordinary microspheres (O). When the hydrogels were squeezed, the N was easily fractured under high strain (99%), whereas the P was not broken, and quickly recovered its initial morphology after the release of load. The P showed excellent tensile properties, with an elongation at break up to 90% and a tensile strength greater than 220 g. The compression strength of the N was 100.44 kPa·m−1, while the resulting strength of P was enhanced to be 248.00 kPa·m−1. Therefore, the various performances of N were improved by adding polymerizable microspheres. In addition, the SEM images indicated that N has a general three-dimensional network structure; the conventional network structure did not exist in the P, which has a novel three-dimensional pore structure in the spherical projection and very dense channels, which led to the compaction of the space between the three-dimensional pore network layers and reduced the flowing of free water wrapped in the network. Therefore, the mechanical strength of hydrogel was enhanced. Full article
(This article belongs to the Section Advanced Composites)
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20 pages, 1903 KB  
Article
Squeezed Interstitial Water and Soil Properties in Pleistocene Blue Clays under Different Natural Environments
by Maria Dolores Fidelibus, Ilenia Argentiero, Filomena Canora, Roberta Pellicani, Giuseppe Spilotro and Gaetano Vacca
Geosciences 2018, 8(3), 89; https://doi.org/10.3390/geosciences8030089 - 8 Mar 2018
Cited by 2 | Viewed by 5627
Abstract
Studies dating almost a century relate clay properties with the structure of the diffuse double layer (DDL), where the charged surfaces of clay crystal behave like an electric capacitor, whose dielectric is the interstitial fluid. The intensity of the inner electric field relates [...] Read more.
Studies dating almost a century relate clay properties with the structure of the diffuse double layer (DDL), where the charged surfaces of clay crystal behave like an electric capacitor, whose dielectric is the interstitial fluid. The intensity of the inner electric field relates to the concentration and type of ions in the DDL. Other important implications of the model are less stressed: this part of the clay soil system, energetically speaking, is conservative. External contribution of energy, work of overburden or sun driven capillarity and long exposure to border low salinity waters can modify the concentration of pore-waters, thus affecting the DDL geometry, with electric field and energy storage variations. The study of clay soils coming from various natural geomorphological and hydrogeological contexts, determining a different salinity of interacting groundwater, shows how the clay interaction with freely circulating waters at the boundaries produces alterations in the native pore water salinity, and, at the nano-scale, variations of electric field and stored energy from external work. The swelling and the shrinkage of clay soil with their volumetric and geotechnical implications should be regarded as variations of the electrostatic and mechanical energy of the system. The study is based on tests on natural clay soil samples coming from a formation of stiff blue clays, widespread in southern Italy. Geotechnical identification and oedometer tests have been performed, and pore waters squeezed out from the specimens have been analyzed. Tested samples have similar grain size, clay fraction and plasticity; sorted according to the classified geomorphological/hydrogeological contexts, they highlight good correlations among dry density, mechanical work performed in selected stages of the oedometric test, swelling and non-swelling behaviour, and electrical conductivity of the squeezed pore waters. The work performed for swelling and non-swelling samples shows well-defined differences; this endorse the relevance of pore-water salinity in determining the volumetric state of clay soils under overburden and specific hydrogeological border conditions, which together define a specific energetic state. Full article
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