Search Results (1,534)

On 22–23 April 2025, a seismic noise survey was conducted at the Maccalube di Aragona, a mud volcano field located in Sicily (southern Italy), with the aim of characterizing the background signal associated with vent activity and the shallow subsurface structure. The experiment, named DEMETRA (DEnse MaccalubE TRomino Acquisition), was carried out within the framework of the multidisciplinary INGV-PROMUD research project, which aims to identify key indicators of mud volcano activity and potential precursors of paroxysmal events. Ambient seismic noise was recorded at 21 sites using a three-component, 24-bit digital tromograph. Measurements were conducted with a dense spatial sampling scheme covering both vent areas and peripheral zones. Preliminary data analyses included spectral estimates, computation of horizontal-to-vertical spectral ratio (HVSR) curves and evaluation of the polarization patterns. The HVSR curves do not display clear amplification peaks but rather show deamplification at specific sites. The polarization patterns exhibit spatial consistency across the vent areas. In addition, transient signals were identified in the background noise at some sites; based on their spectral and polarization characteristics, these signals are possibly associated with degassing, mud emissions, or bubbling phenomena. The dense spatial coverage of the DEMETRA experiment provides a valuable dataset for investigating subsurface properties and dynamic processes in an active mud volcano environment. Full article

This study investigated the electrolytic-plasma hardening (EPH) of cast 20GL steel, used for railway spring beams. The main objective was to analyze the spectral characteristics of the cathodic discharge and establish correlations between the plasma parameters, processing regimes, and resulting surface properties. Optical emission spectroscopy revealed that the plasma at 260 V exhibited a high-energy state with an electron density of ~5.3 × 10¹⁶ cm⁻³ and an electron temperature of 10,031 K. Using these parameters, the heat flux from the plasma to the steel surface was estimated at ~1.5 × 10⁷ W/m², confirming that the discharge provides sufficient energy for surface austenitization. Microstructural analysis demonstrated that the electrolyte flow rate, which determines the cooling rate, is the key parameter controlling phase transformations. At low flow rates, ferrite–pearlite and bainitic structures formed, while a fully martensitic structure and maximum hardness (1046 HV) were achieved at 10 L/min. Tribological tests confirmed the superior wear resistance of the martensitic layers, showing a friction coefficient of 0.454 and a wear volume 3.4 times lower than in the as-cast state. These findings verify that EPH offers an energy-efficient, low-cost method for improving the surface performance and service life of 20GL steel components in heavy-duty railway applications. Full article

In this work, a quantitative analysis of Li in natural brines was carried out by laser-induced breakdown spectroscopy (LIBS) assisted by the τ–algorithm for detailed analysis of the experimental line shapes (τLIBS). Brine samples were collected from different salars located in the Puna plateau (Northwest Argentina) and analyzed by LIBS in the form of solid pressed pellets. The emission intensities of Li I, H_α, and Mg I–II lines were measured and spatially integrated along the line of sight with temporal resolution by using a high-spectral-resolution spectrometer equipped with an intensified charge-coupled device (iCCD) detector. The plasma was characterized through the determination of the electron density and the temperature. The τ–algorithm calculated the optical thicknesses of the Li I lines to generate synthetic intensity profiles that were subsequently fitted to the experimental spectra. By applying the developed τLIBS approach, valuable spectroscopic insight was recovered about the physical processes occurring in the plasma, such as self-absorption. The analytical process involved an univariate external calibration process using the resonant Li I line at 6707.7 Å measured from a series of Li standard samples. Self-absorption effects were evaluated and subsequently compensated. The final LIBS results, with an enhanced accuracy of 15%, were validated by crosschecking them against those obtained with the standard AAS method. Full article

Achieving long-lived room-temperature phosphorescence (RTP) with high quantum efficiency is of significant interest for applications in anti-counterfeiting, flexible optoelectronic displays, and multi-level information encryption. Here, we presented a hydrogen-bond engineering strategy to enhance RTP performance by progressively increasing the number of hydrogen-bonding sites within a polyvinyl alcohol (PVA) matrix. A series of carbazole-based chromophores (Cz, ICz and 2ICz) were embedded into the PVA network, and their photophysical properties were systematically characterized using steady-state photoluminescence spectra, time-decay spectra, Fourier-transform infrared (FTIR), and Raman and X-ray photoelectron spectroscopy (XPS). Spectroscopic analysis revealed that the increased number of N-H groups significantly strengthened hydrogen-bonding interactions, effectively suppressing non-radiative decay pathways and stabilizing triplet excitons. As a result, the phosphorescence lifetime was prolonged up to 1.68 s with a quantum yield of 38.63%. Furthermore, leveraging the spectral overlap integral between the phosphorescent emission and dye absorption, efficient Förster resonance energy transfer (FRET) was realized, enabling tunable multi-color afterglow emissions. This study establishes a design strategy validated by spectroscopy for high-performance RTP materials and highlights their promising potential in advanced optical encryption and flexible photonic applications. Full article

In this study, thermogravimetric analysis (TGA) was coupled with Fourier-transform infrared (FTIR) spectroscopy to systematically investigate the pyrolysis characteristics and mechanisms of cement fiberboard across varying heating rates. Experimental findings demonstrated that the thermal degradation process occurs in four distinct phases. Overlapping decomposition peaks in DTG curves were successfully resolved using a double-Gaussian deconvolution algorithm. A comprehensive kinetic analysis was conducted by integrating model-free iso-conversional methods (Flynn–Wall–Ozawa and Kissinger–Akahira–Sunose analysis) with a model-fitting technique (Coats–Redfern approximation) to determine the activation energies for each degradation stage. A subsequent FTIR spectroscopic analysis revealed that the evolution of gaseous products follows the sequence CO₂ > H₂O > CH₄. The CO₂ release was found to originate from multiple pathways, including the decomposition of organic components and high-temperature inorganic reactions. Notably, while the heating rate had a negligible impact on product speciation, it exhibited a statistically significant influence on CO₂ emission intensities. Finally, mechanistic interpretations integrating Arrhenius parameters with time-resolved infrared spectral features were proposed for each thermal decomposition stage. Full article

Supernovae (SNe) are among the most energetic and transient events in the universe, offering crucial insights into stellar evolution, nucleosynthesis, and cosmic expansion. Optical observations have historically played a central role in the discovery, classification, and physical interpretation of SNe. In this review, we summarize recent progress in the optical study of SNe, with a focus on advancements in time-domain surveys and photometric and spectroscopic follow-up strategies. High-cadence optical monitoring is pivotal in capturing the diverse behaviors of SNe, from early-time emission to late-phase decline. Leveraging data from ARIES telescopes and national/international collaborations, we systematically investigate various SN types, including Type Iax, IIP/L, IIb, IIn/Ibn and Ib/c events. Our analysis includes light curve evolution and spectral diagnostics, providing insights into early emission signatures (e.g., shock breakout), progenitor systems, explosion mechanisms, and circumstellar medium (CSM) interactions. Through detailed case studies, we demonstrate the importance of both early-time and nebular-phase observations in constraining progenitor and CSM properties. This comprehensive approach underscores the importance of coordinated global efforts in time-domain astronomy to deepen our understanding of SN diversity. We conclude by discussing the challenges and opportunities for future optical studies in the era of wide-field observatories such as the Vera C. Rubin Observatory (hereafter Rubin), with an emphasis on detection strategies, automation, and rapid-response capabilities. Full article

Cesium halide perovskite nanocrystals (PNCs) have emerged as promising materials for application in high-color-purity displays due to their exceptional optoelectronic properties, which include narrow emission linewidths, tunable bandgaps, and high photoluminescence quantum yields (PLQYs). However, preserving these characteristics during purification remains a major challenge as surface ligand detachment during the washing process can lead to increased defect states, reduced quantum efficiency, and spectral broadening. The choice of anti-solvent plays a crucial role in maintaining the structural and optical integrity of PNCs, as it directly influences ligand retention and material stability. In this study, we propose an optimized purification strategy for mixed-halide perovskite nanocrystals that incorporates post-synthetic ligand supplementation, in which controlled amounts of oleic acid (OA) and oleylamine (OAm) are sequentially introduced into the crude solution prior to anti-solvent treatment. This approach reinforces surface passivation, suppresses trap state formation, and minimizes halide loss. Consequently, a near-unity PLQY with narrow full-width-at-half-maximum emissions is achieved for both green- and red-emissive nanocrystals, markedly enhancing color purity and providing a promising route toward next-generation wide-color-gamut display technologies. Full article

Theoretical foundations are presented for the application of information–entropy methods from statistical physics to the determination of stellar evolutionary stages. A balance equation involving normalized conditional information and entropy is proposed. The conditional information is defined as the difference between the entropy of the phase space and the conditional probability entropy. A correspondence is demonstrated between theoretical predictions and observational data from stellar emission spectra with respect to their evolutionary classification. The proposed methodology is further applied to the analysis of complex FS CMa-type objects, which exhibit dusty and gaseous structures with components at different evolutionary stages. In this context, the conditional information derived from asymmetric spectral lines is shown to be consistent with the theoretical criteria for the evolutionary status of single, binary, and unclassified stars. Full article

Advancements in flexible, low-cost, and recyclable alternatives to transparent conductive oxides (TCOs) are critical challenges in the sustainability of third-generation solar cells. This work introduces a copper mesh-based transparent electrode for dye-sensitized solar cells, replacing conventional fluorine doped-tin oxide (FTO)-coated glass to simultaneously reduce spectral reflection losses, enhance mechanical flexibility, and enable material recyclability. Titanium dioxide (TiO₂) photoanodes were synthesized and directly deposited onto the mesh via a single-step, low-energy ball milling process, which eliminates TiO₂ paste preparation and high-temperature annealing while reducing fabrication time from over three hours to 30 min. Structural and surface analyses confirmed the deposition of high-purity anatase-phase TiO₂ with strong adhesion to the mesh branches, enabling improved dye loading and electron injection pathways. Optical studies revealed higher visible light absorption for the copper mesh compared to FTO in the visible range, further enhanced upon TiO₂ and Ru-based dye deposition. Electrochemical measurements showed that TiO₂/Cu mesh electrodes exhibited significantly higher photocurrent densities and faster photo response rates than bare Cu mesh, with dye-sensitized Cu mesh achieving the lowest charge transfer resistance in impedance analysis. Techno–economic and sustainability assessments revealed a decrease of 7.8% in cost and 82% in CO₂ emissions associated with the fabrication of electrodes as compared to conventional TCO electrodes. The synergy between high conductivity, transparency, mechanical durability, and a scalable, recyclable fabrication route positions this architecture as a strong candidate for next-generation dye-sensitized solar modules that are both flexible and sustainable. Full article

Temperatures reported for astronomical objects are commonly extreme, and all are ascertained indirectly, using spectroscopy. However, narrow spectral peaks record microscopic behavior (transitions), whereas temperature is a macroscopic (bulk) feature of an object. Using macroscopic theories of heat, light, and their transport, we show that temperature is best defined in terms of the radiant flux of an object (Stefan–Boltzmann law)—including that from large gas bodies—because this flux defines which objects are hotter or colder, and because relevance to mathematical order is the essential attribute of any measurable quantity. Laboratory examples further show that spectroscopic determinations of temperature require the following: (1) use of a large spectral range relevant to that temperature; (2) observation of the unique peak shape characteristic of thermal emissions; (3) accounting for reflections at surfaces; and, most importantly, (4) that conditions are optically thick, a condition fostered by large object size and high temperatures. Temperature of monatomic gas is accurately described by classical kinetic theory because molecular translations are unaffected by electron dynamics. Inelastic molecular collisions provide continuous thermal emissions under optically thick conditions attained in immense astronomical environments. We show how thermal and non-thermal spectroscopic features can be distinguished. Our findings are applied to star-forming regions, intergalactic media, lightning, the Sun’s surface and the corona. Our results resolve long-standing problems regarding heat sources. Full article

The pre-main-sequence evolution of the chemically peculiar (CP) stars on the upper main sequence is still a vast mystery and not well understood. Our analysis of young associations and open clusters aims to find (very) young CP stars to try to put a lower boundary on the age of such objects. Using three catalogues of open clusters and associations, we determined membership probabilities using HDBSCAN. The hot stars from this selection were submitted to synthetic $\Delta a$ photometry, spectral, and light curve classification to determine which ones are CP stars and candidates. Subsequently, we used spectral energy distribution fitting and emission line analysis to check for possible PMS CP stars. The results were compared to the literature. We detected 971 CP stars and candidates in 217 clusters and associations. A relatively large fraction, ∼10% of those, show characteristics of PMS CP stars. This significantly expands the known list of candidate PMS CP stars, bringing us closer to solving the mystery of their origin. Full article

Methane (CH₄) emissions are a major contributor to greenhouse gases and pose significant challenges to global climate mitigation efforts. The accurate determination of CH₄ concentrations via remote sensing is crucial for emission monitoring but remains impeded by surface spectral heterogeneity—notably albedo variations and land cover diversity. This study systematically assessed the sensitivity of three mainstream algorithms, namely, matched filter (MF), albedo-corrected reweighted-L1-matched filter (ACRWL1MF), and differential optical absorption spectroscopy (DOAS), to surface type, albedo, and emission rate through high-fidelity simulation experiments, and proposed a dynamic regularized adaptive matched filter (DRAMF) algorithm. The experiments simulated airborne hyperspectral imagery from the Airborne Visible/InfraRed Imaging Spectrometer-Next Generation (AVIRIS-NG) with known CH₄ concentrations over diverse surfaces (including vegetation, soil, and water) and controlled variations in albedo through the large-eddy simulation (LES) mode of the Weather Research and Forecasting (WRF) model and the MODTRAN radiative transfer model. The results show the following: (1) MF and DOAS have higher true positive rates (TP > 90%) in high-reflectivity scenarios, but the problem of false positives is prominent (TN < 52%); ACRWL1MF significantly improves the true negative rate (TN = 95.9%) through albedo correction but lacks the ability to detect low concentrations of CH₄ (TP = 63.8%). (2) All algorithms perform better at high emission rates (1000 kg/h) than at low emission rates (500 kg/h), but ACRWL1MF performs more robustly in low-albedo scenarios. (3) The proposed DRAMF algorithm improves the F1 score (0.129) by about 180% compared to the MF and DOAS algorithms and improves TP value (81.4%) by about 128% compared to the ACRWL1MF algorithm through dynamic background updates and an iterative reweighting mechanism. In practical applications, the DRAMF algorithm can also effectively monitor plumes. This research indicates that algorithms should be selected considering the specific application scenario and provides a direction for technical improvements (e.g., deep learning model) for monitoring gas emission. Full article

The sixth generation of mobile networks (6G) presents increasing complexity that challenges traditional analysis and performance evaluation methods, necessitating more structured approaches for both research and educational purposes. This study introduces a layered methodology that classifies physical layer impairments, such as amplified spontaneous emission (ASE) noise and fiber nonlinearities into sequential layers. The approach enables independent assessment of individual impairment contributions to overall system performance, facilitating more accurate evaluation of signal quality metrics, including signal-to-noise-ratio (SNR) and optical signal-to-noise-plus-interference ratio (OSNIR) across multiple spectral bands. By implementing this step-by-step analysis framework, researchers can better understand the cumulative impact of various transmission effects, while students can gain progressive insight into complex optical communication principles, making this approach serve dual purposes as both an effective research tool for system optimization and a pedagogical instrument that enhances engineering education. The effectiveness of the methodology is demonstrated through the performance evaluation of a system employing five spectral bands (E, S1, S2, C, and L) under various operating conditions. Full article

Substantial improvements in the performance of optical interconnects based on multi-mode fibers are required to support emerging single-channel data transmission rates of 200 Gb/s and 400 Gb/s. Future optical components must combine very high modulation bandwidths—supporting signaling at 100 Gbaud and 200 Gbaud—with reduced spectral width to mitigate chromatic-dispersion-induced pulse broadening and increased brightness to further restrict flux-confining area in multi-mode fibers and thereby increase the effective modal bandwidth (EMB). A particularly promising route to improved performance within standard oxide-confined VCSEL technology is the introduction of multiple isolated or optically coupled oxide-confined apertures, which we refer to collectively as multi-aperture (MA) VCSEL arrays. We show that properly designed MA VCSELs exhibit narrow emission spectra, narrow far-field profiles and extended intrinsic modulation bandwidths, enabling longer-reach data transmission over both multi-mode (MMF) and single-mode fibers (SMF). One approach uses optically isolated apertures with lateral dimensions of approximately 2–3 µm arranged with a pitch of 10–12 µm or less. Such devices demonstrate relaxation oscillation frequencies of around 30 GHz in continuous-wave operation and intrinsic modulation bandwidths approaching 50 GHz. Compared with a conventional single-aperture VCSELs of equivalent oxide-confined area, MA designs can reduce the spectral width (root mean square values < 0.15 nm), lower series resistance (≈50 Ω) and limit junction overheating through more efficient multi-spot heat dissipation at the same total current. As each aperture lases in a single transverse mode, these devices exhibit narrow far-field patterns. In combination with well-defined spacing between emitting spots, they permit tailored restricted launch conditions in MMFs, enhancing effective modal bandwidth. In another MA approach, the apertures are optically coupled such that self-injection locking (SIL) leads to lasing in a single supermode. One may regard one of the supermodes as acting as a master mode controlling the other one. Streak-camera studies reveal post-pulse oscillations in the SIL regime at frequencies up to 100 GHz. MA VCSELs enable a favorable combination of wavelength chirp and chromatic dispersion, extending transmission distances over MMFs beyond those expected for zero-chirp sources and supporting transfer bandwidths up to 60 GHz over kilometer-length SMF links. Full article

Accurate determination of opacity is critical for understanding radiation transport in both astrophysical and laboratory plasmas. We employ atomic data from R-Matrix calculations to investigate radiative properties in high-energy-density (HED) plasma sources, focusing on opacity variations under extreme plasma conditions. Specifically, we analyze environments such as the base of the convective zone (BCZ) of the Sun ($2\times {10}^6$ K, $N_e={10}^{23}$/cc), and radiative opacity data collected using the inertial confinement fusion (ICF) devices at the Sandia Z facility ($2.11\times {10}^6$ K, $N_e=3.16\times {10}^{22}$/cc) and the Lawrence Livermore National Laboratory National Ignition Facility. We calculate Rosseland Mean Opacities (RMO) within a range of temperatures and densities and analyze how they vary under different plasma conditions. A significant factor influencing opacity in these environments is line and resonance broadening due to plasma effects. Both radiative and collisional broadening modify line shapes, impacting the absorption and emission profiles that determine the RMO. In this study, we specifically focus on electron collisional and Stark ion microfield broadening effects, which play a dominant role in HED plasmas. We assume a Lorentzian profile factor to model combined broadening and investigate its impact on spectral line shapes, resonance behavior, and overall opacity values. Our results are relevant to astrophysical models, particularly in the context of the solar opacity problem, and provide insights into discrepancies between theoretical calculations and experimental measurements. In addition, we investigate the equation-of-state (EOS) and its impact on opacities. In particular, we examine the “chemical picture” Mihalas–Hummer–Däppen EOS with respect to level populations of excited levels included in the extensive R-matrix calculations. This study should contribute to improving opacity models of HED sources such as stellar interiors and laboratory plasma experiments. Full article