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Keywords = smart materials (SM)

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24 pages, 6639 KiB  
Article
Lasso Model-Based Optimization of CNC/CNF/rGO Nanocomposites
by Ghazaleh Ramezani, Ixchel Ocampo Silva, Ion Stiharu, Theo G. M. van de Ven and Vahe Nerguizian
Micromachines 2025, 16(4), 393; https://doi.org/10.3390/mi16040393 - 28 Mar 2025
Cited by 1 | Viewed by 533
Abstract
This study explores the use of citric acid and L-ascorbic acid as reducing agents in CNC/CNF/rGO nanocomposite fabrication, focusing on their effects on electrical conductivity and mechanical properties. Through comprehensive analysis, L-ascorbic acid showed superior reduction efficiency, producing rGO with enhanced electrical conductivity [...] Read more.
This study explores the use of citric acid and L-ascorbic acid as reducing agents in CNC/CNF/rGO nanocomposite fabrication, focusing on their effects on electrical conductivity and mechanical properties. Through comprehensive analysis, L-ascorbic acid showed superior reduction efficiency, producing rGO with enhanced electrical conductivity up to 2.5 S/m, while citric acid offered better CNC and CNF dispersion, leading to higher mechanical stability. The research employs an advanced optimization framework, integrating regression models and a neural network with 30 hidden layers, to provide insights into composition–property relationships and enable precise material tailoring. The neural network model, trained on various input variables, demonstrated excellent predictive performance, with R2 values exceeding 0.998. A LASSO model was also implemented to analyze variable impacts on material properties. The findings, supported by machine learning optimization, have significant implications for flexible electronics, smart packaging, and biomedical applications, paving the way for future research on scalability, long-term stability, and advanced modeling techniques for these sustainable, multifunctional materials. Full article
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10 pages, 4642 KiB  
Article
Preparation and Applications of Multifunctional MXene/Tussah Silk Fabric
by Bingbing Xu, Yue Zhang, Jia Li, Boxiang Wang, Yanhua Lu and Dehong Cheng
Materials 2025, 18(1), 169; https://doi.org/10.3390/ma18010169 - 3 Jan 2025
Cited by 2 | Viewed by 1094
Abstract
The development of functional textiles has become a key focus in recent years, aiming to meet the diverse requirements of modern society. MXene has excellent conductivity, hydrophilicity, and UV resistance, and is widely used in electromagnetic shielding, sensors, energy storage, and photothermal conversion. [...] Read more.
The development of functional textiles has become a key focus in recent years, aiming to meet the diverse requirements of modern society. MXene has excellent conductivity, hydrophilicity, and UV resistance, and is widely used in electromagnetic shielding, sensors, energy storage, and photothermal conversion. Tussah silk (TS) is a unique natural textile raw material and has a unique jewelry luster, natural luxury, and a smooth and comfortable feel. However, there are relatively few studies on the functional finishing of TS fabric with Ti3C2Tx MXene. Here, we developed a multifunctional MXene/tussah silk (MXene/TS) fabric by the deposition of Ti3C2Tx MXene sheets on the surface of TS fabric through a simple padding–drying–curing process. The obtained MXene/TS fabric (five cycles) exhibited excellent conductivity (4.8 S/m), air permeability (313.6 mm/s), ultraviolet resistance (ultraviolet protection factor, UPF = 186.3), photothermal conversion (temperature increase of 11 °C), and strain sensing. Thanks to these superior properties, the MXene/TS fabric has broad application prospects in motion monitoring, smart clothing, flexible wearables, and artificial intelligence. Full article
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27 pages, 4099 KiB  
Review
Toward Customizable Smart Gels: A Comprehensive Review of Innovative Printing Techniques and Applications
by Rizwan Ul Hassan, Naseem Abbas and Jongkuk Ko
Gels 2025, 11(1), 32; https://doi.org/10.3390/gels11010032 - 2 Jan 2025
Cited by 4 | Viewed by 1304
Abstract
New production technologies have transformed modern engineering fields, including electronics, mechanics, robotics, and biomedicine. These advancements have led to the creation of smart materials such as alloys, polymers, and gels that respond to various stimuli. This review focuses on smart materials (SMs), including [...] Read more.
New production technologies have transformed modern engineering fields, including electronics, mechanics, robotics, and biomedicine. These advancements have led to the creation of smart materials such as alloys, polymers, and gels that respond to various stimuli. This review focuses on smart materials (SMs), including their variety and fabrication techniques, that can be used to construct three- or four-dimensional structures. The mechanisms and designs of smart materials, limitations of current printing technologies, and perspectives for their future uses are also discussed in this review. The printed smart materials are expected to have a major impact on the design of real-world applications. Full article
(This article belongs to the Special Issue Customizing Hydrogels: A Journey from Concept to End-Use Properties)
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14 pages, 6320 KiB  
Article
Interactions Between Cationic Micellar Solution and Aromatic Hydrotropes with Subtle Structural Variations
by Bin Liu, Shuo Yin, Xia Wu, Xilian Wei, Huifang Xu, Jing Li and Dongmei Lv
Molecules 2024, 29(22), 5482; https://doi.org/10.3390/molecules29225482 - 20 Nov 2024
Viewed by 916
Abstract
Wormlike micelles (WLMs) with tunable viscoelastic characteristics have emerged as indispensable smart materials with a wide range of applications, which have garnered intense interest over the past few decades. However, quantitatively predicting the effect of various hydrotropes on the rheological behaviors of WLMs [...] Read more.
Wormlike micelles (WLMs) with tunable viscoelastic characteristics have emerged as indispensable smart materials with a wide range of applications, which have garnered intense interest over the past few decades. However, quantitatively predicting the effect of various hydrotropes on the rheological behaviors of WLMs remains a challenge. In this article, micelles were formed in a mixture of 3-hexadecyloxy-2-hydroxypropyltrimethylammonium bromide (R16HTAB) and aromatic hydrotropes (e.g., sodium benzoate, sodium cinnamate and their derivatives, respectively) in an aqueous solution. The phase behavior, viscoelasticity and thickening mechanism were systematically studied by macroscopic observation, rheological measurements, electrostatic potential analysis and cryogenic transmission electron microscopy (Cryo-TEM). Rheological measurements were used to probe the remarkable viscoelastic properties of micelles stemming from their lengthening and entanglement under the interaction between R16HTAB and hydrotropes with structural variations. For an equimolar system of R16HTAB and cosolute (40 mM), the relaxation time decreases in the following order: SpMB > SoHB > S4MS > SmMB > S5MS > SB > SmHB > SoMB > SpHB. These results allow us to predict the possible rules for the self-assembly of R16HTAB and aromatic hydrotropes, which is conductive to directionally designing and synthesizing smart wormlike micelles. Full article
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27 pages, 11381 KiB  
Article
Green Wearable Sensors and Antennas for Bio-Medicine, Green Internet of Things, Energy Harvesting, and Communication Systems
by Albert Sabban
Sensors 2024, 24(17), 5459; https://doi.org/10.3390/s24175459 - 23 Aug 2024
Viewed by 2181
Abstract
This paper presents innovations in green electronic and computing technologies. The importance and the status of the main subjects in green electronic and computing technologies are presented in this paper. In the last semicentennial, the planet suffered from rapid changes in climate. The [...] Read more.
This paper presents innovations in green electronic and computing technologies. The importance and the status of the main subjects in green electronic and computing technologies are presented in this paper. In the last semicentennial, the planet suffered from rapid changes in climate. The planet is suffering from increasingly wild storms, hurricanes, typhoons, hard droughts, increases in seawater height, floods, seawater acidification, decreases in groundwater reserves, and increases in global temperatures. These climate changes may be irreversible if companies, organizations, governments, and individuals do not act daily and rapidly to save the planet. Unfortunately, the continuous growth in the number of computing devices, cellular devices, smartphones, and other smart devices over the last fifty years has resulted in a rapid increase in climate change. It is severely crucial to design energy-efficient “green” technologies and devices. Toxic waste from computing and cellular devices is rapidly filling up landfills and increasing air and water pollution. This electronic waste contains hazardous and toxic materials that pollute the environment and affect our health. Green computing and electronic engineering are employed to address this climate disaster. The development of green materials, green energy, waste, and recycling are the major objectives in innovation and research in green computing and electronics technologies. Energy-harvesting technologies can be used to produce and store green energy. Wearable active sensors and metamaterial antennas with circular split ring resonators (CSSRs) containing energy-harvesting units are presented in this paper. The measured bandwidth of the matched sensor is around 65% for VSWR, which is better than 3:1. The sensor gain is 14.1 dB at 2.62 GHz. A wideband 0.4 GHz to 6.4 GHz slot antenna with an RF energy-harvesting unit is presented in this paper. The Skyworks Schottky diode, SMS-7630, was used as the rectifier diode in the harvesting unit. If we transmit 20 dBm of RF power from a transmitting antenna that is located 0.2 m from the harvesting slot antenna at 2.4 GHz, the output voltage at the output port of the harvesting unit will be around 1 V. The power conversion efficiency of the metamaterial antenna dipole with metallic strips is around 75%. Wearable sensors with energy-harvesting units provide efficient, low-cost healthcare services that contribute to a green environment and minimize energy consumption. The measurement process and setups of wearable sensors are presented in this paper. Full article
(This article belongs to the Section Biomedical Sensors)
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42 pages, 101951 KiB  
Review
Filled Elastomers: Mechanistic and Physics-Driven Modeling and Applications as Smart Materials
by Weikang Xian, You-Shu Zhan, Amitesh Maiti, Andrew P. Saab and Ying Li
Polymers 2024, 16(10), 1387; https://doi.org/10.3390/polym16101387 - 13 May 2024
Cited by 6 | Viewed by 3520
Abstract
Elastomers are made of chain-like molecules to form networks that can sustain large deformation. Rubbers are thermosetting elastomers that are obtained from irreversible curing reactions. Curing reactions create permanent bonds between the molecular chains. On the other hand, thermoplastic elastomers do not need [...] Read more.
Elastomers are made of chain-like molecules to form networks that can sustain large deformation. Rubbers are thermosetting elastomers that are obtained from irreversible curing reactions. Curing reactions create permanent bonds between the molecular chains. On the other hand, thermoplastic elastomers do not need curing reactions. Incorporation of appropriated filler particles, as has been practiced for decades, can significantly enhance mechanical properties of elastomers. However, there are fundamental questions about polymer matrix composites (PMCs) that still elude complete understanding. This is because the macroscopic properties of PMCs depend not only on the overall volume fraction (ϕ) of the filler particles, but also on their spatial distribution (i.e., primary, secondary, and tertiary structure). This work aims at reviewing how the mechanical properties of PMCs are related to the microstructure of filler particles and to the interaction between filler particles and polymer matrices. Overall, soft rubbery matrices dictate the elasticity/hyperelasticity of the PMCs while the reinforcement involves polymer–particle interactions that can significantly influence the mechanical properties of the polymer matrix interface. For ϕ values higher than a threshold, percolation of the filler particles can lead to significant reinforcement. While viscoelastic behavior may be attributed to the soft rubbery component, inelastic behaviors like the Mullins and Payne effects are highly correlated to the microstructures of the polymer matrix and the filler particles, as well as that of the polymer–particle interface. Additionally, the incorporation of specific filler particles within intelligently designed polymer systems has been shown to yield a variety of functional and responsive materials, commonly termed smart materials. We review three types of smart PMCs, i.e., magnetoelastic (M-), shape-memory (SM-), and self-healing (SH-) PMCs, and discuss the constitutive models for these smart materials. Full article
(This article belongs to the Section Polymer Processing and Engineering)
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17 pages, 1970 KiB  
Review
Mapping Smart Materials’ Literature: An Insight between 1990 and 2022
by Raul Mihai Petrașcu, Sever-Gabriel Racz and Dan-Mihai Rusu
Sustainability 2023, 15(20), 15143; https://doi.org/10.3390/su152015143 - 23 Oct 2023
Cited by 3 | Viewed by 2901
Abstract
The field of smart materials (SMs) is an area of great interest in the scientific community and one that is growing considerably from year to year due to the features this field brings to the development of high-performance products and applications. Considering these [...] Read more.
The field of smart materials (SMs) is an area of great interest in the scientific community and one that is growing considerably from year to year due to the features this field brings to the development of high-performance products and applications. Considering these aspects, researchers choose to contribute to this field, and every year, an increasing number of scientific publications appear in the databases. Based on this consideration, the present paper approaches the domain of SMs from a quantitative perspective by carrying out a bibliometric analysis to provide young researchers with a mapping of the most important aspects, as well as the evolution of the field. The bibliometric analysis was carried out in the time frame 1990–2022 in the Web of Science (WoS) database, finding only selected research and review articles based on the most relevant keywords used in the domain. Based on the large number of results identified (8998 publications), the authors designed a classification of the most important aspects of bibliometric analysis. Full article
(This article belongs to the Section Sustainable Materials)
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29 pages, 4603 KiB  
Article
Sustainable Cities, Smart Investments: A Characterization of “A Thousand Days-San Miguel”, a Program for Vulnerable Early Childhood in Argentina
by Maria Sol Gonzalez and Maria Emma Santos
Sustainability 2023, 15(16), 12205; https://doi.org/10.3390/su151612205 - 9 Aug 2023
Cited by 3 | Viewed by 1474
Abstract
In this paper, we provide a thorough description of the “Programa de Acompañamiento Familiar Mil Días” (A Thousand Days, Mil Días), introduced in 2015 in the Municipality of San Miguel, Buenos Aires, Argentina. The program is targeted at pregnant women and mothers with [...] Read more.
In this paper, we provide a thorough description of the “Programa de Acompañamiento Familiar Mil Días” (A Thousand Days, Mil Días), introduced in 2015 in the Municipality of San Miguel, Buenos Aires, Argentina. The program is targeted at pregnant women and mothers with children of up to two years of age who are in a situation of extreme social and health vulnerability. While the target relevant period is the first thousand days of life, from gestation to two years of age, the intended duration is about a year, or until entrance criteria are overcome. We combine statistical analysis of the program’s primary data with qualitative analysis from two in-depth interviews. Our evidence confirms that Mil Días-SM effectively reaches a highly vulnerable population that exhibits interlocking material and educational deprivations, frequently combined with conflict-home environments, and children experiencing health neglect. The one-on-one mentoring provided through the program, along with a battery of other interventions, brings knowledge and support to these families. Children start receiving appropriate stimuli, mothers become aware of the importance of health care for them and their children, and they start feeling more empowered to take command of their lives and families. While the program exhibits remarkable attributes, we identify three aspects in which it could be improved: extending the intended duration time, reducing its dropout rate devising tools to retain the most vulnerable cases, and scaling up its coverage. Current evidence suggests programs like Mil Días are smart investments that can simultaneously contribute to achieving several Sustainable Development Goals. Full article
(This article belongs to the Special Issue Sustainable Cities: Challenges and Potential Solutions)
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16 pages, 4258 KiB  
Article
Thermo-Mechanical Characterization of 4D-Printed Biodegradable Shape-Memory Scaffolds Using Four-Axis 3D-Printing System
by Vukasin Slavkovic, Nikola Palic, Strahinja Milenkovic, Fatima Zivic and Nenad Grujovic
Materials 2023, 16(14), 5186; https://doi.org/10.3390/ma16145186 - 24 Jul 2023
Cited by 11 | Viewed by 2309
Abstract
This study was conducted on different models of biodegradable SMP (shape-memory polymer) scaffolds. A comparison was conducted utilizing a basic FDM (fused deposition modeling)/MEX (material extrusion) printer with a standard printing technique and a novel, modified, four-axis printing method with a PLA (poly [...] Read more.
This study was conducted on different models of biodegradable SMP (shape-memory polymer) scaffolds. A comparison was conducted utilizing a basic FDM (fused deposition modeling)/MEX (material extrusion) printer with a standard printing technique and a novel, modified, four-axis printing method with a PLA (poly lactic acid) polymer as the printing material. This way of making the 4D-printed BVS (biodegradable vascular stent) made it possible to achieve high-quality surfaces due to the difference in printing directions and improved mechanical properties—tensile testing showed a doubling in the elongation at break when using the four-axis-printed specimen compared to the regular printing, of 8.15 mm and 3.92 mm, respectfully. Furthermore, the supports created using this method exhibited a significant level of shape recovery following thermomechanical programming. In order to test the shape-memory effect, after the thermomechanical programming, two approaches were applied: one approach was to heat up the specimen after unloading it inside temperature chamber, and the other was to heat it in a warm bath. Both approaches led to an average recovery of the original height of 99.7%, while the in-chamber recovery time was longer (120 s) than the warm-bath recovery (~3 s) due to the more direct specimen heating in the latter case. This shows that 4D printing using the newly proposed four-axis printing is an effective, promising technique that can be used in the future to make biodegradable structures from SMP. Full article
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28 pages, 6289 KiB  
Article
Research on Talent Cultivating Pattern of Industrial Engineering Considering Smart Manufacturing
by Xugang Zhang, Cui Li and Zhigang Jiang
Sustainability 2023, 15(14), 11213; https://doi.org/10.3390/su151411213 - 18 Jul 2023
Cited by 4 | Viewed by 2937
Abstract
In-depth exploration of the theory and technological applications of smart manufacturing (SM) is lacking in the current talent training model for industrial engineering (IE) majors, and there is a lack of practical education for SM environments. This makes it difficult for students of [...] Read more.
In-depth exploration of the theory and technological applications of smart manufacturing (SM) is lacking in the current talent training model for industrial engineering (IE) majors, and there is a lack of practical education for SM environments. This makes it difficult for students of traditional IE majors to adapt to the modern trend of industrial intelligence and meet the needs of market demand and enterprise development. Therefore, how to cultivate IE talents for SM has become an urgent problem for IE majors to solve. To this end, this paper proposes a new “SM+IE” talent training model, aiming to cultivate more high-quality composite application talents. This model is based on the Lean Manufacturing course and analyzes the effect of the training mode of SM. Secondly, we used the topic of “Sorting Efficiency Improvement” to verify the effectiveness of the new talent training model. The materials were divided into three types: large, medium, and small, and the materials were sorted using traditional IE practices and smart manufacturing-oriented practices. Finally, interviews were conducted with the participants, and both teachers and students indicated that the learning effect of this teaching reform practice was significantly better than that of the traditional IE teaching mode. The results show that the new talent training model improved not only the application and practical skills of the IE students, but also their teamwork and leadership skills. Full article
(This article belongs to the Special Issue Big-Data-Driven Sustainable Manufacturing)
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53 pages, 12839 KiB  
Review
Review of Intelligence for Additive and Subtractive Manufacturing: Current Status and Future Prospects
by M. Azizur Rahman, Tanveer Saleh, Muhammad Pervej Jahan, Conor McGarry, Akshay Chaudhari, Rui Huang, M. Tauhiduzzaman, Afzaal Ahmed, Abdullah Al Mahmud, Md. Shahnewaz Bhuiyan, Md Faysal Khan, Md. Shafiul Alam and Md Shihab Shakur
Micromachines 2023, 14(3), 508; https://doi.org/10.3390/mi14030508 - 22 Feb 2023
Cited by 59 | Viewed by 11781
Abstract
Additive manufacturing (AM), an enabler of Industry 4.0, recently opened limitless possibilities in various sectors covering personal, industrial, medical, aviation and even extra-terrestrial applications. Although significant research thrust is prevalent on this topic, a detailed review covering the impact, status, and prospects of [...] Read more.
Additive manufacturing (AM), an enabler of Industry 4.0, recently opened limitless possibilities in various sectors covering personal, industrial, medical, aviation and even extra-terrestrial applications. Although significant research thrust is prevalent on this topic, a detailed review covering the impact, status, and prospects of artificial intelligence (AI) in the manufacturing sector has been ignored in the literature. Therefore, this review provides comprehensive information on smart mechanisms and systems emphasizing additive, subtractive and/or hybrid manufacturing processes in a collaborative, predictive, decisive, and intelligent environment. Relevant electronic databases were searched, and 248 articles were selected for qualitative synthesis. Our review suggests that significant improvements are required in connectivity, data sensing, and collection to enhance both subtractive and additive technologies, though the pervasive use of AI by machines and software helps to automate processes. An intelligent system is highly recommended in both conventional and non-conventional subtractive manufacturing (SM) methods to monitor and inspect the workpiece conditions for defect detection and to control the machining strategies in response to instantaneous output. Similarly, AM product quality can be improved through the online monitoring of melt pool and defect formation using suitable sensing devices followed by process control using machine learning (ML) algorithms. Challenges in implementing intelligent additive and subtractive manufacturing systems are also discussed in the article. The challenges comprise difficulty in self-optimizing CNC systems considering real-time material property and tool condition, defect detections by in-situ AM process monitoring, issues of overfitting and underfitting data in ML models and expensive and complicated set-ups in hybrid manufacturing processes. Full article
(This article belongs to the Special Issue Intelligent Additive/Subtractive Manufacturing)
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14 pages, 63853 KiB  
Article
Wound-Dressing-Based Antenna Inkjet-Printed Using Nanosilver Ink for Wireless Medical Monitoring
by Chun-Bing Chen, Hsuan-Ling Kao, Li-Chun Chang, Yi-Chen Lin, Yung-Yu Chen, Wen-Hung Chung and Hsien-Chin Chiu
Micromachines 2022, 13(9), 1510; https://doi.org/10.3390/mi13091510 - 12 Sep 2022
Cited by 6 | Viewed by 2356
Abstract
In this paper, we present a wound-dressing-based antenna fabricated via screen-printed and inkjet-printed technologies. To inkjet print a conductive film on wound dressing, it must be screen-printed, UV-curable-pasted, and hard-baked to provide appropriate surface wettability. Two passes were UV-curable-pasted and hard-baked at 100 [...] Read more.
In this paper, we present a wound-dressing-based antenna fabricated via screen-printed and inkjet-printed technologies. To inkjet print a conductive film on wound dressing, it must be screen-printed, UV-curable-pasted, and hard-baked to provide appropriate surface wettability. Two passes were UV-curable-pasted and hard-baked at 100 °C for 2 h on the wound dressing to obtain 65° WCA for silver printing. The silver film was printed onto the wound dressing at room-tempature with 23 μm droplet spacing for three passes, then sintered at 120 °C for 1 h. By optimizing the inkjet printing conditions by modifying the surface morphologies and electrical properties, three-pass printed silver films with 3.15 μm thickness and 1.05 × 107 S/m conductivity were obtained. The insertion losses at the resonant frequency (17 and 8.85 GHz) were −2.9 and −2.1 dB for the 5000 and 10,000 μm microstrip transmission lines, respectively. The material properties of wound dressing with the relative permittivity and loss-tangent of 3.15–3.25 and 0.04–0.05, respectively, were determined by two transmission line methods and used for antenna design. A quasi-Yagi antenna was designed and implemented on the wound-dressing with an antenna bandwidth of 3.2–4.6 GHz, maximal gain of 0.67 dBi, and 42% radiation efficiency. The bending effects parallel and perpendicular to the dipole direction of three fixtures were also examined. The gain decreased from 0.67 to −1.22 dBi and −0.44 dBi for a flat to curvature radius of 5 cm fixture after parallel and perpendicular bending, respectively. Although the maximal gain was reduced with the bending radius, the directivity of the radiation pattern remained unchanged. The feasibility of a wound-dressing antenna demonstrates that inkjet-printed technology enables fast fabrication with low cost and environmental friendliness. Additionally, inkjet-printed technology can be combined with sensing technology to realize remote medical monitoring, such as with smart bandages, for assessment of chronic wound status or basic physical conditions. Full article
(This article belongs to the Special Issue Recent Advances in Inkjet Technology)
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10 pages, 4802 KiB  
Communication
Dual-Band CPW Graphene Antenna for Smart Cities and IoT Applications
by Nathaniel Morales-Centla, Richard Torrealba-Melendez, Edna Iliana Tamariz-Flores, Mario López-López, Cesar Augusto Arriaga-Arriaga, Jesus M. Munoz-Pacheco and Victor R. Gonzalez-Diaz
Sensors 2022, 22(15), 5634; https://doi.org/10.3390/s22155634 - 28 Jul 2022
Cited by 13 | Viewed by 2899
Abstract
In this paper, a dual-band graphene coplanar waveguide antenna is designed for smart cities and internet of things applications. A graphene film is chosen as the conductive material for the radiation patches and ground plane with a thickness of 240 μm and an [...] Read more.
In this paper, a dual-band graphene coplanar waveguide antenna is designed for smart cities and internet of things applications. A graphene film is chosen as the conductive material for the radiation patches and ground plane with a thickness of 240 μm and an electric conductivity of 3.5 × 105 S/m. The dielectric is glass with a dielectric permittivity of 6 and a thickness of 2 mm. The implementation of the antenna on glass permits the integration of the antenna in smart cities and IoT applications. This antenna is based on two trapezoidal patches that generate the dual-band behavior. The overall dimensions of the antenna are 30 mm × 30 mm × 2 mm. The reflection coefficient, gain, and radiation patterns were measured and compared with the simulations. The antenna covers two frequency bands; the lower band covers the 2.45 GHz ISM band, and the upper band range covers from 4 to 7 GHz. Full article
(This article belongs to the Special Issue Advanced Multi-Band Antennas and Millimeter-Wave Components)
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12 pages, 3435 KiB  
Article
Investigations of Thermal Stability and Spectroscopic Features of Sm3+ Doped Strontium Aluminate Glasses
by Pengfei Li, Xiaoyan Zhang, Jinrong Zhang, Xiwei Qi and Xin Liu
Coatings 2022, 12(1), 3; https://doi.org/10.3390/coatings12010003 - 21 Dec 2021
Cited by 8 | Viewed by 3005
Abstract
In the present work, a series of Sm3+ doped transparent strontium aluminate glasses with the composition Al2O3-(3-x)SrO: xSm3+ (x = 0, 0.01, 0.03, 0.06, 0.1, 0.2) were fabricated by a containerless process using an aerodynamic levitation furnace. [...] Read more.
In the present work, a series of Sm3+ doped transparent strontium aluminate glasses with the composition Al2O3-(3-x)SrO: xSm3+ (x = 0, 0.01, 0.03, 0.06, 0.1, 0.2) were fabricated by a containerless process using an aerodynamic levitation furnace. The structural characteristics, density, Vicker’s hardness, and thermal and spectroscopic behaviors of these glasses were investigated. All the glasses exhibit excellent thermal stabilities (Tg ≥ 792 °C) and the glass-forming ability is enhanced with the increasing content of Sm3+. The emission spectra recorded under an excitation of 404 nm show four emission transitions as a result of 4G5/2 translated to the lower states of 6H5/2, 6H7/2, 6H9/2, and 6H11/2, and a bright orange-reddish luminescence can be observed in Al2O3-(3-x)SrO: xSm3+ glasses. The high thermal stability, good glass-forming ability and excellent hardness provide new options for the development of visible orange-reddish lasers and smart photoluminescent glass coating materials. Full article
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16 pages, 4116 KiB  
Article
Design and Self-Assembling Behaviour of Calamitic Reactive Mesogens with Lateral Methyl and Methoxy Substituents and Vinyl Terminal Group
by Alexej Bubnov, Martin Cigl, Deyvid Penkov, Marek Otruba, Damian Pociecha, Hsiu-Hui Chen and Věra Hamplová
Polymers 2021, 13(13), 2156; https://doi.org/10.3390/polym13132156 - 30 Jun 2021
Cited by 5 | Viewed by 2428
Abstract
Smart self-organising systems attract considerable attention in the scientific community. In order to control and stabilise the liquid crystalline behaviour, and hence the self-organisation, the polymerisation process can be effectively used. Mesogenic units incorporated into the backbones as functional side chains of weakly [...] Read more.
Smart self-organising systems attract considerable attention in the scientific community. In order to control and stabilise the liquid crystalline behaviour, and hence the self-organisation, the polymerisation process can be effectively used. Mesogenic units incorporated into the backbones as functional side chains of weakly cross-linked macromolecules can become orientationally ordered. Several new calamitic reactive mesogens possessing the vinyl terminal group with varying flexible chain lengths and with/without lateral substitution by the methyl (methoxy) groups have been designed and studied. Depending on the molecular structure, namely, the type and position of the lateral substituents, the resulting materials form the nematic, the orthogonal SmA and the tilted SmC phases in a reasonably broad temperature range, and the structure of the mesophases was confirmed by X-ray diffraction experiments. The main objective of this work is to contribute to better understanding of the molecular structure–mesomorphic property relationship for new functional reactive mesogens, aiming at further design of smart self-assembling macromolecular materials for novel sensor systems. Full article
(This article belongs to the Special Issue Polymer-Based Sensors)
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