Search Results (126)

The rising demand for sustainable energy solutions has spurred the development of advanced materials for photovoltaic devices. Among these, transparent conductive oxides (TCOs) play a pivotal role in enhancing device efficiency, particularly in silicon-based solar cells. However, the reliance on indium-based TCOs like ITO raises concerns over cost and material scarcity, prompting the search for more abundant and scalable alternatives. This study focuses on the fabrication and characterization of aluminum-doped zinc oxide (ZnO:Al, AZO) thin films deposited via Atomic Layer Deposition (ALD), targeting their application as transparent conductive oxides in silicon solar cells. The ZnO:Al thin films were synthesized by alternating supercycles of ZnO and Al₂O₃ depositions at 225 °C, allowing precise control of composition and thickness. Structural, optical, and electrical properties were assessed using Scanning Electron Microscopy (SEM), Energy-Dispersive X-ray Spectroscopy (EDS), Transmission Electron Microscopy (TEM), Raman spectroscopy, spectroscopic ellipsometry, and four-point probe measurements. The results confirmed the formation of uniform, crack-free ZnO:Al thin films with a spinel-type ZnAl₂O₄ crystalline structure. Optical analyses revealed high transparency (more than 80%) and tunable refractive indices (1.64 ÷ 1.74); the energy band gap was 2.6 ÷ 3.07 eV, while electrical measurements demonstrated low sheet resistance values, reaching 85 Ω/□ for thicker films. This combination of optical and electrical properties underscores the potential of ALD-grown AZO thin films to meet the stringent demands of next-generation photovoltaics. Integration of Zn:Al thin films into silicon solar cells led to an optimized photovoltaic performance, with the best cell achieving a short-circuit current density of 36.0 mA/cm² and a power conversion efficiency of 15.3%. Overall, this work highlights the technological relevance of ZnO:Al thin films as a sustainable and cost-effective alternative to conventional TCOs, offering pathways toward more accessible and efficient solar energy solutions. Full article

Perovskite, as a promising candidate for the next generation of photovoltaic materials, has attracted extensive attention. To date, the power conversion efficiency (PCE) of perovskite solar cells (PSCs) has reached 26.7%, which is competitive with that of commercial silicon cells. However, high PCE is usually achieved in devices with a small surface area fabricated by the spin-coating method. Perovskite thin films, as the most important layer, suffer from poor uniformity and crystallization caused by the large-area fabrication process, which leads to a dramatic drop in efficiency and exhibits poor reproducibility. Here, we summarize common architectures of PSC and perovskite solar modules (PSMs), as well as analyzing the reasons for efficiency loss on the modules. Subsequently, the review describes the mechanism of perovskite growth in detail, and then sums up recent research on small-to-large-area perovskite devices. Large-area fabrication methods mainly include blade coating, slot-die coating, spray-coating, inkjet printing, and screen printing. Moreover, we compare the advantages and disadvantages of each method and their corresponding mechanisms and research progress. The review aims to provide potential logical conclusions and directions for the commercial large-area perovskite fabrication process. Full article

The growing imperative for sustainable building retrofits has spurred significant interest in advanced photovoltaic (PV) solutions. This study evaluates the feasibility and competitiveness of incorporating CIGS thin-film photovoltaic (PV) modules into retrofit projects for aging buildings. By combining qualitative analyses of market and environmental factors with a quantitative multi-criteria index model, this research assesses CIGS performance across five critical dimensions: aesthetic, economic, safety, energy saving, and innovation. The weights assigned to each criterion were determined through expert evaluations derived from structured focus group discussions. The results demonstrate that CIGS exhibits substantial strengths in aesthetic, economic, safety, energy saving, and innovation while maintaining reasonable economic feasibility. The quantitative assessment demonstrated that CIGS thin-film solar cells received the highest overall score (88.92), surpassing silicon-based photovoltaics (86.03), window retrofitting (88.83), and facade cladding (82.21) in all five key metrics of aesthetics, economic feasibility, safety, energy efficiency, and innovation. The findings indicate that CIGS technology exhibits not only exceptional visual adaptability but also attains balanced performance with regard to environmental and structural metrics. This renders it a highly competitive and comprehensive solution for sustainable building retrofits. Full article

Three-dimensional flexible solar fabrics based on hydrogenated amorphous silicon (a-Si:H) thin film solar cells were prepared and characterized. A glass fiber fabric with a polytetrafluoroethylene (PTFE) coating proved to be a suitable textile substrate. Interwoven metal wires enable an integrated electrical interconnection. An array of solar cells consisting of an a-Si:H layer stack with a highly p-type/intrinsic/highly n-type doping profile was deposited onto it. Silver was used as the back contact with indium tin oxide (ITO) as the front contact. The best solar cells show an efficiency of 3.9% with an open-circuit voltage of 876 mV and a short-circuit current density of 11.4 mA/cm². The high series resistance limits the fill factor to 39%. The potential of the textile solar cells is shown by the achieved pseudo fill factor of 79% when neglecting the series resistance, resulting in a pseudo efficiency of 7.6%. With four textile solar cells connected in a series, an open-circuit voltage of about 3 V is achieved. Full article

Flexibility, light weight, and mechanical robustness are the key advantages of flexible photovoltaic (PV) modules, making them highly versatile for sustainable energy solutions. Unlike traditional rigid PV modules, their flexible nature makes them incredibly versatile for harnessing energy in places where doing so was once impossible. They have a wide range of applications due to their flexibility and moldability, making it possible to conform these modules to surfaces like curved rooftops and other irregular structures. In this paper, we provide a comprehensive review of all the materials used in flexible PV modules with a focus on their role in sustainability. We thoroughly discuss the active-layer materials for crystalline silicon (c-Si)-based solar cells (SC) and thin-film solar cells such as cadmium telluride (CdTe), as well as copper indium gallium diselenide (CIGS), amorphous thin-film silicon (a-Si), perovskite and organic solar cells. Various properties, such as the optical, barrier, thermal, and mechanical properties of different substrate materials, are reviewed. Transport layers and conductive electrode materials are discussed with a focus on emerging trends and contributions to sustainable PV technology. Various fabrication techniques involved in making flexible PV modules, along with advantages, disadvantages, and future trends, are highlighted in the paper. The commercialization of flexible PV is also discussed, which is a crucial milestone in advancing and adapting new technologies in the PV industry with a focus on contributing toward sustainability. Full article

The rapid proliferation of photovoltaic (PV) solar cells as a clean energy source has raised significant concerns regarding their end-of-life (EoL) management, particularly in terms of sustainability and waste reduction. This review comprehensively examines challenges, opportunities, and future directions in the recycling of PV solar cells, focusing on mechanical, thermal, and chemical recycling techniques. It also evaluates the scalability and practicality of these methods to different PV technologies, including crystalline silicon and thin-film modules. It explores the economic and environmental impacts of these processes, highlighting the necessity of developing robust recycling infrastructure and innovative technologies to address the anticipated surge in PV waste. Additionally, this review discusses the critical role of government policies and industry collaboration in overcoming the barriers to effective recycling. Furthermore, the importance of integrating design-for-recyclability principles into PV module development is emphasized, as it can significantly enhance material recovery and process efficiency. By advancing these strategies, the solar industry can achieve greater sustainability, reduce resource depletion, and mitigate environmental risks, thereby ensuring the long-term viability of solar energy as a key component of global renewable energy initiatives. Full article

In order to reduce manufacturing costs, the design of silicon-based solar modules is changing from a super-multi-busbar design to a zero-busbar (0BB) design. In this study, two different 0BB technologies based on heterojunction with intrinsic thin-layer solar cells—conventional soldering, and Integrated Film Covering (IFC)—were investigated. IFC-based 0BB technology was found to have a lower contact resistance, which well matches the theoretical calculations and module power testing results. To further measure module reliability, a series of tests on solders and silver pastes were carried out. The results show that Sn43Pb43Bi14 solder is more suitable for soldering-based 0BB technology, whereas Sn32Pb42Bi26 solder is more suitable for IFC-based technology. Additionally, silver paste, which is used for solder ribbon contact areas (SRCAs), is suitable for soldering-based 0BB technology. When Ag@Cu paste is used in SRCAs with IFC-based 0BB technology, a reliable connection can also be achieved. After optimization, modules using both techniques were subjected to and passed lifetime tests, including the thermal cycling, humidity freeze, and hot-spot tests required in IEC standards, as well as more rigorous tests such as thermal–dynamic and thermal–static mechanical loading. The results show that the two technologies have great potential for future mass production. Full article

The development of new encapsulating coatings for flexible solar cells (SCs) can help address the complex problem of the short lifespan of these devices, as well as optimize the technological process of their production. In this study, new laminate-type protective composite coatings were prepared using a silicon oxynitride thin-film matrix obtained by curing the pre-ceramic polymer perhydropolysilazane (PHPS) through two low-temperature methods: (i) thermal annealing at 180 °C and (ii) exposure to UV radiation at wavelengths of 185 and 254 nm. Single-walled carbon nanotubes (SWCNTs) were used as fillers via dry transfer, facilitating their horizontal orientation within the matrix. The optical, adhesive, and structural properties of the matrix films and SiO_xN_y/SWCNT composite coatings, along with their long-term stability, were studied using Fourier transform infrared spectroscopy (FTIR), UV-Vis spectroscopy, HR-SEM, spectral ellipsometry, and a progressive-load scratch test. In this work, the optical constants of PHPS-derived films were systematically studied for the first time. An antireflection effect was observed in the composites revealing their two-component nature associated with (i) the refractive index of the SiO_xN_y matrix film and (ii) the embedding of a SWCNT filler into the SiO_xN_y matrix. The curing method of PHPS was shown to significantly affect the resulting properties of the films. In addition to being used as protective multifunctional coatings for SCs, both SiO_xN_y/SWCNT composites and SiO_xN_y matrix films also function as broadband optical antireflective coatings. Furthermore, due to the very low friction coefficients observed in the mechanical tests, they show potential as scratch resistant coatings for mechanical applications. Full article

Unlike current silicon-based photovoltaic technology, the development of last-generation thin-film solar cells has been marked by groundbreaking advancements in new materials and novel structures to increase performance and lower costs. However, physically building each new proposal to evaluate the device’s efficiency can involve unnecessary effort and time. Numerical simulation tools provide a solution by allowing researchers to predict and optimize solar cell performance without physical testing. This paper reviews thirteen of the main numerical simulation tools for thin-film solar cells, including SCAPS, AMPS, AFORS-HET, ASPIN3, GPVDM, SESAME, SILVACO, SENTAURUS, and ADEPT. This review evaluates each tool’s features, modeling methods, numerical approaches, and application contexts. The findings reveal notable differences in material modeling, numerical accuracy, cost, and accessibility among the tools. Each tool’s strengths and limitations in simulating thin-film solar cells are highlighted. This study emphasizes the necessity of selecting suitable simulation tools based on specific research requirements. It provides a comparative analysis to assist researchers in choosing the most effective software for optimizing thin-film solar cells, contributing to advancements in photovoltaic technology. Full article

The rapid deployment of solar photovoltaic (PV) systems underscores their potential as vital clean energy solutions with reduced carbon emissions and increasingly competitive installation costs. This review examines PV waste management from a sustainable perspective, focusing on environmental impacts and technological advancements. Various solar cell technologies, including crystalline silicon, thin-film, and emerging third-generation cells like perovskite and organic photovoltaics, are analyzed for their life cycle and environmental effects. Effective disposal and recycling methods, such as physical separation and thermal and chemical treatments, are critically evaluated to mitigate ecological harm. The study highlights the need for improved recycling processes and sustainable practices to enhance the environmental benefits of PV systems. Future solutions call for better recycling techniques, increased efficiency in renewable materials, and comprehensive life cycle assessments to support the global transition to sustainable energy. This review aims to foster the integration of sustainable practices in the renewable energy sector, ensuring that PV systems contribute to a cleaner and more sustainable future. Full article

This research, which involved a comprehensive methodology, including depositing electroplated copper on a copper seed layer and Al-doped ZnO (AZO) thin films on textured silicon substrates using DC magnetron sputtering with varying substrate heating, has yielded significant findings. The study thoroughly investigated the effects of substrate temperature (Ts) on copper adhesion strength and morphology using the peel force test and electron microscopy. The peel force test was conducted at angles of 90°, 135°, and 180°. The average adhesion strength was about 0.2 N/mm for the samples without substrate heating. For the samples with substrate heating at 100 °C, the average peeling force of the electroplated copper film was about 1 N/mm. The average peeling force increased to 1.5 N/mm as the substrate heating temperature increased to 200 °C. The surface roughness increases as the annealing temperature of the Cu/AZO/Si sample increases. These findings not only provide a reliable and robust method for applying AZO transparent conductive films onto silicon solar cells but also underscore its potential to significantly enhance the efficiency and durability of solar cells significantly, thereby instilling confidence in the field of solar cell technology. Full article

Over the last two decades, thin film solar cell technology has made notable progress, presenting a competitive alternative to silicon-based solar counterparts. CIGS (CuIn_1−xGa_xSe₂) solar cells, leveraging the tunable optoelectronic properties of the CIGS absorber layer, currently stand out with the highest power conversion efficiency among second-generation solar cells. Various deposition techniques, such as co-evaporation using Cu, In, Ga, and Se elemental sources, the sequential selenization/Sulfurization of sputtered metallic precursors (Cu, In, and Ga), or non-vacuum methods involving the application of specialized inks onto a substrate followed by annealing, can be employed to form CIGS films as light absorbers. While co-evaporation demonstrates exceptional qualities in CIGS thin film production, challenges persist in controlling composition and scaling up the technology. On the other hand, magnetron sputtering techniques show promise in addressing these issues, with ongoing research emphasizing the adoption of simplified and safe manufacturing processes while maintaining high-quality CIGS film production. This review delves into the evolution of CIGS thin films for solar applications, specifically examining their development through physical vapor deposition methods including thermal evaporation and magnetron sputtering. The first section elucidates the structure and characteristics of CIGS-based solar cells, followed by an exploration of the challenges associated with employing solution-based deposition techniques for CIGS fabrication. The second part of this review focuses on the intricacies of controlling the properties of CIGS-absorbing materials deposited via various processes and the subsequent impact on energy conversion performance. This analysis extends to a detailed examination of the deposition processes involved in co-evaporation and magnetron sputtering, encompassing one-stage, two-stage, three-stage, one-step, and two-step methodologies. At the end, this review discusses the prospective next-generation strategies aimed at improving the performance of CIGS-based solar cells. This paper provides an overview of the present research state of CIGS solar cells, with an emphasis on deposition techniques, allowing for a better understanding of the relationship between CIGS thin film properties and solar cell efficiency. Thus, a roadmap for selecting the most appropriate deposition technique is created. By analyzing existing research, this review can assist researchers in this field in identifying gaps, which can then be used as inspiration for future research. Full article

The global interest in environmental issues and sustainable energy has propelled extensive research in photovoltaic (PV) technologies. Brazil has emerged as one of the top ten solar energy producers and flexible PV suppliers in the world. In this context, organic photovoltaic cells (OPVs) have garnered attention due to their flexibility and ability to integrate into various surfaces, albeit facing challenges regarding lifespan and efficiency compared to silicon cells. This review examines the current state of research on OPVs and thin-film solar technologies, employing the systematic literature review methodology Proknow-C. The review includes an analysis of raw materials such as conductive polymers, fabrication processes including film deposition and encapsulation, and technological advancements that enhance the efficiency and stability of OPVs. Utilizing the Proknow-C methodology, a bibliographic portfolio was constructed to identify the current state of research in this field. Of 268 papers from major scientific databases, only 30 were deemed relevant to the theme, highlighting a significant research gap. This paper is a valuable resource for researchers, providing an updated overview and a foundation for future investigations in organic photovoltaics. The results emphasize the importance of materials such as conductive polymers and donor–acceptor molecules and the role of nanotechnology in advancing OPVs. Innovations in manufacturing techniques, such as inkjet and blade coating-based printing techniques, are shown to increase efficiency by providing precise control over film thickness and uniformity and reducing costs through lower material waste. Overall, this review highlights the necessity of further exploration and collaboration within the scientific community to address the challenges and propel advancements in organic photovoltaic cells. These advancements are crucial for transitioning to cleaner energy sources, reinforcing the ongoing significance of thin-film technologies in energy innovation. Full article

Perovskite solar cells (PSCs), which are constructed using organic–inorganic combination resources, represent an upcoming technology that offers a competitor to silicon-based solar cells. Electron transport materials (ETMs), which are essential to PSCs, are attracting a lot of interest. In this section, we begin by discussing the development of the PSC framework, which would form the foundation for the requirements of the ETM. Because of their exceptional electronic characteristics and low manufacturing costs, perovskite solar cells (PSCs) have emerged as a promising proposal for future generations of thin-film solar energy. However, PSCs with a compact layer (CL) exhibit subpar long-term reliability and efficacy. The quality of the substrate beneath a layer of perovskite has a major impact on how quickly it grows. Therefore, there has been interest in substrate modification using electron transfer layers to create very stable and efficient PSCs. This paper examines the systemic alteration of electron transport layers (ETLs) based on electron transfer layers that are employed in PSCs. Also covered are the functions of ETLs in the creation of reliable and efficient PSCs. Achieving larger-sized particles, greater crystallization, and a more homogenous morphology within perovskite films, all of which are correlated with a more stable PSC performance, will be guided by this review when they are developed further. To increase PSCs’ sustainability and enable them to produce clean energy at levels previously unheard of, the difficulties and potential paths for future research with compact ETLs are also discussed. Full article

In the dynamic field of photovoltaic technology, the pursuit of efficiency and sustainability has led to continuous novelty, shaping the landscape of solar energy solutions. One of the key elements affecting the efficiency of photovoltaic cells of II^nd and III^rd generation is the presence of transparent conductive oxide (TCO) layers, which are key elements impacting the efficiency and durability of solar panels, especially for DSSC, CdTe, CIGS (copper indium gallium diselenide) or organic, perovskite and quantum dots. TCO with low electrical resistance, high mobility, and high transmittance in the VIS–NIR region is particularly important in DSSC, CIGS, and CdTe solar cells, working as a window and electron transporting layer. This layer must form an ohmic contact with the adjacent layers, typically the buffer layer (such as CdS or ZnS), to ensure efficient charge collection Furthermore it ensures protection against oxidation and moisture, which is especially important when transporting the active cell structure to further process steps such as lamination, which ensures the final seal. Transparent conductive oxide layers, which typically consist of materials such as indium tin oxide (ITO) or alternatives such as fluorine-doped tin oxide (FTO), serve dual purposes in photovoltaic applications. Primarily located as the topmost layer of solar cells, TCOs play a key role in transmitting sunlight while facilitating the efficient collection and transport of generated electrical charges. This complex balance between transparency and conductivity highlights the strategic importance of TCO layers in maximizing the performance and durability of photovoltaic systems. As the global demand for clean energy increases and the photovoltaic industry rapidly develops, understanding the differential contribution of TCO layers becomes particularly important in the context of using PV modules as building-integrated elements (BIPV). The use of transparent or semi-transparent modules allows the use of building glazing, including windows and skylights. In addition, considering the dominant position of the Asian market in the production of cells and modules based on silicon, the European market is intensifying work aimed at finding a competitive PV technology. In this context, thin-film, organic modules may prove competitive. For this purpose, in this work, we focused on the electrical parameters of two different thicknesses of a transparent FTO layer. First, the influence of the FTO layer thickness on the transmittance over a wide range was verified. Next, the chemical composition was determined, and key electrical parameters, including carrier mobility, resistivity, and the Hall coefficient, were determined. Full article