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Search Results (962)

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Keywords = sealing condition

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11 pages, 1037 KiB  
Article
Bonding to Demineralized Dentin: Impact of Immediate and Delayed Dentin Sealing over Time
by Erika Pérez-Soto, Rim Bourgi, Louis Hardan, Carlos Enrique Cuevas-Suarez, Ana Josefina Monjáras-Ávila, Miguel Ángel Fernández-Barrera, Nicolas Nassar, Monika Lukomska-Szymanska, Rima Daoui, Naji Kharouf and Youssef Haikel
Dent. J. 2025, 13(8), 354; https://doi.org/10.3390/dj13080354 - 5 Aug 2025
Abstract
Background/Objectives: Immediate dentin sealing (IDS) has been widely investigated in sound dentin; however, its efficacy on demineralized dentin remains insufficiently explored. This in vitro experimental study aimed to evaluate the shear bond strength (SBS) of indirect composite resin restorations bonded to demineralized dentin [...] Read more.
Background/Objectives: Immediate dentin sealing (IDS) has been widely investigated in sound dentin; however, its efficacy on demineralized dentin remains insufficiently explored. This in vitro experimental study aimed to evaluate the shear bond strength (SBS) of indirect composite resin restorations bonded to demineralized dentin using IDS, assessed at 24 h and after 6 months of aging. Methods: Twenty-five extracted premolars were randomly divided into five groups: (1) control (no sealing), (2) IDS applied to sound dentin (sound-IDS), (3) IDS applied to demineralized dentin (carious-IDS), (4) delayed dentin sealing (DDS) on sound dentin (sound-DDS), and (5) DDS on demineralized dentin (carious-DDS). SBS values were analyzed using a three-way analysis of variance (ANOVA) with dentin condition (sound vs. demineralized), aging time (24 h vs. 6 months), and sealing strategy (control, IDS, DDS) as independent variables. Statistical analyses were performed using SigmaPlot 12.0, with significance set at p < 0.05. Results: The results showed that IDS led to significantly higher SBS than DDS (p < 0.05). Bond strength was significantly influenced by dentin condition (p < 0.05), and all interactions between variables—particularly between dentin condition and sealing strategy, and between aging time and treatment—were statistically significant (p < 0.001). Overall, bond strength was higher at 24 h than after 6 months. IDS showed optimal performance in sound dentin, while DDS resulted in better long-term outcomes in demineralized dentin. Conclusions: These findings suggest that DDS may be the more effective approach in cases of carious or demineralized dentin. Full article
(This article belongs to the Section Restorative Dentistry and Traumatology)
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37 pages, 7429 KiB  
Article
Study on the Influence of Window Size on the Thermal Comfort of Traditional One-Seal Dwellings (Yikeyin) in Kunming Under Natural Wind
by Yaoning Yang, Junfeng Yin, Jixiang Cai, Xinping Wang and Juncheng Zeng
Buildings 2025, 15(15), 2714; https://doi.org/10.3390/buildings15152714 - 1 Aug 2025
Viewed by 153
Abstract
Under the dual challenges of global energy crisis and climate change, the building sector, as a major carbon emitter consuming 33% of global primary energy, has seen its energy efficiency optimization become a critical pathway towards achieving carbon neutrality goals. The Window-to-Wall Ratio [...] Read more.
Under the dual challenges of global energy crisis and climate change, the building sector, as a major carbon emitter consuming 33% of global primary energy, has seen its energy efficiency optimization become a critical pathway towards achieving carbon neutrality goals. The Window-to-Wall Ratio (WWR), serving as a core parameter in building envelope design, directly influences building energy consumption, with its optimized design playing a decisive role in balancing natural daylighting, ventilation efficiency, and thermal comfort. This study focuses on the traditional One-Seal dwellings (Yikeyin) in Kunming, China, establishing a dynamic wind field-thermal environment coupled analysis framework to investigate the impact mechanism of window dimensions (WWR and aspect ratio) on indoor thermal comfort under natural wind conditions in transitional climate zones. Utilizing the Grasshopper platform integrated with Ladybug, Honeybee, and Butterfly plugins, we developed parametric models incorporating Kunming’s Energy Plus Weather meteorological data. EnergyPlus and OpenFOAM were employed, respectively, for building heat-moisture balance calculations and Computational Fluid Dynamic (CFD) simulations, with particular emphasis on analyzing the effects of varying WWR (0.05–0.20) on temperature-humidity, air velocity, and ventilation efficiency during typical winter and summer weeks. Key findings include, (1) in summer, the baseline scenario with WWR = 0.1 achieves a dynamic thermal-humidity balance (20.89–24.27 °C, 65.35–74.22%) through a “air-permeable but non-ventilative” strategy, though wing rooms show humidity-heat accumulation risks; increasing WWR to 0.15–0.2 enhances ventilation efficiency (2–3 times higher air changes) but causes a 4.5% humidity surge; (2) winter conditions with WWR ≥ 0.15 reduce wing room temperatures to 17.32 °C, approaching cold thresholds, while WWR = 0.05 mitigates heat loss but exacerbates humidity accumulation; (3) a symmetrical layout structurally constrains central ventilation, maintaining main halls air changes below one Air Change per Hour (ACH). The study proposes an optimized WWR range of 0.1–0.15 combined with asymmetric window opening strategies, providing quantitative guidance for validating the scientific value of vernacular architectural wisdom in low-energy design. Full article
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13 pages, 13107 KiB  
Article
Ceramic Isolated High-Torque Permanent Magnet Coupling for Deep-Sea Applications
by Liying Sun, Xiaohui Gao and Yongguang Liu
J. Mar. Sci. Eng. 2025, 13(8), 1474; https://doi.org/10.3390/jmse13081474 - 31 Jul 2025
Viewed by 158
Abstract
Permanent magnetic couplings provide critical advantages for deep-sea systems through static-sealed, contactless power transmission. However, conventional metallic isolation sleeves incur significant eddy current losses, limiting efficiency and high-speed operation. Limited torque capacities fail to meet the operational demands of harsh marine environments. This [...] Read more.
Permanent magnetic couplings provide critical advantages for deep-sea systems through static-sealed, contactless power transmission. However, conventional metallic isolation sleeves incur significant eddy current losses, limiting efficiency and high-speed operation. Limited torque capacities fail to meet the operational demands of harsh marine environments. This study presents a novel permanent magnet coupling featuring a ceramic isolation sleeve engineered for deep-sea cryogenic ammonia submersible pumps. The ceramic sleeve eliminates eddy current losses and provides exceptional corrosion resistance in acidic/alkaline environments. To withstand 3.5 MPa hydrostatic pressure, a 6-mm-thick sleeve necessitates a 10 mm operational air gap, challenging magnetic circuit efficiency. To address this limitation, an improved 3D magnetic equivalent circuit (MEC) model was developed that explicitly accounts for flux leakage and axial end-effects, enabling the accurate characterization of large air gap fields. Leveraging this model, a Taguchi method-based optimization framework was implemented by balancing key parameters to maximize the torque density. This co-design strategy achieved a 21% increase in torque density, enabling higher torque transfer per unit volume. Experimental validation demonstrated a maximum torque of 920 Nm, with stable performance under simulated deep-sea conditions. This design establishes a new paradigm for high-power leak-free transmission in corrosive, high-pressure marine environments, advancing applications from deep-sea propulsion to offshore energy systems. Full article
(This article belongs to the Section Ocean Engineering)
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21 pages, 6310 KiB  
Article
Geological Evaluation of In-Situ Pyrolysis Development of Oil-Rich Coal in Tiaohu Mining Area, Santanghu Basin, Xinjiang, China
by Guangxiu Jing, Xiangquan Gao, Shuo Feng, Xin Li, Wenfeng Wang, Tianyin Zhang and Chenchen Li
Energies 2025, 18(15), 4034; https://doi.org/10.3390/en18154034 - 29 Jul 2025
Viewed by 183
Abstract
The applicability of the in-situ pyrolysis of oil-rich coal is highly dependent on regional geological conditions. In this study, six major geological factors and 19 key parameters influencing the in-situ pyrolysis of oil-rich coal were systematically identified. An analytic hierarchy process incorporating index [...] Read more.
The applicability of the in-situ pyrolysis of oil-rich coal is highly dependent on regional geological conditions. In this study, six major geological factors and 19 key parameters influencing the in-situ pyrolysis of oil-rich coal were systematically identified. An analytic hierarchy process incorporating index classification and quantification was employed in combination with the geological features of the Tiaohu mining area to establish a feasibility evaluation index system suitable for in-situ development in the study region. Among these factors, coal quality parameters (e.g., coal type, moisture content, volatile matter, ash yield), coal seam occurrence characteristics (e.g., seam thickness, burial depth, interburden frequency), and hydrogeological conditions (e.g., relative water inflow) primarily govern pyrolysis process stability. Surrounding rock properties (e.g., roof/floor lithology) and structural features (e.g., fault proximity) directly impact pyrolysis furnace sealing integrity, while environmental geological factors (e.g., hazardous element content in coal) determine environmental risk control effectiveness. Based on actual geological data from the Tiaohu mining area, the comprehensive weight of each index was determined. After calculation, the southwestern, central, and southeastern subregions of the mining area were identified as favorable zones for pyrolysis development. A constraint condition analysis was then conducted, accompanied by a one-vote veto index system, in which the thresholds were defined for coal seam thickness (≥1.5 m), burial depth (≥500 m), thickness variation coefficient (≤15%), fault proximity (≥200 m), tar yield (≥7%), high-pressure permeability (≥10 mD), and high-pressure porosity (≥15%). Following the exclusion of unqualified boreholes, three target zones for pyrolysis furnace deployment were ultimately selected. Full article
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16 pages, 2870 KiB  
Article
Development and Characterization of Modified Biomass Carbon Microsphere Plugging Agent for Drilling Fluid Reservoir Protection
by Miao Dong
Processes 2025, 13(8), 2389; https://doi.org/10.3390/pr13082389 - 28 Jul 2025
Viewed by 280
Abstract
Using common corn stalks as raw materials, a functional dense-structured carbon microsphere with good elastic deformation and certain rigid support was modified from biomass through a step-by-step hydrothermal method. The composition, thermal stability, fluid-loss reduction performance, and reservoir protection performance of the modified [...] Read more.
Using common corn stalks as raw materials, a functional dense-structured carbon microsphere with good elastic deformation and certain rigid support was modified from biomass through a step-by-step hydrothermal method. The composition, thermal stability, fluid-loss reduction performance, and reservoir protection performance of the modified carbon microspheres were studied. Research indicates that after hydrothermal treatment, under the multi-level structural action of a small amount of proteins in corn stalks, the naturally occurring cellulose, polysaccharide organic compounds, and part of the ash in the stalks are adsorbed and encapsulated within the long-chain network structure formed by proteins and cellulose. By attaching silicate nanoparticles with certain rigidity from the ash to the relatively stable chair-type structure in cellulose, functional dense-structured carbon microspheres were ultimately prepared. These carbon microspheres could still effectively reduce fluid loss at 200 °C. The permeability recovery value of the cores treated with modified biomass carbon microspheres during flowback reached as high as 88%, which was much higher than that of the biomass itself. With the dense network-like chain structure supplemented by small-molecule aldehydes and silicate ash, the subsequent invasion of drilling fluid was successfully prevented, and a good sealing effect was maintained even under high-temperature and high-pressure conditions. Moreover, since this functional dense-structured carbon microsphere achieved sealing through a physical mechanism, it did not cause damage to the formation, showing a promising application prospect. Full article
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16 pages, 1859 KiB  
Article
Simulation of Effect on Charge Accumulation Distribution in Laminar Oil Flow with Bubbles in Oil Passage of Converter Transformer
by Wen Si, Haibo Li, Hongshun Liu and Xiaotian Gu
Energies 2025, 18(15), 3992; https://doi.org/10.3390/en18153992 - 26 Jul 2025
Viewed by 230
Abstract
The converter transformer is subjected to AC/DC composite voltage during operation, and the sealed and time-varying internal state makes its electric field distribution and charge accumulation unable to be monitored in real-time experiments. In this paper, aiming at the influence of bubbles in [...] Read more.
The converter transformer is subjected to AC/DC composite voltage during operation, and the sealed and time-varying internal state makes its electric field distribution and charge accumulation unable to be monitored in real-time experiments. In this paper, aiming at the influence of bubbles in the oil passage of the converter transformer on charge accumulation before discharge, a simulation model in a laminar flow environment is established, and four different calculation conditions are set to simulate the charge accumulation in 1 s. It is found that under laminar flow conditions, the trapped bubbles on the insulation paper wall play an obvious role in intensifying the charge accumulation in transformer oil, and the extreme range of charge density will increase by about 104 times. Bubbles aggravate the electric field distortion, and the insulation strength of bubbles is lower, which becomes the weak link of insulation. In the laminar flow environment, the oil flow will take away part of the accumulated charge in the oil, but in the case of trapped bubbles, the charge accumulation in the insulating paper will increase from the order of 10−2 to 10−1. In the case of no bubbles, the transformer oil layer flow will increase the charge accumulation in the insulation paper by 4–5 orders of magnitude. Therefore, it can be seen that the flow of transformer oil will increase the deterioration level of insulation paper. And when the transformer oil is already in the laminar flow state, the influence of laminar flow velocity on charge accumulation is not obvious. The research results in this paper provide a time-varying simulation reference state for the charge accumulation problem that cannot be measured experimentally under normal charged operation conditions, and we obtain quantitative numerical results, which can provide a valuable reference for the study of transformer operation and insulation discharge characteristics. Full article
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22 pages, 6823 KiB  
Article
Design Optimization of Valve Assemblies in Downhole Rod Pumps to Enhance Operational Reliability in Oil Production
by Seitzhan Zaurbekov, Kadyrzhan Zaurbekov, Doszhan Balgayev, Galina Boiko, Ertis Aksholakov, Roman V. Klyuev and Nikita V. Martyushev
Energies 2025, 18(15), 3976; https://doi.org/10.3390/en18153976 - 25 Jul 2025
Viewed by 273
Abstract
This study focuses on the optimization of valve assemblies in downhole rod pumping units (DRPUs), which remain the predominant artificial lift technology in oil production worldwide. The research addresses the critical issue of premature failures in DRPUs caused by leakage in valve pairs, [...] Read more.
This study focuses on the optimization of valve assemblies in downhole rod pumping units (DRPUs), which remain the predominant artificial lift technology in oil production worldwide. The research addresses the critical issue of premature failures in DRPUs caused by leakage in valve pairs, i.e., a problem that accounts for approximately 15% of all failures, as identified in a statistical analysis of the 2022 operational data from the Uzen oilfield in Kazakhstan. The leakage is primarily attributed to the accumulation of mechanical impurities and paraffin deposits between the valve ball and seat, leading to concentrated surface wear and compromised sealing. To mitigate this issue, a novel valve assembly design was developed featuring a flow turbulizer positioned beneath the valve seat. The turbulizer generates controlled vortex motion in the fluid flow, which increases the rotational frequency of the valve ball during operation. This motion promotes more uniform wear across the contact surfaces and reduces the risk of localized degradation. The turbulizers were manufactured using additive FDM technology, and several design variants were tested in a full-scale laboratory setup simulating downhole conditions. Experimental results revealed that the most effective configuration was a spiral plate turbulizer with a 7.5 mm width, installed without axis deviation from the vertical, which achieved the highest ball rotation frequency and enhanced lapping effect between the ball and the seat. Subsequent field trials using valves with duralumin-based turbulizers demonstrated increased operational lifespans compared to standard valves, confirming the viability of the proposed solution. However, cases of abrasive wear were observed under conditions of high mechanical impurity concentration, indicating the need for more durable materials. To address this, the study recommends transitioning to 316 L stainless steel for turbulizer fabrication due to its superior tensile strength, corrosion resistance, and wear resistance. Implementing this design improvement can significantly reduce maintenance intervals, improve pump reliability, and lower operating costs in mature oilfields with high water cut and solid content. The findings of this research contribute to the broader efforts in petroleum engineering to enhance the longevity and performance of artificial lift systems through targeted mechanical design improvements and material innovation. Full article
(This article belongs to the Special Issue Petroleum and Natural Gas Engineering)
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15 pages, 882 KiB  
Article
Effects of Modified Atmosphere Packaging on Postharvest Physiology and Quality of ‘Meizao’ Sweet Cherry (Prunus avium L.)
by Jianchao Cui, Xiaohui Jia, Wenhui Wang, Liying Fan, Wenshi Zhao, Limin He and Haijiao Xu
Agronomy 2025, 15(8), 1774; https://doi.org/10.3390/agronomy15081774 - 24 Jul 2025
Viewed by 402
Abstract
Sweet cherry (Prunus avium L.) is becoming increasingly popular in China, but its postharvest quality deteriorates significantly during harvest storage and transport. Here, we investigated the efficiency of different modified atmosphere packaging (MAP) treatments on the quality and physiology of ‘Meizao’ sweet [...] Read more.
Sweet cherry (Prunus avium L.) is becoming increasingly popular in China, but its postharvest quality deteriorates significantly during harvest storage and transport. Here, we investigated the efficiency of different modified atmosphere packaging (MAP) treatments on the quality and physiology of ‘Meizao’ sweet cherry during 60 days of cold storage (0 ± 0.5 °C). Fruits were sealed in four types of MAP low-density polyethylene (LDPE) liners (PE20, PE30, PE40, and PE50), with unsealed 20 μm LDPE packaging bags used as the control. Our findings demonstrated that PE30 packaging established an optimal gas composition (7.0~7.7% O2 and 3.6~3.9% CO2) that effectively preserved ‘Meizao’ sweet cherry quality. It maintained the fruit color, firmness, soluble solid content (SSC), titratable acidity (TA), and vitamin C (Vc) content while simultaneously delaying deteriorative processes such as weight loss, pedicel browning, and fruit decay. These results indicate that PE30 was the most suitable treatment for preserving the quality of ‘Meizao’ sweet cherries during cold storage. Furthermore, physiological research showed that significant inhibition of respiration rate was achieved by PE30, accompanied by maintained activities of antioxidant enzymes (CAT, POD, and SOD), which consequently led to reduced accumulations of ethanol and malondialdehyde (MDA) during cold storage. To date, no systematic studies have investigated the physiological and biochemical responses of ‘Meizao’ to different thickness-dependent LDPE-MAP conditions. These observations highlight the power of the optimized PE30 packaging as an effective method for extending the fruit storage life, delaying postharvest senescence, and maintaining fruit quality of ‘Meizao’ sweet cherry. Full article
(This article belongs to the Section Horticultural and Floricultural Crops)
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14 pages, 4097 KiB  
Article
Preparation and Performance Evaluation of Graphene Oxide-Based Self-Healing Gel for Lost Circulation Control
by Wenzhe Li, Pingya Luo and Xudong Wang
Polymers 2025, 17(15), 1999; https://doi.org/10.3390/polym17151999 - 22 Jul 2025
Viewed by 320
Abstract
Lost circulation is a major challenge in oil and gas drilling operations, severely restricting drilling efficiency and compromising operational safety. Conventional bridging and plugging materials rely on precise particle-to-fracture size matching, resulting in low success rates. Self-healing gels penetrate loss zones as discrete [...] Read more.
Lost circulation is a major challenge in oil and gas drilling operations, severely restricting drilling efficiency and compromising operational safety. Conventional bridging and plugging materials rely on precise particle-to-fracture size matching, resulting in low success rates. Self-healing gels penetrate loss zones as discrete particles that progressively swell, accumulate, and self-repair in integrated gel masses to effectively seal fracture networks. Self-healing gels effectively overcome the shortcomings of traditional bridging agents including poor adaptability to fractures, uncontrollable gel formation of conventional downhole crosslinking gels, and the low strength of conventional pre-crosslinked gels. This work employs stearyl methacrylate (SMA) as a hydrophobic monomer, acrylamide (AM) and acrylic acid (AA) as hydrophilic monomers, and graphene oxide (GO) as an inorganic dopant to develop a GO-based self-healing organic–inorganic hybrid plugging material (SG gel). The results demonstrate that the incorporation of GO significantly enhances the material’s mechanical and rheological properties, with the SG-1.5 gel exhibiting a rheological strength of 3750 Pa and a tensile fracture stress of 27.1 kPa. GO enhances the crosslinking density of the gel network through physical crosslinking interactions, thereby improving thermal stability and reducing the swelling ratio of the gel. Under conditions of 120 °C and 6 MPa, SG-1.5 gel demonstrated a fluid loss volume of only 34.6 mL in 60–80-mesh sand bed tests. This gel achieves self-healing within fractures through dynamic hydrophobic associations and GO-enabled physical crosslinking interactions, forming a compact plugging layer. It provides an efficient solution for lost circulation control in drilling fluids. Full article
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10 pages, 2486 KiB  
Article
Performance of Miniature Carbon Nanotube Field Emission Pressure Sensor for X-Ray Source Applications
by Huizi Zhou, Wenguang Peng, Weijun Huang, Nini Ye and Changkun Dong
Micromachines 2025, 16(7), 817; https://doi.org/10.3390/mi16070817 - 17 Jul 2025
Viewed by 347
Abstract
There is a lack of an effective approach to measure vacuum conditions inside sealed vacuum electronic devices (VEDs) and other small-space vacuum instruments. In this study, the application performance of an innovative low-pressure gas sensor based on the emission enhancements of multi-walled carbon [...] Read more.
There is a lack of an effective approach to measure vacuum conditions inside sealed vacuum electronic devices (VEDs) and other small-space vacuum instruments. In this study, the application performance of an innovative low-pressure gas sensor based on the emission enhancements of multi-walled carbon nanotube (MWCNT) field emitters was investigated, and the in situ vacuum performance of X-ray tubes was studied for the advantages of miniature dimension and having low power consumption, extremely low outgassing, and low thermal disturbance compared to conventional ionization gauges. The MWCNT emitters with high crystallinity presented good pressure sensing performance for nitrogen, hydrogen, and an air mixture in the range of 10−7 to 10−3 Pa. The miniature MWCNT sensor is able to work and remain stable with high-temperature baking, important for VED applications. The sensor monitored the in situ pressures of the sealed X-ray tubes successfully with high-power operations and a long-term storage of over two years. The investigation showed that the vacuum of the sealed X-ray tube is typical at a low 10−4 Pa level, and pre-sealing degassing treatments are able to make the X-ray tube work under high vacuum levels with less outgassing and keep a stable high vacuum for a long period of time. Full article
(This article belongs to the Section D:Materials and Processing)
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22 pages, 10008 KiB  
Article
Design and Testing of a Device to Investigate Dynamic Performance of Aero-Engine Rotor–Stator Rubbing Dynamics
by Qinqin Mu, Qun Yan, Peng Sun, Yonghui Chen, Jiaqi Chang and Shiyu Huo
Eng 2025, 6(7), 162; https://doi.org/10.3390/eng6070162 - 17 Jul 2025
Viewed by 207
Abstract
To analyze the wear performance induced by rotor–stator rubbing in an aero-engine sealing structure under authentic operating conditions, a transonic rotor system with double bearing is constructed. This system incorporates the disk, shaft, blades, joint bolts, and auxiliary support structure. The system was [...] Read more.
To analyze the wear performance induced by rotor–stator rubbing in an aero-engine sealing structure under authentic operating conditions, a transonic rotor system with double bearing is constructed. This system incorporates the disk, shaft, blades, joint bolts, and auxiliary support structure. The system was evaluated in terms of its critical speed, vibration characteristics, component strength under operational conditions, and response characteristics in abnormal extreme scenarios. A ball screw-type feeding system is employed to achieve precise rotor–stator rubbing during rotation by controlling the coating feed. Additionally, a quartz lamp heating system is used to apply thermal loads to coating specimens, and the appropriate heat insulation and cooling measures are implemented. Furthermore, a high-frequency rubbing force test platform is developed to capture the key characteristics caused by rubbing. The test rig can conduct response tests of the system with rotor–stator rubbing and abrasion tests with tip speeds reaching 425 m/s, feed rates ranging from 2 to 2000 μm/s, and heating temperatures up to 1200 °C. Test debugging has confirmed these specifications and successfully executed rubbing tests, which demonstrate stability throughout the process and provide reliable rubbing force test results. This designed test rig and analysis methodology offers valuable insights for developing high-speed rotating machinery. Full article
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19 pages, 6394 KiB  
Article
Effect of Water Content and Cementation on the Shear Characteristics of Remolded Fault Gouge
by Weimin Wang, Hejuan Liu, Haizeng Pan and Shengnan Ban
Appl. Sci. 2025, 15(14), 7933; https://doi.org/10.3390/app15147933 - 16 Jul 2025
Viewed by 209
Abstract
The strength parameters of fault gouge are critical factors that influence sealing capacity and fault reactivation in underground gas storage reservoirs. This study investigates the shear characteristics of remolded fault gouge under varying hydro-mechanical conditions, focusing on the coupled influence of water content [...] Read more.
The strength parameters of fault gouge are critical factors that influence sealing capacity and fault reactivation in underground gas storage reservoirs. This study investigates the shear characteristics of remolded fault gouge under varying hydro-mechanical conditions, focusing on the coupled influence of water content and cementation. Sixty fault gouge samples are prepared using a mineral mixture of quartz, montmorillonite, and kaolinite, with five levels of water content (10–30%) and three cementation degrees (0%, 1%, 3%). Direct shear tests are conducted under four normal stress levels (100–400 kPa), and microstructural characteristics are examined using SEM. The results show that shear strength and cohesion exhibit a non-monotonic trend with water content, increasing initially and then decreasing, while the internal friction angle decreases continuously. Higher cementation degrees not only enhance shear strength and reduce the softening effect caused by water but also shift the failure mode from ductile sliding to brittle, cliff-type rupture. Moreover, clay content is found to modulate the degree—but not the trend—of strength parameter responses to water and cementation variations. Based on the observed mechanical behavior, a semi-empirical shear strength prediction model is developed by extending the classical Mohr–Coulomb criterion with water–cementation coupling terms. The model accurately predicts cohesion and internal friction angle as functions of water content and cementation degree, achieving strong agreement with experimental results (R2 = 0.8309 for training and R2 = 0.8172 for testing). These findings provide a practical and interpretable framework for predicting the mechanical response of fault gouge under complex geological conditions. Full article
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29 pages, 18412 KiB  
Article
Freeze-Drying as a Stabilization Strategy for Natural Dyes Derived from Lawsonia inermis L. and Indigofera suffruticosa
by Valvanuz Cahuantzi, Rosalba Patiño Herrera, Norma Verónica Zavala Alonso, Daniela Salado Leza, María Selene Berber Mendoza and Elías Pérez
Analytica 2025, 6(3), 22; https://doi.org/10.3390/analytica6030022 - 9 Jul 2025
Viewed by 467
Abstract
This study focuses on the stabilization of a natural hair dye derived from Lawsonia inermis L. (henna) and Indigofera suffruticosa (indigo). Although various formulations already exist, they are designed for immediate use and cannot be stored. Lawsonia, a primary component of the [...] Read more.
This study focuses on the stabilization of a natural hair dye derived from Lawsonia inermis L. (henna) and Indigofera suffruticosa (indigo). Although various formulations already exist, they are designed for immediate use and cannot be stored. Lawsonia, a primary component of the dye, tends to degrade after release. To ensure its stability, freeze-drying was implemented as a protective measure. Colorimetric analysis confirmed the dye’s ability to maintain an intense, uniform coloration even after multiple washing cycles. Stability tests demonstrate that freeze-drying effectively enhances the dye’s stability and capacity to retain its physical properties and color under various environmental conditions, demonstrating its potential for long-term use. The dye’s pH (5.05) aligns with the natural pH of hair, promoting cuticle sealing and improving hair health. Cytotoxicity tests confirmed the dye’s safety, showing no harmful effects. Gray hair exhibited a total color difference (ΔE) of 64.06 after the initial application, using natural gray hair as a reference. By the third application, ΔE increased to 69.86 and gradually decreased to 68.20 after 15 washing cycles, highlighting its long-term durability. Gray hair exposed to 720 h of UV radiation showed a ΔE of 17.34, whereas dyed gray hair exhibited a ΔE of 2.96 compared to non-UV-exposed samples. This indicates superior resistance to color degradation in dyed hair. Also, SEM imaging revealed the dye’s restorative effects, progressively improving hair cuticle structure with each application. Full article
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15 pages, 982 KiB  
Article
Numerical Investigation of CO2 Injection Effects on Shale Caprock Integrity: A Case Study of Opalinus Clay
by Haval Kukha Hawez, Hawkar Bakir, Karwkh Jamal, Matin Kakakhan, Karzan Hussein and Mohammed Omar
Gases 2025, 5(3), 15; https://doi.org/10.3390/gases5030015 - 8 Jul 2025
Viewed by 663
Abstract
Carbon dioxide (CO2) geosequestration is a critical technology for reducing greenhouse gas emissions, with shale caprocks, such as Opalinus Clay (OPA), serving as essential seals to prevent CO2 leakage. This study employs computational fluid dynamics and finite element analysis to [...] Read more.
Carbon dioxide (CO2) geosequestration is a critical technology for reducing greenhouse gas emissions, with shale caprocks, such as Opalinus Clay (OPA), serving as essential seals to prevent CO2 leakage. This study employs computational fluid dynamics and finite element analysis to investigate the hydromechanical behavior of OPA during CO2 injection, integrating qualitative and quantitative insights. Validated numerical models indicate that capillary forces are the most critical factor in determining the material’s reaction, with an entry capillary pressure of 2–6 MPa serving as a significant threshold for CO2 breakthrough. The numbers show that increasing the stress loading from 5 to 30 MPa lowers permeability by 0.3–0.45% for every 5 MPa increase. Porosity, on the other hand, drops by 9.2–9.4% under the same conditions. The OPA is compacted, and axial displacements confirm numerical models with an error margin of less than 10%. Saturation analysis demonstrates that CO2 penetration becomes stronger at higher injection pressures (8–12 MPa), although capillary barriers slow migration until critical pressures are reached. These results demonstrate how OPA’s geomechanical stability and fluid dynamics interact, indicating that it may be utilized as a caprock for CO2 storage. The study provides valuable insights for enhancing injection techniques and assessing the safety of long-term storage. Full article
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18 pages, 2215 KiB  
Article
Research on Sealing Performance of Supercritical Hydrogen Cylindrical Seals Based on Multi-Objective Optimization of Spiral Grooves
by Xueliang Wang, Zegan Gao, Wei Zhang, Junjie Lu, Min Jiang, Leibo Wu and Xuejing Wu
Lubricants 2025, 13(7), 299; https://doi.org/10.3390/lubricants13070299 - 7 Jul 2025
Viewed by 307
Abstract
Aimed at hydrogen turbines, this research employs advanced noncontact cylindrical sealing and optimizes its sealing structure to enhance efficiency. Therefore, this paper considers the variable density and viscosity cylindrical sealing model with actual gas effects and explores the impact of groove parameters on [...] Read more.
Aimed at hydrogen turbines, this research employs advanced noncontact cylindrical sealing and optimizes its sealing structure to enhance efficiency. Therefore, this paper considers the variable density and viscosity cylindrical sealing model with actual gas effects and explores the impact of groove parameters on load capacity, leakage, and friction force under two different temperature and pressure conditions. A multivariate linear regression analysis model is established. Subsequently, the NSGAII algorithm is used to perform multi-objective optimization design under operational conditions. The TOPSIS methods are applied to select the optimal parameters. This study shows that the groove depth of the spiral groove has the most significant impact on sealing performance when the groove depth is 2 μm. Full article
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