Search Results (1,616)

This study investigates the enhancement of hydrogen production efficiency in water electrolysis through the application of external magnetic fields. A series of controlled experiments were conducted using four distinct electrode materials—stainless steel (SS), low-carbon steel (LCS), titanium (Ti), and platinum-plated titanium (Ti/Pt)—to identify the optimal configuration for maximizing gas output. The research evaluated the influence of electrolyte concentration (KOH), current density, and magnetic field intensity ranging from 0 to 1800 G. Our findings indicate that the application of a 200 G magnetic field leads to a notable 6% increase in the rate of gas production compared to non-magnetized conditions. Specifically, a magnetic field oriented parallel to the electrode plates outperformed a perpendicular orientation by approximately 5%, a phenomenon attributed to the Lorentz force facilitating ionic mass transfer and gas bubble detachment. Furthermore, the integration of ion-exchange and proton-exchange membranes (MC-3470 and N-117) effectively isolated the anodic and cathodic products, elevating hydrogen purity from 67.4% to approaching 100% without compromising electrolysis efficiency. These results demonstrate that the strategic coupling of moderate magnetic fields with optimized electrode configurations provides a promising pathway for improving the efficiency and cleanliness of hydrogen production, which is essential for its role as a sustainable energy carrier. Full article

To achieve carbon neutrality, increasing efforts have been devoted to the clean utilization of fossil fuels. This study investigates the effect of reaction temperature on methane catalytic cracking over a biochar-supported iron catalyst. Corn stalks were heated to make biochar which was used as the carrier. To obtain biochar with a high specific surface area and well-developed porous structure, chemical activation was employed. The catalyst was made by adding iron to the biochar using the soaking method. This iron biochar catalyst is used to study its effectiveness in catalyzing methane cracking. The biochar-supported Fe catalyst was studied for its effectiveness in catalyzing methane cracking at different temperatures (800–950 °C). The results indicate that a higher temperature favors methane conversion in terms of reaction efficiency and cumulative conversion levels. At 950 °C, the catalyst exhibits the best performance, with a peak conversion rate of up to 85%, and it can still maintain a stable conversion rate of around 55% after prolonged reaction, yielding the total conversion of 57.6%. Raising the temperature can significantly promote the transformation of solid-phase products from highly blocking amorphous carbon to more ordered graphitized carbon. In addition, the reacted catalyst shows a remarkably reduced specific surface area, the disappearance of micropores, and a considerable increase in average pore size. Carbon nanotubes with various diameters and morphologies were formed on the catalyst surface. Full article

The purpose of this study is to examine how the leadership competence of school leaders supports the implementation of psychosocial safety climate (PSC) within an educational workplace. While recent studies have considered how various leadership styles influence PSC, the processes through which school leaders at different levels enact and develop PSC in practice continue to receive limited attention. This study addresses this gap through a qualitative case study at a school in Aotearoa, New Zealand, which employed a sequential data collection process comprising 26 interviews and three focus groups. This investigation found that exemplary leadership, overcoming complexity, and multiskilled leadership are pivotal competencies that enable PSC implementation within a school setting. More broadly, we discuss how these key leadership competencies facilitate the development of policies, practices, and procedures that promote teachers’ psychological health and the four domains of the PSC framework. Finally, we propose a Leader Competence–PSC Framework as a practical tool for investigating and evaluating school leader competence across specific PSC domains. Full article

In rapidly urbanizing metropolitan areas, children increasingly face risks to their physical and mental health, largely due to constrained access to suitable outdoor spaces that support regular physical activity. The uneven distribution and varying quality of these urban outdoor environments further intensify such risks by limiting children’s opportunities for safe, stimulating, and health-promoting activities. However, the existing research often lacks a systematic framework to quantify these spatial inequities across multiple dimensions. This study aims to fill this gap by constructing a robust analytical framework for evaluating outdoor environmental quality. It quantifies spatial distribution and determinants of these inequalities. The framework is structured around four core dimensions: Safety, Facility Variety, Fun, and Greenness. Taking Beijing as a case study, data from 1598 primary and secondary schools were analyzed. The Gini coefficient and Moran’s I were used to evaluate the equality and spatial clustering of environmental indicators, while the Geographically Weighted Regression model explored how Spatial Construction, Social Development, and Economic Level shape environmental quality. The results reveal the following findings: (1) the quality of children’s outdoor physical activity environments in Beijing is notably unequal, especially regarding Greenness and Fun; (2) these disparities correspond closely to the city’s “core–periphery” metropolitan structure; and (3) the relationships between metropolitan-level factors and environmental quality exhibit strong spatial heterogeneity. This study provides a comprehensive framework for evaluating and visualizing inequalities in children’s outdoor environments, offering empirical support for inclusive and health-oriented urban governance. Full article

Environmental fires pose a serious threat to energy security, ecosystems and public safety, whilst traditional halogenated flame retardants suffer from limitations such as high environmental residue risks and insufficient flame-retardant efficacy. In this study, sodium alginate (SA) was utilised as the matrix, with the incorporation of ammonium polyphosphate (APP) and phytic acid (PA), in conjunction with SiO₂-APTES surface modification, to prepare nitrogen–phosphorus synergistic bio-based flame-retardant gels. The present study systematically investigated the influence of the N/P molar ratio on the gelation kinetics, rheological behaviour, microstructure and flame-retardant performance of the gel. The study revealed a nitrogen–phosphorus coupled gas–solid two-phase synergistic flame-retardant mechanism. The results indicate that at an N/P ratio of 1/4, the gel forms a stable dual-network structure comprising ionic cross-links and Si–O–P covalent bonds. In the gas phase, the thermal decomposition of APP releases inert NH₃, which dilutes oxygen and quenches gas-phase radicals (·OH, ·H). In the condensed phase, the phosphate groups of PA-catalysed SA form Si–O–P covalent bonds with SiO₂ under the mediation of APTES, creating a dense, insulating char layer. In comparison with the control group (N/P = 0/0), the optimal gel sample (N/P = 1/4) demonstrated a 33% increase in shear stress, a 10% reduction in the peak heat release rate (HRR), a 75% decrease in total smoke production (TSP), and a 150% increase in char layer thickness after combustion, while maintaining adequate mechanical strength, thermal stability, and environmental friendliness. This work provides novel insights and strategies for the development of green, highly efficient flame-retardant materials for environmental fire prevention and control. Full article

This study evaluates the seismic performance and life-cycle economic implications of designing essential urban mid-rise reinforced concrete moment-resistant frame (MRF) buildings to maintain linear elastic behavior up to the Immediate Occupancy (IO) performance level. While most urban buildings are commonly designed to respond non-linearly in order to reduce initial construction costs, the current Mexico City Building Code (MCBC) permits that essential facilities, such as hospitals and schools, maintain linear behavior during moderate-to-strong earthquakes. This code establishes a maximum story drift ratio equal to 0.0075 for essential buildings constituted by MRF subjected to seismic events with a 250-year recurrence interval; in addition, it recommends ductile structural behavior to achieve Life Safety performance at a 450-year recurrence interval. Given the significant differences in occupancy, functionality, and contents of critical facilities, here it is analyzed whether the linear elastic design criterion is efficient for both secondary care hospitals and public schools. Two three-story and five-story MRF buildings, located on firm and transition soil, respectively, are analyzed. This study addresses the probability of brittle-type failure risk, the optimal allowable story drift at the IO performance level, the potential need for use-dependent drift limits, and the contribution of contents and nonstructural components to the total expected seismic losses. The seismic risk and economic performance are quantified through seismic hazard analysis, incremental dynamic analysis, fragility modeling, Monte Carlo simulation, and life-cycle cost evaluation. Full article

To address the challenges of complex, heterogeneous, and blurred sensitivity boundaries in the sensitive data sources of civil aviation passengers, this paper proposes a hierarchical measurement method. This model integrates information entropy and random forest, achieving measurable sensitivity. Firstly, the correlation between data sensitivity level and business characteristics is established. Then, a Random Forest-based Hierarchical Measurement with Sensitivity Information Content Analysis (RF-HM-SICA) model integrating information entropy and random forest is proposed to construct a sensitivity measurable hierarchical measurement method for passenger sensitive data. The experimental results show that the RF-HM-SICA model exhibits high stability, generalization capability, and boundary sample protection ability under different data sizes and sensitivity levels, making it suitable for solving the multidimensional heterogeneity measurement problem of sensitive data of civil aviation passengers and providing support for data security sharing protection. In particular, the recognition accuracy and precision for high-sensitivity data approach 1.0 across datasets of different scales, while RF-HM-SICA exhibits the lowest misclassification rate among all compared models. Full article

With natural gas demand growing rapidly in this century, solidified natural gas technology holds great potential for strengthening energy resilience and delivering secure global gas supply. However, this technology is still impeded by insufficient gas uptake capacity and sluggish hydrate formation rate. Environmentally benign peptides have recently emerged as a novel class of green hydrate promoters. Different from single amino acids, peptides exhibit significant structural diversity owing to their varying sequences and combinations of their constituent amino acid monomers, showing great potential in hydrate-based applications. In this work, a unique tripeptide promoter, L-glutathione reduced (GSH), was employed, and the thermodynamic influence factors in methane hydrate formation were systematically investigated. Furthermore, as a highly hydrophilic amino acid, L-arginine was chosen for a comparative kinetic investigation with extremely hydrophilic GSH. The results revealed that experimental pressure showed a strong effect on the methane uptake rate, while it presented little influence on final methane storage capacity. The initial temperature greatly affected the average induction time, the rate of hydrate growth, and the yields of hydrates promoted by GSH. Increasing temperature resulted in a significant reduction in both the hydrate formation rate and methane uptake at 3 h. Therefore, in the GSH-promoted hydrate formation process, suitable pressure and temperature should be carefully chosen for desirable hydrate performance. Furthermore, the initial 15 min hydrate formation rate of 0.3 wt% L-arginine is 52.4% lower than that of 0.3 wt% GSH. The final methane uptake of 0.3 wt% arginine is substantially smaller than that of 0.3 wt% GSH. Although both GSH and arginine exhibit strong hydrophilic properties, the tripeptide GSH is more effective than the amino acid arginine in enhancing methane hydrate formation. The insights gained from this work offer a theoretical foundation for the application of peptide-based promoters in solidified natural gas technology. Full article

In response to corrosion challenges encountered during the gathering and transportation of wet natural gas, this study systematically investigates the corrosion behavior of L245NCS steel in environments containing O₂, H₂S, CO₂ and simulated oilfield-produced water. The research employs a combined approach involving high-pressure autoclave experiments and transparent flow loop simulations. Autoclave tests reproduce gas phase, liquid phase, and gas–liquid interface conditions under a controlled O₂-H₂S-CO₂ mixture, while a visual flow loop equipped with elbows and undulating sections is used to examine liquid accumulation behavior and flow characteristics under dynamic, real-world operating conditions. Results indicate that corrosion is most severe at the gas–liquid interface. H₂S is identified as the primary corrosive agent, exerting a stronger influence than CO₂ or O₂. Liquid accumulation is the main factor leading to non-uniform corrosion distribution, and its formation is influenced by water content, pressure, temperature difference, and pipeline shutdown and restart operations. Critical areas such as low-lying sections, downhill bottoms, and the beginning of uphill sections exhibit localized corrosion rates up to 61.4% higher than areas without liquid accumulation. This integrated methodology bridges mechanistic understanding with engineering practice, providing a basis for corrosion risk assessment, optimal monitoring point placement, and integrity management of wet gas pipelines. Full article

This study presents the development and numerical investigation of a full-section fog curtain dust suppression system installed in the return airway of a fully mechanized longwall mining face, designed to mitigate airborne dust emissions escaping from the return airway during coal extraction. To optimize nozzle selection, comparative experiments were conducted under varying water pressure conditions. A porous medium model was employed to represent the dust capture mesh, enabling a systematic analysis of the pressure drop and airflow resistance characteristics across a range of wind velocities; the model parameters—viscous resistance coefficient (D) and inertial resistance coefficient (C₂)—were calibrated accordingly. Subsequently, coupled computational fluid dynamics simulations of fog dispersion and airflow fields were performed using a validated full-scale geometric model of the fully mechanized mining face. The influence of mesh pore size—via its effect on droplet size distribution uniformity—on the spatial distribution and velocity profile of the airflow field was quantitatively evaluated. The results show that the optimal spray nozzle was the fan-shaped atomizing spray nozzle, with a selected water pressure of 0.6 MPa. The droplet concentration in the porous media section increased from 0.026 kg∙m⁻³ to 0.052 kg∙m⁻³, and the volume share increased from 51.5% to 74.5%. The concentration of the filtered droplet increased from 0.00067 kg∙m⁻³ to 0.0013 kg∙m⁻³, and the size of particles adsorbed by the porous media increased from 140 μm in the proportion of most particles to 0.0013 kg∙m⁻³. The proportion of most particles above 140 μm was reduced to a range of 0–80 μm, and the optimal pore size was selected to be 100 mesh. Dust measurements were conducted at different measuring points in the return airway of the 25212 comprehensive mining face in the Hongliulin North plate area. The overall dust removal rates at points A, B, and C reached 88.90%, 83.71%, and 84.85%, and the respiratory dust removal rates reached 81.24%, 79.39%, and 80.33%, respectively, indicating that dust removal is effective. Full article

Under long-term heavy load and complex service environments, polyurethane-modified asphalt (PUMA) struggles to simultaneously satisfy the requirements of rutting and cracking resistance of asphalt pavements, as cyclic stress loading reduces the elastic recovery and low-temperature toughness of polyurethane (PU). To address this issue, this study employed hydroxylated crumb rubber (HCR), which is obtained by activating the surface of crumb rubber (CR) and can chemically crosslink with PU in asphalt to form a crosslinked network structure. The aim was to enhance the rutting and cracking resistance of PUMA by utilizing the elasticity and low-temperature toughness of CR. An orthogonal design was employed to systematically design a modified asphalt formulation with PU and HCR (PU/HCRMA) by controlling the isocyanate index and the contents of PU and HCR. The basic properties, rheological properties, and viscoelastic properties of PU/HCRMA were systematically investigated. The results demonstrate that the rutting and cracking resistance of PU/HCRMA are substantially enhanced, with an improvement of 28.91% in the rutting factor at 64 °C compared to PUMA and a reduction of 49.93 MPa in the stiffness modulus at −24 °C. Simultaneously, incorporating HCR in PUMA enhances its viscosity and flow resistance while reducing temperature susceptibility. Furthermore, by providing load-bearing sites, HCR endows PU/HCRMA with exceptional elastic recovery and deformation resistance. Results from FTIR and FM confirm the reaction between isocyanate groups in the PU prepolymer and the hydroxyl groups on the surface of HCR and the formation of HCR-PU crosslinked networks. Finally, PU/HCRMA asphalt mixtures demonstrate significant improvements in both rutting and cracking resistance. This research outcome provides a new direction for the development of high-performance road asphalt materials. Full article

Inclusive education (IE) aims to promote meaningful participation and a sense of belonging for all learners. However, limited research has examined how students with learning difficulties (LDs) experience inclusion in everyday school life. This study explored how primary school students with mild LDs perceive their participation, relationships with teachers and peers, and the role of inclusive classes (ICs) within mainstream Greek primary education. A qualitative design was adopted, and data were collected through semi-structured interviews with ten Grade 6 students receiving support through ICs. Transcripts were analyzed using thematic analysis. Findings indicated that participation was associated with perceived competence in academic tasks, with language-based activities frequently described as cognitively demanding and stressful. Belonging was predominantly felt through peer acceptance and supportive teacher practices rather than solely through classroom placement. The ICs were perceived as providing individualized support and emotional safety, although some ambivalence regarding withdrawal from the mainstream classroom was reported. Students stressed the need for flexible assessment and clearer instructional guidance to enhance fairness and participation. Overall, the findings show that inclusion is experienced as a dynamic interaction between academic accessibility, interpersonal relationships, and supportive learning environments. They also underline the importance of incorporating student voice into inclusive practice. Full article

The evaluation of sweet spots for infill wells is critical to identifying premium reservoir zones, avoiding fracture hits, and achieving safe, efficient development with maximum production potential. Firstly, considering that geological and engineering factors—such as high fracability and good reservoir quality—are conducive to the formation of complex fracture networks and sufficient gas production after fracturing, quantitative evaluation indicators for fracability and geological properties have been established. Secondly, a classification method for different sweet spot tiers in infill wells was proposed. Lastly, taking the Changning infill pilot wells as an example, for sections not affected by fracture interference, higher sweet spot evaluation scores show a strong correlation with improved predictive performance of tracer-based gas production forecasts. Conversely, in fracture-interfered zones, a discrepancy was observed between the sweet spot evaluation results and actual gas production volumes. The horizontal wellbores were classified into a six-tier system (L1–L6), with tailored fracturing design recommendations provided accordingly. This study offers scientific guidance for the precise evaluation of sweet spots in infill wells and the design of customized staged fracturing, thereby significantly enhancing fracturing effectiveness. Full article

Broken gangue in goafs exhibits complex mechanical deformation and seepage evolution under coupled loading and hydraulic action, which directly affects the hydraulic stability and water-hazard prevention of mining engineering. In this study, a systematic investigation was carried out to elucidate the evolution of seepage characteristics in a granular broken-rock assemblage under coupled hydraulic–mechanical loading. Four mono-sized specimen groups with particle-size ranges of 5–10 mm, 10–15 mm, 15–20 mm, and 20–25 mm were prepared. Using a modified rock triaxial–hydraulic testing system, nominal uniaxial compression tests, triaxial compression tests under different moisture conditions, and staged axial loading–seepage coupling tests were conducted. The results indicated pronounced particle-size effects: with increasing particle size, the nominal uniaxial compressive strength decreased (maximum reduction of 41.26%), while the crushing ratio increased (from 0.99% to 28.89%). The compression–densification process exhibited a staged evolution characterized by “slow increase–rapid increase–stable increase.” Water-induced deterioration intensified with increasing water content, and the compressive strength reduction reached 29.8% under saturated conditions. The evolution of seepage behavior was jointly governed by loading rate and particle size. Both pore pressure and pore-pressure gradient increased with loading rate. The permeability–porosity relationship was nonmonotonic, with an inflection occurring at a porosity of approximately 0.30–0.32, accompanied by an order-of-magnitude variation in the Darcy-flow deviation factor, indicating a progressive nonlinear deviation from Darcy behavior. These observations reflected a competitive mechanism involving “compaction-induced flow resistance increase–fragmentation and rearrangement–local channel regeneration.” Numerical simulations performed in COMSOL6.2 further confirmed, at the microscopic level, that the development of preferential local seepage channels and the expansion of stagnant-water zones were the fundamental causes of locally enhanced seepage capacity under an overall compaction background. The findings provide a theoretical basis for understanding water–rock interaction mechanisms in goafs and offer reference for mine water-hazard mitigation and groundwater resource protection. Full article

To address severe mine pressure disasters induced by the coupling of mining-induced dynamic stress and impact disturbance during close-distance coal seam mining, this paper takes the No. 8 and No. 9 close-distance coal seams in the 119 mining area of a coal mine in Ningxia, China, as the engineering background. Theoretical analysis and FLAC^3D numerical simulation methods were adopted to systematically study the evolution of overburden structure, the manifestation law of mine pressure caused by mining disturbance, and the dynamic response mechanism of roadway surrounding rock under impact load. The findings demonstrate: ① Based on key block theory and elasticity mechanics theory, the stress transfer mechanism of the complete bearing type overburden rock in close-range coal seams was clarified. The calculation model of floor plastic zone depth and additional stress was derived, and the influence mechanism of the bearing state of interlayer rock strata on the stability of underlying coal seam roadways was revealed. ② Comparative numerical simulations of mining schemes revealed that both schemes formed a “goaf pressure relief-workface-coal pillar” load-bearing configuration with “upward subsidence and downward bulging” basin-shaped settlement. Scheme A exhibited significantly increased stress peaks and interlayer plastic zones due to repeated mining-induced stress, substantially elevating the risk of strong mine pressure manifestation and surrounding rock instability. ③ Under 8 MPa cosine impact load with a vibration frequency of 50 Hz (peak particle vibration velocity of 9.57 m/s), compared with the unsupported roadway, the bolt–cable collaborative support system reduced the peak displacement of surrounding rock by over 35% and decreased the shock wave propagation velocity by more than 40%, effectively suppressing the expansion of plastic zones and the transfer of impact energy, while significantly enhancing the impact resistance of the roadway. This study not only provides a systematic theoretical basis for close-distance coal seam mining and rock burst prevention but also offers scientific guidance and technical reference for surrounding rock control and dynamic disaster prevention of roadways in similar close-distance coal seam mining projects, which is of important engineering value for ensuring the safe and efficient mining of underground coal resources. Full article