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Keywords = rubber ring

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16 pages, 8118 KiB  
Article
The Influence of Long-Term Service on the Mechanical Properties and Energy Dissipation Capacity of Flexible Anti-Collision Rings
by Junhong Zhou, Jia Lu, Wei Jiang, Ang Li, Hancong Shao, Zixiao Huang, Fei Wang and Qiuwei Yang
Coatings 2025, 15(8), 880; https://doi.org/10.3390/coatings15080880 - 27 Jul 2025
Viewed by 276
Abstract
This study investigates the long-term performance of flexible anti-collision rings after 12 years of service on the Xiangshan Port Highway Bridge. Stepwise loading–unloading tests at multiple loading rates (0.8–80 mm/s) were performed on the anti-collision rings, with full-field strain measurement via digital image [...] Read more.
This study investigates the long-term performance of flexible anti-collision rings after 12 years of service on the Xiangshan Port Highway Bridge. Stepwise loading–unloading tests at multiple loading rates (0.8–80 mm/s) were performed on the anti-collision rings, with full-field strain measurement via digital image correlation (DIC) technology. The results show that: The mechanical response of the anti-collision ring shows significant asymmetric tension–compression, with the tensile peak force being 6.8 times that of compression. A modified Johnson–Cook model was developed to accurately characterize the tension–compression force–displacement behavior across varying strain rates (0.001–0.1 s−1). The DIC full-field strain analysis reveals that the clamping fixture significantly influences the tensile deformation mode of the anti-collision ring by constraining its inner wall movement, thereby altering strain distribution patterns. Despite exhibiting a corrosion gradient from severe underwater degradation to minimal surface weathering, all tested rings demonstrated consistent mechanical performance, verifying the robust protective capability of the rubber coating in marine service conditions. Full article
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16 pages, 2699 KiB  
Article
Investigation of the Mechanical and Thermal Properties of MWCNT/SiC-Filled Ethylene–Butene–Terpolymer Rubber
by Li Zhang, Jianming Liu, Duanjiao Li, Wenxing Sun, Zhi Li, Yongchao Liang, Qiang Fu, Nian Tang, Bo Zhang, Fei Huang, Xuelian Fan, Pengxiang Bai, Yuqi Wang, Zuohui Liu, Simin Zhu and Dan Qiao
Crystals 2025, 15(6), 539; https://doi.org/10.3390/cryst15060539 - 5 Jun 2025
Cited by 1 | Viewed by 808
Abstract
Rubber is widely used in daily lives, such as in automobile tires, conveyor belts, sealing rings, and gaskets. The performance of rubber determines its service life. Therefore, it is of crucial importance to improve the performance of rubber. Theoretical studies have found that [...] Read more.
Rubber is widely used in daily lives, such as in automobile tires, conveyor belts, sealing rings, and gaskets. The performance of rubber determines its service life. Therefore, it is of crucial importance to improve the performance of rubber. Theoretical studies have found that the inherent properties of nanofillers themselves, the interfacial bonding force between fillers and the matrix, and the uniform dispersibility of nanofillers in the polymer matrix are the most significant factors for enhancing the performance of rubber nanocomposites. This study systematically investigated the synergistic enhancement effect of silicon carbide (SiC) and multi-walled carbon nanotubes (MWCNTs) on the mechanical and thermal properties of ethylene–butene–terpolymer (EBT) composites. By optimizing the addition amount of fillers and improving the interfacial bonding between fillers and the matrix, the influence of filler content on the properties of composites was studied. The results demonstrate that the addition of SiC and MWCNTs significantly improved the storage modulus, tensile strength, hardness, and thermal stability of the composites. In terms of mechanical properties, the tensile strength of the composites increased from 6.68 MPa of pure EBT to 8.46 MPa, and the 100% modulus increased from 2.14 MPa to 3.81 MPa. Moreover, hardness was significantly enhanced under the reinforcement of SiC/CNT fillers. In terms of thermal stability, the composites exhibited excellent resistance to deformation at high temperatures. Through the analysis of the mechanical and thermal properties of the composites, the synergistic enhancement mechanism between SiC and MWCNTs was revealed. The research results provide a theoretical basis for the design and engineering applications of high-performance ethylene–butylene rubber composites. Full article
(This article belongs to the Section Macromolecular Crystals)
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19 pages, 18308 KiB  
Article
Computational Investigation of Aerodynamic Behaviour in Rubber O-Ring: Effects of Flow Velocity and Surface Topology
by Thomas Singleton, Adil Saeed and Zulfiqar Ahmad Khan
Appl. Sci. 2025, 15(9), 5006; https://doi.org/10.3390/app15095006 - 30 Apr 2025
Viewed by 303
Abstract
This report uses computational fluid dynamics (CFDs) to investigate the aerodynamics of a rubber O-ring, with a focus on assessing the influence of fluid velocity and surface topology whilst providing a detailed methodology that promotes correct procedures. A steady state scenario was set [...] Read more.
This report uses computational fluid dynamics (CFDs) to investigate the aerodynamics of a rubber O-ring, with a focus on assessing the influence of fluid velocity and surface topology whilst providing a detailed methodology that promotes correct procedures. A steady state scenario was set up, modelling laminar airflow across two O-rings with 5 μm and 100 μm surface finishes, respectively. Analysis showed that increasing the fluid velocity from 0.01 m/s to 2 m/s significantly translates the separation points downstream, consolidating wake regions behind the airfoil. The CFD simulations also infer that as the fluid velocity increases, the frictional drag coefficients decrease from 3.13 to 0.11, and the pressure drag coefficients increase from 0.55 to 0.6, implying that the recirculation of flowlines behind the O-ring becomes the most hindering factor on aerodynamics. Conversely, variations in surface roughness showed negligible effects on the flow field. This insensitivity is attributed to the low Reynolds number (Re) used in all simulations, where a roughness of 5 μm or 100 μm remains well within the laminar sublayer, therefore minimising their impact on boundary layer disruption and flow separation. Full article
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23 pages, 8915 KiB  
Article
Multi-Objective Optimization of Motor Sealing Performance: Numerical and Experimental Approach
by Weiru Zhou and Zonghong Xie
Materials 2025, 18(9), 2064; https://doi.org/10.3390/ma18092064 - 30 Apr 2025
Viewed by 294
Abstract
Rubber seals have been widely applied in mechanical sealing structures in various fields such as automobiles, aerospace, and deep-sea hydraulic systems. The current analysis methods for O-ring sealing performance mainly include experiments and simulations. This study takes the motor sealing structure as the [...] Read more.
Rubber seals have been widely applied in mechanical sealing structures in various fields such as automobiles, aerospace, and deep-sea hydraulic systems. The current analysis methods for O-ring sealing performance mainly include experiments and simulations. This study takes the motor sealing structure as the research object and proposes a multi-objective optimization method for designing sealing structures. Based on the finite element analysis model, the main indicators related to sealing performance were obtained. These indicators transfer to multi-objective optimization analysis to determine the influence of different groove depths on sealing performance. The analysis results show that when the bolt preload is 50 N, a groove depth of 0.9 mm is the optimal design scheme. The optimal relationship between the O-ring diameter D and the sealing structure groove depth is H = 0.6 D. Moreover, a prototype test under the condition of IPX7 requirement verifies the optimal design scheme’s waterproof performance. The proposed method provides multiple design schemes for comprehensive evaluation considering different sealing structures. It reveals that the sealing performance is not only determined by rubber material characteristics but also by seal structure dimension. Full article
(This article belongs to the Section Mechanics of Materials)
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26 pages, 9353 KiB  
Review
The Review of Selected Non-Pneumatic Tires Properties—Load Carrying Mechanism, Structure of Non-Pneumatic Tires
by Marcin Żmuda and Jerzy Jackowski
Materials 2025, 18(7), 1566; https://doi.org/10.3390/ma18071566 - 30 Mar 2025
Viewed by 890
Abstract
In recent years, non-pneumatic tires have been gaining popularity, which can be seen in the increase in research results and proposals from world-class tire manufacturers (mainly as technology demonstrators). The possibility of eliminating the need to maintain compressed air is a major factor [...] Read more.
In recent years, non-pneumatic tires have been gaining popularity, which can be seen in the increase in research results and proposals from world-class tire manufacturers (mainly as technology demonstrators). The possibility of eliminating the need to maintain compressed air is a major factor in the development of non-pneumatic tires and their usage in vehicles. Articles and patents were reviewed in relation to the load transfer mechanism, the design of non-pneumatic tire components, and recommendations for materials. Non-pneumatic tire top loaders are a desirable type of this type of wheel compared to bottom loaders, because they transfer loads over a larger part of the wheel, which increases their load capacity. Most non-pneumatic tires consist of a rim, an elastic structure, and a shear beam/band with a tread. The rim is used to secure the elastic structure and can be fitted with vibration dampers in the form of circumferential rubber rings. The gradient elastic structure, in comparison with the homogeneous structure (same thickness or dimensions of the elements), allows the range of axle displacements to be adjusted to the desired level without the need to increase the size of the wheel, and also influences the change in the location of the maximum stresses. The shear beam/ band mimics the properties of compressed air used in pneumatic tires. The shear beam/ band made as a webbing geometry ensures uniform pressure in the contact patch. The reinforced composite shear beam/ band ensures adequate bending strength with low energy losses and a small thickness of the beam/ band. Materials commonly used in the tire industry are used as reinforcement for the shear beam/ band, which was illustrated by the results of our own research. Full article
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19 pages, 6256 KiB  
Article
Ultraviolet-Follow Curing-Mediated Extrusion Stabilization for Low-Yield-Stress Silicone Rubbers: From Die Swell Suppression to Dimensional Accuracy Enhancement
by Bing Liu and Baoji Ma
Polymers 2025, 17(6), 811; https://doi.org/10.3390/polym17060811 - 19 Mar 2025
Cited by 1 | Viewed by 454
Abstract
Direct ink writing (DIW) of low-yield-stress UV-curable silicone rubber faces challenges in maintaining dimensional accuracy due to post-extrusion swelling and viscoelastic deformation. This study proposes an ultraviolet-follow curing (UFC) method to enhance geometric precision by UV-follow curing (UFC) during deposition. The effects of [...] Read more.
Direct ink writing (DIW) of low-yield-stress UV-curable silicone rubber faces challenges in maintaining dimensional accuracy due to post-extrusion swelling and viscoelastic deformation. This study proposes an ultraviolet-follow curing (UFC) method to enhance geometric precision by UV-follow curing (UFC) during deposition. The effects of UFC on filament dimensions—including width, length, cross-sectional geometry, and roundness—were systematically investigated. The mechanical properties of the printed structures were also evaluated to assess their functional integrity. The experimental results demonstrated that UFC effectively reduced extrusion swelling, achieving a filament-width deviation reduction of 22–81% and a filament-length deviation of 1.4–1.8% compared to conventional DIW. The printed rings exhibited improved roundness uniformity with reduced geometric fluctuations. Crucially, UFC enhances dimensional accuracy without compromising the mechanical performance of low-yield-stress silicones, providing a viable strategy for the high-precision additive manufacturing of soft elastomeric architectures. Full article
(This article belongs to the Section Polymer Processing and Engineering)
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11 pages, 2484 KiB  
Article
High-Pressure Hydrogen Influence on Cellulose Nanofibers Filled Nitrile Rubber: Performance in Storage Applications
by Sheng Ye, Sohail Yasin, Haijie Zhi, Yihu Song, Chaohua Gu and Jianfeng Shi
Fibers 2025, 13(3), 29; https://doi.org/10.3390/fib13030029 - 5 Mar 2025
Viewed by 973
Abstract
High-pressure hydrogen storage systems (up to 100 MPa) require advanced materials for safety and reliability, particularly for rubber seals, which are prone to degradation under extreme conditions. This study explores the use of cellulose nanofibers (CNFs) and cellulose nanocrystals (CNCs) as sustainable nanofillers [...] Read more.
High-pressure hydrogen storage systems (up to 100 MPa) require advanced materials for safety and reliability, particularly for rubber seals, which are prone to degradation under extreme conditions. This study explores the use of cellulose nanofibers (CNFs) and cellulose nanocrystals (CNCs) as sustainable nanofillers for nitrile butadiene rubber (NBR) latex nanocomposites. CNFs and CNCs were evaluated for their effects on mechanical properties, crosslink density, and resistance to high-pressure hydrogen exposure in rubber O-rings. A life cycle assessment (LCA) was carried to assess the environmental impact of these nanocomposites. The results showed that CNF-filled NBR composites exhibited better resistance to bubble formation under hydrogen exposure compared to CNC-filled ones. However, the LCA indicated relatively high environmental impacts for both, reaching up to 2.5 kg CO2 eq. in Global Warming Potential (GWP), highlighting the need for further optimization of production processes. This study demonstrates the potential of cellulose nanofillers to improve NBR performance while advancing sustainable hydrogen storage materials. Full article
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17 pages, 25447 KiB  
Article
Research on the Reciprocating Friction and Installation Force of Seals in Deep-Sea Samplers
by Hao Zhang, Yongjun Wang, Jiawang Chen, Yanjie Sun, Yongchun Shen and Hao Wang
Appl. Sci. 2025, 15(4), 1867; https://doi.org/10.3390/app15041867 - 11 Feb 2025
Viewed by 889
Abstract
It is crucial to accurately characterize the static and dynamic properties of seals for the design of deep-sea equipment. This study investigated the movement resistance of O-rings under high pressure (up to 30 MPa) and low temperature (2 °C). Numerical simulation models were [...] Read more.
It is crucial to accurately characterize the static and dynamic properties of seals for the design of deep-sea equipment. This study investigated the movement resistance of O-rings under high pressure (up to 30 MPa) and low temperature (2 °C). Numerical simulation models were set up to investigate the effects of material properties and seal structure dimensions on the reciprocating friction and installation force of O-rings. Furthermore, a novel resistance testing rig was developed to facilitate the measurement of reciprocating friction and installation force of O-rings under high pressure and low temperature. The results of this study indicate that nitrile rubber (NBR) has a reduced sensitivity to temperature variations, and the hardening of the material due to the low temperatures encountered in deep-sea environments does not substantially increase its movement resistance. Conversely, fluororubber (FKM) exhibits superior static sealing reliability. We optimized the sealing structure of the pressure-maintaining trapping instrument (PMTI) and successfully conducted field tests at the South China Sea. The results of this study may serve as a valuable reference for the sealing design of deep-sea equipment. Full article
(This article belongs to the Section Marine Science and Engineering)
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20 pages, 7540 KiB  
Article
Investigation into the Synergistic Effects of Sediment Concentration and Particle Size on the Friction and Wear Properties of Nitrile Butadiene Rubber
by Lun Wang, Xincong Zhou, Qipeng Huang, Xueshen Liu, Zhenjiang Zhou and Shaopeng Xing
J. Mar. Sci. Eng. 2025, 13(1), 33; https://doi.org/10.3390/jmse13010033 - 29 Dec 2024
Cited by 1 | Viewed by 956
Abstract
Nitrile Butadiene Rubber (NBR) is commonly used in ships’ water-lubricated tail bearings. However, sediment in the water significantly affects these bearings’ friction and wear performance. This study investigates NBR test blocks’ friction and wear behavior in conjunction with ZCuSn10Zn2 copper ring friction pairs [...] Read more.
Nitrile Butadiene Rubber (NBR) is commonly used in ships’ water-lubricated tail bearings. However, sediment in the water significantly affects these bearings’ friction and wear performance. This study investigates NBR test blocks’ friction and wear behavior in conjunction with ZCuSn10Zn2 copper ring friction pairs within a sediment-laden water lubrication environment. Two primary factors were considered: sediment particle concentration and sediment particle size. Friction and wear tests were conducted under pure water and sediment-laden conditions using the ZY-1 ring block friction and wear tester. The friction coefficients, wear quantities, and variations in mass concentrations and sediment particle sizes were measured and compared. The surface morphology of the test blocks was analyzed using a laser confocal microscope. The findings indicate that as sediment concentration increases, the particle size’s impact on NBR’s abrasive wear diminishes. The variation in particle size directly influences the number of particles that penetrate the interface between the friction partners and the nature of three-body wear. Conversely, changes in particle concentration primarily affect the extent of wear; specifically, both the wear volume and the average coefficient of friction of the NBR specimens increase with rising sediment concentration. The wear mechanisms observed on the surface of the NBR test blocks are predominantly characterized by micro-cutting, rolling wear, and the coexistence of both wear modes. This study offers valuable insights for the design and optimization of water-lubricated bearings. Full article
(This article belongs to the Section Ocean Engineering)
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13 pages, 5367 KiB  
Article
Lightweight Neural Network Optimization for Rubber Ring Defect Detection
by Weihan Gao, Ziyi Huang and Haijun Hu
Appl. Sci. 2024, 14(24), 11953; https://doi.org/10.3390/app142411953 - 20 Dec 2024
Viewed by 794
Abstract
Surface defect detection based on machine vision and convolutional neural networks (CNNs) is an important and necessary process that enables rubber ring manufacturers to improve production quality and efficiency. However, such automatic detection always consumes substantial computer resources to guarantee detection accuracy. To [...] Read more.
Surface defect detection based on machine vision and convolutional neural networks (CNNs) is an important and necessary process that enables rubber ring manufacturers to improve production quality and efficiency. However, such automatic detection always consumes substantial computer resources to guarantee detection accuracy. To solve this problem, in this paper, a CNN optimization algorithm based on the Ghost module is presented. First, the convolutional layer is replaced with the Ghost module in CNNs so that feature maps can be generated using cheaper linear operations. Second, an optimization method is used to obtain the best replacement of the Ghost module to balance computer resource consumption and detection accuracy. Finally, an image preprocessing method that includes inverting colors is applied. This algorithm is integrated into YOLOv5, trained on a dataset of rubber ring surface defects. Compared to the original network, the network size decreases by 30.5% and the computational cost decreases by 23.1%, whereas the average precision only decreases by 1.8%. Additionally, the network’s training time decreases by 16.1% as a result of preprocessing. These results show that the proposed approach greatly helps practical rubber ring surface defect detection. Full article
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21 pages, 11263 KiB  
Article
Hooked-End Steel Fibers Affecting Damping Ratio of Modified Self-Compacting Concrete with Rubber and Marble/Granite Additions
by Amauri Ernesto Gomes, Luisa A. Gachet, Rosa Cristina C. Lintz, Mirian de L. N. M. Melo and Wislei R. Osório
Materials 2024, 17(23), 5717; https://doi.org/10.3390/ma17235717 - 22 Nov 2024
Cited by 1 | Viewed by 865
Abstract
The aim of this investigation is to determine the effects of hooked-end steel fibers on both the fresh and hardened properties of modified self-compacting concretes (SCC). For this purpose, the steel fibers are associated with other residue contents (i.e., marble, granite, and rubber). [...] Read more.
The aim of this investigation is to determine the effects of hooked-end steel fibers on both the fresh and hardened properties of modified self-compacting concretes (SCC). For this purpose, the steel fibers are associated with other residue contents (i.e., marble, granite, and rubber). These concatenated material contents constitute a novelty since no investigations are reported. It is found that with the increase in rubber content, a better ability to absorb energy is observed. This indicates that a good alternative to structural material is provided. Fresh properties are evaluated by using flow, T500 time, V-funnel, and J-ring methods. The mechanical behavior is evaluated in terms of compressive strength, tensile strength, static and dynamic modulus of elasticity, and damping ratio. Experimental results of the water absorption, porosity, and density are also attained. It is also found that an SCC mixture containing steel fiber, marble/granite residue, and rubber content is a potential mixture to be considered when designing in SCC associated with an improved damping ratio. Although the rubber content decreases the mechanical behavior and slump flow, the concatenated utilization of marble/granite residues and steel fiber contents provides a slight improvement in the damping result. An environmental benefit can also be associated since cement consumption is decreased with marble additions. Full article
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17 pages, 7037 KiB  
Article
Experimental Study on the Bending Mechanical Properties of Socket-Type Concrete Pipe Joints
by Xu Liang, Jian Xu, Xuesong Song, Zhongyao Ren and Li Shi
Buildings 2024, 14(11), 3655; https://doi.org/10.3390/buildings14113655 - 17 Nov 2024
Viewed by 887
Abstract
In modern infrastructure construction, the socket joint of concrete pipelines is a critical component in ensuring the overall stability and safety of the pipeline system. This study conducted monotonic and cyclic bending loading tests on DN300 concrete pipeline socket joints to thoroughly analyse [...] Read more.
In modern infrastructure construction, the socket joint of concrete pipelines is a critical component in ensuring the overall stability and safety of the pipeline system. This study conducted monotonic and cyclic bending loading tests on DN300 concrete pipeline socket joints to thoroughly analyse their bending mechanical properties. The experimental results indicated that during monotonic loading, the relationship between the joint angle and bending moment exhibited nonlinear growth, with the stress state of the socket joint transitioning from the initial contact between the rubber ring and the socket to the eventual contact between the spigot and socket concrete. During the cyclic loading phase, the accumulated joint angle, secant stiffness, and bending stiffness of the pipeline interface significantly increased within the first 1 to 7 cycles and stabilised between the 8th and 40th cycles. After 40 cycles of loading, the bending stiffness of the joint reached 1.5 kN·m2, while the stiffness of the pipeline was approximately 8500 times that of the joint. Additionally, a finite element model for the monotonic loading of the concrete pipeline socket joint was established, and the simulation results showed good agreement with the experimental data, providing a reliable basis for further simulation and analysis of the joint’s mechanical performance under higher loads. This study fills the gap in research on the mechanical properties of concrete pipeline socket joints, particularly under bending loads, and offers valuable references for related engineering applications. Full article
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17 pages, 3894 KiB  
Article
Using Thin Ultra-High-Molecular-Weight Polyethylene Coatings to Reduce Friction in Frost-Resistant Rubbers
by Elena Torskaya, Ivan Shkalei, Fedor Stepanov, Yulia Makhovskaya, Afanasy Dyakonov and Natalia Petrova
Polymers 2024, 16(20), 2870; https://doi.org/10.3390/polym16202870 - 11 Oct 2024
Cited by 3 | Viewed by 1497
Abstract
Frost-resistant rubbers retain their highly elastic properties over a wide temperature range. They are used in various friction units (e.g., seals), but their high friction coefficient and low wear resistance lead to the need for frequent replacement. In this paper, we propose applying [...] Read more.
Frost-resistant rubbers retain their highly elastic properties over a wide temperature range. They are used in various friction units (e.g., seals), but their high friction coefficient and low wear resistance lead to the need for frequent replacement. In this paper, we propose applying thin (several hundred microns) UHMWPE coatings to formed rubber rings. The application technology depends on the required coating thickness. Friction tests of the coatings and pure UHMWPE were performed using the ball-on-disk (unidirectional sliding) scheme for various loads and velocities. In the experiments, the friction coefficients and temperatures near the contact area were determined. Friction tracks were studied using microscopy methods. The sliding contact of the ball and the two-layer material was modeled to obtain the dependences of the deformation component of friction on the sliding velocity for coatings of different thicknesses. UHMWPE is sensitive to frictional heating, so the thermal problem of determining the temperature in the contact area was also solved. It is shown that the minimum friction coefficient occurs for coatings with a thickness of 600 μm. At the same time, in the case of the 300 μm coating, the surface of the friction track is practically no different from the initial one. Thus, the studied combination of polymers provides antifrictional properties and wear resistance to the surface layer while maintaining the damping properties of rubber. Full article
(This article belongs to the Special Issue Advances in Functional Polymers and Composites)
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12 pages, 2939 KiB  
Communication
In Situ Efficient End Functionalization of Polyisoprene by Epoxide Compounds via Neodymium-Mediated Coordinative Chain Transfer Polymerization
by Xiuhui Zhang, Jing Dong, Feng Wang, Xuequan Zhang and Heng Liu
Polymers 2024, 16(18), 2672; https://doi.org/10.3390/polym16182672 - 22 Sep 2024
Cited by 1 | Viewed by 1605
Abstract
The Nd-mediated coordinative chain transfer polymerization (CCTP) of dienes represents one of the state-of-the-art techniques in the current synthetic rubber field. Besides having well-controlled polymerization behaviors as well as high atom economies, it also allows for the generation of highly reactive Al-capped polydienyl [...] Read more.
The Nd-mediated coordinative chain transfer polymerization (CCTP) of dienes represents one of the state-of-the-art techniques in the current synthetic rubber field. Besides having well-controlled polymerization behaviors as well as high atom economies, it also allows for the generation of highly reactive Al-capped polydienyl chain-ends, which hold great potential, yet much less explored up to date, in achieving end functionalization to mimic the structure of natural rubber. In this study, we demonstrate an efficient in situ method to realize end-functionalizing polyisoprene by introducing epoxide compounds into a CCTP system. The end functionalization efficiency was 92.7%, and the obtained polymers were systematically characterized by 1H NMR, 1H,1H-COSY NMR, DOSY NMR, and MALDI TOF. NMR studies revealed that a maximum of two EO units were introduced to the chain ends, and based on density functional theory (DFT) studies, an energy barrier of 33.3 kcal/mol was required to be overcome to open the ring of the EO monomer. Increasing the ratio of [Ip]/[Nd] resulted in gradually increased viscosities for the reaction medium and therefore gave rise to an end functionalization efficiency that decreased from 92.7% to 74.2%. The end hydroxyl group can also be readily converted to other functionalities, as confirmed by NMR spectroscopy. Full article
(This article belongs to the Section Polymer Chemistry)
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16 pages, 5578 KiB  
Article
The Change of Sealing Property in the Aging Process of NBR Sealing Equipment Based on Finite Element Analysis
by Min Zhu, Desheng Ma, Yuan Zhou, Hanyuan Huang, Zhaoqun Shao, Fei Wu and Biao Li
Coatings 2024, 14(9), 1178; https://doi.org/10.3390/coatings14091178 - 12 Sep 2024
Cited by 3 | Viewed by 1345
Abstract
Sealing rings are the core components of flange sealing structures and play a crucial role in the storage and operation of gas generators. The aging and deformation of seals affect the safe operation of the device. This paper aims to investigate the effect [...] Read more.
Sealing rings are the core components of flange sealing structures and play a crucial role in the storage and operation of gas generators. The aging and deformation of seals affect the safe operation of the device. This paper aims to investigate the effect of rubber aging on the sealing performance of the components, which is realized by nonlinear finite element analysis. Firstly, an accelerated degradation test method was used to obtain the compression permanent deformation and stress–strain curve of rubber during the aging process. A two-dimensional finite element model of the sealing structure was constructed and the Yeoh model was utilized to describe the mechanical response of rubber. During the simulation, the contact area was modified based on the compression permanent deformation, and the Yeoh model was updated based on the stress–strain curve changes obtained by the test. The impact of key parameters such as material property changes, rubber physical section deformation, and fluid pressure on sealing performance during the seal ring aging process was systematically studied. The numerical results indicate that due to the aging deformation of rubber seals, there is a significant decrease in contact stress and contact width, as well as a shift in maximum equivalent stress area. Taking into account these findings, this study proposes a new design concept for sealing structures. This provides a relatively simple research method for studying flange sealing structure performance. Full article
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