Search Results (11)

The complexity of the pore system hindered our understanding of the storage and transport properties of organic-rich shales, which in turn brought challenges to the efficient exploration and development of shale oil and gas. This study, based on elemental, mineralogical, petrographic, and petrophysical approaches, attempts to reveal the pore structure and fractal characteristics of a suite of Permian shales collected from the northeastern Sichuan Basin, China. The results showed that meso-pores make up the main proportion of the total pore volume in the Permian shale in this study; most of the pore size distribution patterns for micro pores and meso-macropores are bimodal. Pores related to clay minerals, organic matter pores, and intragranular dissolution pores are the main storage spaces in these shales. In these samples, ink-bottle pores dominate, with some slit and wedge-shaped ones developed. The morphology of the pores in the studied shales is mainly ink-bottle pores, with some slit-shaped and wedge-shaped pores. The fractal dimension D₂ is greater than D₁, indicating that the homogeneity of pore space is stronger than that of the specific surface area. Quartz in Permian shales inhibits the development of macro- and mesopore spaces and enhances pore heterogeneity, while clay minerals facilitate the development of macro- and mesopore spaces and attenuate pore heterogeneity. The organic matter content shows a negative impact on the macropore volume due to the stripped occurrence and matrix filling. This study has a vital significance for current exploration and development of shale gas in Permian strata in the Sichuan Basin and offers insights for Permian shales in other basins all over the world. Full article

In the field of enhanced oil recovery (EOR), particularly for water control in high-temperature reservoirs, there is a critical need for effective in-depth water shutoff and conformance control technologies. Polymer-based in situ-cross-linked gels are extensively employed for enhanced oil recovery (EOR), yet their short gelation time under high-temperature reservoir conditions (e.g., >120 °C) limits effective in-depth water shutoff and conformance control. To address this, we developed a hydrogel system via the in situ cross-linking of polyacrylamide (PAM) with phenolic resin (PR), reinforced by silica sol (SS) nanoparticles. We employed a variety of research methods, including bottle tests, viscosity and rheology measurements, scanning electron microscopy (SEM) scanning, density functional theory (DFT) calculations, differential scanning calorimetry (DSC) measurements, quartz crystal microbalance with dissipation (QCM-D) measurement, contact angle (CA) measurement, injectivity and temporary plugging performance evaluations, etc. The composite gel exhibits an exceptional gelation period of 72 h at 130 °C, surpassing conventional systems by more than 4.5 times in terms of duration. The gelation rate remains almost unchanged with the introduction of SS, due to the highly pre-dispersed silica nanoparticles that provide exceptional colloidal stability and the system’s pH changing slightly throughout the gelation process. DFT and SEM results reveal that synergistic interactions between organic (PAM-PR networks) and inorganic (SS) components create a stacked hybrid network, enhancing both mechanical strength and thermal stability. A core flooding experiment demonstrates that the gel system achieves 92.4% plugging efficiency. The tailored nanocomposite allows for the precise management of gelation kinetics and microstructure formation, effectively addressing water control and enhancing the plugging effect in high-temperature reservoirs. These findings advance the mechanistic understanding of organic–inorganic hybrid gel systems and provide a framework for developing next-generation EOR technologies under extreme reservoir conditions. Full article

Solar radiation, particularly ultraviolet radiation (UVR, 280–400 nm), is known to play a significant role in driving primary production in marine ecosystems. However, our understanding of the specific effects of UVR on the primary production of natural phytoplankton communities is still limited. We utilized the ¹³C stable isotope to quantify primary production and conducted experiments using different types of incubation bottles (polycarbonate and quartz bottles) to compare the primary production in the absence and presence of UVR. Although we observed a weak inhibitory effect at the surface of the water column, UVR exposure resulted in an approximately 1.5-fold increase in primary production over the euphotic zone. The enhanced primary production during the study period can be attributed to the combined effect of low UVB (280–320 nm) dose and abundant nutrient conditions. Notably, our size-fractionated measurements revealed that UVR exposure led to a two-fold increase in primary production in large cells (>2 μm) compared to the exposure of solely photosynthetically active radiation (PAR). In contrast, there was no significant difference in the primary production of small cells (<2 μm) between the absence and presence of UVR. These findings highlight the advantages of large cells when exposed to UVR, emphasizing the importance of phytoplankton cell size in determining their response to UVR. However, it is important to note that the effects of UVR on phytoplankton are influenced by various environmental factors, which interact with solar radiation, shaping the dynamics of phytoplankton responses to UVR. Full article

Shale oil and gas are currently the major fields of unconventional hydrocarbon exploration and development. The Fengcheng Formation (FF) shale in the Mahu Sag of the Junggar Basin is an alkaline lacustrine organic-rich shale with an extremely prospective shale oil potential. However, its strong heterogeneity and complex pore structure greatly influence the development of shale oil. It is significant to investigate the pore and geochemical characteristics of shale reservoirs for shale oil extraction. In this study, the pore structure and geochemical characteristics of FF have been investigated using core analysis, Rock-Eval pyrolysis, X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), mercury injection capillary pressure (MICP), low-temperature gas adsorption (LTGA), and X-ray computed tomography (X-ray CT). The results show that the shale of FF has moderate organic matter abundance, and the kerogen is mainly of Type II, which is now at the peak of oil generation. Shale minerals are mainly composed of carbonate (dolomite and calcite) and siliceous (quartz and feldspar) minerals, with extremely low clay mineral content. The pore types are mainly intergranular pores (inter-P), intragranular pores (intra-P), and microfractures associated with mineral particles. The pore space is contributed predominantly by micropores of 0.5–1.2 nm and mesopores of 10–50 nm, whereas macropores are underdeveloped. The pores are mostly ink bottle- and slit-shaped, and the pore connectivity is relatively poor. The pore development of shale in the FF is influenced by organic matter abundance, thermal maturity, mineral composition, etc. Organic matter content (TOC), thermal maturity (Ro), and carbonate minerals have a positive effect on pore development, and the pore volume (PV) increases with TOC, Ro, and carbonate minerals. While clay minerals show a negative effect, the PV decreases with clay minerals. Additionally, the influence of the clay mineral content on the pore morphology of shale should not be ignored. This study investigates the pore structure and geochemical characteristics of the alkaline lacustrine shale of FF in Mahu Sag, which is significant to deepen the understanding of alkaline lacustrine shale and to improve the production of shale oil. Full article

To clarify the reservoir characteristics of laminated shale, the occurrence mechanism of shale oil and its influencing factors in the Gulong Sag, northern Songliao Basin, are studied to better guide the exploration and development of shale oil there. First, X-ray diffraction (XRD) and field-emission scanning electron microscopy (FE-SEM) are used to characterize the pore types, pore geneses and factors influencing the pore volume in the study area. Second, the organic matter of the samples is extracted with a mixture of dichloromethane and methanol. Total organic carbon (TOC), nitrogen adsorption and Rock-Eval tests are performed on the samples before and after extraction to reveal the pore size distribution after extraction. The factors influencing free and adsorbed shale oil and the lower limit of pore size are discussed in detail. The results show that interparticle pores (interP pores), intraparticle pores (intraP pores), organic matter pores (OM pores) and microfractures can be found in the laminated shale (Q1) in the Gulong Sag, Songliao Basin, and that the interP pores and intercrystalline pores in clay minerals are the main pores. The FE-SEM results show that the diameters of interP pores vary from several hundred nanometers to several microns, and their morphologies are mainly triangular, strip-shaped or irregular. The morphology of the intercrystalline pores in the clay minerals is generally irregular, depending on the crystal type and arrangement of clay minerals. According to the characteristics of the nitrogen adsorption and desorption curves, the pore morphologies are mainly slit-shaped pores, parallel-plate-shaped pores and ink-bottle-shaped pores. The pore size distribution is mostly bimodal, and the pore volume contribution is the greatest in the pore size range of 10~20 nm. Before and after extraction, the overall characteristics of the pore size distribution change only slightly, but the number of micropores increases significantly. Different minerals have different degrees of influence on the proportions of micropores, mesopores and macropores. Quartz mainly inhibits the formation of micropores, while the overall effect on mesopores and macropores is positive depending on the diagenetic period. Feldspar has a strong positive correlation with the micropore and mesopore proportions but is not highly correlated with the macropore proportions. The influence of the carbonate mineral content on the pore volume is not obvious because of its complex composition. The TOC content and vitrinite reflectance (Ro) are the two most important factors controlling free oil and adsorbed oil, and the contents of mineral components, such as felsic minerals, carbonate minerals and clay minerals, have no obvious correlation with shale oil content. With increasing pore volume, the contents of free oil and adsorbed oil increase, but the proportion of adsorbed oil decreases gradually. The correlation between the specific surface area and adsorbed oil content is poor. At normal temperatures and pressures, the lower limit of the pore diameters that can contain free oil is 4 nm, and the lower limit of the pore diameters that can contain movable oil is 10 nm. Full article

The construction industry is particularly responsible for the appearance of the earth and the environment and for its partial degradation related to climate warming through the production of cement, brick burning, and the processing of substrates for the production of building materials (lime, gypsum, polystyrene, processed materials, etc.). An important aspect of the 21st century has been the overproduction and excessive use of natural resources, including sand. The purpose of this article is to analyze the possibility of using glass sand as a substitute for quartz sand in the production of materials resulting from hydrothermal treatment (so-called silicate bricks). The article is a review of the research conducted since 2016 on laboratory tests on the modification of silicate mass with glass sand from recycled bottle glass, the properties of the mass modified in this way (hydration temperature, consistency, and humidity of the mixture), its physical and mechanical properties, and its structural and potential durability, which is related to, e.g., the direction and degree of crystallization of the C-S-H phase. Tests of compressive strength, density, water absorption, oxide composition (XRF), structure (XRD), microstructure (SEM), and porosity (CT analysis using computer tomography) were carried out. A special point of the research was the use of geochemical modeling code in the form of the GEMS-PSI program in the process of analyzing the modification of silicate mass by glass sand, which is beneficial in limiting ineffective modifications, thus saving time, money, and energy. Studies have shown that the use of glass cullet has a positive effect on the consistency of the modified raw material mass, on the density (1.6–1.75 kg/dm³), and on the compressive strength (15.729–20.3 MPa), while the crystallization of the C-S-H phase occurs in the direction of natrolite and gyrolite, less frequently towards the M-S-H or brucite phase. Full article

Exploring the relationship between formation pressure and shale pore evolution is helpful for the enrichment and development of marine shale gas accumulation theory. The thermal evolution experiment was carried out on the Xiamaling Formation (Pr3x) lowly matured marine shale, which has a similar sedimentary environment to the Longmaxi Formation (S1l) highly matured marine shale. Comparative experiments of open and semi-closed pyrolysis and multiple pore structure characterization techniques, including CO₂ and N₂ physisorption, mercury intrusion porosimetry, and field emission scanning electron microscopy, were conducted. The marine shale pore evolutionary model under formation pressure is proposed by characterizing pore evolution, and hydrocarbon expulsion and retention for shales under and without formation fluid pressures. The results show that the existence of formation pressure increases the percentage of quartz and reduces the content of clay minerals. The change in formation pressure has no obvious effect on the maturity evolution of shale samples. With the increase of formation pressure, the pore morphology of shale gradually changes from narrow slit pores to ink bottle-shaped pores. The retained hydrocarbons in shale mainly occupy the mesopore space, and the existence of formation pressure promotes hydrocarbon expulsion, especially the hydrocarbon expulsion in the mesopore. In addition, formation pressure improves pore connectivity, especially in the high-over mature stage of shale. With the increase of formation pressure, the micropore volume decreases slightly, the mesopore volume increases significantly, and the macropore volume changes have two stages. Full article

Miners around Zimbabwe used to supply gold concentrates from sulphide flotation to the Kwekwe Roasting Plant (Zimbabwe) for toll treatment. The concentrates were roasted in Edward’s roasters and the calcine product was leached by cyanidation. Due to inefficient roasting, overall gold recoveries of 75–80% left behind a rich calcine leach residue at the Kwekwe Roasting Plant. The characterization performed to establish a potential process route involved several techniques, such as X-ray diffraction (XRD), scanning electron microscopy (SEM), fire assaying and inductively coupled plasma (ICP). Assays conducted on samples from the 350,000 tons tailings dam residue, created over the operational years, gave an average Au grade of 8.58 g/t and 12.54 g/t for Ag. The base metals assayed—0.11% Cu, 0.10% Pb, 0.17% Zn and 26.05% Fe. SiO₂ (36.1%), Fe₂O₃ (36.9%), Mg₃Si₄O₁₀ (OH)₂ (8.9%), NaAlSi₃O₈ (6.9%), and Fe₃O₄ (6.4%)—were the major mineral phases in the cyanide leach residue. SEM gold scans on 24 polished sections showed only 2 discrete gold particles of less than 5 µm, with one partially liberated and associated with quartz, while the other was fully liberated. Therefore, the particulate gold in the calcine leach residue was negligible. It was deduced from the analysis after ultrafine milling (P₈₀ < 5 µm) followed by cyanidation that 68.53% of the gold was sub-microscopic. Direct cyanidation using bottle roll resulted in only 2.33% of the total gold being leachable, indicating that the calcine leach residue was highly refractory. Diagnostic leaching by sequential use of acids in order of their strength resulted in HCl leachable phases (CaCO₃, CaMg(CO₃)₂, PbS, Fe1-XS, and Fe₂O₃) freeing 4.2% of the total Au during subsequent cyanidation leach. H₂SO₄ leachable phases (Cu–Zn sulphides, labile FeS₂) released an additional 26.57% during cyanidation, whereas HNO₃ leachable phases (FeS₂, FeAsS) released a further 20.98% of Au. After acid treatment and subsequent cyanidation, hot caustic leach of the residue followed by carbon in pulp resulted 4.43% of the total gold being eluted. Therefore, 4.43% of the total gold was surface bound. From the analysis after diagnostic acid leaching, it was deduced that a total of 54.08% of the gold was in the acid-leachable phase. Due to cost and environmental considerations, H₂SO₄ was selected for the evaluation of acid digestion as a pretreatment stage followed by cyanidation. Increasing the H₂SO₄ strength for the pretreatment of the calcine leach residue increased gold recoveries during cyanidation. Full article

In this study, the microstructure of mock-up mortar specimens for a historic environment, composed of different mixtures, was studied using mercury intrusion porosity (MIP) and microcomputed tomography (µCT), highlighting the advantages and drawbacks of both techniques. Porosity, sphericity, and pores size distribution were studied, evaluating changes according to mortar composition (aerial and hydraulic binders, quartz sand, and crushed limestone aggregate). The µCT results were rendered using 3D visualization software, which provides complementary information for the interpretation of the data obtained using 3D data-analysis software. Moreover, µCT contributes to the interpretation of MIP results of mortars. On the other hand, MIP showed significant ink-bottle effects in lime and cement mortars samples that should be taken into account when interpreting the results. Moreover, the MIP results highlighted how gypsum mortar samples display a porosity distribution that is best studied using this technique. This multi-analytical approach provides important insights into the interpretation of the porosimetric data obtained. This is crucial in the characterization of mortars and provides key information for the study of building materials and cultural heritage conservation. Full article

The Chinese spirit baijiu is currently the world’s bestselling spirit, with more than ten billion liters sold in 2018. This is a figure that puts its sales higher than whiskey, vodka, gin, and tequila combined. The multitude of baijiu varieties available in the market differ in several ways ranging from aging to the traditional artisanship involved in producing the final spirit to several other features, including the rarity of the bottle. A result of these differences is a wide distribution of prices for the various baijiu products. Consequently, a single bottle of baijiu can cost anywhere from a few dollars, up to thousands of US dollars. The price differences among the various baijiu spirits necessitate the existence of reliable scientific methods that can efficiently differentiate and authenticate the qualities of baijiu spirits. In addition, the existence of such methods facilitates the prevention of counterfeit sales of the final product. Considering this, we introduce an analytical chemistry method that distinguishes amongst different baijiu spirits based on fluorescence spectroscopy. Its attributes include the low cost and convenience that allows analysis either before or while the spirit is in the market. Our work herein focuses on the analysis of thirty different varieties of baijiu spirits from six different distilleries from East Asia and North America by fluorescence emission spectroscopy, which is associated to the price of the product. For the analysis, we employed a HORIBA FLUOROLOG 3 (HORIBA—Jobin Yvon) spectrometer. Major advantages of this method include the low cost, as no consumables except a quartz reusable cuvette are required, the minimal waste, and finally the quick processing of data. Full article

The main aim of the current investigation was to contemplate the impact of high-voltage electric field cold plasma (HVCP) on different quality characteristics (enzymes, microbial activities, coloring pigments, ascorbic acid, polyphenolic compounds, °Brix, acidity, and color index) of carrot juice in correlation with thermal processing. A carrot juice (250 mL) sample sealed in pre-sterilized food-grade bottles, which placed between two dielectric quartz plates for HVCP treatment. The gap between the plates was 30 mm, and a stable and uniform plasma dielectric barrier discharge (DBD) generated for 3 and 4 min at 60, 70, and 80 kV. Air was used as a working gas during the DBD-based plasma treatment. The observed rise in temperature was 2–5 °C during the HVCP treatment. A water bath was used to carry out thermal treatment (100 °C for 5 min). The maximum inactivation of enzymes and microorganisms was achieved with thermal treatment and then with HVCP treatment at 70 kV for 4 min. However, maximum retention of coloring compounds, ascorbic acid, total phenols, flavonoids, and tannins was found following HVCP (70 kV for 4 min) treatment compared to thermal treatment. The °Brix, pH, and acidity remained unchanged irrespective of treatments. These findings suggest that HVCP treatment at 70 kV for 4 min may be a good alternative to thermal treatment, and it may successfully be applied in carrot juice production, resulting in reduced enzymes, lower microbial activity, and improved bioactive compounds. The prospects of overcoming the existing conventional physical and chemical methods for sterilization make it a novel and more economical technique to maintain food’s natural nourishment, composition, appearance, structure, and freshness. Full article