Search Results (48)

Quarry dust (QD) landfill causes environmental issues that cannot be ignored. In this study, we systematically explore its potential application as a supplementary cementitious material (SCM) in cemented paste backfill (CPB), revealing the activated mechanism of modified QD (MQD) and exploring the hydration process and workability of CPB containing QD/MQD. The experimental results show that quartz, clinochlore and amphibole components react with CaO to form reactive dicalcium silicate (C₂S) and amorphous glass phases, promoting pozzolanic reactivity in MQD. QD promotes early aluminocarbonate (M_c) formation through CaCO₃-derived CO₃²⁻ release but shifts to hemicarboaluminate (H_c) dominance at 28 d. MQD releases active Al³⁺/Si⁴⁺ due to calcination and deconstruction, significantly increasing the amount of ettringite (AFt) in the later stage. With the synergistic effect of coarse–fine particle gradation, MQD-type fresh backfill can achieve a 161 mm flow spread at 20% replacement. Even if this replacement rate reaches 50%, a strength of 19.87 MPa can still be maintained for 28 days. The good workability and low carbon footprint of MQD-type backfill provide theoretical support for—and technical paths toward—QD recycling and the development of low-carbon building materials. Full article

This study presents the geotechnical evaluation of phosphogypsum, a byproduct of phosphate fertilizer production. The objective is to assess the suitability of phosphogypsum or its mixtures with natural materials as a technically viable and environmentally responsible backfill material for the restoration of closed and abandoned quarries. This study adds to the scarce existing literature on the use of phosphogypsum for quarry reclamation and further investigates the behavior of phosphogypsum mixtures incorporating clay and marble dust. A comprehensive experimental program was conducted to evaluate typical geotechnical properties, i.e., grain size distribution, Atterberg limits, compaction characteristics, permeability, compressibility, and shear strength. The results indicate that phosphogypsum is fine grained, low in plasticity, and exhibits relatively high permeability and compressibility, which limits its application as a deep fill material. The addition of clay increased the liquid and plastic limits but had a limited positive effect on strength and compressibility. In contrast, mixtures with marble dust improved particle gradation, reduced permeability, and enhanced compaction behavior without significantly increasing plasticity or settlements. Notably, the most promising mixture of phosphogypsum with a modest proportion of marble dust demonstrates improved shear strength and reduced hydraulic conductivity, making it suitable for use in the upper layers of quarry fills. Full article

The disposal and recycling of industrial by-products such as marble and limestone powders pose pressing environmental challenges due to the substantial amounts of waste generated annually by marble processing plants and limestone quarries. The integration of these by-products into concrete production is justified by their widespread availability and the potential to alleviate the environmental burden. This study used a statistical mixture design approach to systematically assess the effects of limestone and marble powders, with varying fineness levels, as partial cement replacements (up to 17%) on the rheological and mechanical properties of self-compacting concrete (SCC). The experimental findings revealed that the density of the SCC mixtures ranged from 2475 to 2487 kg/m³. Mixtures incorporating limestone powder exhibited superior flowability, achieving a slump flow of up to 69 cm, an 8% improvement compared to those containing marble powder. However, marble powder with a specific surface area of 330 m²/kg demonstrated significant improvements in compressive and tensile strengths, with increases of 18%. Statistical analysis using analysis of variance (ANOVA) validated the reliability of the predictive models developed, which demonstrated coefficients of determination (R²) that exceeded 0.94 and p-values below 0.05. These models enable precise predictions of critical performance metrics, including density, slump flow, box flow, compressive strength, and tensile strength, thus reducing the need for extensive experimental procedures. Full article

The purpose of this paper was to identify the types of stone used in the “Resthouses” along the Northwest Royal Road connecting Angkor in Cambodia and Phimai in Thailand and to determine their sources through magnetic susceptibility measurements and chemical composition analyses. Laterite was the primary building material for the “Resthouses”, except for Pr. Ku Sila Khan in Thailand. Pr. Ku Sila Khan, located at the northernmost point of the Northwest Royal Road, was primarily built with fine-grained red sandstone. Based on the magnetic susceptibility and the V, Sr, and As contents of the laterite, the following pairs of “Resthouses” were likely sourced from the same quarries: Pr. Sampov and Pr. Saman Teng, Pr. Kok Ac Chring and Pr. Kok Mon, Pr. Ta Muan and Pr. Thamo, and Pr. Ban Bu and Pr. Non Kong. Fine-grained red sandstone, white siliceous sandstone, red siliceous sandstone, and gray sandstone were used for the frame material of the openings. The Rb vs. Ti diagram and magnetic susceptibility measurements suggest that the fine-grained red sandstone and siliceous white sandstone used in the “Resthouses” in Thailand were likely sourced from the Khok Kruat Formation and the Phu Phan Formation, respectively. However, the red siliceous sandstone and white siliceous sandstone used in the “Resthouses” in Cambodia are presumed to have been sourced from the Sao Khua Formation and the Phra Wihan Formation, respectively. Gray sandstone from the Phu Kradung Formation was uniquely used in the frame material of the openings of Pr. Sampov and Pr. Kok Mon in Cambodia. In conclusion, the sandstone used in the door and window frames of the “Resthouses” appears to have been determined by the surrounding geology. Laterite was used as the primary building material for the “Resthouses” along the Northwest Royal Road, whereas valuable sandstone was used for those along the East Royal Road. This suggests that the Northwest Royal Road was of lesser importance compared to the East Royal Road. Full article

The construction industry’s evolution towards sustainability necessitates the adoption of environmentally friendly materials and practices. Geopolymer concrete (GeC) stands out as a promising alternative to conventional concrete due to its reduced carbon footprint and potential for cost savings. This study explores the predictive capabilities of soft computing models in estimating the compressive strength of GeC, utilizing multi-layer perceptron (MLP) neural networks and hybrid systems incorporating the Gannet Optimization Algorithm (GOA) and Grey Wolf Optimizer (GWO). A dataset comprising 63 observations from a quarry mine in Malaysia is employed, with influential parameters normalized and utilized for model development. Consequently, we integrate optimization algorithms (GOA and GWO) with MLP to fine-tune the model’s parameters and improve prediction accuracy. The models are evaluated using R², RMSE, and VAF. Various MLP architectures are explored, evaluating transfer functions and training techniques to optimize performance. In addition, hybrid models GOA–MLP and GWO–MLP are developed, with parameters fine-tuned to enhance predictive accuracy. During the training phase, the GWO–MLP model achieved an R² of 0.981, RMSE of 0.962, and VAF of 97.44%, compared to MLP’s R² of 0.95, RMSE of 0.918, and VAF of 94.59%. During the testing phase, GWO–MLP also showed the best performance with an R² of 0.976, RMSE of 1.432, and VAF of 97.51%, outperforming both MLP and GOA–MLP. The GOA–MLP model demonstrated improved performance over MLP with an R² of 0.963, RMSE of 0.811, and VAF of 95.78% in the training phase and R² of 0.944, RMSE of 2.249, and VAF of 92.86% in the testing phase. Hence, the results show that the GWO–MLP model consistently outperforms both MLP and GOA–MLP models. Sensitivity analysis further elucidates the impact of key parameters on compressive strength, aiding in the optimization of GeC formulations for enhanced mechanical properties. Overall, the study underscores the efficacy of machine learning models in predicting GeC compressive strength, offering insights for sustainable construction practices. Full article

Very large quantities of stone waste sludge are disposed in exhausted quarries and have a very low reuse rate to date. The paper considers the possibility of using these types of industrial waste in partial substitution of natural aggregates for the production of lime-based plasters. Traditional materials based on lime, the only material with a carbon neutrality life cycle, have considerable potential for use as components of green materials for plastering and finishing building surfaces in both new construction and historic heritage conservation. The paper presents the preliminary results of a research activity aimed at developing pre-packaged products based on Traditional Lime Putty (TLP) by partially replacing natural aggregates with Stone Waste Sludge (SWS), with a low rate of recovery from the Apricena limestone production district in Apulia. The mineralogical and chemical analysis carried out using XRD (X-Ray Diffraction), TG-DTA (Thermo Gravimetry-Differential Thermal Analysis), and hydrochloric acid attack test showed that the SWS consisted of 98.4 % CaCO₃ by mass. The particle sizes measured by laser diffraction technique are below 22.5 μm for the 92% mass of the sample. The high fineness of the stone waste was confirmed by the Blaine-specific surface method, which equals to 9273.79 cm²/gr. The behavior of three fresh mixtures for prepacked coarse plaster, fine plaster, and finishing plaster with 12.90%, 17.94%, and 18.90 by mass of SWS, respectively, was evaluated by spreading test and applicability tests on a perforated ceramic slab. The finishing plaster has the highest consistency value of 235 mm, while the fine plaster and the coarse plaster have values of 205 mm and 155 mm, respectively. The coarse plaster is suitable for use as base plaster (arriccio) or second layer rendering (tonachino) up to a thickness of approximately 1 cm. Both the fine plaster and finishing plasters can be used for the surfaces finishing with the application of layers of a few millimeters thick. Full article

Clays are components in the fine portion of aggregates, less than 75 microns in size (micro-fines), which are usually washed away when producing coarse or fine (manufactured sand) aggregates in quarries. When marginal sources of aggregates are being used, the content of this washed portion can be quite high, and there is an incentive to keep as much of it in the aggregate, including the clays. The present paper presents a comprehensive treatment of the role of clays in terms of the characterization of their composition and quantification of their effects on the rheological and mechanical properties of cementitious systems, as well as the means to mitigate deleterious influences. It is shown that the strategy for neutralizing the effect of micro-fines containing clays on increased water demand in concrete can be quantified in terms of the combination of their content in concrete and their nature as characterized by the methylene blue value (MBV); this is a more rational approach to considering their influence than their content in specific aggregates as specified in standards. The effect of low and medium MBV aggregates on the water requirement can be neutralized by lignosulfonates when their content in the concrete is below a threshold value of about 150 kg/m³; polycarboxylates (PC) are required at higher contents; for high MBV aggregates, a combination of PC and clay mitigating admixture (CMA) is required. It is also demonstrated that with proper treatment, such micro-fines can be turned into useful fillers, enhancing the strength of concrete and thus also serving as a means for reducing cement content. Full article

Naturally occurring asbestos (NOA) represents a matter of social and environmental concern due to its potential release in the atmosphere during rock excavation and grinding in quarry and road tunnel activities. In most cases, NOA occurs in serpentinites, i.e., rocks deriving from low-grade metamorphic hydration of mantle peridotites. The potential release of asbestos fibers from serpentinite outcrops depends on several features, such as serpentinization degree, rock deformation, weathering, and abundance of fibrous veins. In this study, we selected a set of serpentinite samples from a representative outcrop in Tuscany (Italy), and we analyzed them by Optical, Scanning, and Transmission Electron Microscopies. The samples were treated by grinding tests following the Italian guidelines Decrees 14/5/96 and 152/2006 for the determination of the Release Index (RI), i.e., the fiber amount released through controlled crushing tests. The fine-grained powder released during the tests was analyzed by quantitative Fourier transform infrared spectroscopy (FTIR) to determine the variety and the amount of released fibers and to assess the potential hazard of the different serpentinite samples. Results indicate that the amount of released fibers is mostly related to serpentinite deformation, with the highest RI values for cataclastic and foliated samples, typically characterized by widespread occurrence of fibrous veins. Conversely, massive pseudomorphic serpentinite revealed a very low RI, even if their actual chrysotile content is up to 20–25%. Based on our original findings from the RI results, a preliminary investigation of the outcrop at the mesoscale would be of primary importance to obtain a reliable hazard assessment of NOA sites, allowing the primary distinction among the different serpentinites lithotypes and the effective fiber release. Full article

Phosphate waste rock (PWR) is gaining attention as a potential alternative aggregate for concrete. Its valorization could reduce the environmental impacts of quarrying natural resources and stockpiling phosphate mining waste. This study comprehensively investigated the properties of fine and coarse aggregates produced from three rock types selected from PWR in Morocco: Flint, Phosflint, and Dolomite. A range of techniques was used to study their characteristics, including microstructural observations up to the microscale and X-ray computed tomography (X-CT), mineralogical and chemical compositions, physical and geotechnical properties such as Los Angeles (LA), micro-Deval (M_DE), flexural strength, real dry density, and total porosity. The results showed that the coarse fractions of Flint, Phosflint, and Dolomite are code A or B of NF P 18-545 and exhibit good shape, density, and water absorption properties. Flint aggregates had the highest wear and fragmentation resistance with the lowest and finest porosity. They contained mainly quartz but also small proportions of Dolomite and fluorapatite. Phosflint aggregates had high resistance, shown by code A in LA and M_DE values, and flexural strength equal to 17.1 MPa. They contained phosphate microfacies with a Ca/P atomic ratio equal to 1.8, cemented by cryptocrystalline silica. Dolomite aggregates’ mineralogical make-up consisted mainly of dolomite with the presence of quartz particles in addition to impurities. They also displayed significant total porosity (10–12%), as confirmed by X-CT. These findings were discussed to develop insights for the use of three types of PWR as alternative aggregates for concrete production. This investigation contributes to unveiling the properties of PWR as concrete aggregates and encourages circularity between the mining and construction sectors. Full article

Driven by the insatiable demand for construction materials, excessive quarrying for natural aggregates and the demand for raw materials for cement production pose significant environmental challenges, including habitat loss and resource depletion. To address these concerns, this study investigates the use of fibre-reinforced self-compacting concrete (FR-SCC) with high-volume fly ash (HVFA) and varying levels of recycled concrete aggregates (RCA) as substitutes for fine and coarse aggregates. This approach aims to simultaneously address environmental concerns by reducing reliance on virgin resources by utilizing the recycled aggregates and enhancing the performance of concrete through the combined benefits of fly ash and fibre reinforcement. In this study, Self-Compacting Concrete (SCC) mixes were created with 50% of fly ash replaced with conventional cement content, which was taken from the previous literature. Fine and coarse aggregate utilized in this investigation were replaced with processed recycled aggregates at varying levels from 0% to 100% at an interval of 25%, offering a promising solution to alleviate the environmental burden associated with excessive quarrying while contributing to sustainable construction practices. Additionally, replacement levels of aggregate synthetic polypropylene fibres (PF) were added into the concrete matrix up to 1% at an interval of 0.25%. This research contributes to the development of sustainable construction practices by promoting resource efficiency and minimizing environmental impact. The study found that SCC mixes with fibres and recycled aggregates maintained self-compactability, with polypropylene fibres and fly ash improving workability and cohesion. With this combination of materials, the highest strength value of 55.31 MPa was observed and the study promotes sustainable construction by reducing reliance on virgin resources and minimizing environmental impact. Full article

Many historic buildings and monuments on the Salento Peninsula (Apulia, southern Italy) were built from locally quarried Miocene calcarenites belonging to the Pietra Leccese Formation (Late Burdigalian–early Messinian). The main facies consists of a homogeneous and porous biomicrite, pale yellow in colour and fine- to medium-grained, very rich in planktonic Foraminifera and massive or thick-bedded in outcrop. Additionally, there are other facies, among which Piromafo stands out for its aesthetic appearance, enhanced by its greenish-brown or greenish-grey colours. Piromafo occurs in the upper part of the Pietra Leccese Fm. and is represented by a fine- to medium-grained glauconitic and phosphatic biomicrite with macrofossils, especially Bivalves and Gastropods. Despite its important historical use as a building and ornamental material, especially in Roman and Baroque architecture, a research gap exists in the scientific literature describing the properties of the stone and their correlation. Therefore, the aim of this paper is to present a wide range of properties useful in explaining the in situ behaviour and damage susceptibility of the stone in monuments and buildings, but also to assist in selecting preservation treatments and strategies. An overall assessment of the main petrophysical and mechanical properties, especially for restoration/conservation purposes, was performed using both standard and unconventional techniques. Starting with rock fabric inspection, particular attention was given to the relationship between the pore size distribution and the hydraulic and thermal properties of the material. Unconfined compressive strength, flexural strength, and indirect tensile strength were also estimated. The findings reveal a significant correlation between the pore size distribution and the hydraulic and thermal properties of Piromafo, impacting its durability and suitability for use in conservation. Specifically, the thermal properties, influenced by the mineral composition and fabric, indicate the potential for using Piromafo as an effective refractory and insulation material, which justifies the origin of its name and confirms what is already stated in the specific literature. Additionally, correlations were proposed among the various mechanical parameters evaluated, including the Schmidt hammer rebound values with compressive strength and tangent modulus. The mechanical analysis shows that the material possesses adequate properties for structural applications. Full article

This paper presents a study on the combined use of two by-products, namely quarry dust (QD) and ferronickel slag (FNS), as a full substitute for natural sand to improve the greenness of concrete production. Quarry dust was used in increments of 25% to a maximum of 75% substitution, where nickel slag was used as the remaining proportion of fine aggregate. All the combinations of quarry dust and nickel slag were found to be compliant with AS 2758.1 and they showed notably better grading than 100% sand. In this research, standard concrete tests, such as the slump test for fresh concrete, and compression, tensile and shrinkage tests for hardened concrete, were conducted. Scanning electron microscopy and X-ray diffraction analysis were also conducted for microstructural investigation. The results concluded that the combinations of quarry dust and nickel slag in concrete as a whole substitution of sand provide similar results for these properties. Specifically, 25% quarry dust with 75% nickel slag proved to be the most promising alternative to sand, with compressive and splitting tensile strengths of 62 and 4.29 MPa, respectively, which were 16% and 20% higher than those of the control mix. Also, lower drying shrinkage was observed for this combination compared to the control mix. The higher strength is attributed to the rough texture and angular shape of both quarry dust and nickel slag providing a better mechanical interlocking. The validity of this result has also been confirmed through image analysis of micrographs from various specimens. In microstructural investigations, specimens with QD and FNS exhibited fewer voids and a more compact surface compared to the control specimen. This shows the potential for further research into the use of quarry dust and nickel slag in the production of green concrete. Full article

Chert, a by-product rock of sand quarrying, has historically posed economic challenges for aggregate production, resulting in significant “waste” accumulation in quarries. Our study investigates the effect of microwave irradiation on the mechanical properties of chert gravel, a mineralogically homogenous material composed of fine quartz grains. The results, which demonstrate that increased irradiation time leads to a substantial decrease in chert gravel strength (by a factor of 4–6 for 2.5 min of irradiation), underscore the potential impact of this research on comminution processes. With quenching altering the fractional content of the samples after the crushing test, reducing the Gravel-to-Sand ratio, this study is driven by the promising potential of crushed chert gravel as a pivotal aggregate within the concrete and asphalt industries, offering a practical solution to their material needs. The urgent need to rehabilitate previously utilized quarry areas, offering an environmentally beneficial solution for which we all should be responsible, motivated the present study. Full article

Wollastonite (CaSiO₃) is the most researched and well-defined mineral in the field of CO₂ mineralization, but it is also a sought-after process mineral and thus, not easily justified for large scale ex situ carbon sequestration, which requires an energy-intensive step of comminution to increase reactivity. Wollastonite-rich mine tailings are a side stream with an already fine particle size resulting from the extractive process, but their effective utilization is problematic due to legislation, logistics, a high number of impurities, and chemical inconsistency. In this study, the accelerated weathering (aqueous carbonation) of high-calcite (CaCO₃) wollastonite tailings was studied under elevated temperatures and high partial pressures of CO₂ to determine the carbon sequestration potential of those tailings compared to those of pure reference wollastonite originating from the same quarry. The main process variables were pressure (20–100 bar), temperature (40 °C–60 °C), and time (10 min–24 h). Despite consisting largely of non-reactive silicates and primary calcite, very fine tailings showed promise in closed-chamber batch-type aqueous carbonation, achieving a conversion extent of over 28% in one hour at 100 bar and 60 °C. Full article

Marble has been a prominent natural stone exploited since ancient times, commonly employed as a building material and ornamental stone. However, the disposal of waste generated from marble extraction, particularly fine sludge, poses significant environmental challenges for the dimensional stone industry. The difficulty in managing and recovering these materials, exacerbated by local regulations and the absence of suitable recovery protocols, often leads to landfilling. This issue is exemplified by the Carrara Marble Basin in the Apuan Alps (Tuscany, Italy), where more than half of the extracted marble remains as quarry waste or debris. Modern cutting technologies have intensified the production of finer materials and sawing residue, known as “marmettola”, ranging in size from fine sand to silt. The disposal of these materials, commonly through landfilling or abandonment, has profound environmental repercussions. This research primarily aimed to carry out a preliminary physical, mineralogical, and morphological characterization of the fine waste and sludges generated from Carrara Marble exploitation. The findings reveal the high granulometric uniformity of the materials, and a nearly pure carbonate composition, suggesting potential for reuse in various industrial sectors such as paper, plastics, and pharmaceuticals production. Full article