Search Results (2,658)

Given the importance of nickel in lithium-ion batteries and the expectation of the growth in electric vehicles and electrical devices, the demand for nickel in battery production is expected to increase dramatically. Nickel is primarily sourced from laterite saprolite ore, and there is now substantial interest in moving from ferronickel smelting technology to nickel matte technology in its processing to produce high-grade nickel. This research involved a thermodynamic modelling and lab–scale experiment on the smelting of nickel matte. Nickel concentrate from laterite saprolite was used, and CaS, produced from commercially available gypsum, was employed as a sulfurizing agent. The matte smelting experiment was conducted at 1500 °C to optimize CaS and C consumption. During smelting with CaS, matte particles form, although sufficient reduction of nickel and iron from the concentrate is not achieved. By consuming carbon, the reduction potential of iron is increased, and this process, along with enriching the matte with iron, aids in the transportation of nickel. At a nickel grade in the matte with a Ni/Fe ratio of approximately 1, the nickel recovery only reached 63%. Upon achieving a nickel recovery exceeding 93%, the Ni/Fe ratio reached 0.44, corresponding to a nickel grade reduction to 22.78%. By employing analytical techniques and thermodynamic modelling, we have successfully determined the sulfidizing of nickel, identified the ideal CaS and C additions, and characterized the structure and quality of the slag produced during nickel matte smelting, supplying vital technological data necessary for practical application. Full article

Manganese is a critical raw material and there is currently a great interest in decarbonization in the metallurgical sector for its production. Hydrogen use in manganese and its alloys’ production is in principle possible for sustainable production; however, this requires a technological shift from traditional carbothermic processes to completely new processes; like the HAlMan process. To design a process, it is crucially important to optimize the process conditions (such as temperature) and minimize the quantity of hydrogen gas and the related energy consumptions. In the present work, energy and mass balances for a hydrogen-based reduction reactor were carried out employing thermodynamics software and analytical approaches from room temperatures to 900 °C. It was found that the quantity of hydrogen gas required for the pre-reduction of manganese ore can be significantly reduced via coupling the reduction reactor with a calciner and the hot charge of the calcined ore into the reduction reactor. Moreover, hot H₂-H₂O gas mixture from the reduction reactor outlet can be used for preheating the hydrogen feed of the reactor, and the calcination of the ore, while a portion or all its hydrogen can be recovered and looped. The integrated coupled calcination-reduction process was found to be operated with no external energy supply, or insignificant fuel use. Full article

Nystatin is a polyene macrolide antibiotic with broad-spectrum antifungal activity and serves as a key therapeutic agent for superficial fungal infections. This review systematically elaborates on its multicomponent chemical nature, its mechanism of action targeting ergosterol, and highlights the potential adverse effects, such as cardiotoxicity, associated with impurities like RT6 (albonoursin). The fundamental analytical techniques for quality control are outlined. Furthermore, the clinical applications and combination therapy strategies of nystatin in treating oral diseases, vaginitis, and otitis externa are summarized in detail. Regarding biosynthesis, the assembly mechanism of nystatin A₁ via the type I polyketide synthase pathway and its subsequent modification processes are thoroughly discussed. Emphasis is placed on the latest advances and potential of gene-editing technologies, particularly CRISPR/Cas9, in the targeted knockout of genes responsible for toxic components and in optimizing production strains to enhance nystatin yield and purity. Finally, this review prospects the future development of nystatin towards improved safety and efficacy through structural optimization, innovative delivery systems, and synthetic biology strategies, aiming to provide a reference for its further research and clinical application. Full article

The maritime sector is undergoing a profound transformation driven by disruptive technologies and global decarbonization objectives, placing new demands on Maritime Education and Training (MET) systems. Equipping maritime professionals with competencies for low-carbon shipping is now as critical as technological advancement itself. This study examines how disruptive technologies can be effectively integrated into MET frameworks to support environmental sustainability, using Panama as a representative case study of a major flag and maritime service state. A mixed-methods approach was adopted, combining a structured literature review, expert surveys, and a multi-criteria decision-making analysis based on the Analytic Hierarchy Process (AHP). The findings reveal a significant misalignment between existing MET curricula and the competencies required for decarbonized maritime operations. Key gaps include limited training in alternative fuels, emissions measurement and reporting, energy-efficient technologies, digital analytics, and regulatory compliance. Stakeholders also reported fragmented training provision, uneven access to emerging technologies, and weak coordination between academia, industry, and regulators, particularly in developing contexts. The results highlight the urgent need for curriculum reform and stronger cross-sector collaboration to align MET with evolving technological and regulatory demands. The study provides an applied, evidence-based framework for MET reform, with insights transferable to other systems facing similar decarbonization challenges. Full article

This paper presents the results of a comprehensive technological study of three bronze sculptures from the Jin Empire period (1115–1234 AD) from the collection of the Museum of Archaeology and Ethnography at the Institute of History, Archaeology and Ethnography of the Peoples of the Far East, Far Eastern Branch of the Russian Academy of Sciences (IHAE FEB RAS). Using photon-counting computed tomography (PCCT) and energy-dispersive X-ray spectroscopy (EDS), the production techniques were reconstructed, differences in alloy composition were identified, and specific features of the casting processes were determined. Tomographic analysis revealed two fundamentally different manufacturing approaches: a multi-stage technology involving the use of different alloys and the assembly of separately cast elements, and a single-cast technology with a homogeneous structure. Elemental analysis of the three sculptures using EDS demonstrated significant compositional variability—from 21% to 67% copper and from 9% to 69% tin in different parts of the objects—confirming the complexity of the technological processes. An expanded study of 20 bronze sculptures using portable X-ray fluorescence analysis (pXRF) allowed for the identification of four typological alloy groups: classic balanced lead–tin bronzes (Cu 30–58%, Sn 16–23%, Pb 16–28%), high-lead bronzes (Pb up to 52%), high-tin bronzes (Sn up to 30%), and low-tin alloys (Sn less than 11%). The morphological features of the sculptures suggest one of their possible interpretations as ancestor spirits used in ritual practices. The research findings contribute to the study of Jurchen metallurgical traditions and demonstrate the potential of interdisciplinary, non-destructive analytical methods for reconstructing the technological, social, and cultural aspects of medieval Far Eastern societies. Full article

Driven by the national policy of total water resources control and efficiency improvement, the behavior of water resource utilization reduction by firms is widespread, which may have an impact on the value of firms. This study integrates dynamic capability theory and signaling theory to construct a dual-path analytical framework, systematically investigating the impact of water utilization reduction on firm value and its intrinsic mechanisms. Based on data from Chinese A-share listed companies spanning 2012–2023, fixed-effect models, mediation-effect tests, and heterogeneity analysis are employed for empirical verification. The results reveal that water utilization reduction exerts a significant dual-path promoting effect on firm value: it enhances financial performance (ROA) primarily through technological innovation, reflecting the process of resource orchestration and dynamic capability construction; concurrently, it boosts market performance (Tobin’s Q) mainly by improving ESG performance as a signaling channel, mirroring the capital market’s positive pricing of green signals. Further heterogeneity analysis indicates that these effects are more pronounced during the policy deepening stage, in non-water-intensive industries, and in humid/sub-humid regions. This study contributes theoretical support and empirical evidence for firms’ green transformation and the formulation of differentiated water resource policies by the government, highlighting the synergistic development of high-quality economic growth and ecological civilization construction. Full article

This paper presents the design and optimization, based on electromagnetic simulation, of a fifth-order bandpass filter centered at 30 GHz, implemented using Gap Waveguide (GWG) technology and pole-type cylindrical resonators, intended for applications in 5G communication systems and high-frequency satellite links. Unlike conventional Chebyshev designs reported in the literature, this study proposes an integrated methodology that combines theoretical synthesis, full-wave electromagnetic modeling, and multivariable optimization, while accounting for manufacturing constraints. The developed method encompasses the electromagnetic characterization of individual resonators, the extraction of cavity–cavity coupling parameters, and the complete implementation of the filter using full-wave electromagnetic simulations. A distinctive aspect of the proposed approach is the explicit incorporation of practical manufacturing effects, such as rounded corners induced by machining processes, alongside analytical and numerical geometric compensation procedures that preserve the device’s electrical response. Furthermore, a combination of gradient-based optimization algorithms and evolutionary strategies is employed to align the electromagnetic response with the target theoretical behavior. The results obtained through electromagnetic simulation indicate that the designed filter achieves return losses exceeding 20 dB and a fractional bandwidth of 4.95%, consistent with the reference Chebyshev response. Finally, the potential extension of the proposed approach to higher frequency bands is discussed conceptually, laying the groundwork for future work that includes experimental validation. Full article

Solanum betaceum (tamarillo) is Andean fruit rich in secondary metabolites with increasing relevance in food, nutraceutical, and biotechnological research. Despite growing scientific interest, the available evidence remains fragmented and methodologically heterogeneous. This systematic review consolidates and critically analyzes recent studies on the bioactive composition of S. betaceum, the effects of conventional and emerging processing technologies, and the functional activities reported for fresh fruits, by-products, and processed matrices. A comprehensive search of Lens.org, Scopus, and PubMed was conducted following PRISMA 2020 guidelines. From 1049 records identified, 65 studies published between 2020 and 2025 met the inclusion criteria and were included in the qualitative synthesis. The literature reveals substantial variability in polyphenols, anthocyanins, carotenoids, vitamin C, and other metabolites, driven by cultivar, maturity stage, edaphoclimatic conditions, and analytical approaches. Emerging technologies such as ultrasound-assisted extraction, high-pressure homogenization, and spray drying generally improved the recovery and stability of bioactive compounds, whereas intensive thermal treatments were associated with degradation of thermolabile constituents. Functional evidence supports antioxidant, antimicrobial, metabolic modulatory, and cytotoxic activities; however, interpretation is limited by inconsistent reporting practices, limited bioaccessibility assessment, and the predominance of in vitro models. Overall, S. betaceum shows considerable functional and technological potential, but further standardized methodologies, mechanistic studies, and human-relevant models are required to support translational and industrial validation. Full article

Oxidative stress contributes significantly to chronic disease burden, necessitating identification of accessible dietary antioxidant sources. Pigeon peas (Cajanus cajan L.) contain substantial bioactive compounds, yet most exist in bound forms with limited bioavailability. This study evaluated wild fermentation combined with systematic extraction optimization to enhance antioxidant recovery from pigeon peas. Seeds underwent wild fermentation in brine solution, followed by extraction under varying conditions (seven solvent systems, three temperatures, and three-time durations). Multiple complementary assays assessed antioxidant capacity (total phenolic content, DPPH radical scavenging, ferric reducing power, and ABTS activity). Fermentation substantially improved antioxidant properties across all parameters, with particularly pronounced effects on radical scavenging activities. Extraction optimization identified 70% methanol at 40 °C for 24 h as optimal, demonstrating marked improvements over conventional protocols. Strong intercorrelations among assays confirmed coordinated enhancement of multiple antioxidant mechanisms rather than isolated changes. The findings demonstrate that both biotechnological processing and analytical methodology critically influence antioxidant characterization in pigeon peas. This integrated approach offers practical guidance for developing antioxidant-rich functional foods, particularly relevant for resource-limited settings where pigeon peas serve as dietary staples. The study establishes foundation for translating fermentation technology into nutritional interventions, though further research addressing bioavailability, microbiological characterization, and bioactive compound identification remains essential. Full article

Near-infrared (NIR) spectroscopy has emerged as a pivotal non-destructive analytical technique within the cheese industry, offering rapid and precise insights into the chemical composition and quality attributes of various cheese types. This review explores the evolution of NIR spectral sensors, highlighting key technological advancements and their integration into cheese production processes as well as final products already in markets. In addition, the review discusses challenges such as calibration complexities, the influence of sample heterogeneity and the need for robust data and interpretation models through spectroscopy coupled with AI methods. The future potential of NIR spectral sensors, including real-time in-line monitoring and the development of portable devices for on-site analysis, is also examined. This review aims to provide a critical assessment of current NIR spectral sensors and their impact on the cheese industry, offering insights for researchers and industry professionals aiming to enhance quality control and innovation in cheese production, as well as authenticity and fraud studies. The review concludes that the integration of advanced NIR spectroscopy with AI represents a transformative approach for the cheese industry, enabling more accurate, efficient and sustainable quality assessment practices that can strengthen both production consistency and consumer trust. Full article

Improving the thermal utilisation of organic production waste to generate energy is integral to solving one of the most pressing issues of our time: transitioning away from fossil fuels. In this context, the thermal utilisation of organic waste, particularly sewage sludge (SS) and lignin-containing by-products from the biochemical industry, is of considerable scientific and practical interest. This study provides a thorough analysis of the co-combustion processes involving SS, lignin-based pellets and briquettes, and their mixtures with various component ratios. The aim of the work is to evaluate the fuel properties, thermokinetic characteristics, and potential for synergistic interactions during joint fuel combustion, considering the mechanical impact on lignin during granulation. The aim is to optimise conditions for the thermal utilisation of industrial waste. The study employed standard analytical methods: the thermophysical properties of the fuels were determined; morphological analysis of the particle surface was conducted using scanning electron microscopy; and X-ray fluorescence analysis was performed to identify the inorganic oxide phase. It has been established that lignin briquettes have the highest lower heating value, exceeding that of lignin pellets and sewage sludge by 7% and 27%, respectively. Thermogravimetric analysis (TGA) in an oxidising atmosphere (air, heating rate of 10 °C/min) made it possible to determine the following key combustion parameters: the ignition temperature of the coke residue (T_i); the temperature at which oxidation is complete (T_b); the maximum combustion rate (R_max); and the combustion efficiency index (Q). The ignition temperature of the coke residue was 262.1 °C for SS, 291.8 °C for lignin pellets, and 290.0 °C for lignin briquettes. Analysis of co-combustion revealed non-linear behaviour in the thermograms, indicating synergistic effects, which are manifested by a decrease in the maximum combustion rate compared to the additive prediction, particularly in mixtures with a moderate lignin content (25–50%). It was established that the main synergistic interactions between the mixture components occurred during moisture evaporation and the combustion of coke residue. These results are valuable for designing and operating power plants that focus on co-combusting industrial organic waste, and they contribute to the development of thermal utilisation technologies within closed production cycles. Full article

Rare earth elements (REEs) are not scarce in nature; however, they rarely occur in economically viable concentrations. Over recent decades, demand for REE has increased substantially due to advances in high-technology industries and the expansion of clean energy technologies. At present, global REE production is highly concentrated, leading to instability in the international market and reinforcing the need to identify new resources. This study presents a mineralogical characterization of REE+Y occurrences in the Serra da Mesa Granitic Massif (SMGM), the type granite of the Tocantins Subprovince, Goiás Tin Province, Brazil. The objective is to evaluate its potential for REE+Y enrichment in ion-adsorption–type (IA-type) weathering profiles. Petrography, electron probe microanalysis (EPMA), and scanning electron microscopy (SEM) were applied to samples of the parental granite and associated alluvial sediments. The main REE-bearing minerals identified are allanite, bastnäsite-(Y), fluocarbonates, xenotime-(Y), zircon, and fergusonite-(Y), showing wide compositional variability. Bastnäsite-(Y) and xenotime display the highest REE+Y contents, reaching up to 74.2 wt.% and 65.1 wt.%, respectively. Bastnäsite and other fluocarbonates occur as alteration products of allanite, indicating REE+Y mobilization associated with F- and CO₂-rich fluids under low-temperature hydrothermal conditions. Alteration textures and low EPMA analytical totals suggest hydration, metamictization, and fluid-mediated neoformation processes. The abundance of REE+Y-bearing minerals, their susceptibility to weathering, and the presence of secondary fluocarbonates indicate that the SMGM represents a promising target for IA-type REE+Y mineralization within the Goiás Tin Province. Full article

In this work, an archeological adhesive collected at Cantagrilli (near Florence) was chemically analyzed by applying gas chromatography/mass spectrometry, infrared spectroscopy, and nuclear magnetic resonance spectrometry combined with the archeobotanical investigations. Data identify triterpenes, aged anhydride, benzoyl resin, and gelatinized starch in the sample. The multi-analytical approach allowed us to identify some molecular compounds, as well as their state of chemical decomposition (especially by applying the mass spectrometry techniques). On the other hand, archeobotanical measurements have provided useful but not unequivocal information regarding the possible origin of triterpenes from some terrestrial plants, combined with the presence of microorganisms and transformed chemicals (such as starch modified into gelatin). All this information is very useful to Prehistoric Archeologists for understanding the cultural processes and technologies used by ancient populations. Full article

Under rapid urbanization and ecological transformation, balancing authenticity preservation with adaptive reuse presents a major challenge for industrial heritage landscapes. This study investigates the Dagushan Iron Mine in Anshan, China’s first large-scale open-pit iron mine and once the deepest in Asia, which is currently undergoing ecological backfilling that threatens its core landscape morphology and spatial integrity. Using a mixed-method approach combining archival research, spatial documentation, qualitative interviews, and expert evaluation through the Analytic Hierarchy Process (AHP), we construct a cross-validated evidence chain to examine how evidence-based industrial landscape heritage values can inform low-intervention digital narrative strategies for off-site learning. This study contributes theoretically by reframing authenticity and integrity under ecological transition as the traceability and interpretability of landscape evidence, rather than material survival alone. Evaluation involving key stakeholders reveals a value hierarchy in which historical value ranks highest, followed by social and cultural values, while scientific–technological and ecological–environmental values occupy the mid-tier. Guided by these weights, we develop a four-layer value-to-narrative translation framework and an animation design pathway that supports curriculum-aligned learning for off-site students. This study establishes an operational link between evidence chain construction, value weighting, and digital storytelling translation, offering a transferable workflow for industrial heritage landscapes undergoing ecological restoration, including sites with World Heritage potential or status. Full article

With the advancement of digital technology, serious games have become an essential tool for disseminating and educating individuals about cultural heritage. However, systematic empirical research remains limited with respect to how visual elements influence users’ cognitive and emotional engagement through interactive behaviors. Using the “Macau Historic Centre Science Popularization System” as a case study, this mixed-methods study investigates the mechanisms by which visual elements affect user experience and learning outcomes in digital interactive environments. Eye-tracking data, behavioral logs, questionnaires, and semi-structured interviews from 30 participants were collected to examine the impact of visual elements on cognitive resource allocation and emotional engagement. The results indicate that the game intervention significantly enhanced participants’ retention and comprehension of cultural knowledge. Eye-tracking data showed that props, text boxes, historic buildings, and the architectural light and shadow shows (as incentive feedback elements) had the highest total fixation duration (TFD) and fixation count (FC). Active-interaction visual elements showed a stronger association with emotional arousal and were more likely to elicit high-arousal experiences than passive-interaction elements. The FC of architectural light and shadow shows a positive correlation with positive emotions, immersion, and a sense of accomplishment. Interview findings revealed users’ subjective experiences regarding visual design and narrative immersion. This study proposes an integrated analytical framework linking “visual elements–interaction behaviors–cognition–emotion.” By combining eye-tracking and information dynamics analysis, it enables multidimensional measurement of users’ cognitive processes and emotional responses, providing empirical evidence to inform visual design, interaction mechanisms, and incentive strategies in serious games for cultural heritage. Full article