Search Results (2,807)

Under the background of “dual-carbon”, the development of energy internet is an inevitable trend for China’s low-carbon energy transition. This paper proposes a hydrogen-coupled electrothermal integrated energy system (HCEH-IES) operation mode and optimizes the source-side structure of the system from the level of carbon trading policy combined with low-carbon technology, taps the carbon reduction potential, and improves the renewable energy consumption rate and system decarbonization level; in addition, for the operation optimization problem of this electric–gas–heat integrated energy system, a flexible energy system based on electric–gas–heat is proposed. Furthermore, to address the operation optimization problem of the HCEH-IES, a deep reinforcement learning method based on Soft Actor–Critic (SAC) is proposed. This method can adaptively learn control strategies through interactions between the intelligent agent and the energy system, enabling continuous action control of the multi-energy flow system while solving the uncertainties associated with source-load fluctuations from wind power, photovoltaics, and multi-energy loads. Finally, historical data are used to train the intelligent body and compare the scheduling strategies obtained by SAC and DDPG algorithms. The results show that the SAC-based algorithm has better economics, is close to the CPLEX day-ahead optimal scheduling method, and is more suitable for solving the dynamic optimal scheduling problem of integrated energy systems in real scenarios. Full article

Antioxidants regulate oxidative reactions by impeding, delaying, or inhibiting the oxidation of biomolecules. Concerns regarding the toxicity of synthetic antioxidants have driven the search for safer alternatives. In this study, the antioxidant activities of three nontoxic carbon-based nanomaterials—carbon dots from citric acid precursor (CB-Ca), iron-doped carbon dots (CB-Fe) and carbon dots derived from Momordica charantia leaves (CB-Mc)—were investigated using 2,2-diphenyl-1-picrylhydrazyl (DPPH) radical scavenging, hydrogen peroxide (H₂O₂) scavenging, ferric-reducing antioxidant power, and total antioxidant capacity (TAC) assays. Scavenging activity was carried out at varying concentrations, and half-maximal inhibitory concentration (IC₅₀) was calculated using non-linear regression. Reductive ability and TAC were expressed as mg ascorbic acid equivalents/g nanomaterial. CB-Fe exhibited the most potent DPPH scavenging activity (IC₅₀ = 254.2 ± 37.37 µg/mL), surpassing CB-Mc and CB-Ca by 2- to 3-fold. In contrast, CB-Ca had the highest H₂O₂ scavenging (IC₅₀ = 84.2 ± 11.87 µg/mL), while CB-Mc had the highest TAC of 77.95 mg ascorbic acid Eq/g. CB-Fe also displayed superior ferric ion reducing capacity. The study concluded that each carbon dot type exhibits unique antioxidant profiles and may offer some special advantages in nanomedicine and other applications. Full article

This study reports the synthesis and comprehensive spectroscopic characterization of 4-indolylcyanamide (4ICA), a novel indole-derived infrared (IR) probe designed for assessing local microenvironments in biological systems. 4ICA was synthesized via a two-step procedure with an overall yield of 43%, and its structure was confirmed using high-resolution mass spectrometry and ¹HNMR. Fourier Transform Infrared (FTIR) spectroscopy revealed that the cyanamide group stretching vibration of 4ICA exhibits exceptional solvent-dependent frequency shifts, significantly greater than those of conventional cyanoindole probes. A strong linear correlation was observed between the vibrational frequency and the combined Kamlet–Taft parameter, underscoring the dominant role of solvent polarizability and hydrogen bond acceptance in modulating its spectroscopic behavior. Quantum chemical calculations employing density functional theory (DFT) with a conductor-like polarizable continuum model (CPCM) provided further insight into the solvatochromic shifts and suppression of Fermi resonance in high-polarity solvents such as DMSO. Additionally, IR pump–probe measurements revealed short vibrational lifetimes (~1.35 ps in DMSO and ~1.13 ps in ethanol), indicative of efficient energy relaxation. With a transition dipole moment nearly twice that of traditional nitrile-based probes, 4ICA demonstrates enhanced sensitivity and signal intensity, establishing its potential as a powerful tool for site-specific environmental mapping in proteins and complex biological assemblies using nonlinear IR techniques. Full article

Cross-linked polymers are indispensable in advanced applications, but suffer from poor recyclability due to permanent covalent networks. Herein, we report recyclable supramolecular polyurea elastomers that integrate ureidopyrimidinone-based quadruple hydrogen-bonding motifs directly into the polymer backbone. The dynamic and reversible nature of these motifs imparts the SPUEs with remarkable malleability and reprocessability while preserving the robustness of conventional polyureas. The SPUEs display remarkable mechanical robustness, solvent resistance, and facile reprocessability through hot-pressing, producing homogeneous films with minimal performance loss. Impressively, tensile strength, elongation at break, and toughness retained high recovery after reprocessing, demonstrating excellent closed-loop mechanical recyclability. This work showcases supramolecular engineering as a powerful strategy to reconcile mechanical robustness with recyclability in cross-linked polymers, offering new opportunities for sustainable thermosets and elastomers in circular materials design. Full article

Given the climate change observed in the past few decades, sustainable development and the use of renewable energy sources are urgent. In this scenario, hydrogen production through electrolyzers is a promising renewable source and energy vector because of its ultralow greenhouse emissions and high energy content. Hydrogen can be used in a variety of applications, from transportation to electricity generation, contributing to the diversification of the energy matrix. In this context, this paper presents an autonomous isolated DC microgrid system for generating and storing electrical energy to be exclusively used for feeding an electrolyzer hydrogen production plant, which has been retrofitted for green hydrogen production. Experimental verification was performed at Itaipu Parquetec, which consists of an alkaline electrolysis unit directly integrated with a battery energy storage system and renewable sources (e.g., photovoltaic and wind) by using an isolated DC microgrid concept based on DC/DC and AC/DC converters. Experimental results revealed that the new electrolyzer DC microgrid increases the system’s overall efficiency in comparison to the legacy thyristor-based power supply system by 26%, and it autonomously controls the energy supply to the electrolyzer under optimized conditions with an extremely low output current ripple. Another advantage of the proposed DC microgrid is its ability to properly manage the startup and shutdown process of the electrolyzer plant under power generation outages. This paper is the result of activities carried out under the R&D project of ANEEL program No. PD-10381-0221/2021, entitled “Multiport DC-DC Converter and IoT System for Intelligent Energy Management”, which was conducted in partnership with CTG-Brazil. Full article

This study explored the optimization of green hydrogen production via seawater electrolysis powered by a hybrid photovoltaic (PV)-wind system in KwaZulu-Natal, South Africa. A Box–Behnken Design (BBD), adapted from Response Surface Methodology (RSM), was utilized to address the synergistic effect of key operational factors on the integration of renewable energy for green hydrogen production and its economic viability. Addressing critical gaps in renewable energy integration, the research evaluated the feasibility of direct seawater electrolysis and hybrid renewable systems, alongside their techno-economic viability, to support South Africa’s transition from a coal-dependent energy system. Key variables, including electrolyzer efficiency, wind and PV capacity, and financial parameters, were analyzed to optimize performance metrics such as the Levelized Cost of Hydrogen (LCOH), Net Present Cost (NPC), and annual hydrogen production. At 95% confidence level with regression coefficient (R² > 0.99) and statistical significance (p < 0.05), optimal conditions of electricity efficiency of 95%, a wind-turbine capacity of 4960 kW, a capital investment of $40,001, operational costs of $40,000 per year, a project lifetime of 29 years, a nominal discount rate of 8.9%, and a generic PV capacity of 29 kW resulted in a predictive LCOH of 0.124$/kg H₂ with a yearly production of 355,071 kg. Within the scope of this study, with the goal of minimizing the cost of production, the lowest LCOH observed can be attributed to the architecture of the power ratios (Wind/PV cells) at high energy efficiency (95%) without the cost of desalination of the seawater, energy storage and transportation. Electrolyzer efficiency emerged as the most influential factor, while financial parameters significantly affected the cost-related responses. The findings underscore the technical and economic viability of hybrid renewable-powered seawater electrolysis as a sustainable pathway for South Africa’s transition away from coal-based energy systems. Full article

Energy management in hybrid fuel cell ship systems faces the dual challenges of optimizing hydrogen consumption and ensuring power quality. This study proposes an Improved Weighted Antlion Optimization (IW-ALO) algorithm for multi-objective problems. The method incorporates a dynamic weight adjustment mechanism and an elite-guided strategy, which significantly enhance global search capability and convergence performance. By integrating IW-ALO with the Equivalent Consumption Minimization Strategy (ECMS), an improved weighted ECMS (IW-ECMS) is developed, enabling real-time optimization of the equivalence factor and ensuring efficient energy sharing between the fuel cell and the lithium-ion battery. To validate the proposed strategy, a system simulation model is established in Matlab/Simulink 2017b. Compared with the rule-based state machine control and optimization-based ECMS methods over a representative 300 s ferry operating cycle, the IW-ECMS achieves a hydrogen consumption reduction of 43.4% and 42.6%, respectively, corresponding to a minimum total usage of 166.6 g under the specified load profile, while maintaining real-time system responsiveness. These reductions reflect the scenario tested, characterized by frequent load variations. Nonetheless, the results highlight the potential of IW-ECMS to enhance the economic performance of ship power systems and offer a novel approach for multi-objective cooperative optimization in complex energy systems. Full article

The high efficiency, light weight, and reliability of hydrogen energy electrochemical equipment are among the future development directions. Membrane electrode assemblies (MEAs) and electrolyzers, as key components, have structures and strengths that determine the efficiency of their power generation and the hydrogen production efficiency of electrolyzers. This article summarizes the evolution of membrane electrode and electrolyzer structures, and their power and efficiency in recent years, highlighting the significant role of integrated structures in promoting proton transport and enhancing performance. Finally, it proposes the development direction of integrating electrolyte and electrode manufacturing using phase-change methods. Full article

This study evaluates the techno-economic feasibility of integrating wind power with hydrogen-based storage to decarbonize the Raglan Mine in northern Canada. Using HOMER simulations with real 2021 operational data, six progressive scenarios were modeled, ranging from partial substitution of diesel generators to complete site-wide electrification, including heating, transport, and mining equipment. Results show that complete decarbonization (Scenario 6) is technically achievable and could avoid up to 143,000 tCO₂eq annually (~2.15 Mt over 15 years), but remains economically prohibitive under current technology costs. In contrast, Scenario 2 Case 2, which combines solid oxide fuel cells with thermal charge controllers, emerges as the most viable near-term pathway, avoiding ~61,000 tCO₂eq annually (~0.91 Mt over 15 years) while achieving improved return on investment. A qualitative multi-criteria framework highlights this configuration as the best trade-off between technical feasibility, environmental performance, and economic viability. At the same time, complete decarbonization remains a longer-term target contingent on cost reductions and policy support. Overall, the findings provide clear evidence that hydrogen storage, when coupled with wind power, can deliver substantial and measurable decarbonization benefits for Arctic mining operations. Full article

Hydrogen is increasingly recognized as a clean energy vector and storage medium, yet its viability and strategic role in the Western Balkans remain underexplored. This study provides the first comprehensive techno-economic, environmental, and strategic evaluation of hydrogen production pathways in Albania. Results show clear trade-offs across options. The levelized cost of hydrogen (LCOH) is estimated at 8.76 €/kg H₂ for grid-connected, 7.75 €/kg H₂ for solar, and 7.66 €/kg H₂ for wind electrolysis—values above EU averages and reliant on lower electricity costs and efficiency gains. In contrast, fossil-based hydrogen via steam methane reforming (SMR) is cheaper at 3.45 €/kg H₂, rising to 4.74 €/kg H₂ with carbon capture and storage (CCS). Environmentally, Life Cycle Assessment (LCA) results show much lower Global Warming Potential (<1 kg CO₂-eq/kg H₂) for renewables compared with ~10.39 kg CO₂-eq/kg H₂ for SMR, reduced to 3.19 kg CO₂-eq/kg H₂ with CCS. However, grid electrolysis dominated by hydropower entails high water-scarcity impacts, highlighting resource trade-offs. Strategically, Albania’s growing solar and wind projects (electricity prices of 24.89–44.88 €/MWh), coupled with existing gas infrastructure and EU integration, provide strong potential. While regulatory gaps and limited expertise remain challenges, competition from solar-plus-storage, regional rivals, and dependence on external financing pose additional risks. In the near term, a transitional phase using SMR + CCS could leverage Albania’s gas assets to scale hydrogen production while renewables mature. Overall, Albania’s hydrogen future hinges on targeted investments, supportive policies, and capacity building aligned with EU Green Deal objectives, with solar-powered electrolysis offering the potential to deliver environmentally sustainable green hydrogen at costs below 5.7 €/kg H₂. Full article

This article examines the growing potential of low-emission hydrogen as an innovative solution supporting the decarbonization of the agricultural sector. It discusses its potential applications on farms, including as an energy source for powering agricultural machinery, producing fertilizers, and storing energy from renewable sources. Within the European context, it considers actions arising from the European Green Deal and the “Fit for 55” strategy, which promote the development of hydrogen infrastructure and support research into low-emission technologies. The article also discusses global initiatives and trends in the development of the hydrogen economy, pointing to international cooperation, investment, and the need for technology standardization. It highlights the challenges related to cost, infrastructure, and scalability, as well as the opportunities hydrogen offers for a sustainable and energy-efficient agriculture of the future. Full article

Methane pyrolysis produces hydrogen (H₂) with solid carbon black as a co-product, eliminating direct CO₂ emissions and enabling a low-carbon supply when combined with renewable or low-carbon heat sources. In this study, we propose a hybrid geothermal pyrolysis configuration in which an enhanced geothermal system (EGS) provides base-load preheating and isothermal holding, while either electrical or solar–thermal input supplies the final temperature rise to the catalytic set-point. The work addresses four main objectives: (i) integrating field-scale geothermal operating envelopes to define heat-integration targets and duty splits; (ii) assessing scalability through high-pressure reactor design, thermal management, and carbon separation strategies that preserve co-product value; (iii) developing a techno-economic analysis (TEA) framework that lists CAPEX and OPEX, incorporates carbon pricing and credits, and evaluates dual-product economics for hydrogen and carbon black; and (iv) reorganizing state-of-the-art advances chronologically, linking molten media demonstrations, catalyst development, and integration studies. The process synthesis shows that allocating geothermal heat to the largest heat-capacity streams (feed, recycle, and melt/salt hold) reduces electric top-up demand and stabilizes reactor operation, thereby mitigating coking, sintering, and broad particle size distributions. High-pressure operation improves the hydrogen yield and equipment compactness, but it also requires corrosion-resistant materials and careful thermal-stress management. The TEA indicates that the levelized cost of hydrogen is primarily influenced by two factors: (a) electric duty and the carbon intensity of power, and (b) the achievable price and specifications of the carbon co-product. Secondary drivers include the methane price, geothermal capacity factor, and overall conversion and selectivity. Overall, geothermal-assisted methane pyrolysis emerges as a practical pathway to turquoise hydrogen, if the carbon quality is maintained and heat integration is optimized. The study offers design principles and reporting guidelines intended to accelerate pilot-scale deployment. Full article

Environmental pollution caused by shipping has always received great attention from the international community. Currently, due to the difficulty of fully electrifying medium- and large-scale ships, the hybrid energy ship power system (HESPS) will be the main type in the future. Considering the economic and long-term energy efficiency of ships, as well as the uncertainty of the output power of renewable energy units, this paper proposes an improved design for an integrated power system for large cruise ships, combining renewable energy and a hybrid energy storage system. An energy management strategy (EMS) based on time-gradient control and considering load dynamic response, as well as an energy storage power allocation method that considers the characteristics of energy storage devices, is designed. A bi-level power capacity optimization model, grounded in comprehensive scenario planning and aiming to optimize maximum return on equity, is constructed and resolved by utilizing an improved particle swarm optimization algorithm integrated with dynamic programming. Based on a large-scale cruise ship, the aforementioned method was investigated and compared to the conventional planning approach. It demonstrates that the implementation of this optimization method can significantly decrease costs, enhance revenue, and increase the return on equity from 5.15% to 8.66%. Full article

Today, hydrogen is already widely regarded as up-and-coming source of energy. It is essential to meet energy needs while reducing environmental pollution, since it has a high energy capacity and does not emit carbon oxide when burned. However, for the widespread application of hydrogen energy, it is necessary to search new technical solutions for both its production and storage. A promising effective and cost-efficient method of hydrogen generation and storage can be the use of solid materials, including nanomaterials in which chemical or physical adsorption of hydrogen occurs. Focusing on the recommendations of the DOE, the search is underway for materials with high gravimetric capacity more than 6.5% wt% and in which sorption and release of hydrogen occurs at temperatures from −20 to +100 °C and normal pressure. This review aims to summarize research on hydrogen generation and storage using silicon nanostructures and silicon composites. Hydrogen generation has been observed in Si nanoparticles, porous Si, and Si nanowires. Regardless of their size and surface chemistry, the silicon nanocrystals interact with water/alcohol solutions, resulting in their complete oxidation, the hydrolysis of water, and the generation of hydrogen. In addition, porous Si nanostructures exhibit a large internal specific surface area covered by SiH_x bonds. A key advantage of porous Si nanostructures is their ability to release molecular hydrogen through the thermal decomposition of SiHx groups or in interaction with water/alkali. The review also covers simulations and theoretical modeling of H₂ generation and storage in silicon nanostructures. Using hydrogen with fuel cells could replace Li-ion batteries in drones and mobile gadgets as more efficient. Finally, some recent applications, including the potential use of Si-based agents as hydrogen sources to address issues associated with new approaches for antioxidative therapy. Hydrogen acts as a powerful antioxidant, specifically targeting harmful ROS such as hydroxyl radicals. Antioxidant therapy using hydrogen (often termed hydrogen medicine) has shown promise in alleviating the pathology of various diseases, including brain ischemia–reperfusion injury, Parkinson’s disease, and hepatitis. Full article

The decarbonization of hard-to-defossilize sectors, such as international maritime transport, requires innovative, and at times disruptive, energy solutions that combine efficiency, scalability, and climate benefits. Therefore, power-to-liquid (PtL) routes have stood out for their potential to use low-emission electricity for the production of synthetic fuels, via electrolytic hydrogen and CO₂ capture. However, the high energy demand inherent to these routes poses significant challenges to large-scale implementation. Moreover, PtL routes are usually at most neutral in terms of CO₂ emissions. This study evaluates, from a thermo-energetic perspective, the optimization potential of an e-methanol synthesis route through integration with a biomass oxy-fuel combustion process, making use of electrolytic oxygen as the oxidizing agent and the captured CO₂ as the carbon source. From the standpoint of a first-law thermodynamic analysis, mass and energy balances were developed considering the full oxygen supply for oxy-fuel combustion to be met through alkaline electrolysis, thus eliminating the energy penalty associated with conventional oxygen production via air separation units. The balance closure was based on a small-scale plant with a capacity of around 100 kta of methanol. In this integrated configuration, additional CO₂ surpluses beyond methanol synthesis demand can be directed to geological storage, which, when combined with bioenergy with carbon capture and storage (BECCS) strategies, may lead to net negative CO₂ emissions. The results demonstrate that electrolytic oxygen valorization is a promising pathway to enhance the efficiency and climate performance of PtL processes. Full article