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26 pages, 8865 KiB  
Article
Multiscale Geometric Characterization and Discrimination of Dermatoglyphs (Fingerprints) on Hardened Clay—A Novel Archaeological Application of the GelSight Max
by Katarzyna Peta, W. James Stemp, Tera Stocking, Richard Chen, George Love, Matthew A. Gleason, Brett A. Houk and Christopher A. Brown
Materials 2025, 18(13), 2939; https://doi.org/10.3390/ma18132939 - 21 Jun 2025
Cited by 2 | Viewed by 1373
Abstract
A relatively new GelSight Max measurement instrument was applied to the microtopographies of experimental hardened clay surfaces, both with and without fingerprint (dermatoglyph) impressions, and the surface of an archaeological pottery handle fragment with a preserved fingerprint (paleodermatoglyph). The experimental clay surfaces were [...] Read more.
A relatively new GelSight Max measurement instrument was applied to the microtopographies of experimental hardened clay surfaces, both with and without fingerprint (dermatoglyph) impressions, and the surface of an archaeological pottery handle fragment with a preserved fingerprint (paleodermatoglyph). The experimental clay surfaces were documented in order to determine the instrument’s ability to capture these surfaces in three-dimensions by imprinting them onto an elastomeric tactile membrane. Fingerprints on the experimental hardened clay and the archaeological pottery fragment were mathematically documented to test this instrument’s ability to capture these impressions. The surface texture measurements of the hardened clay and the pottery fragment were mathematically compared using conventional topographic characterization parameters (height and hybrid), fractal dimensions (Das) with associated coefficients of determination (R2), and multiscalar geometric characterization parameters, particularly relative area (Srel), area-scale complexity (Asfc), relative length (RL), and length-scale complexity (Lsfc). The surfaces of the experimental hardened clay with and without fingerprints and the archaeological pottery handle fragment with a fingerprint can be discriminated using some conventional height parameters, as well as some multiscale geometric topographic characterization parameters. Specifically, relative area (Srel), area-scale complexity (Asfc), relative length (RL), and length-scale complexity (Lsfc) could all discriminate between the hardened clay block with and without fingerprints and the fingerprint on the archaeological pottery handle fragment at different scales of measurement. Mean square ratios (MSRs) above 90% and 95% confidence levels indicated that the discrimination of these multiscale geometric characterizations was significant. In sum, the GelSight Max has the potential to be a valuable instrument for archaeologists studying pottery and fingerprints. Full article
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25 pages, 5689 KiB  
Article
Compositional Analysis of Longshan Period Pottery and Ceramic Raw Materials in the Yongcheng Region, Henan Province
by Linyu Xia, Yinhong Li, Ge Zhang, Jialing Li and Li Jaang
Materials 2025, 18(12), 2681; https://doi.org/10.3390/ma18122681 - 6 Jun 2025
Viewed by 594
Abstract
This study systematically analyzes the composition and microstructure of Neolithic pottery unearthed from the Dazhuzhuang, Likou, and Biting Sites in the Yongcheng District using techniques such as X-ray fluorescence spectroscopy (XRF), X-ray diffraction (XRD), infrared spectroscopy (IR), and scanning electron microscopy with energy-dispersive [...] Read more.
This study systematically analyzes the composition and microstructure of Neolithic pottery unearthed from the Dazhuzhuang, Likou, and Biting Sites in the Yongcheng District using techniques such as X-ray fluorescence spectroscopy (XRF), X-ray diffraction (XRD), infrared spectroscopy (IR), and scanning electron microscopy with energy-dispersive spectroscopy (SEM-EDS). The results show that although the raw materials for pottery at the three sites were likely sourced from nearby ancient soil layers, significant differences in chemical composition and manufacturing techniques are evident. Pottery from the Dazhuzhuang Site is mainly composed of argillaceous gray pottery, with relatively loose raw material selection and a wide fluctuation in SiO2 content (64.98–71.07%), reflecting diversity in raw material sources. At the Likou Site, argillaceous black pottery predominates, characterized by higher Al2O3 content (17.78%) and significant fluctuations in CaO content (1.46–2.22%), suggesting the addition of calcareous fluxes and the adoption of standardized manufacturing techniques. Pottery from the Biting Site mainly consists of argillaceous gray pottery, showing higher Al2O3 content (17.36%), stable SiO2 content (65.19–69.01%), and the lowest CaO content (0.84–1.81%). The microstructural analysis further reveals that the black pottery (from the Likou Site) displays dense vitrified regions and localized iron enrichment. In contrast, the gray pottery (from the Dazhuzhuang and Biting Sites) shows clay platelet structures and vessel-type-specific differences in porosity. This research provides important scientific evidence for understanding raw material selection, manufacturing techniques, and regional cultural interactions in the Yongcheng area during the Longshan Culture period. Full article
(This article belongs to the Special Issue Materials in Cultural Heritage: Analysis, Testing, and Preservation)
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21 pages, 35065 KiB  
Article
A Provenance Study of Ceramic Artifacts from the Area of Makariopolsko Village, NE Bulgaria
by Bilyana Kostova, Svetlana Todorova, Katerina Mihaylova, Chavdar Lalov and Ralitza Berberova
Geosciences 2025, 15(6), 193; https://doi.org/10.3390/geosciences15060193 - 22 May 2025
Viewed by 420
Abstract
The Roman site at Makariopolsko village in Northeastern Bulgaria has been identified as a ceramic production center, featuring single- and double-chamber kilns, abundant ceramic material, and a nearby water source. Geological assessments also reveal local clay deposits. Previous archaeological studies have noted similar [...] Read more.
The Roman site at Makariopolsko village in Northeastern Bulgaria has been identified as a ceramic production center, featuring single- and double-chamber kilns, abundant ceramic material, and a nearby water source. Geological assessments also reveal local clay deposits. Previous archaeological studies have noted similar Roman production sites in the region, primarily focusing on the study of the kilns and the macroscopic description and classification of the ceramics. However, there has been a lack of research into the pottery’s composition and the sourcing of raw materials, which is essential for understanding the area’s cultural and economic context. This study aims to determine the raw material and firing temperature of the ceramic from the site at Makariopolsko village. Clay samples (both raw and fired at 1100 °C) and ceramic were subjected to chemical, statistical, phase X-ray structural, and thermal analyses. The findings indicate the use of calcareous illite–kaolinitic clay, sourced locally, with an added sandy component. The ceramics were fired at temperatures of 570–760 °C and 920–945 °C. These results, which support the site’s identification as a pottery production center, highlight advanced pottery skills and the dual functional capabilities of the kilns. Additionally, they pave the way for further research into regional production center relationships. Full article
(This article belongs to the Section Geoheritage, Geoparks and Geotourism)
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18 pages, 10811 KiB  
Article
Compositional Analysis of Cultic Clay Objects from the Iron Age Southern Levant
by David Ben-Shlomo
Religions 2025, 16(6), 661; https://doi.org/10.3390/rel16060661 - 22 May 2025
Viewed by 561
Abstract
Compositional analysis conducted on pottery and other ceramic items can shed light on their place of production and in certain cases, on technological aspects of the production sequence. The methods used, petrography and chemical analysis, can also be employed on cultic terracotta such [...] Read more.
Compositional analysis conducted on pottery and other ceramic items can shed light on their place of production and in certain cases, on technological aspects of the production sequence. The methods used, petrography and chemical analysis, can also be employed on cultic terracotta such as figurines, cult stands, models, or other clay objects. Several studies of such analyses of items from various periods in the Southern Levant have been published, mostly from temple contexts. This paper focuses particularly on two groups of items: clay models from the favissa at Yavneh and pillar figurines and other (mostly horse) figurines from Jerusalem and Tell en-Nasbeh in Iron Age Judah. These two groups are both roughly dated to the time span between the 9th and 7th centuries BCE. While the former group is of objects representing a temple context in Philistia, the latter is likely related to a domestic cult in Judah. The analysis of these objects is also examined against the background of a robust compositional analysis of regular pottery from the sites. The compositional analysis can indicate whether these objects were locally produced or imported from various regions (thus possibly brought by pilgrims), as well as whether they were “mass-produced” in a single workshop. The results can shed light on aspects of religious and cultic conducts in these occasions as well as compare domestic and temple-related cultic behaviors. Full article
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51 pages, 41402 KiB  
Article
A Digitally Enhanced Ethnography for Craft Action and Process Understanding
by Xenophon Zabulis, Partarakis Nikolaos, Vasiliki Manikaki, Ioanna Demeridou, Arnaud Dubois, Inés Moreno, Valentina Bartalesi, Nicolò Pratelli, Carlo Meghini, Sotiris Manitsaris and Gavriela Senteri
Appl. Sci. 2025, 15(10), 5408; https://doi.org/10.3390/app15105408 - 12 May 2025
Viewed by 947
Abstract
Traditional ethnographic methods have long been employed to study craft practices, yet they often fall short of capturing the full depth of embodied knowledge, material interactions, and procedural workflows inherent in craftsmanship. This paper introduces a digitally enhanced ethnographic framework that integrates Motion [...] Read more.
Traditional ethnographic methods have long been employed to study craft practices, yet they often fall short of capturing the full depth of embodied knowledge, material interactions, and procedural workflows inherent in craftsmanship. This paper introduces a digitally enhanced ethnographic framework that integrates Motion Capture, 3D scanning, audiovisual documentation, and semantic knowledge representation to document both the tangible and dynamic aspects of craft processes. By distinguishing between endurant (tools, materials, objects) and perdurant (actions, events, transformations) entities, we propose a structured methodology for analyzing craft gestures, material behaviors, and production workflows. The study applies this proposed framework to eight European craft traditions—including glassblowing, tapestry weaving, woodcarving, porcelain pottery, marble carving, silversmithing, clay pottery, and textile weaving—demonstrating the adaptability of digital ethnographic tools across disciplines. Through a combination of multimodal data acquisition and expert-driven annotation, we present a comprehensive model for craft documentation that enhances the preservation, education, and analysis of artisanal knowledge. This research contributes to the ongoing evolution of ethnographic methods by bridging digital technology with Cultural Heritage studies, offering a robust framework for understanding the mechanics and meanings of craft practices. Full article
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21 pages, 12646 KiB  
Article
Visual Localization and Path Planning for a Dual-Arm Collaborative Pottery Robot
by Wei Zhang, Xirui Feng, Liangyu Cao, Tuo Wang, Guina Wang and Yiyang Chen
Symmetry 2025, 17(4), 532; https://doi.org/10.3390/sym17040532 - 31 Mar 2025
Viewed by 588
Abstract
The convergence of art and technology represents an emerging trend, and it has become crucial to apply advanced technologies to traditional art forms in order to drive innovation in the way art is created, experienced, and understood. The aim of this paper is [...] Read more.
The convergence of art and technology represents an emerging trend, and it has become crucial to apply advanced technologies to traditional art forms in order to drive innovation in the way art is created, experienced, and understood. The aim of this paper is to explore new paths for the integration of art and technology through the development of a symmetric dual-arm collaborative ceramics robot, thereby facilitating the automation and technologization of ceramics creation. This study utilizes machine vision techniques and path planning algorithms. Specifically, machine vision technology is utilized to identify and locate the clay embryos and to complete the production of purple clay teapots through dual-arm collaboration. The successful application of the pottery robot proves the possibility of art-enabling technology, which helps to promote the innovative development of the entire art field and broaden the forms and boundaries of artistic expression. Full article
(This article belongs to the Section Computer)
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11 pages, 6234 KiB  
Article
Where Did Vessels Come from? A Study of Pottery Provenance from the Site of Velika Humska Čuka, Serbia
by Maja Gajić-Kvaščev, Ognjen Mladenović, Petar Milojević and Aleksandar Bulatović
Materials 2025, 18(5), 1083; https://doi.org/10.3390/ma18051083 - 28 Feb 2025
Cited by 1 | Viewed by 760
Abstract
The archaeological materials from the Velika Humska Čuka site on the northern fringe of the Niš Basin in southeastern Serbia were analyzed to reveal the provenance of ceramics and other artifacts. This study focused on the elemental analysis of 61 samples, including local [...] Read more.
The archaeological materials from the Velika Humska Čuka site on the northern fringe of the Niš Basin in southeastern Serbia were analyzed to reveal the provenance of ceramics and other artifacts. This study focused on the elemental analysis of 61 samples, including local clay pits, potsherds, and whole vessels. Samples were chosen based on stylistic and typological characteristics to distinguish local and “foreign” pottery. Elemental analysis was conducted using energy-dispersive X-ray fluorescence (EDXRF) spectrometry, complemented by principal component analysis (PCA) for data interpretation. Results indicated that the majority of pottery samples, over 80%, were produced using local clay from deposits near the site. However, approximately 20% of the analyzed vessels were made using clay from deposits near the Bubanj site, 8 km south of Velika Humska Čuka. A vessel on a hollow high foot combining stylistic elements of the Bubanj-Hum I group and Early Eneolithic Pannonian groups was made of clay not sourced from any identified local deposits, suggesting its non-local origin. While the predominance of local materials suggests self-sufficient production, the use of non-local clays and stylistic influences highlights long-distance connections and exchanges. The study emphasizes the importance of Velika Humska Čuka in understanding the development of ceramic traditions and the cultural dynamics of the Early Eneolithic in the Central Balkans. Full article
(This article belongs to the Special Issue Materials in Cultural Heritage: Analysis, Testing, and Preservation)
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26 pages, 17771 KiB  
Article
From Andalusia to the Atlantic During Early Globalization: Multidisciplinary Archaeometric Approach to Ceramic Production from Jerez de la Frontera (Spain)
by Saúl Guerrero Rivero, Javier G. Iñañez, Fernando Amores Carredano, Joana B. Torres, André Teixeira, Gorka Arana and José Luis Sánchez Zavala
Ceramics 2025, 8(1), 20; https://doi.org/10.3390/ceramics8010020 - 24 Feb 2025
Viewed by 913
Abstract
The technological development of ceramic production during the early modern period in the Iberian Peninsula is a crucial topic in historical archaeological research. The present study analyzes pottery from Jerez de la Frontera, Andalusia, focusing on ceramic materials from the Convent of Santo [...] Read more.
The technological development of ceramic production during the early modern period in the Iberian Peninsula is a crucial topic in historical archaeological research. The present study analyzes pottery from Jerez de la Frontera, Andalusia, focusing on ceramic materials from the Convent of Santo Domingo (late 15th to early 17th centuries). Through the analysis of production wastes, including dolia and olive jars (botijas), this text unveils key aspects of regional ceramics practices. Using a multidisciplinary archaeometric approach, we applied petrography, X-ray diffraction (XRD), and inductively coupled plasma mass spectrometry (ICP-MS) to investigate compositional, technological, and provenance characteristics. The petrographic analysis identified clay matrix variability and mineral inclusions, indicating diverse raw material sources and production techniques. The XRD analysis confirmed key mineral phases that reflect controlled firing temperatures, while the ICP-MS analyses provided trace element profiles that were used to distinguish between local and non-local raw materials. Together, these results reveal technological shifts and resource diversity over time, challenging the assumption that Seville was the sole supplier of ceramics for Atlantic trade. This study establishes Jerez as a potential complementary production center, offering a new understanding of early globalization processes and ceramics manufacturing in southwestern Andalusia. Full article
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21 pages, 8676 KiB  
Article
Glazed Pottery Throughout the Middle and Modern Ages in Northern Spain
by Ainhoa Alonso-Olazabal, Juan Antonio Quirós Castillo, Maria Cruz Zuluaga and Luis Ángel Ortega
Heritage 2025, 8(1), 24; https://doi.org/10.3390/heritage8010024 - 10 Jan 2025
Viewed by 970
Abstract
A total of forty samples of medieval and modern glazed pottery from northern Spain were studied. Chemical and microstructural analyses of the glazes were performed by scanning electron microscopy coupled with electron dispersive spectroscopy (SEM-EDX), while the chemical composition of the pottery bodies [...] Read more.
A total of forty samples of medieval and modern glazed pottery from northern Spain were studied. Chemical and microstructural analyses of the glazes were performed by scanning electron microscopy coupled with electron dispersive spectroscopy (SEM-EDX), while the chemical composition of the pottery bodies and slips were determined by X-ray Fluorescence (XRF). The glazes studied come from the Santa Barbara Hill site (Tudela), the Treviño Castle site (Treviño), the Vega workshop (Burgos) and the Torrentejo village (Labastida) and correspond to transparent glazes and opaque white glazes. Transparent glazes were lead glazes with variable PbO content. Opaque white glazes were lead-tin and lead–alkaline–tin glazes. The glaze was mainly applied to a pre-fired body made of local clays, but the glazes of the Santa Barbara Hills pottery (Tudela) were applied to raw bodies. The microstructure of the interfaces indicates a single firing process for the glazed pottery from Tudela and a double firing process in the rest of the sites. Some correlation are identified between the use of specific clays to produce different glaze colours. White opaque glazes are applied to calcium-rich clays. Similarly, calcium-rich clays were used to produce dark green transparent glazes, while clays and slips aluminium–rich were used to produce light green and light honey glazes. Iron was also identified as the main colouring agent, although copper was also used. The white glazes were opacified by the addition of cassiterite and sometimes quartz and feldspar. The glazed pottery was mainly of local origin, but the identification of some non-local pottery at all sites suggests a pottery trade. Full article
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45 pages, 14544 KiB  
Article
Intelligent Pottery Wheel Machine Design: Enhancing Pottery Throwing Quality and Efficiency
by Yilun Wang, Xunchen Liu, Lijuan Fu, Bo Mu, Mingzhang Chen, Hailin Wu, Kang Dong and Xuejie Sun
Appl. Sci. 2024, 14(17), 7989; https://doi.org/10.3390/app14177989 - 6 Sep 2024
Cited by 2 | Viewed by 3121
Abstract
The pottery wheel machine is an essential piece of equipment in ceramics manufacturing. This paper presents the design of an intelligent pottery wheel machine aimed at addressing the issues of low clay material utilization and the challenges of pottery throwing operations. Traditional techniques [...] Read more.
The pottery wheel machine is an essential piece of equipment in ceramics manufacturing. This paper presents the design of an intelligent pottery wheel machine aimed at addressing the issues of low clay material utilization and the challenges of pottery throwing operations. Traditional techniques require exceptional craftsmanship and proficient mechanical operation, and existing pottery wheel machines still demand attention to equipment usage and clay material knowledge. The intelligent pottery wheel machine integrates central positioning, automatic clay feeding, and clay storage. The pull mechanism stores and precisely feeds clay, regulating usage and minimizing excess. The automated settings of the clay storage and power push system replace the need for manual assessment of clay density and quality, ensuring balanced and high-quality clay extrusion. The continuous feeding setting allows for automatic addition of clay, saving replenishment time and reducing the labor intensity of adding clay. The lifting mechanism ensures that the clay body remains centered, avoiding repeated manual adjustments and allowing users to focus on creating pottery rather than spending excessive time mastering the centering technique. The machine’s lightweight, modular design reduces clay waste, making the process more sustainable. By saving clay materials and improving throwing efficiency, it enhances the success rate of throwing. Full article
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23 pages, 3097 KiB  
Systematic Review
Innovations in Clay-Based Irrigation Technologies—A Systematic Review
by Evgenia Mahler
Sustainability 2024, 16(16), 7029; https://doi.org/10.3390/su16167029 - 16 Aug 2024
Cited by 2 | Viewed by 2732
Abstract
Arid and semi-arid areas are suffering from declines in fresh water availability, making food security in these regions strongly dependent on the adaptability of agricultural production to the minimum usage of irrigation water. In response to this critical need, efforts have been directed [...] Read more.
Arid and semi-arid areas are suffering from declines in fresh water availability, making food security in these regions strongly dependent on the adaptability of agricultural production to the minimum usage of irrigation water. In response to this critical need, efforts have been directed towards enhancing irrigation efficiency and exploring innovative clay-based subsurface irrigation systems. These systems use clay materials as porous emitters and operate on the principle of capillary water movement from the pottery to the root zone, effectively reducing water evaporation and demonstrating significant water-saving potential. This article presents the results of a systematic literature review, with a specific focus on identifying recent developments and innovations in clay-based subsurface irrigation technologies, describing cases of applicability and indicating directions for future research. This review follows the Preferred Reporting Items for Systematic Reviews and Meta-Analyses (PRISMA) guidelines and involved the screening of 233 articles that were found through searches on the databases Web of Science and Science Direct combined with searches of Google Scholar and citation searches. As a result, 58 research articles were investigated. The webtool Rayyan was used for the screening of the articles and the synthesis of the results. The spectrum of clay-based irrigation systems identified in the investigated articles includes traditional methods such as clay pot and clay pipe irrigation as well as more recent advancements in the field such as Subsurface Irrigation with Ceramic Emitters (SICE), Self-regulating Low-Energy Clay-based Irrigation (SLECI), and Ceramic Patch Subsurface Drip Irrigation Line (CP-SDIL) and pottery dripper technologies. This paper offers a comprehensive analysis of each irrigation system, highlighting their main characteristics, advantages, and limitations. Particular attention is paid to the reported outcomes related to yield responses, water use efficiency, and suitability for various agricultural applications. This review indicates as a primary benefit of these systems their potential to allow water conservation, which is especially advantageous in regions with a restricted irrigation water supply. However, a major drawback is the challenge of scaling these systems effectively. Hence, the recommended areas for future research centre on the necessity of substantial economic assessments of and discussion on the potential social impact to promote the scalability of clay-based irrigation systems. Full article
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27 pages, 6545 KiB  
Article
Compositional and Microstructural Investigations of Prehistoric Ceramics from Southern Romania (Middle Neolithic Pottery)
by Rodica-Mariana Ion, Ancuta-Elena Pungoi, Lorena Iancu, Ramona Marina Grigorescu, Gabriel Vasilievici, Anca Irina Gheboianu, Sofia Slamnoiu-Teodorescu and Elvira Alexandrescu
Appl. Sci. 2024, 14(13), 5755; https://doi.org/10.3390/app14135755 - 1 Jul 2024
Cited by 1 | Viewed by 2287
Abstract
In this paper, based on our previous expertise on ceramic artifacts, several archaeometric methods applied to some samples collected from the Dudești archaeological site (Oltenia region, Romania) are reported for the first time in the literature. The chemical composition, and microstructural and morphological [...] Read more.
In this paper, based on our previous expertise on ceramic artifacts, several archaeometric methods applied to some samples collected from the Dudești archaeological site (Oltenia region, Romania) are reported for the first time in the literature. The chemical composition, and microstructural and morphological characterization of these samples offer important conclusions about the processing conditions. Some specific techniques such as X-ray diffraction (XRD), wavelength-dispersive X-ray fluorescence (WDXRF), optical microscopy (OM), stereomicroscopy, environmental scanning electron microscopy (ESEM), Fourier-transform infrared spectroscopy (FTIR), and Raman spectroscopy provide compositional information about composition and the decay processes. Additionally, the Brunauer–Emmett–Teller (BET) method helps to estimate pore sizes and specific surface areas. A thermogravimetric analysis (TGA/TDG) was used to establish details regarding the production technology and also the raw materials source used to make the ceramics. The obtained results indicated that the ceramics are based on a paste of muscovite and feldspar, with high plasticity, together with quartz and hematite/goethite and calcite, the latter in very low concentrations. According to the obtained results, we could assume that clays from the investigated samples had a low concentration of calcium. Gypsum is present as paste in a very low concentration, identified by the presence of a sulphate group in WDXRF. In the same context, iron oxides have a significant impact on the firing atmosphere of iron-rich clay, resulting in blackening under reducing conditions and a reddish coloration under oxidative conditions. The use of hematite and gypsum as pigments further contributes to the color variations in the pottery. The consistent firing temperature range of 200–600 °C in Dudești pottery implies a standardized production process, the variation in color being dependent on the specific reducing/oxidative regime conditions (reducing atmosphere followed by rapid oxidation). This relationship between clay composition and local sources suggests a connection to Neolithic pottery production in the region and their color depending on the reducing/oxidative regime conditions. Full article
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20 pages, 4170 KiB  
Article
Autochthonous or Allochthonous, the Prehistoric Pottery of Cueva de Los Postes
by Virginia Lattao, Sara Garcês, Hugo Gomes, Pierluigi Rosina and Hipólito Collado
Appl. Sci. 2024, 14(11), 4706; https://doi.org/10.3390/app14114706 - 30 May 2024
Viewed by 1170
Abstract
Cueva de Los Postes is located in the southern part of the Spanish Extremadura region, in the Fuentes de León municipality. This study analyzed pottery found during archaeological excavations in Cueva de Los Postes. The aim was to determine whether the raw materials [...] Read more.
Cueva de Los Postes is located in the southern part of the Spanish Extremadura region, in the Fuentes de León municipality. This study analyzed pottery found during archaeological excavations in Cueva de Los Postes. The aim was to determine whether the raw materials had common or separate origins and determine whether or not the origin of the pottery raw material was regional. In this regard, several pottery fragments were found in different phases (Neolithic and Copper Age) of the Holocene occupation of Cueva de Los Postes. These were analyzed using ATR-FTIR (Fourier Transform Infrared spectroscopy). The analyzed samples demonstrated no strong differences in their composition. In order to identify a possible origin for the kaolinite of the analyzed pottery, six samples of clay sediments were taken from inside and around the cave and subjected to ATR-FTIR. This was done to compare their compositions and check for a possible correlation with the pottery. The analyzed pottery, from different stratigraphic units, shows homogeneity in raw material. This finding, and the analyses made of the regional sediments, confirm that the raw material was regional and that there was a continuous use of it. Full article
(This article belongs to the Special Issue Novel Ceramic Materials: Processes, Properties and Applications)
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14 pages, 3276 KiB  
Article
Mineralogical Characterization of Raw Clay from Rujište (Serbia) Used in Traditional Pottery Manufacture
by Maja Milošević, Predrag Dabić, Jelena Gulicovski, Vladimir Dodevski and Milena Rosić
Minerals 2024, 14(5), 469; https://doi.org/10.3390/min14050469 - 28 Apr 2024
Cited by 2 | Viewed by 2162
Abstract
The pottery produced from the Rujište deposit in Serbia has been protected under the guidance of UNESCO and the Sector for Intangible Cultural Heritage of Serbia since 2019. A study was conducted to evaluate the mineralogical characteristics of the raw clay from this [...] Read more.
The pottery produced from the Rujište deposit in Serbia has been protected under the guidance of UNESCO and the Sector for Intangible Cultural Heritage of Serbia since 2019. A study was conducted to evaluate the mineralogical characteristics of the raw clay from this deposit. This study used various techniques, such as X-ray diffraction (XRD), infrared (IR) spectroscopy, X-ray fluorescence (XRF), and differential thermal analysis (DTA) to characterize the clay. This study found that the clay contained mostly clay minerals (56.3%–41.9%), with illite, smectite, and chlorite as the predominant phases. Other phases identified were quartz, feldspars, carbonates, and iron-bearing minerals (43.8%–58.1%). The chemical analyses revealed a high abundance of silica (>52 wt.%) and alumina (~16 wt.%), with Fe2O3 (~6 wt.%), K2O (~2.8 wt.%), and a similar content of MgO as the main constituents. The physical features that were investigated included the granulometry (clay: ~31%–44%, silt: ~ 26%–23%, and sand: ~ 42%–32%), specific surface area (97 to 107 m2 g−1), cation exchange capacity (12.5–13.7 mmol 100 g−1), and color (yellowish to moderate brown). The preliminary results suggest that most of the raw clay from the Rujište deposit might be suitable for use in traditional pottery manufacture. Full article
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14 pages, 2996 KiB  
Article
An Archaeometric Study of the Iron Age Ceramics from Quinta do Almaraz Archaeologic Site (8th to 5th Centuries BC)—Colour and Mineralogical Characterization
by Luis Filipe Vieira Ferreira, Ana Olaio, Manuel Francisco Costa Pereira and Isabel Luisa Ferreira Machado
Colorants 2024, 3(2), 111-124; https://doi.org/10.3390/colorants3020008 - 25 Apr 2024
Cited by 1 | Viewed by 1953
Abstract
The ceramic pastes of ca. 31 samples recovered from the Almaraz archaeological site, located in the south bench of Tagus River, were studied in detail using XRF, micro-Raman and GSDR spectroscopies, as well as the XRD technique. The ceramic sherds could be grouped [...] Read more.
The ceramic pastes of ca. 31 samples recovered from the Almaraz archaeological site, located in the south bench of Tagus River, were studied in detail using XRF, micro-Raman and GSDR spectroscopies, as well as the XRD technique. The ceramic sherds could be grouped into six categories, red slip tableware, decorated tableware, yellow slip tableware, grey tableware, common tableware, and handmade pottery. Our studies of the mineralogic composition of the sherds’ body indicate all ceramics were produced locally, using siliceous clays in most cases and calcareous clays in a few ones. Micro-Raman and ground state diffuse reflectance absorption spectroscopy provided useful information regarding the materials used to produce the coloured ceramics: hematite and brookite for the red slip and decorated ceramics, jacobsite or carbon black for the black decoration or grey ceramics. For the yellow slip tableware, a simple engobe rich in yellow clay was used. XRF spectroscopic studies provided the elemental composition of all samples, and biplots of the potassium (K) versus calcium (Ca) contents, normalized to the silicon content of each ceramic paste, clearly show Pliocene and Miocene local clays sources were used to produce most ceramics. Only one sherd can be considered a Lisbon production. Full article
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