Search Results (30)

Biochar is a soil amendment that has the potential to effectively improve soil salinization. However, there is a paucity of studies on sodium adsorption using biochar, and the adsorption mechanism remains unclear. To better understand the adsorption mechanism of Na⁺ on the surface of biochar, both pyrochar and hydrochar were produced at different temperatures. The capacity and influencing factors of Na⁺ adsorption in biochar were analyzed via batch adsorption experiments. Pore filling dominated the Na⁺ adsorption in the concentration of the NaCl solution when it was ≤100 mg/L, where wheat straw pyrochar (WB, 3.95–4.94 mg/g Na) and poplar wood chip pyrochar (PB, 0.62–0.70 mg/g Na) presented the release and adsorption of Na⁺, respectively. When the concentration of the NaCl solution was >100 mg/L, the adsorption capacity of WB (25.44–36.45 mg/g) was significantly higher than PB (4.46–6.23 mg/g). Both the adsorption and release of Na⁺ in hydrochar was insufficient. In a high concentration of NaCl solution, ion exchange became the key mechanism determining the adsorption of Na⁺ in pyrochar, in which K⁺ contributed to more than 94% of the Na⁺ adsorption. The findings proposed strategies for the structural design of biochar used for Na adsorption. These will promote the utilization of solid biowaste for sodium adsorption and the potential of soil salinization amendment for agriculture in arid lands. Full article

Wood fuel from the agroforestry sector is one of the main strategies cited by the EU for reducing energetic dependance on foreign markets. Its sustainability, both economic and environmental, can be improved through the optimization of harvesting and chipping operations. This study was focused on the dynamic and energetic balance of the chipping phase carried out by a chipper operated by the power-take-off (PTO) of a medium-power tractor. Both machines were equipped with sensors for real-time monitoring of fuel consumption, PTO torque and speed, trunk diameter and working time during the comminution of 61 poplar trees grown in a medium rotation coppice system. The data analysis was carried out on the entire dataset (about 29,000 records) without considering their belonging to different trees. By means of proper data ordinations, it has been possible to define all the intervals in which the chipping stopped (e.g., between two trees) and to exclude them from the intervals of actual chipping. This has allowed forcomputation of operative and actual working time, as well as of the basic power required to operate the chipper and the power for actual chipping. Subsequently, the parameter values observed during actual chipping were related to the cutting diameters measured at the same instant. Subsequently, the dataset was divided according to seven diameter classes, and, for each class, the descriptive statistical indices of working time, work productivity, CO₂ emissions, energy requirement and fuel consumption were calculated. Eventually, the correlation between the variations in trunk diameter and other parameters was verified both on the whole dataset and based on the class average values. The analysis made it possible to identify the conditions of greatest efficiency for the chipper. More generally, the method could help to increase the accuracy of measurements aimed at characterizing the performance of chippers from the point of view of dynamic energy requirements as well as in relation to different wood species. Full article

The thermo-chemical conversion of biomass wastes is a practical approach for the value-added reclamation of bioenergy in large quantities, and pyrolysis plays a core role in this process. In this work, poplar (PR) and cedar (CR) were used as staple wood biomasses to investigate the apparent kinetics of TG/DTG at different heating rates. Secondly, miscellaneous wood chips (MWC), in which PR and CR were mixed in equal proportion, were subjected to comprehensive investigations on their pyrolysis behavior and product evolution in a fixed bed reactor with pyrolysis temperature, catalyst, and the flow rate H₂O steam as influencing factors. The results demonstrated that both PR and CR underwent three consecutive pyrolysis stages, the TG/DTG curves shifted to higher temperatures, and the peak temperature intervals also enhanced as the heating rate increased. The kinetic compensation effect expression and apparent reaction kinetic model of CR and PR pyrolysis were obtained based on the law of mass action and the Arrhenius equation; the reaction kinetic parameter averages of Ea and A of its were almost the same, which were about 72.38 kJ/mol and 72.36 kJ/mol and 1147.11 min⁻¹ and 1144.39 min⁻¹, respectively. The high temperature was beneficial for the promotion of the pyrolysis of biomass, increased pyrolysis gas yield, and reduced tar yield. This process was strengthened in the presence of the catalyst, thus significantly increasing the yield of hydrogen-rich gas to 117.9 mL/g_-biomass. It was observed that H₂O steam was the most effective activator for providing a hydrogen source for the whole reaction process, promoted the reaction to proceed in the opposite direction of H₂O steam participation, and was beneficial to the production of H₂ and other hydrocarbons. In particular, when the flow rate of H₂O steam was 1 mL/min, the gas yield and hydrogen conversion were 76.94% and 15.90%, and the H₂/CO was 2.07. The yields of H₂, CO, and CO₂ in the gas formation were significantly increased to 107.35 mL/g_-biomass, 53.70 mL/g_-biomass, and 99.31 mL/g_-biomass, respectively. Therefore, H₂ was the most dominant species among gas products, followed by C-O bond-containing species, which provides a method for the production of hydrogen-rich gas and also provides ideas for compensating or partially replacing the fossil raw material for hydrogen production. Full article

After a period of significant development, poplar cultivation in Italy has been in rapid decline since the 1980s. Because of its marked ductility, poplar is valuable for both wood furniture and energy production. Production could be increased through mechanization, because innovative machinery and equipment can reduce the exposure of forest workers to common risk factors, ensure greater and better productivity, increase the efficiency of operations, and reduce costs. There are various systems for the mechanization of poplar production (from traditional to advanced and pushed mechanization). We describe the range of possibilities (in terms of both the techniques adopted and the machines used) for planting, harvesting, and chopping poplar. Based on our analysis of operating costs, we conclude that mechanized poplar production could reduce the average cost per ton of wood chips (EUR/t) by 23% and the average gross cost per hectare of wood chips produced (EUR/ha) by 37%. Full article

Woody biomass feedstock processing, including sorting, drying, and size reduction of biomass to provide standardized reactor-ready biomass to the biorefinery, is crucial to biofuel conversion. This study compares two comminution technology systems applied to woody biomass processing at a depot before being utilized for biofuel production at a biorefinery. The conventional comminution technology, known as the hammermill system, is compared with a rotary shear system developed by Forest Concepts™. Potential economic savings of using the new technology are evaluated by applying a deterministic and a stochastic partial capital budgeting model based on results from an experiment that processed chipped hybrid poplar chips and forest residues with both systems. The stochastic partial capital model estimates that savings will vary between approximately USD 28 and USD 42 per ton of reactor-ready processed biomass, with mean and median values around USD 34 per ton. It is 90% likely that savings will be between USD 30 and USD 39 per ton of reactor-ready processed biomass. The estimated savings are mainly due to differences in input (feedstock) to output (reactor-ready biomass) yields between technologies, affecting feedstock and drying costs. Full article

Exploiting renewable energy sources is one of the main strategies defined by the EU to overcome dependence on foreign markets for energy supply. Wood fuel sourced from the agroforestry sector can contribute significantly to achieving the goal, though its economic and environmental sustainability is intimately dependent on proper harvesting and chipping operations. In the present article, both economic and environmental aspects of Medium Rotation Coppice (MRC) were investigated regarding chipping. A small-scale chipper and tractor were equipped with real-time sensors to monitor time, t (s); fuel consumption, F (cm³); PTO torque, M (daNm); PTO speed, s (min⁻¹); and stem diameter, D (mm) during the comminution of 61 poplar plants (gathered in 5 classes according to trunk diameter) grown in MRC system. More than 29,000 records were taken and analyzed. Predictive models for working time, working productivity, CO₂ emission, energy consumption, fuel consumption and costs were also produced. Higher diametric classes exhibited lower fuel consumption, less CO₂ emission and less energy demand during chipping. Time and operating costs were statistically different among classes, with minimum values of 0.22 (SD ± 0.02) h·Mg⁻¹ and 12.07 (SD ± 0.93) €·Mg⁻¹ in class 5 and maximum values of 0.64 (SD ± 0.09) h·Mg⁻¹ and 35.34 (SD ± 4.88) €·Mg⁻¹ in class 1, respectively. Fuel consumption ranges from 3.04 (SD ± 0.88) L·Mg⁻¹ in class 5 to 7.32 (SD ± 1.46) L·Mg⁻¹ in class 1. The lowest CO₂ emission of 8.03 (SD ± 2.32) kg·Mg⁻¹ was found class 5. However, the total cost of coppice production did not exceed large-scale MRC production due to the lower purchase price of the machinery involved. Eventually, predictive models showed high reliability as estimating tools for important variables, such as working time, working productivity, CO₂ emissions, energy consumption, fuel consumption and costs. Full article

Lignin characteristics are significantly affected by kraft processing and isolation conditions. In the studies carried out in this context, commercial lignins or isolated lignins from industrial black solutions are generally preferred. In this study, in order to conduct more comprehensive research, three lignin samples were isolated from kraft black liquor obtained from laboratory cooking trials of pine, poplar, and wheat straw chips, representing softwoods, hardwoods, and annual plants, respectively, according to efficient pulping studies. In addition, another lignin-containing industrial waste was provided from a pulp mill (OBL). The acidification method was applied for isolating lignin from black liquor samples. After isolating the lignin samples from different sources, they were characterized and compared with the commercially available kraft lignin sample (Indulin AT). Total phenolic groups, carboxyl groups, purity, functional groups, nitrobenzene oxidation products, molecular weight, thermal stability, and element contents were analyzed. The isolated lignin samples (except wheat straw) were as pure as commercial lignin. Since the wheat straw was agricultural waste and an annual plant, inorganic elements such as P, K, and Si were more abundant than in the other samples. However, the polydispersity and molecular weight of all of the isolated lignin samples were higher than those of commercial lignin. Because the ash contents of the lignin samples for pine, poplar, OBL, and indulin AT were between 1 and 3%, they can be used for high-value applications. In particular, despite some disadvantages, wheat straw lignin has greater potential for use in extruders than softwood lignins due to their syringyl content. Full article

Studies on the use of biomass from short rotation coppices for briquette production as a sustainable biofuel have been scarce in the literature. This study investigated the effects of two process variables, hammer mill screen size at three levels (5.3, 10.3, and 25.4 mm) and moisture content at three levels (13.6, 19, and 25% (w.b.)), on the properties of briquettes from poplar Max-4 trees. The whole tree was divided into two fractions, the crown and the stem, and briquettes were produced from them. The effects of the variables on compressed density, relaxed density, relaxation ratio, and the shatter index of the briquettes were analyzed. The results showed that the combined interaction of the variables had no significant effects (p > 0.05) on the compressed density, relaxed density, and relaxation ratio of the briquettes. However, hammer mill screen size and moisture content both significantly influenced the shatter index irrespective of the tree fraction (p < 0.05). Hammer mill screen sizes of 5.3 and 10.3 mm at moisture contents of 13.6 and 19% (w.b.) resulted in good quality briquettes across the properties investigated for both the crown and stem poplar tree fractions. This study shows that high-quality briquettes can be produced from poplar Max-4 woody biomass. Full article

Plantation forestry has a long history in Europe and still supports local industry, generating employment, improving environmental quality, and mitigating climate change. As part of these plantations, medium-rotation poplars (5–8 years) provide good quality logs for fiber production, and the branches and tops can be converted into green energy. Finding a cost-effective harvesting system for this plantation is challenging due to the small tree size and the need for log production, which prevents whole-tree chipping. To verify the economic benefit of using small mechanized cut-to-length (CTL) technology, four different CTL chains were tested in western Slovakia. All chains tested consisted of a harvester and a forwarder. Each machine had a skilled operator and was timed while cutting and processing (or forwarding) eight experimental sample plots. Sample plots were randomly assigned to each treatment, and each one covered an area between 0.08 and 0.10 ha (120–170 trees). Harvester productivity ranged from 2.2 to 4.2 bone-dry tons per scheduled machine hour (BDT SMH⁻¹), and harvester cost from EUR 11 to EUR 22 BDT⁻¹. Forwarding productivity and cost ranged from EUR 2.0 to 4.5 BDT SMH⁻¹ and from EUR 9 to 20 BDT⁻¹. Total harvesting costs ranged between EUR 26 and 36 BDT⁻¹. Choosing a smaller harvester is preferable due to the small tree size, which caps productivity regardless of a machine’s intrinsic potential. Furthermore, small harvesters and forwarders are lighter on the ground, which can be a valuable asset on the many wet sites planted with poplar. Full article

For sustainable agriculture, the contentious input of peat in growing media needs to be replaced by a substitute with the best possible water-holding capacity (WHC). Wood from fast growing poplar trees, cultivated in short rotation coppices (SRC), is a suitable alternative if it is processed correctly in a twin-screw extruder. The processing parameters, such as the aperture setting of the extruder, moisture content, and specific energy demand (SED), during twin-screw extrusion, as well as their influence on fibre properties such as WHC and particle size distribution, are investigated. SRC-poplar wood chips from clone Max3 are the raw material used for this research. As a result, the best volume-based WHC (75%) at −1 kPa suction tension was achieved for dry extruded wood chip fibre at an aperture setting of 15 mm and an SED of 340 kWh*t⁻¹. The smallest SED of 140 kWh*t⁻¹ was measured at apertures of 35 mm and 40 mm, which resulted in a volume-based WHC of approximately 30% and a dry matter mass flow during processing of 0.289 t*h⁻¹ (40 mm). The particle size distribution of semi-dry wood chips has the highest fine fraction as well as the smallest coarse fraction. Conclusively, poplar wood can be processed fresh and dry into fibre at an acceptable SED, which results in an acceptable WHC. Full article

The use of oak barrel alternatives, including oak chips, oak staves and oak powder, is quite common in the production of spirits obtained from the distillation of vegetal fermented products such as grape pomace. This work explored the use of unconventional wood formats such as peeled and sliced wood. The use of poplar wood was also evaluated to verify its technological uses to produce aged spirits. To this aim, GC-MS analyses were carried out to obtain an aromatic characterisation of experimental distillates treated with these products. Moreover, the same spirits were studied for classification purposes using NMR, NIR and e-nose. A significant change in the original composition of grape pomace distillate due to sorption phenomena was observed; the intensity of this effect was greater for poplar wood. The release of aroma compounds from wood depended both on the toasting level and wood assortment. Higher levels of xylovolatiles, namely, whisky lactone, were measured in samples aged using sliced woods. Both the NIR and NMR analyses highlighted similarities among samples refined with oak tablets, differentiating them from the other wood types. Finally, E-nose seemed to be a promising alternative to spectroscopic methods both for the simplicity of sample preparation and method portability. Full article

Considering the increasing need to produce energy from renewable sources, the interest towards Medium Rotation Coppices (MRC) plantations has increased. One of the main issues that require tackling for the comprehensive sustainability of these plantations is related to the development of sustainable harvesting systems. Indeed, as a consequence of the average tree diameters at a breast height (dbh) of about 15 cm, single-pass harvesting typical of short rotation coppice is not applicable. Therefore, these plantations are generally harvested with machinery specifically developed for forest operations, as for instance harvesters, feller-bunchers and forwarders. In the Mediterranean area, the availability of such machines is still limited to a few big forest enterprises. Indeed, the majority of forest contractors carry out their activities in the framework of small-scale forestry, without the financial possibility of purchasing expensive machineries. Thus, the present study had the objective to evaluate the performance of two small-scale harvesting systems in a 7-year-old poplar plantation in Central Italy. The difference between the two systems was the different machinery applied for wood extraction, i.e., a forestry-fitted farm tractor equipped with winch (WINCH) and a fork lift prototype, attached to a crawler tractor (CFL). Extraction via CFL system reached very high working performance with about 21.5 m³ SMH⁻¹ (Scheduled Machine Hours, including delays), comparable to the productivities reported in the literature for forwarders working in similar plantations. Harvesting costs with CFL were 24.74 EUR m⁻³, of which 4.48 EUR m⁻³ was for felling with chainsaw, 4.61 EUR m⁻³ for extraction with CFL prototype and 15.64 EUR m⁻³ for wood chipping. WINCH showed unsatisfactory results instead, possessing a wood chip production cost of 41.95 EUR m⁻³, which is practically equivalent to the market price of wood chips. Full article

The aim of this work was to improve the understanding of dry matter losses (DML) that occur in wood chips during the initial phase of storage in outdoor piles. For this purpose, a laboratory scale storage chamber was developed and investigated regarding its ability to recreate the conditions that chips undergo during the initial phase of outdoor storage. Three trials with poplar Max-4 (Populus maximowiczii Henry × Populus nigra L.) chips were performed for 6–10 weeks in the storage chamber under controlled temperature and assisted humidity. Two different set-ups were investigated to maintain a high relative humidity (RH) inside the storage chamber; one using water containers, and one assisted with a humidifier. Moisture content (MC) and DML of the chips were measured at different storage times to evaluate their storage behaviour in the chamber. Additionally, microbiological analyses of the culturable fraction of saproxylic microbiota were performed, with a focus on mesophilic fungi, but discriminating also xerophilic fungi, and mesophilic bacteria, with focus on actinobacteria, in two trials, to gain a view on the poplar wood chip-inhabiting microorganisms as a function of storage conditions (moisture, temperature) and time. Results show that DML up to 8.8–13.7% occurred in the chips within 6–10 storage weeks. The maximum DML were reached in the trial using the humidifier, which seemed a suitable technique to keep a high RH in the testing chamber, and thus, to analyse the wood chips in conditions comparable to those in outdoor piles during the initial storage phase. Full article

The combustion of biomass is a process that is increasingly used for the generation of heat and energy through different types of wood and agricultural waste. The emissions generated by the combustion of biomass include different kinds of macro- and micropollutants whose formation and concentration varies according to the physical and chemical characteristics of the biomass, the combustion conditions, the plants, and the operational parameters of the process. The aim of this work is to evaluate the effect of biomass moisture content on the formation of volatile organic compounds (VOCs) during the combustion process. Wet and dry poplar chips, with a moisture content of 43.30% and 15.00%, respectively, were used in a cogeneration plant based on a mobile grate furnace. Stack’s emissions were sampled through adsorbent tubes and subsequently analyzed by thermal desorption coupled with the GC/MS. The data obtained showed that, depending on the moisture content of the starting matrix, which inevitably influences the quality of combustion, there is significant variation in the production of VOCs. Full article

Replacing fossil energy sources with renewable energy sources is a key strategic action to limit environmental issues. To achieve this goal, substitution with biomass is beneficial due to its versatility in various fields. In terms of circular economy and sustainability, the possibility of energy exploitation of residual biomass is particularly desirable in small-medium enterprises. The use of supply chain by-products can improve sustainability and create opportunities for companies. The purpose of this study is to evaluate the suitability of residual biomass of conifers and broad-leaved trees to produce quality pellets using an agri-pellet machine activated by the power take-off of a tractor. This system can be employed at the farm level. Wood biomass of four species was tested; poplar, stone pine, black locust, and oak. Wood chips samples were analyzed to determine their qualitative characteristics following the technical standard ISO 17225-4. Based on the results, different wood blends were created to produce pellets, subsequently characterized according to ISO 17225-2. The analyses carried out on wood chips and pellets were bulk density, moisture, ash content, calorific value, elemental composition, chlorine, sulfur, and heavy metals. In addition, particles size was measured only for wood chips, while the length, diameter, mechanical durability, and ash melting behaviors were determined only for pellets. Some of the analyzed mixtures show acceptable values according to the current ISO technical standards. The values related to the apparent pellet bulk density and the durability test highlight that not all the mixtures are suitable to produce quality pellets. Results also represent a good starting point for future studies. Full article