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Keywords = placer gold deposits

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18 pages, 8700 KiB  
Article
The Application of Integrated Geochemical and Geophysical Exploration for Prospecting Potential Prediction of Copper and Gold Polymetallic Deposits in the Fudiyingzi–Bacheli Area, Heilongjiang Province
by Liang Chen, Huiyan Wang, Chengye Sun, Xiaopeng Chang and Weizhong Ding
Minerals 2025, 15(6), 597; https://doi.org/10.3390/min15060597 - 2 Jun 2025
Viewed by 487
Abstract
The Duobaoshan mineralization area in Heilongjiang Province is a key copper–molybdenum–gold polymetallic region in China. Its southeastern Fudiyingzi–Bacheli area, located at the intersection of the NW-trending copper and NE-trending gold belts, exhibits favorable mineralization conditions. Despite over 70 years of placer gold mining [...] Read more.
The Duobaoshan mineralization area in Heilongjiang Province is a key copper–molybdenum–gold polymetallic region in China. Its southeastern Fudiyingzi–Bacheli area, located at the intersection of the NW-trending copper and NE-trending gold belts, exhibits favorable mineralization conditions. Despite over 70 years of placer gold mining and the discovery of one small copper deposit and one gold deposit, the area remains underexplored with significant peripheral exploration potential. This study integrates 1:50,000 geological mapping, high-precision magnetic surveys, phase-induced polarization, and soil geochemistry through multi-source data fusion for comprehensive mineral prediction. Key steps include delineating Cu, Au, and Mo anomalies and analyzing their associations with Zn, Cd, Ag, As, etc.; inferring NE-, NW-, and near-EW-trending linear structures via magnetic boundary enhancement; dividing high/low resistivity zones and identifying nine significant and six weak phase anomalies using phase-induced polarization; establishing a mineralization model based on typical deposits; and delineating four priority exploration targets. These results provide a scientific basis for further exploration in shallow coverage areas. Full article
(This article belongs to the Section Mineral Exploration Methods and Applications)
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31 pages, 14774 KiB  
Article
Morphostructural and Genetic Features of Native Gold in Apocarbonate Tremolite–Diopside Skarns (Ryabinovoye Deposit, Far East, Russia)
by Veronika I. Rozhdestvina and Galina A. Palyanova
Minerals 2025, 15(6), 571; https://doi.org/10.3390/min15060571 - 27 May 2025
Viewed by 476
Abstract
We studied the chemical composition and morphostructural features of micron and submicron-sized particles of native gold in apocarbonate tremolite–diopside skarns of the Ryabinovoye deposit located on the southeastern margin of the Aldan Shield (Far East, Russia). Polished sections of lump ore samples containing [...] Read more.
We studied the chemical composition and morphostructural features of micron and submicron-sized particles of native gold in apocarbonate tremolite–diopside skarns of the Ryabinovoye deposit located on the southeastern margin of the Aldan Shield (Far East, Russia). Polished sections of lump ore samples containing native gold were analyzed by scanning electron microscopy in combination with X-ray microanalysis using different modes of visualization and X-ray diffraction methods. Gold particles, clearly visible after etching the surface of some polished sections with acids and partial or complete dissolution of some host minerals, were also examined. Native gold from the studied deposit is of high fineness (above 970‰) and contains (in wt.%) <1.59 Ag and less commonly <0.37 Cu and <0.15 Zn. Native gold is found intergrown with tremolite, diopside, and other magnesian silicates, as well as calcite, fluorite, magnetite, and sphalerite. Rare microinclusions of pyrrhotite, galena, and clinohumite are present in gold grains. It was found that native gold inherits the morphology of tremolite crystals and aggregates, which is determined by the size and shape of the voids bounded by its crystals. Gold localized in the intercrystalline spaces and in the zones of conjugation with remobilized calcite has irregular, lumpy shapes and partially or completely faceted grains with a dense structure. The nature of the localization and distribution of native gold in ores is due to the crystallization of the tremolite component of skarns. Apparently, the processes of gold accumulation are caused by the thermal activation of solid-phase differentiation of the substance of carbonate rocks, in which the processes of destruction of the original minerals and collective recrystallization play a significant role. It is likely that at some gold skarn deposits, carbonate rocks could be the source of gold. Data on the morphology and sizes of native gold segregations, as well as on the intergrown minerals, can be used to improve gold extraction technologies. A specific group of minerals intergrown with native gold in gold skarn deposits can be used as a diagnostic feature in the primary search for placer gold. The obtained results will help to better understand the formation of native gold in apocarbonate tremolite–diopside skarns. Full article
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16 pages, 7943 KiB  
Article
Unraveling a Rare Polygonal Gold–Pyrite Assemblage: Insights from the Lena Province, Bodaibo Mining District (Russia)
by Isabella Pignatelli, Gaston Giuliani, Christophe Morlot and Louis-Dominique Bayle
Crystals 2025, 15(1), 4; https://doi.org/10.3390/cryst15010004 - 24 Dec 2024
Cited by 1 | Viewed by 1278
Abstract
A rare polygonal gold assemblage from the Bodaibo mining district (Russia) was analyzed in this study. It resembles cubic native gold from the same area described as a gold pseudomorph after pyrite. The polygonal assemblage differs from these cubic gold samples by the [...] Read more.
A rare polygonal gold assemblage from the Bodaibo mining district (Russia) was analyzed in this study. It resembles cubic native gold from the same area described as a gold pseudomorph after pyrite. The polygonal assemblage differs from these cubic gold samples by the absence of striations, its stepped morphology, and the presence of euhedral pyrite. It was analyzed with non-destructive techniques (SEM, VSI, and X-ray CT) in order to preserve the integrity of this exceptional sample. The experimental data allowed us to understand how this rare sample could be formed. A formation of secondary deposits, i.e., eluvial placers, is compatible with the mobilization and precipitation of gold by surface effects on primary pyrite, as well as oxidation episodes producing iron oxides/hydroxides. The redox condition in the geological environment caused the pyrite dissolution and release of gold in its structure, leading to the formation of a thin layer of gold on pyrite by epitaxy rather than pseudomorphism. Full article
(This article belongs to the Section Mineralogical Crystallography and Biomineralization)
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21 pages, 4180 KiB  
Article
Mineralogical Method as an Effective Way to Predict Gold Ore Types of Deposits in Platform Areas (East of the Siberian Platform)
by Zinaida Nikiforova
Minerals 2024, 14(6), 631; https://doi.org/10.3390/min14060631 - 20 Jun 2024
Cited by 1 | Viewed by 1604
Abstract
The study of the mineralogical and geochemical features of placer gold and the mechanisms of its distribution in the territory east of the Siberian platform, overlain by a thick cover of Mesozoic–Cenozoic deposits, where traditional methods of searching for gold fields are not [...] Read more.
The study of the mineralogical and geochemical features of placer gold and the mechanisms of its distribution in the territory east of the Siberian platform, overlain by a thick cover of Mesozoic–Cenozoic deposits, where traditional methods of searching for gold fields are not effective, allowed researchers, for the first time, to establish the stages of ore formation and to predict the types of gold deposits and their location. The identified indicators of placer gold (morphology, granulometry, chemical composition, micro-inclusions, and internal structures) indicate that ore occurrences in both the Precambrian and Mesozoic stages of ore formation were primary sources of placer gold. The identification of characteristic indicators in placer gold for certain types of gold deposits allowed researchers to prove the formation of gold ore sources east of the Siberian platform for the first time: low-sulfide quartz gold, gold–ferruginous quartzite, gold–copper–porphyry, and gold–platinoid formations are found in the Precambrian stage of ore formation and gold–silver, gold–sulfide–quartz, and gold–rare metal formations are found in the Mesozoic stages of ore formation. Thus, for the first time, based on a huge amount of factual material, it is proved that the mineralogical and geochemical features of placer gold carry enormous information about both the endogenous origin of gold (stages of ore formation—Precambrian and Mesozoic) and the expected type of formation of the predicted deposits. It is established that the predicted type of ore sources corresponds to a certain geological and structural position; this contributes to a more correct selection of methods for searching for ore and placer gold deposits in closed territories and assessing their prospects. In general, the application of the mineralogical method for the first time makes it possible to develop criteria for predicting resources and types of gold deposits, and to assess the prospects of gold mining potential in platform areas at a new level of knowledge. Full article
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15 pages, 6874 KiB  
Article
Formation of Intergrowths of Platinum-Group Minerals and Gold from Magmatogenic Ores in Relation to Phase Changes in Pt-Pd-Fe-Cu-Au System
by Alexander Okrugin and Boris Gerasimov
Minerals 2024, 14(3), 326; https://doi.org/10.3390/min14030326 - 21 Mar 2024
Viewed by 1714
Abstract
The article discusses the features of the chemical composition and the formation of intergrowths of platinum-group minerals, gold, gold-bearing phases, and other ore minerals present in placers collected from the Anabar River in the northeast part of the Siberian platform. Based on an [...] Read more.
The article discusses the features of the chemical composition and the formation of intergrowths of platinum-group minerals, gold, gold-bearing phases, and other ore minerals present in placers collected from the Anabar River in the northeast part of the Siberian platform. Based on an analysis of changes in the phase compositions of these intergrowths of noble metals with other ore minerals on (Pt, Pd)-Fe-Au and Pd-Cu-Au phase equilibrium diagrams, potential trends in the crystallization of natural polymineral alloys from multicomponent low-sulfide metallic liquids are discussed. The similarity of the microstructures of natural and metallurgical alloys indicates that the formation of natural multiphase Au-PGE intergrowths occurred in a similar manner to the crystallization of multicomponent synthetic alloys. The authors suggest that magmatic Au-PGE mineralization occurs during the crystallization of a noble-metal-containing, low-sulfide, Cr-rich oxide melt separated from silicate mafic–ultramafic magma. Magmatic gold–platinum deposits are commonly associated with sulfide or oxide disseminated-schlieren ores in layered mafic–ultramafic intrusions. However, due to the high solubility of gold and platinoids in sulfide minerals, PGMs in sulfide ores occur as isomorphic impurities or as microphases and dispersed inclusions that cannot form placers. Therefore, the authors suggest that magmatic Au-PGE mineralization occurs during the crystallization of an immiscible low-sulfide, high-Cr oxide liquid separated from silicate mafic–ultramafic magma. In the northeast part of the Siberian platform, potential sources for these placers are likely alkaline, high-Ti mafic–ultramafic intrusions, as confirmed by the presence of silicate inclusions in ferroan platinum similar in composition to melteigite. Full article
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22 pages, 12690 KiB  
Article
Geochemical Overprinting and Secondary Placer Crystal Formation in the La Cholla District, Quartzsite, Arizona, USA: Evidence from Copper Isotopes, Morphology, and Trace Elements
by Erik B. Melchiorre, Ryan Mathur, George Kamenov and Jorge Paredes
Minerals 2023, 13(11), 1444; https://doi.org/10.3390/min13111444 - 15 Nov 2023
Cited by 1 | Viewed by 2013
Abstract
Geochemical overprinting on placer gold deposits produces complex deposits with apparently paradoxical geochemical and morphological attributes. The La Cholla placer gold deposits near Quartzsite, Arizona, USA, contain sharp and often undamaged gold crystals within high-energy gravels as a result of postdepositional recrystallization by [...] Read more.
Geochemical overprinting on placer gold deposits produces complex deposits with apparently paradoxical geochemical and morphological attributes. The La Cholla placer gold deposits near Quartzsite, Arizona, USA, contain sharp and often undamaged gold crystals within high-energy gravels as a result of postdepositional recrystallization by localized hot springs. Geothermal fluids emanated from a basin-bounding fault and left a distinct signature that includes recrystallized gold with low Pb and δ65Cu > 1.14‰, secondary uraninite and carnotite, travertine deposits, and mounds of highly silicified placer gravels. Surrounding these deposits are placer gravels with angular gold morphology and geochemistry indicative of flash-flood pulse placers with a lode gold source < 5 km and gold particles with low Pb and δ65Cu < 0.77‰. The multitude of small local lode gold source veins is likely related to specialized fluid migration along mid-Tertiary detachment faults. The unroofing of these veins at 5 to 17 Ma by high-angle Basin and Range faulting led to extensive placer development, with subsequent localized modification by geothermal fluid migration along the same faults. This study documents geochemical overprinting and modification of placer deposits and bears upon the study of other placers containing crystalline gold and uranium mineralization. Similar deposits may document past geothermal activity and identify structural fluid conduits and steep paleo-topographic gradients. Full article
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33 pages, 28729 KiB  
Article
Native Gold and Unique Gold–Brannerite Nuggets from the Placer of the Kamenny Stream, Ozerninsky Ore Cluster (Western Transbakalia, Russia) and Possible Sources
by Sergey M. Zhmodik, Evgeniya V. Airiyants, Dmitriy K. Belyanin, Bulat B. Damdinov, Nikolay S. Karmanov, Olga N. Kiseleva, Alexander V. Kozlov, Alexander A. Mironov, Tatyana N. Moroz and Victor A. Ponomarchuk
Minerals 2023, 13(9), 1149; https://doi.org/10.3390/min13091149 - 30 Aug 2023
Cited by 2 | Viewed by 2250
Abstract
We carried out a comprehensive study of native gold (morphology, composition, intergrowths, and microinclusions) from alluvial deposits of the Kamenny stream (Ozerninsky ore cluster, Western Transbaikalia, Russia). The study showed that there were four types of native gold, which differed significantly in their [...] Read more.
We carried out a comprehensive study of native gold (morphology, composition, intergrowths, and microinclusions) from alluvial deposits of the Kamenny stream (Ozerninsky ore cluster, Western Transbaikalia, Russia). The study showed that there were four types of native gold, which differed significantly in their characteristics and probably had different primary sources from which placers were formed: gold–quartz, oxidized gold–sulfide, gold–silver, and zones of listvenites with copper–gold and gold–brannerite (Elkon-type). Particular attention was paid to the study of unique, both in size and in composition, gold–brannerite nuggets of the Kamenny stream. It was established that the gold in the gold–brannerite nuggets (GBNs) had wide variations in chemical composition and mineral features. According to them, there were five different fineness types of native gold: 750–800‰; 850–880‰; 880–920‰; 930–960‰; and 980–1000‰. The data obtained indicated a multistage, possibly polygenic, and probably polychronous formation of GBN gold–uranium mineralization. The first stage was the formation of early quartz–nasturanium–gold–W–rutile–magnetite association (Middle–Late Paleozoic age). The second was the crystallization of brannerite and the replacement of an earlier pitchblende with brannerite (Late Triassic (T3)–Early Jurassic (J1) age). The third was the formation of the hematite–barite–rutile–gold association as a result of deformation–hydrothermal processes, which was associated with the appearance of zones of alteration in brannerite in contact with native gold with 8–15 wt.% Ag. The fourth was hypergene or the low-temperature hydrothermal alteration of minerals of early stages with the development of iron hydroxides (goethite) with impurities of manganese, tellurium, arsenic, phosphorus, and other elements. The carbon isotopic composition of an organic substance indicates the involvement of a biogenic carbon source. In the OOC area, there were signs that the composition of the GBNs and the quartz–chlorite–K–feldspar-containing rocks corresponded to Elkon-type deposits. Full article
(This article belongs to the Special Issue Native Gold as a Specific Indicator Mineral for Gold Deposits)
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38 pages, 5802 KiB  
Review
Palladian Gold: Chemical Composition, Minerals in Association, and Physicochemical Conditions of Formation at Different Types of Gold Deposits
by Galina A. Palyanova, Pavel S. Zhegunov, Tatiana V. Beliaeva, Valery V. Murzin, Andrey A. Borovikov and Nikolay A. Goryachev
Minerals 2023, 13(8), 1019; https://doi.org/10.3390/min13081019 - 30 Jul 2023
Cited by 8 | Viewed by 3338
Abstract
This paper reviews and summarizes the available information on the composition of palladian gold with various contents and sets of isomorphic impurities (Ag, Cu, Hg) at 50 deposits and ore occurrences with Au-Pd mineralization. It is revealed that Palladian gold is represented by [...] Read more.
This paper reviews and summarizes the available information on the composition of palladian gold with various contents and sets of isomorphic impurities (Ag, Cu, Hg) at 50 deposits and ore occurrences with Au-Pd mineralization. It is revealed that Palladian gold is represented by the systems Au–Pd, Au–Pd–Hg, Au–Pd–Cu, and Au–Pd–Ag–Hg, but more frequently corresponds to Au–Pd–Ag, Au–Pd–Ag–Cu, and Au–Pd–Ag–Cu–Hg. Objects with palladian gold belong to different types of gold deposits and to the deposits at which the main components of ores are PGE, Cr, Cu, Ni, V, and Ti. We propose a classification of the types of deposits with palladian gold: (1) PGE ore deposits related to mafic–ultramafic magmatic complexes (two subtypes—(a) low-sulfide-grade (less than 2%–5% sulfides) Alaskan, and (b) high-sulfide-grade (more than 5% sulfides) Norilsk); (2) orogenic gold deposits (OG); (3) epithermal (porphyry) gold–copper deposits (EPGC); (4) iron oxide copper gold deposits (IOCG); (5) ferruginous quartzite deposits; (6) volcanic exhalation; and (7) gold-PGE placers of five subtypes corresponding to the types of 1–5 primary sources. Physicochemical conditions of the formation of palladian gold at some deposits of type 1 cover two areas—magmatic high-temperature and hydrothermal low-temperature. At the majority of deposits of types 2–4, its formation proceeds with the participation of hydrothermal fluids (300–60 °C) of various salinities (0.2–30 wt.% NaCl eq.). Palladian gold is mainly high-fineness (910‰–990‰), is less frequently medium-fineness, and contains Ag and Cu, but does not contain Hg at the deposits of types 1, 3, and 4. The only exception is the Au-Pd-Hg Itchayvayam ore occurrence (Kamchatka, Russia), for which two varieties of Pd,Hg-bearing native gold (fineness 816‰–960‰ and 580‰–660‰) are determined. Low-fineness palladian gold with the major content of Ag is typical of OGD deposits. Medium-fineness palladian gold occurs at ferruginous quartzite deposits and in volcanic exhalations. Hg, Ag, Cu-bearing high-fineness palladian gold is present mainly in placer deposits (type 7). The most common minerals in association with palladian gold are arsenides, stibioarsenides, sulfides, stannides, bismuthides, tellurides, and selenides of Pd and Pt. These are typical of deposit types 1 and 7. The minerals of Au, Ag, and Cu (tetra-auricupride, aurostibite, chalcopyrite, bornite, chalcocite, eucairite, etc.) are in association with palladian gold at OG, EPGC, and IOCG deposits. Hg minerals (cinnabar, tiemannite, coloradoite, potarite) are at some deposits (types 1, 2, 7-1, 7-4). Cu, Fe, and Pd oxides (tenorite, hematite, magnetite, PdO, (Pd,Cu)O) and Fe and Pd hydroxides (goethite, (Fe,Pd)OOH) occur at the deposits of the 3, 4, and 7 groups and indicate the highly oxidizing conditions of ore formation. The most common minerals among host minerals are quartz and muscovite, including fuchsite (Cr-Ms), chlorite, albite, K-feldspar, hornblende, and carbonates (calcite, siderite, etc.). The fineness, content, and set of impurities in palladian gold and minerals in association with it reflect the mineralogy of Au-Pd ores and allow them to be used as indicators for the deposit types. Full article
(This article belongs to the Special Issue Native Gold as a Specific Indicator Mineral for Gold Deposits)
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20 pages, 17830 KiB  
Article
Characterization of Gold of the Murcielago Fluvial Placer (Central Honduras) and Its Possible Primary Sources
by Sabrina Nazzareni, Simona Alunno, Federica Zaccarini, Michele Mattioli, Alessandro Murroni, Alessandro Di Michele and Alberto Renzulli
Geosciences 2023, 13(6), 175; https://doi.org/10.3390/geosciences13060175 - 10 Jun 2023
Viewed by 2176
Abstract
The Murcielago gold placer is located in the Lepaguare Valley, Olancho Department (Central Honduras). The placer mineralogy includes silicates (quartz, garnets, amphibole, Ca-pyroxene, micas, epidote, and tourmaline); calcite; and in the heavy fraction, zircon, ilmenite–rutile, magnetite, hematite, cassiterite, and cinnabar. Gold grains recovered [...] Read more.
The Murcielago gold placer is located in the Lepaguare Valley, Olancho Department (Central Honduras). The placer mineralogy includes silicates (quartz, garnets, amphibole, Ca-pyroxene, micas, epidote, and tourmaline); calcite; and in the heavy fraction, zircon, ilmenite–rutile, magnetite, hematite, cassiterite, and cinnabar. Gold grains recovered from the Murcielago placer production plant are mainly flattened grains with a moderately to high elliptical shape. The composition of the gold grains varies continuously in the range Au46Ag54 to Au88Ag12. Few of them are characterized by Au-rich rims of a few microns in size (Ag 3-1 atoms percent (at%)). Gold from the Canan lode deposit, a nearby hydrothermal Au mineralization area, has a composition (from Au54Ag44 to Au81Ag19) overlapping the composition of the Murcielago grains. Inclusions in the alluvial gold particles are arsenopyrite, pyrite, acanthite, sphalerite, and hematite. On the basis of the placer mineralogy and the gold grains analyses, possible gold source(s) include the Canan lode and skarn gold deposits in the area. We obtained new data on the Murcielago gold placer that will be the basis for an exploration of the potential sources of gold in the area. Full article
(This article belongs to the Special Issue Geochemistry and Geochronology of Mineral Deposits)
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23 pages, 21306 KiB  
Article
Typomorphic Features and Source of Native Gold from the Sykhoi Log Area Placer Deposits, Bodaibo Gold-Bearing District, Siberia, Russia
by Alexander Lalomov, Antonina Grigorieva, Alexei Kotov and Lidiya Ivanova
Minerals 2023, 13(5), 707; https://doi.org/10.3390/min13050707 - 22 May 2023
Cited by 11 | Viewed by 2618
Abstract
The Bodaibo gold-bearing district in the Lena gold province of Siberia is one of the largest and oldest placer gold-bearing provinces in the world. Approximately 1650 tons of gold has been extracted from the region. Precise studies on the source of these unique [...] Read more.
The Bodaibo gold-bearing district in the Lena gold province of Siberia is one of the largest and oldest placer gold-bearing provinces in the world. Approximately 1650 tons of gold has been extracted from the region. Precise studies on the source of these unique placer deposits are lacking and still controversial. Native gold from four different locations was gathered to investigate its morphology, chemical signatures, structure and inclusions. Some data on primary bedrock mineralization were obtained from the published literature. The linear weathering crusts developed along the zones of disjunctive dislocations near the Sukhoi Log gold deposit were researched. If they coincided with zones of low-grade veinlet-disseminated gold–quartz–sulphide mineralization with small gold grain sizes, a supergene replacement of primary mineralization was known to have occurred, accompanied by the formation of gold-rich rims and an increase in the size, content and purity of gold. Such mineralization associated with linear weathering crusts can be a source of local eluvial–proluvial placers, while placers of large valleys are formed due to low-sulphide gold–quartz lodes. Full article
(This article belongs to the Special Issue Native Gold as a Specific Indicator Mineral for Gold Deposits)
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25 pages, 7199 KiB  
Article
Pd,Hg-Rich Gold and Compounds of the Au-Pd-Hg System at the Itchayvayam Mafic-Ultramafic Complex (Kamchatka, Russia) and Other Localities
by Galina Palyanova, Anton Kutyrev, Tatiana Beliaeva, Vladimir Shilovskikh, Pavel Zhegunov, Elena Zhitova and Yurii Seryotkin
Minerals 2023, 13(4), 549; https://doi.org/10.3390/min13040549 - 13 Apr 2023
Cited by 4 | Viewed by 2430
Abstract
The unique minerals of the Au-Pd-Hg system in gold grains from heavy concentrates of the Itchayvayam placers and watercourses draining and ore samples of the Barany outcrop at the Itchayvayam mafic–ultramafic complex (Kamchatka, Russia) were investigated. Gold grains from watercourses draining and heavy [...] Read more.
The unique minerals of the Au-Pd-Hg system in gold grains from heavy concentrates of the Itchayvayam placers and watercourses draining and ore samples of the Barany outcrop at the Itchayvayam mafic–ultramafic complex (Kamchatka, Russia) were investigated. Gold grains from watercourses draining and heavy concentrates of the Itchayvayam placers contain substitution structures formed by Pd,Hg-rich low-fineness gold (Au0.59–0.52Pd0.24–0.25Hg0.17–0.23, 580‰–660‰) and Pd,Hg-poor high-fineness gold (Au0.94–0.90Pd0.02–0.04Hg0.03, 910‰–960‰). Potarite (PdHg) without and with impurities (Au < 7.9, Cu < 3.5, Ag < 1.2 wt.%), Ag-poor high-fineness gold (Au0.91Ag0.09, 950‰), Ag,Pd,Hg-bearing middle-fineness gold (Au0.75Ag0.08Pd0.09Hg0.08—Au0.88Ag0.09Pd0.02Hg0.01, 820‰–930‰), and Pd,Hg-rich low-fineness gold with minor contents Ag and Cd (Au0.51–0.55Pd0.25–0.22Hg0.21–0.16Ag0.03–0.06Cd0.01, fineness 580‰–630‰) were observed as individual microinclusions in the ore samples of the Barany outcrop. XRD and EBSD study results show that the Pd,Hg-rich low-fineness gold is isotypic to gold and has the same structure type, but different cell dimensions. According to data obtained for the Itchayvayam and some deposits and ore occurrences with Pd,Hg-bearing gold, the stable ternary phases and solid solutions of the following compositions in the Au-Pd-Hg system have been identified: Pd,Hg-poor gold (Au0.94–0.90Pd0.02–0.04Hg0.03), Pd,Hg-rich gold (Au0.59–0.52Pd0.24–0.25Hg0.17–0.23), Au-potarite (PdHg0.62Au0.38—Pd1.04Hg0.96—Au0.80Pd0.68Hg0.52), and Au,Hg-bearing palladium (Pd0.7Au0.3Hg0.1). The genesis of Pd,Hg-rich gold is insufficiently studied. We supposed that the meteoric waters or low-temperature hydrotherms rich in Pd and Hg could lead to the replacement Pd,Hg-poor gold by Pd,Hg-rich gold. High concentrations of Pd in Pd,Hg-bearing gold indicate a genetic relationship with mafic–ultramafic rocks. Full article
(This article belongs to the Special Issue Native Gold as a Specific Indicator Mineral for Gold Deposits)
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13 pages, 10049 KiB  
Article
Paragenetic Association of Platinum and Gold Minerals in Placers of the Anabar River in the Northeast of the Siberian Platform
by Alexander Okrugin and Boris Gerasimov
Minerals 2023, 13(1), 96; https://doi.org/10.3390/min13010096 - 7 Jan 2023
Cited by 6 | Viewed by 2715
Abstract
Areal placers of diamond and precious metals (platinum and gold) of unknown origin are widespread in the Anabar River basin on the northeastern part of the Siberian Platform. This article discusses the typomorphic features of palladium gold (porpezite) and ferroan platinum, which, in [...] Read more.
Areal placers of diamond and precious metals (platinum and gold) of unknown origin are widespread in the Anabar River basin on the northeastern part of the Siberian Platform. This article discusses the typomorphic features of palladium gold (porpezite) and ferroan platinum, which, in addition to fragmented individual grains, sometimes form close growths, which indicates their obvious genetic relationship. This can be used to delimit the primary sources of commercial components of complex placers by their genetic types. The composition of minerals was determined on a Camebax-Micro (Cameca, France) microprobe analyzer, and their microstructural relationships were studied using the scanning microscope JSM-6480LV JEOL. Determination of the structure and parameters of elementary lattices of minerals was carried out on the D8 Discover diffractometer. According to microprobe analysis, the Pd content in porpezite ranges from 0.73% to 12.83%, Ag does not exceed 2.75% and Cu reaches 3–4%. Considering the composition, such a gold–platinum mineral association from placers of the Anabar river is close to precious metals from placers of the Gulinsky massif, as well as Au–PGE ore occurrences related to ultramafic–mafic intrusions of other regions of the world. Complex gold–platinum-metal mineralizations are usually closely related to parent rocks and are often observed in sulfide and chromite ores of layered ultramafic–mafic intrusions with complex metasomatic and hydrothermal transformations. It is shown that in such cases gold and platinum form a magmatogenic paragenesis of minerals that coexist until the separation of hydrothermal solutions from magma, which, as a rule, transports Au and Ag with a small fraction of PGE from the fluid-ore-magmatic system in accordance with the model of the formation of gold–porphyry deposits. Within the Anabar diamond-bearing region, according to modern geophysical data, a significant number of local gravimagnetic anomalies associated with the presence of intrusive massifs of basic and alkaline-ultrabasic rocks in the cover and within the basement have been identified. This allows us to assume that the buried parent rocks of the Anabar Au–Pt placers may be located in both the Precambrian and Phanerozoic strata. Full article
(This article belongs to the Special Issue Native Gold as a Specific Indicator Mineral for Gold Deposits)
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15 pages, 8719 KiB  
Article
Internal Structures of Placer Gold as an Indicator of Endogenous and Exogenous Processes
by Zinaida Nikiforova
Minerals 2023, 13(1), 68; https://doi.org/10.3390/min13010068 - 30 Dec 2022
Cited by 5 | Viewed by 2193
Abstract
The study of the internal structures of placer gold on the territory of the east of the Siberian platform, overlain by a thick cover of Mz-Kz deposits, where traditional methods of searching for gold deposits are not effective, allowed us to determine, for [...] Read more.
The study of the internal structures of placer gold on the territory of the east of the Siberian platform, overlain by a thick cover of Mz-Kz deposits, where traditional methods of searching for gold deposits are not effective, allowed us to determine, for the first time, the stages of ore formation and conditions of its occurrence. The identified indicators of the internal structures of placer gold (structures of primary recrystallization, secondary recrystallization, thick high-grade shells) indicate that placer gold content is formed mainly due to the supply and repeated redeposition of native gold from ancient gold-bearing deposits of the Precambrian stage of ore formation to younger ones. The discovered coarse-, medium-grained, mono-grained, unclear-zonal, granulation and disintegration structures suggest a supply of gold from nearby ore sources of the Mesozoic stage of ore formation. In the weathering crust, a high-grade shell is formed. In the hydrodynamic environment, the internal structures of gold practically do not change and fully correspond to the internal structures of endogenous gold. In aeolian conditions, the internal structures are transformed. In ancient gold-bearing conglomerates, under the impact of lithostatic pressure, as well as in metamorphogenic conditions, when the PT conditions change, the internal structure changes. Thus, for the first time, on a huge factual material, it is proved that the internal structures contain extensive information both about the endogenous origin of gold (the stages of ore formation—Precambrian and Mesozoic) and about its transformation in various exogenous conditions. The identified indicator of the internal structures of placer gold for certain types of sources contribute to a more correct selection of methods for searching for ore and placer gold deposits in closed territories and assessing their prospects. The use of this method makes it possible to develop criteria for forecasting different sources and types of gold deposits based on internal structures. Full article
(This article belongs to the Special Issue Native Gold as a Specific Indicator Mineral for Gold Deposits)
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16 pages, 13284 KiB  
Article
Gold Provenance in Placers from Pureo Area, Southern Chile Coastal Cordillera, and Their Relationship with Paleozoic Metamorphic Rocks
by Pablo Becerra, Pablo Sanchez-Alfaro, José Piquer, Gaëlle Plissart, Belén Garroz and Daniela Kunstmann
Minerals 2022, 12(9), 1147; https://doi.org/10.3390/min12091147 - 10 Sep 2022
Cited by 4 | Viewed by 3135
Abstract
Southern Chile placer gold deposits have been known and exploited since Spanish colonial times. Despite this, precise knowledge about their origin is scarce. This work aims to identify possible primary sources of the gold in the Pureo placers by studying the morphological and [...] Read more.
Southern Chile placer gold deposits have been known and exploited since Spanish colonial times. Despite this, precise knowledge about their origin is scarce. This work aims to identify possible primary sources of the gold in the Pureo placers by studying the morphological and chemical characteristics of gold particles according to their spatial distribution. The former was determined by measurements and classification under a binocular microscope, allowing us to acquire a set of parameters related to the amount of transport that had affected the samples. The microchemical characteristics were determined by studying gold particles using optical microscopy, scanning electron microscopy (SEM) and electron microprobe (EMPA), where the native gold composition (in terms of major and minor elements) and the suite of mineral inclusions were obtained. The results regarding morphological characteristics suggest a low amount of transport from a primary source (<15 km). Microchemical data from gold particles indicate two compositional sub-populations, distinguished in both native gold composition (<15 Ag wt% with up to 4 Hg wt% and >15 Ag wt% with Hg bellow 1 wt%) and mineral inclusions (pyrite-galena rich and arsenopyrite rich, respectively), indicating two different primary gold sources. These results suggest a local origin of gold in the Coastal Cordillera, where the possible primary sources are associated with (i) massive sulfide deposits present in Paleozoic–Triassic metamorphic rocks and (ii) hydrothermal deposits associated with more recent Cenozoic intrusive activity. These conclusions have implications for the exploration of new placer deposits and of gold-bearing hypogene deposits (e.g., metamorphosed VMS deposits) in unexplored zones of southern Chile Coastal Cordillera. Full article
(This article belongs to the Special Issue Native Gold as a Specific Indicator Mineral for Gold Deposits)
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20 pages, 9781 KiB  
Article
Petrographic and Geochemical Analysis of Indus Sediments: Implications for Placer Gold Deposits, Peshawar Basin, NW Himalaya, Pakistan
by Abdul Mateen, Ali Wahid, Hammad Tariq Janjuhah, Muhammad Saleem Mughal, Syed Haroon Ali, Numair Ahmed Siddiqui, Munib Ahmed Shafique, Olga Koumoutsakou and George Kontakiotis
Minerals 2022, 12(8), 1059; https://doi.org/10.3390/min12081059 - 22 Aug 2022
Cited by 17 | Viewed by 7216
Abstract
Alluvial placer gold deposits that accumulate in streams across the globe are essentially allochthonous sedimentary deposits that are transported from their source to their location of deposition. The purpose of this study was to find placer gold deposits in alluvial sediments along the [...] Read more.
Alluvial placer gold deposits that accumulate in streams across the globe are essentially allochthonous sedimentary deposits that are transported from their source to their location of deposition. The purpose of this study was to find placer gold deposits in alluvial sediments along the Indus River in the NW Himalaya of Pakistan. The investigated region was divided into five clusters based on river morphology. The research focused on mineralogical distribution, sediment source, gold transport distance, elemental composition, and gold concentration in river sediments. Throughout, during the deposition at point and channel bars, the mixed source of alluvial sediments was revealed by its mineralogical composition. However, the SEM analysis demonstrated that the gold grains had a high flatness index, indicating that they had been transported a significant distance. The elemental composition of several samples revealed a significant concentration of silicon dioxide, iron oxide, and alumina oxide transported from the Himalaya. The study of the trace elements indicated gold and related base metals with granitic provenance were transported from an acidic/granitic source. Based on gold concentration, it is demonstrated that the left riverbank (clusters C1, C2, and C3) has a higher concentration of gold deposits and higher potential for economic gold exploration than the right bank (clusters C4 and C5) due to the lower velocity of running water in the study area. The findings revealed that the studied area has good potential for commercial exploration of gold resources, and the workflow can be adopted in any region with a similar geological setting and morphology. Full article
(This article belongs to the Special Issue Economic Mineral Deposits: A Review)
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