Search Results (168)

This paper serves as a comprehensive and practical resource to guide researchers in selecting suitable metals for use as photocathodes in radio-frequency (RF) and superconducting radio-frequency (SRF) electron guns. It offers an in-depth review of bulk and thin-film metals commonly employed in many applications. The investigation includes the photoemission, optical, chemical, mechanical, and physical properties of metallic materials used in photocathodes, with a particular focus on key performance parameters such as quantum efficiency, operational lifetime, chemical inertness, thermal emittance, response time, dark current, and work function. In addition to these primary attributes, this study examines essential parameters such as surface roughness, morphology, injector compatibility, manufacturing techniques, and the impact of chemical environmental factors on overall performance. The aim is to provide researchers with detailed insights to make well-informed decisions on materials and device selection. The holistic approach of this work associates, in tabular format, all photo-emissive, optical, mechanical, physical, and chemical properties of bulk and thin-film metallic photocathodes with experimental data, aspiring to provide unique tools for maximizing the effectiveness of laser cleaning treatment. Full article

To address the corrosion of 304 stainless steel in marine environments, TiO₂/NiCo₂S₄ composite photoanodes were fabricated via anodic oxidation and hydrothermal methods. X-ray diffraction, scanning electron microscope, energy-dispersive x-ray spectroscopy, and x-ray photoelectron spectroscopy analyses indicated the growth of hexagonal NiCo₂S₄ particles on anatase TiO₂ nanotube arrays, forming a type-II heterojunction. Spectroscopy of ultraviolet-visible diffuse reflectance absorption showed that NiCo₂S₄ extended TiO₂’s light absorption into the visible region. Electrochemical tests revealed that under visible light, the composite photoanode decreased the corrosion potential of 304ss to −0.7 V vs. SCE and reduced charge transfer resistance by 20% compared to pure TiO₂. The enhanced performance stemmed from efficient electron-hole separation and transport enabled by the type-II heterojunction. Cyclic voltammetry tests indicated the composite’s electrochemical active surface area increased 1.8-fold, demonstrating superior catalytic activity. In conclusion, the TiO₂/NiCo₂S₄ composite photoanode offers an effective approach for marine corrosion protection of 304ss. Full article

Belle II is a particle physics experiment working at an high luminosity collider within a hard irradiation environment. The Time-Of-Propagation detector, aimed at the charged particle identification, surrounds the Belle II tracking detector on the barrel part. This detector is composed by 16 modules, each module contains a finely fused silica bar, coupled to microchannel plate photomultiplier tube (MCP-PMT) photo-detectors and readout by high-speed electronics. The MCP-PMT lifetime at the nominal collider luminosity is about one year, this is due to the high photon background degrading the quantum efficiency of the photocathode. An alternative to these MCP-PMTs is multi-pixel photon counters (MPPC), known as silicon photomultipliers (SiPM). The SiPMs, in comparison to MCP-PMTs, have a lower cost, higher photon detection efficiency and are unaffected by the presence of a magnetic field, but also have a higher dark count rate that rapidly increases with the integrated neutron flux. The dark count rate can be mitigated by annealing the damaged devices and/or operating them at low temperatures. We tested SiPMs, with different dimensions and pixel sizes from different producers, to study their time resolution (the main constraint that has to satisfy the photon detector) and to understand their behavior and tolerance to radiation. For these studies we irradiated the devices to radiation up to $5\times {10}^{11}1$ MeV neutrons equivalent (neq) per cm² fluences; we also started studying the effect of annealing on dark count rates. We performed several measurements on these devices, on top of the dark count rate, at different conditions in terms of overvoltage and temperatures. These measurements are: IV-curves, amplitude spectra, time resolution. For the last two measurements we illuminated the devices with a picosecond pulsed laser at very low intensities (with a number of detected photons up to about twenty). We present results mainly on two types of SiPMs. A new SiPM prototype developed in collaboration with FBK with the aim of improving radiation hardness, is expected to be delivered in September 2025. Full article

In recent years, protecting stainless steel from corrosion has become crucial, particularly in harsh environments. The present study focuses on improving the photocathodic corrosion resistance of 304 stainless steel (304SS) by fabricating TiO₂/CuO composite coatings using the spin coating technique with varying CuO weight percentages. Structural characterization through X-ray diffraction (XRD) confirmed the presence of the anatase phase of TiO₂ and the successful integration of CuO. Raman spectroscopy demonstrated redshifts in the TiO₂ characteristic peaks, suggesting changes in bond lengths attributed to CuO incorporation. These findings were further corroborated by Fourier-transform infrared (FTIR) spectroscopy. Surface characterization showed uniform, porous coatings with pore sizes ranging from 75 to 200 nm, which contributed to improved barrier properties. UV–visible diffuse reflectance spectroscopy (UV-DRS) demonstrated enhanced visible light absorption in the heterostructures. Mott–Schottky analysis confirmed improved charge carrier density and favorable band alignment, facilitating efficient charge separation. The electrochemical performance was evaluated in 3.5% NaCl solution under dark and light environments. The results demonstrated that the TiO₂/CuO heterostructure significantly enhanced electron transfer and suppressed electron-hole recombination, providing adequate photocathodic protection. Notably, under illumination, the TiO₂/CuO (0.005 g) coating achieved a corrosion potential of −255 mV vs SCE and reduced the corrosion current density to 0.460 × 10⁻⁶ mA cm⁻². These findings suggest that TiO₂/CuO coatings offer a promising, durable, and cost-effective solution for corrosion protection in industries such as oil, shipbuilding, and pipelines. Full article

The optimization of photoinjector brightness is crucial for achieving the highest performance at X-ray free-electron lasers. To this end, photocathode laser pulse shaping has been identified as a key technology for enhancing photon flux and lasing efficiency at short wavelengths. Supported by beam dynamics simulations, we identify transversely and longitudinally truncated Gaussian electron bunches as a beneficial bunch shape in terms of the projected emittance and 5D brightness. The realization of such pulses from chirped Gaussian pulses is studied for 514 nm and 257 nm wavelengths by inserting an amplitude mask in the symmetry plane of the pulse stretcher to achieve longitudinal shaping and an aperture for transverse beam shaping. Using this scheme, transversely and longitudinally truncated Gaussian pulses can be generated and later used for the production of up to 3 nC electron bunches in the photoinjector. The 3D pulse shape at a wavelength of 514 nm is characterized via imaging spectroscopy, and second-harmonic generation frequency-resolved optical gating (SHG FROG) measurements are also performed to analyze the shaping scheme’s efficacy. Furthermore, this pulse-shaping scheme is transferred to a UV stretcher, allowing for direct application of the shaped pulses to cesium telluride photocathodes. Full article

This study focuses on enhancing the photoelectrocatalytic (PEC) performance of LaFeO₃ photocathodes by incorporating Ag nanocrystals. LaFeO₃, a perovskite-type metal oxide semiconductor, has potential in PEC water splitting but suffers from fast charge carrier recombination. Ag nanoparticles are introduced due to their surface plasmon resonance (SPR) property and ability to form Schottky junctions with LaFeO₃. A series of Ag/LaFeO₃ materials are prepared using the molten salt method for LaFeO₃ synthesis and the direct reduction method for Ag loading. The results show that Ag nanoparticles are uniformly dispersed on LaFeO₃. The 3 mol% Ag/LaFeO₃ photocathode demonstrates a remarkable ninefold increase in photocurrent density (15 mA·cm⁻² at −0.2 V vs. RHE) compared to pure LaFeO₃ (1.7 mA·cm⁻²). The band gap of LaFeO₃ is reduced from 2.07 eV to 1.92 eV with 3 mol% Ag loading, and the charge transfer impedance is reduced by 77%, while the carrier concentration increases by 2.3 times. The novelty of this work lies in the comprehensive investigation of the interaction mechanisms between Ag nanoparticles and LaFeO₃, which lead to enhanced light absorption, improved charge separation, and increased electrochemical activity. The optimized Ag loading not only improves the photocatalytic efficiency but also enhances the stability of the photocathode. This work provides valuable insights into the interaction between Ag and LaFeO₃, and offers experimental and theoretical support for developing efficient photocatalytic materials for PEC water splitting. Full article

Developing high-efficiency photoelectrodes plays an important role in the photoelectrocatalytic generation of hydrogen peroxide (H₂O₂) in the photoelectrochemical (PEC) water splitting field. In this work, an innovative strategy was proposed, the synergistic photocatalytic production of H₂O₂ using a bidirectional photoanode–photocathode coupling system under visible-light irradiation. Fe₂O₃-Ti, as the photoanode, which was built by way of Fe₂O₃ loaded on Ti-mesh using the hydrothermal-calcination method, was investigated in terms of the suitability of its properties for PEC H₂O₂ production after optimization of the bias voltage, the type of electrolyte solution, and the concentration of the electrolyte. Afterwards, a H-type double-electrode coupling system with an Fe₂O₃-Ti photoanode and a WO₃@Co₂SnO₄ photocathode was established for the bidirectional synergistic production of H₂O₂ under visible-light irradiation. The yield of H₂O₂ reached 919.56 μmol·L⁻¹·h⁻¹ in 2 h over −0.7 V with 1 mol·L⁻¹ of KHCO₃ as the anolyte and 0.1 mol·L⁻¹ Na₂SO₄ as the catholyte (pH = 3). It was inferred that H₂O₂ production on the WO₃@Co₂SnO₄ photocathode was in line with the 2e^- oxygen reduction reaction (ORR) principle, and on the Fe₂O₃-Ti photoanode was in line with the 2e^- water oxidation reaction (WOR) rule, or it was indirectly promoted by the electrolyte solution KHCO₃. This work provides an innovative idea and a reference for anode–cathode double coupling systems for the bidirectional production of H₂O₂. Full article

We prepared antimony metal films via electrodeposition, followed by the synthesis of Sb₂S₃ films through a chemical vapor phase reaction. Finally, an Sb₂O₃ film was deposited onto the Sb₂S₃ film using a chemical bath method, successfully constructing a heterojunction photocathode of Sb₂S₃/Sb₂O₃; the synthesized Sb₂S₃/Sb₂O₃ heterojunction is classified as a Type I heterostructure. The resulting Sb₂S₃/Sb₂O₃ heterojunction exhibited a photocurrent density of −0.056 mA cm⁻² at −0.15 V (vs. RHE), which is 1.40 times higher than that of Sb₂S₃ alone under simulated solar illumination. Additionally, the Sb₂S₃/Sb₂O₃ heterojunction demonstrated a lower carrier recombination rate and a faster charge transfer rate compared to Sb₂S₃, as evidenced by photoluminescence and electrochemical impedance spectroscopy tests. For these reasons, the Sb₂S₃/Sb₂O₃ heterojunction obtained a hydrogen precipitation rate of 0.163mL cm⁻² h⁻¹, which is twice the hydrogen precipitation rate of Sb₂S₃, under the condition of 60 min of light exposure. The significant enhancement in photoelectrochemical performance is attributed to the formation of the Sb₂S₃/Sb₂O₃ heterojunction, which improves both carrier separation and charge transfer efficiency. This heterojunction strategy holds promising potential for visible light-driven photoelectrochemical water splitting. Full article

Copper(I) oxide (Cu₂O)-based photocathodes are promising materials for carbon dioxide (CO₂) reduction under visible light due to copper’s abundance and favorable energy band alignment. However, Cu₂O suffers from photocorrosion and chemical instability. Here, we present a novel approach utilizing a porous titanosilicate material (ETS-10) as a protective layer for Cu₂O, addressing these limitations. The Cu₂O was electrodeposited and coated with a thin ETS-10 layer, which prevents photocorrosion, enhances charge separation and transfer, and facilitates CO₂ capture through its highly porous structure. Comprehensive structural, compositional, and morphological analyses confirmed that ETS-10 effectively stabilized Cu₂O while maintaining its electronic properties (UV–Vis, XPS). The Cu₂O/ETS-10 photocathode exhibited a 25% enhancement in the photocurrent density at 0.0–0.1 V vs. RHE and significantly improved stability compared to bare Cu₂O. The thin ETS-10 layer acted as a passivation layer, improving charge transfer via tunneling mechanisms. This study introduces a multicomponent photocathode system, demonstrating a new application of ETS-10 in photoelectrochemical cells. The results highlight the potential of ETS-10 to enhance the efficiency and stability of photocathodes, offering a pathway for the design of advanced systems for solar-driven CO₂ reduction and artificial photosynthesis. Full article

Z-scheme Zn₃In₂S₆/NiFe₂O₄ nanocomposites were prepared by electrospinning and hydrothermal methods, and their photocathodic protection performance was studied on 304 SS and Q235 CS in NaCl solution (3.5 wt.%). The two-dimensional Zn₃In₂S₆ loaded on the one-dimensional NiFe₂O₄ resulted in faster electron migration and enhanced light absorption capability. Moreover, it had been observed through electrochemical testing that the assembly of Zn₃In₂S₆/NiFe₂O₄ heterojunctions improves the efficacy of photocathodic protection. Following illumination, the self-corrosion potentials of 304 SS and Q235 CS coupled with Zn₃In₂S₆/NiFe₂O₄ nanocomposites decreased by 1040 mV and 560 mV, and the photoinduced current densities were 1.2 times and 3.9 times greater than the value of Zn₃In₂S₆. Furthermore, the mechanism of enhanced photocathodic protection performance for Zn₃In₂S₆/NiFe₂O₄ heterojunctions was systematically discussed. XPS and ESR analysis indicated that Zn₃In₂S₆/NiFe₂O₄ composites follow the Z-scheme electron migration path and retain the stronger reduction and oxidation capacity of Zn₃In₂S₆/NiFe₂O₄. Therefore, the Z-scheme heterostructures are responsible for the realization of cathodic protection for carbon steel. Full article

Water photoelectrolysis cells based on photoelectrochemical water splitting seem to be an interesting alternative to other traditional green hydrogen generation processes (e.g., water electrolysis). Unfortunately, the practical application of this technology is currently hindered by several difficulties: low solar-to-hydrogen (STH) efficiency, expensive electrode materials, etc. A novel concept, based on a tandem photoelectrolysis cell configuration with an anion-conducting membrane separating the photoanode from the photocathode, has already been proposed in the literature. This approach allows the use of low-cost metal oxide electrodes and nickel-based co-catalysts. In this paper, we conducted a study to evaluate the economic and environmental sustainability of this technology, using the environmental life cycle cost. Preliminary results have revealed two main interesting aspects: the negligible percentage of externalities in the total cost (<0.15%), which means a positive environmental impact, and as evidenced by the net present value (NPV), there are potentially financial conditions that favour future investment. In fact, an NPV higher than 150,000 EUR can be achieved after 15 years. Full article

In this study, the luminescence efficiency of a crystal-form barium fluoride (BaF₂) inorganic scintillator was assessed for medical imaging applications. For the experiments, we used a typical medical X-ray tube (50–140 kVp) for estimating the absolute luminescence efficiency (AE). Furthermore, we examined the spectral matching of the inorganic scintillator with a series of optical detectors. BaF₂ showed a higher AE than cerium fluoride (CeF₃), comparable to that of commercially available bismuth germanate (Bi₄Ge₃O₁₂-BGO), but lower than that of the gadolinium orthosilicate (Gd₂SiO₅:Ce-GSO:Ce) inorganic scintillator. The maximum AE of BaF₂ was 2.36 efficiency units (EU is the S.I. equivalent μWm⁻²/(mR/s) at 140 kVp, which is higher than that of the corresponding fluoride-based CeF₃ (0.8334 EU)) at the same X-ray energy. GSO:Ce and BGO crystals, which are often integrated in commercial positron emission tomography (PET) scanners, had AE values of 7.76 and 3.41, respectively. The emission maximum (~310 nm) of BaF₂ is adequate for coupling with flat-panel position-sensitive (PS) photomultipliers (PMTs) and various photocathodes. The luminescence efficiency results of BaF₂ were comparable to those of BGO; thus, it could possibly be used in medical imaging modalities, considering its significantly lower cost. Full article

The present study investigates the effect of manganese incorporation on the structural, dielectric, and waste bioconversion of LiTaO₃ ferroelectric material. Conventional solid-state synthesis techniques were utilized to produce powder samples, which were subsequently analyzed using room-temperature X-ray diffraction (XRD) for phase identification. The analysis revealed that the material forms a continuous solid solution within the composition range of 0 to 25 mol% of manganese (Mn), exhibiting R3c-Rombohedral symmetry. Thermal investigations of Raman spectra permitted approaching the ferroelectric–paraelectric phase transition, and dielectric measurements were performed in all investigated samples. The results show that the temperature of ferroelectric-paraelectric phase transition (Tc) decreased with the increasing Mn content. Optical properties of the prepared materials were also measured and tested as photocathodes for microbial fuel cells (MFCs), showing promising performance for x = 0.10, which exceeds values found with other dopants. Full article

Delafossite CuFeO₂ has emerged as a promising earth-abundant p-type photocathode for solar fuel generation due to its stability in aqueous conditions and its favorable light absorption characteristics. However, practical photocurrent generation in CuFeO₂ has consistently fallen short of its theoretical potential. This limitation is attributed primarily to suboptimal practical visible light absorption, resulting in diminished incident photon-to-current conversion efficiency (IPCE). Challenges related to charge separation and transport, originating from low acceptor density and inherent low conductivity, further contribute to the reported suboptimal performance of delafossite CuFeO₂. Thus, the present review comprehensively documents the latest advancements in the field of CuFeO₂ photocathode research, with a particular emphasis on strategies to overcome the challenges currently being faced and on the illustration of pathways that may lead to the enhancement of critical performance parameters such as photocurrents, photovoltage, and fill factor. Full article

The intensified charge-coupled device (ICCD), known for its exceptional low-light detection performance and time-gating capability, has been widely applied in remote Raman spectroscopy systems. However, existing ICCDs face significant challenges in meeting the comprehensive requirements of high gating speed, high sensitivity, high resolution, miniaturization, and adaptability to extreme environments for the upcoming lunar remote Raman spectroscopy missions. To address these challenges, this study developed a microstrip photocathode (MP-ICCD) specifically designed for lunar remote Raman spectroscopy. A comprehensive testing method was also proposed to evaluate critical performance parameters, including optical gating width, optimal gain voltage, and relative resolution. The MP-ICCD was integrated into a prototype remote Raman spectrometer equipped with a 40 mm aperture telescope and tested under outdoor sunlight conditions. The experimental results demonstrated that the developed MP-ICCD successfully achieved a minimum optical gating width of 6.0 ns and an optimal gain voltage of 870 V, with resolution meeting the requirements for Raman spectroscopy detection. Under outdoor solar illumination, the prototype remote Raman spectrometer utilizing the MP-ICCD accurately detected the Raman spectra of typical lunar minerals, including quartz, olivine, pyroxene, and plagioclase, at a distance of 1.5 m. This study provides essential technical support and experimental validation for the application of MP-ICCD in lunar Raman spectroscopy missions. Full article