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Search Results (185)

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Keywords = periodic boundary value condition

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21 pages, 10296 KiB  
Article
Spatiotemporal Mechanical Effects of Framework–Slope Systems Under Frost Heave Conditions
by Wendong Li, Xiaoqiang Hou, Jixian Ren and Chaoyang Wu
Appl. Sci. 2025, 15(14), 7877; https://doi.org/10.3390/app15147877 - 15 Jul 2025
Viewed by 203
Abstract
To investigate the slope instability caused by differential frost heaving mechanisms from the slope crest to the toe during frost heave processes, this study takes a typical silty clay slope in Xinjiang, China, as the research object. Through indoor triaxial consolidated undrained shear [...] Read more.
To investigate the slope instability caused by differential frost heaving mechanisms from the slope crest to the toe during frost heave processes, this study takes a typical silty clay slope in Xinjiang, China, as the research object. Through indoor triaxial consolidated undrained shear tests, eight sets of natural and frost-heaved specimens were prepared under confining pressure conditions ranging from 100 to 400 kPa. The geotechnical parameters of the soil in both natural and frost-heaved states were obtained, and a spatiotemporal thermo-hydro-mechanical coupled numerical model was established to reveal the dynamic evolution law of anchor rod axial forces and the frost heave response mechanism between the frame and slope soil. The analytical results indicate that (1) the frost heave process is influenced by slope boundaries, resulting in distinct spatial variations in the temperature field response across the slope surface—namely pronounced responses at the crest and toe but a weaker response in the mid-slope. (2) Under the coupled drive of the water potential gradient and gravitational potential gradient, the ice content in the toe area increases significantly, and the horizontal frost heave force exhibits exponential growth, reaching its peak value of 92 kPa at the toe in February. (3) During soil freezing, the reverse stress field generated by soil arching shows consistent temporal variation trends with the temperature field. Along the height of the soil arch, the intensity of the reverse frost heave force field displays a nonlinear distribution characteristic of initial strengthening followed by attenuation. (4) By analyzing the changes in anchor rod axial forces during frost heaving, it was found that axial forces during the frost heave period are approximately 1.3 times those under natural conditions, confirming the frost heave period as the most critical condition for frame anchor design. Furthermore, through comparative analysis with 12 months of on-site anchor rod axial force monitoring data, the reliability and accuracy of the numerical simulation model were validated. These research outcomes provide a theoretical basis for the design of frame anchor support systems in seasonally frozen regions. Full article
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15 pages, 299 KiB  
Article
Relation-Theoretic Boyd–Wong Contractions of Pant Type with an Application to Boundary Value Problems
by Doaa Filali and Faizan Ahmad Khan
Mathematics 2025, 13(14), 2226; https://doi.org/10.3390/math13142226 - 8 Jul 2025
Viewed by 155
Abstract
Non-unique fixed-point theorems play a pivotal role in the mathematical modeling to solve certain typical equations, which admit more than one solution. In such situations, traditional outcomes fail due to uniqueness of fixed points. The primary aim of the present article is to [...] Read more.
Non-unique fixed-point theorems play a pivotal role in the mathematical modeling to solve certain typical equations, which admit more than one solution. In such situations, traditional outcomes fail due to uniqueness of fixed points. The primary aim of the present article is to investigate a non-unique fixed-point theorem in the framework of a metric space endowed with a local class of transitive binary relations. To obtain our main objective, we introduce a new nonlinear contraction-inequality that subsumes the ideas involved in four noted contraction conditions, namely: almost contraction, Boyd–Wong contraction, Pant contraction and relational contraction. We also establish the corresponding uniqueness theorem for the proposed contraction under some additional hypotheses. Several examples are furnished to illustrate the legitimacy of our newly proved results. In particular, we deduce a fixed-point theorem for almost Boyd–Wong contractions in the setting of abstract metric space. Our results generalize, enhance, expand, consolidate and develop a number of known results existing in the literature. The practical relevance of the theoretical findings is demonstrated by applying to study the existence and uniqueness of solution of a specific periodic boundary value problem. Full article
23 pages, 5565 KiB  
Article
Advanced Numerical Analysis of Heat Transfer in Medium and Large-Scale Heat Sinks Using Cascaded Lattice Boltzmann Method
by Fatima Zahra Laktaoui Amine, Mustapha El Alami, Elalami Semma, Hamza Faraji, Ayoub Gounni and Amina Mourid
Appl. Sci. 2025, 15(13), 7205; https://doi.org/10.3390/app15137205 - 26 Jun 2025
Viewed by 278
Abstract
Medium- and large-scale heat sinks are critical for thermal load management in high-performance systems. However, their high heat flux densities and limited space complicate cooling, leading to risks of overheating, performance degradation, or failure. This study employs the Cascaded Lattice Boltzmann Method (CLBM) [...] Read more.
Medium- and large-scale heat sinks are critical for thermal load management in high-performance systems. However, their high heat flux densities and limited space complicate cooling, leading to risks of overheating, performance degradation, or failure. This study employs the Cascaded Lattice Boltzmann Method (CLBM) to enhance their thermal performance. This numerical approach is known for being stable, accurate when dealing with complex boundaries, and efficient when computing in parallel. The numerical code was validated against a benchmark configuration and an experimental setup to ensure its reliability and accuracy. While previous studies have explored mixed convection in cavities or heat sinks, few have addressed configurations involving side air injection and boundary conditions periodicity in the transition-to-turbulent regime. This gap limits the understanding of realistic cooling strategies for compact systems. Focusing on mixed convection in the transition-to-turbulent regime, where buoyancy and forced convection interact, the study investigates the impact of Rayleigh number values (5×107 to 5×108) and Reynolds number values (103 to 3×103) on heat transfer. Simulations were conducted in a rectangular cavity with periodic boundary conditions on the vertical walls. Two heat sources are located on the bottom wall (Th = 50 °C). Two openings, one on each side of the two hot sources, force a jet of fresh air in from below. An opening at the level of the cavity ceiling’s axis of symmetry evacuates the hot air. Mixed convection drives the flow, exhibiting complex multicellular structures influenced by the control parameters. Calculating the average Nusselt number (Nu) across the surfaces of the heat sink reveals significant dependencies on the Reynolds number. The proposed correlation between Nu and Re, developed specifically for this configuration, fills the current gap and provides valuable insights for optimizing heat transfer efficiency in engineering applications. Full article
(This article belongs to the Special Issue Recent Research on Heat and Mass Transfer)
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7 pages, 833 KiB  
Communication
Nonlinear Waves of a Surface Charge at the Boundary of a Semi-Infinite Cold Plasma in a Constant Magnetic Field
by Oleg M. Gradov
Physics 2025, 7(2), 16; https://doi.org/10.3390/physics7020016 - 14 May 2025
Viewed by 408
Abstract
In this paper, an equation describing nonlinear wave phenomena on the surface of magnetically active plasma in the approximation of the complete homogeneity of processes along the direction of the constant magnetic field is obtained. One of its solutions, in the form of [...] Read more.
In this paper, an equation describing nonlinear wave phenomena on the surface of magnetically active plasma in the approximation of the complete homogeneity of processes along the direction of the constant magnetic field is obtained. One of its solutions, in the form of a pulse having the shape of rapidly decaying oscillations with a changing period, is found to essentially depend on the magnitude of the magnetic field and shown to be approximately described by a specially selected analytical function. A detailed analytical analysis of the properties of another solitary wave formation existing under conditions of resonant coincidence of its carrier frequency with the corresponding value of its eigen surface oscillations in the considered cold semi-infinite plasma, in which a constant magnetic field is directed along its boundary, is also carried out. The conditions for the excitation of wave disturbances are determined, and analytical expressions that adequately describe the space–time structure of nonlinear waves are proposed. Full article
(This article belongs to the Section Statistical Physics and Nonlinear Phenomena)
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20 pages, 3656 KiB  
Article
Parametric Building Envelopes Rationalized in Terms of Their Solar Performance in a Temperate Climate
by Jacek Abramczyk and Wiesław Bielak
Energies 2025, 18(10), 2479; https://doi.org/10.3390/en18102479 - 12 May 2025
Viewed by 361
Abstract
The article presents a method of shaping unconventional building envelopes characterized by their effective solar performance in a temperate climate. An analysis related to the impact of geometric shape on the solar direct radiation falling on building envelopes was presented in terms of [...] Read more.
The article presents a method of shaping unconventional building envelopes characterized by their effective solar performance in a temperate climate. An analysis related to the impact of geometric shape on the solar direct radiation falling on building envelopes was presented in terms of polyhedral forms. It was based on interdisciplinary issues located in the fields of solar radiation, unconventional forms of buildings, numerical simulations, and artificial neural networks. The elaborated method’s algorithm was employed to describe the relationships between the envelope systems and the amount of the radiation falling on these systems, identified during the performed simulations. Two novel parametric models were defined to execute the simulations. The first was an initial geometric model defined by a number of arbitrary independent variables. The second was defined by one dependent variable representing the quantity of the solar radiation falling on each envelope. The analysis carried out showed that the invented trapezoidal forms of envelopes allowed for better control of the incident solar radiation in relation to the forms generated with other methods. The invented trapezoidal forms of envelopes can increase the amount of their direct solar irradiation up to 63%, compared to prior pyramidal forms. Although the climatic loads used were related to Strzyżów characterized by the geographical coordinates 49.9 N and 21.9 E and located in Central Europe, it was possible to adapt the method to other meteorological boundary conditions by changing the values of the defined parameters. The resultant parametric solar model can be employed to search for many diversified discrete solar envelopes of buildings and rational arrangements of their external planes so that the direct solar radiation falling on these envelopes can be increased during cold periods and restricted during hot summer periods of the year. Full article
(This article belongs to the Special Issue Advances in Energy Efficiency and Conservation of Green Buildings)
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22 pages, 3493 KiB  
Article
Oscillations of the Oil Pipeline Axis with Consideration of the Inertia Component When Pumping Diesel Fuel
by Roman Tutko and Vasyl Lozynskyi
Energies 2025, 18(10), 2472; https://doi.org/10.3390/en18102472 - 12 May 2025
Viewed by 450
Abstract
This study examines a single-span beam crossing without longitudinal deformation compensators during diesel fuel pumping. In addition to static forces, namely, the weight of the pipeline and the transported product, the analysis considers vertical components of inertial forces acting on the oil product [...] Read more.
This study examines a single-span beam crossing without longitudinal deformation compensators during diesel fuel pumping. In addition to static forces, namely, the weight of the pipeline and the transported product, the analysis considers vertical components of inertial forces acting on the oil product and the pipeline itself. These forces are directed perpendicularly to the abscissa axis connecting the endpoints of the crossing. The inertial effects cause significant vertical oscillations of the pipeline, which have not been sufficiently addressed in previous research. This work aims to study these oscillations to determine the displacements of points along the pipeline axis, the magnitudes of the inertial forces, and the resulting bending moments at the crossing. A classical Fourier series method is applied to solve the formulated boundary value problem. The results show that oscillations occur in the vertical plane, are symmetrical relative to the center of the span, and are undamped. The maximum vertical displacement reaches approximately 57 mm at the midpoint of the crossing, and the oscillation period is around 0.415 s. Inertial force distribution and bending moments are also symmetric about the center. A detailed analysis with small time steps confirmed that the oscillations are strictly periodic, exhibiting equal displacements in the upward and downward directions. The results highlight that fatigue loads arise during the operation of such crossings, which is important for assessing the strength and stability of oil pipeline structures under real operating conditions. Full article
(This article belongs to the Special Issue Advances in Gas Transportation by Pipeline and LNG)
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19 pages, 5605 KiB  
Article
Toward a Sustainable Indoor Environment: Coupling Geothermal Cooling with Water Recovery Through EAHX Systems
by Cristina Baglivo, Alessandro Buscemi, Michele Spagnolo, Marina Bonomolo, Valerio Lo Brano and Paolo Maria Congedo
Energies 2025, 18(9), 2297; https://doi.org/10.3390/en18092297 - 30 Apr 2025
Viewed by 446
Abstract
This study presents a preliminary analysis of an innovative system that combines indoor air conditioning with water recovery and storage. The device integrates Peltier cells with a horizontal Earth-to-Air Heat Exchanger (EAHX), exploiting the ground stable temperature to enhance cooling and promote condensation. [...] Read more.
This study presents a preliminary analysis of an innovative system that combines indoor air conditioning with water recovery and storage. The device integrates Peltier cells with a horizontal Earth-to-Air Heat Exchanger (EAHX), exploiting the ground stable temperature to enhance cooling and promote condensation. Warm, humid air is pre-cooled via the geothermal pipe, then split by a fan into two streams: one passes over the cold side of the Peltier cells for cooling and dehumidification, while the other flows over the hot side and heats up. The two airstreams are then mixed in a water storage tank, which also serves as a thermal mixing chamber to regulate the final air temperature. The analysis investigates the influence of soil thermal conditions on condensation within the horizontal pipe and the resulting cooling effect in indoor spaces. A hybrid simulation approach was adopted, coupling a 3D model implemented in COMSOL Multiphysics® with a 1D analytical model. Boundary conditions and meteorological data were based on the Typical Meteorological Year (TMY) for Palermo. Two scenarios were considered. In Case A, during the hours when air conditioning is not operating (between 11 p.m. and 9 a.m.), air is circulated in the exchanger to pre-cool the ground and the air leaving the exchanger is rejected into the environment. In Case B, the no air is not circulated in the heat exchanger during non-conditioning periods. Results from the June–August period show that the EAHXs reduced the average outdoor air temperature from 27.81 °C to 25.45 °C, with relative humidity rising from 58.2% to 66.66%, while maintaining nearly constant specific humidity. The system exchanged average powers of 102 W (Case A) and 96 W (Case B), corresponding to energy removals of 225 kWh and 212 kWh, respectively. Case A, which included nighttime soil pre-cooling, showed a 6% increase in efficiency. Condensation water production values range from around 0.005 g/s with one Peltier cell to almost 0.5 g/s with seven Peltier cells. As the number of Peltier cells increases, the cooling effect becomes more pronounced, reducing the output temperature considerably. This solution is scalable and well-suited for implementation in developing countries, where it can be efficiently powered by stand-alone photovoltaic systems. Full article
(This article belongs to the Section B: Energy and Environment)
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25 pages, 7113 KiB  
Article
Assessing Characteristics of Strong Dynamic Loads in Deep Coal Mining and Their Mechanisms in Triggering Secondary Disasters
by Wentao Ren, Jiazhuo Li, Xuwei Li, Changbin Wang, Shun Liu and Hang Qiu
Appl. Sci. 2025, 15(8), 4529; https://doi.org/10.3390/app15084529 - 19 Apr 2025
Viewed by 305
Abstract
After entering deep mining, coal mines often experience various intense dynamic load phenomena due to increasingly complex geological conditions, which can lead to secondary disasters, where it is urgent to identify their sources and analyze their disaster-causing effects. This article takes the 3310 [...] Read more.
After entering deep mining, coal mines often experience various intense dynamic load phenomena due to increasingly complex geological conditions, which can lead to secondary disasters, where it is urgent to identify their sources and analyze their disaster-causing effects. This article takes the 3310 working face in Gu Cheng Coal Mine as the engineering background, and uses theoretical analysis, numerical simulation, on-site monitoring, and other methods to analyze the spatial and temporal distribution of dynamic load events during the mining period of this face. The study classifies dynamic load events based on this background into roof-type, fault-type, and coal pillar-type classes, revealing the differences in the spectra, waveforms, and disaster-causing effects of each class. The results show that the strong dynamic load events are mainly concentrated in the working face roof and fault zone areas. The first principal frequency of the three classes has an estimated boundary between 30 and 60 Hz. The waveform decay coefficients of the roof-type, coal pillar-type, and fault-type strong dynamic load events have average values of 4.53, 1.57, and 1.41, respectively. By adopting the above research methods, a theoretical basis can be provided for the source of dynamic loads, thereby achieving source-based prevention and control of rock burst. Full article
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20 pages, 2862 KiB  
Article
Characterizing Seasonal Variation of the Atmospheric Mixing Layer Height Using Machine Learning Approaches
by Yufei Chu, Guo Lin, Min Deng, Hanqing Guo and Jun A. Zhang
Remote Sens. 2025, 17(8), 1399; https://doi.org/10.3390/rs17081399 - 14 Apr 2025
Cited by 1 | Viewed by 523
Abstract
As machine learning becomes more integrated into atmospheric science, XGBoost has gained popularity for its ability to assess the relative contributions of influencing factors in the atmospheric boundary layer height. To examine how these factors vary across seasons, a seasonal analysis is necessary. [...] Read more.
As machine learning becomes more integrated into atmospheric science, XGBoost has gained popularity for its ability to assess the relative contributions of influencing factors in the atmospheric boundary layer height. To examine how these factors vary across seasons, a seasonal analysis is necessary. However, dividing data by season reduces the sample size, which can affect result reliability and complicate factor comparisons. To address these challenges, this study replaces default parameters with grid search optimization and incorporates cross-validation to mitigate dataset limitations. Using XGBoost with four years of data from the atmospheric radiation measurement (ARM) (Southern Great Plains (SGP) C1 site, cross-validation stabilizes correlation coefficient fluctuations from 0.3 to within 0.1. With optimized parameters, the R value can reach 0.81. Analysis of the C1 site reveals that the relative importance of different factors changes across seasons. Lower tropospheric stability (LTS, ~0.53) is the dominant factor at C1 throughout the year. However, during DJF, latent heat flux (LHF, 0.44) surpasses LTS (0.22). In SON, LTS (0.58) becomes more influential than LHF (0.18). Further comparisons among the four long-term SGP sites (C1, E32, E37, and E39) show seasonal variations in relative importance. Notably, during JJA, the differences in the relative importance of the three factors across all sites are lower than in other seasons. This suggests that boundary layer development in the summer is not dominated by a single factor, reflecting a more intricate process likely influenced by seasonal conditions such as enhanced convective activity, higher temperatures, and humidity, which collectively contribute to a balanced distribution of parameter impacts. Furthermore, the relative importance of LTS gradually increases from morning to noon, indicating that LTS becomes more significant as the boundary layer approaches its maximum height. Consequently, the LTS in the early morning in autumn exhibits greater relative importance compared to other seasons. This reflects a faster development of the mixing layer height (MLH) in autumn, suggesting that it is easier to retrieve the MLH from the previous day during this period. The findings enhance understanding of boundary layer evolution and contribute to improved boundary layer parameterization. Full article
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18 pages, 16053 KiB  
Article
Modelling the Transition from Shear-Driven Turbulence to Convective Turbulence in a Vertical Heated Pipe
by Shijun Chu, Elena Marensi and Ashley P. Willis
Mathematics 2025, 13(2), 293; https://doi.org/10.3390/math13020293 - 17 Jan 2025
Viewed by 855
Abstract
Heated pipe flow is widely used in thermal engineering applications, but the presence of buoyancy force can cause intermittency, or multiple flow states at the same parameter values. Such changes in the flow lead to substantial changes in its heat transfer properties and [...] Read more.
Heated pipe flow is widely used in thermal engineering applications, but the presence of buoyancy force can cause intermittency, or multiple flow states at the same parameter values. Such changes in the flow lead to substantial changes in its heat transfer properties and thereby significant changes in the axial temperature gradient. We therefore introduce a model that features a time-dependent background axial temperature gradient, and consider two temperature boundary conditions—fixed temperature difference and fixed boundary heat flux. Direct numerical simulations (DNSs) are based on the pseudo-spectral framework, and good agreement is achieved between present numerical results and experimental results. The code extends Openpipeflow and is available at the website. The effect of the axially periodic domain on flow dynamics and heat transfer is examined, using pipes of length L=5D and L=25D. Provided that the flow is fully turbulent, results show close agreement for the mean flow and temperature profiles, and only slight differences in root-mean-square fluctuations. When the flow shows spatial intermittency, heat transfer tends to be overestimated using a short pipe, as shear turbulence fills the domain. This is particularly important when shear turbulence starts to be suppressed at intermediate buoyancy numbers. Finally, at such intermediate buoyancy numbers, we confirm that the decay of localised shear turbulence in the heated pipe flow follows a memoryless process, similar to that in isothermal flow. While isothermal flow then laminarises, convective turbulence in the heated flow can intermittently trigger bursts of shear-like turbulence. Full article
(This article belongs to the Special Issue Numerical Simulation and Methods in Computational Fluid Dynamics)
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45 pages, 65058 KiB  
Article
Pattern Dynamics Analysis of Host–Parasite Models with Aggregation Effect Based on Coupled Map Lattices
by Shuo Liang, Wenlong Wang and Chunrui Zhang
Mathematics 2025, 13(1), 125; https://doi.org/10.3390/math13010125 - 31 Dec 2024
Cited by 1 | Viewed by 764
Abstract
Host–parasitoid systems are an essential area of research in ecology and evolutionary biology due to their widespread occurrence in nature and significant impact on species evolution, population dynamics, and ecosystem stability. In such systems, the host is the organism being attacked by the [...] Read more.
Host–parasitoid systems are an essential area of research in ecology and evolutionary biology due to their widespread occurrence in nature and significant impact on species evolution, population dynamics, and ecosystem stability. In such systems, the host is the organism being attacked by the parasitoid, while the parasitoid depends on the host to complete its life cycle. This paper investigates the effect of parasitoid aggregation attacks on a host in a host–parasitoid model with self-diffusion on two-dimensional coupled map lattices. We assume that in the simulation of biological populations on a plane, the interactions between individuals follow periodic boundary conditions. The primary objective is to analyze the complex dynamics of the host–parasitoid interaction model induced by an aggregation effect and diffusion in a discrete setting. Using the aggregation coefficient k as the bifurcating parameter and applying central manifold and normal form analysis, it has been shown that the system is capable of Neimark–Sacker and flip bifurcations even without diffusion. Furthermore, with the influence of diffusion, the system exhibits pure Turing instability, Neimark–Sacker–Turing instability, and Flip–Turing instability. The numerical simulation section explores the path from bifurcation to chaos through calculations of the maximum Lyapunov exponent and the construction of a bifurcation diagram. The interconversion between different Turing instabilities is simulated by adjusting the timestep and self-diffusion coefficient values, which is based on pattern dynamics in ecological modeling. This contributes to a deeper understanding of the dynamic behaviors driven by aggregation effects in the host–parasitoid model. Full article
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18 pages, 621 KiB  
Article
On Non-Linear Differential Systems with Mixed Boundary Conditions
by Miklós Rontó
Axioms 2024, 13(12), 866; https://doi.org/10.3390/axioms13120866 - 11 Dec 2024
Viewed by 684
Abstract
For the constructive analysis of locally Lipschitzian system of non-linear differential equations with mixed periodic and two-point non-linear boundary conditions, a numerical-analytic approach is developed, which allows one to study the solvability and construct approximations to the solution. The values of the unknown [...] Read more.
For the constructive analysis of locally Lipschitzian system of non-linear differential equations with mixed periodic and two-point non-linear boundary conditions, a numerical-analytic approach is developed, which allows one to study the solvability and construct approximations to the solution. The values of the unknown solution at the two extreme points of the given interval are considered as vector parameters whose dimension is the same as the dimension of the given differential equation. The original problem can be reduced to two auxiliary ones, with simple separable boundary conditions. To study these problems, we introduce two different types of parametrized successive approximations in analytic form. To prove the uniform convergence of these series, we use the appropriate technique to see that they form Cauchy sequences in the corresponding Banach spaces. The two parametrized limit functions and the given boundary conditions generate a system of algebraic equations of suitable dimensions, the so-called system of determining equations, which give the numerical values of the introduced unknown parameters. We prove that the system of determining equations define all possible solutions of the given boundary value problems in the domain of definition. We established also the existence of the solution based on the approximate determining system, which can always be produced in practice. The theory was presented in detail in the case of a system of differential equations consisting of two equations and having two different solutions. Full article
(This article belongs to the Section Mathematical Analysis)
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19 pages, 603 KiB  
Article
Chebyshev Polynomials in the Physics of the One-Dimensional Finite-Size Ising Model: An Alternative View and Some New Results
by Nicholay S. Tonchev and Daniel Dantchev
Condens. Matter 2024, 9(4), 53; https://doi.org/10.3390/condmat9040053 - 2 Dec 2024
Viewed by 1391
Abstract
For studying the finite-size behavior of the Ising model under different boundary conditions, we propose an alternative to the standard transfer matrix technique approach based on Abelès theorem and Chebyshev polynomials. Using it, one can easily reproduce the known results for periodic boundary [...] Read more.
For studying the finite-size behavior of the Ising model under different boundary conditions, we propose an alternative to the standard transfer matrix technique approach based on Abelès theorem and Chebyshev polynomials. Using it, one can easily reproduce the known results for periodic boundary conditions concerning the Lee–Yang zeros, the exact position-space renormalization-group transformation, etc., and can extend them by deriving new results for antiperiodic boundary conditions. Note that in the latter case, one has a nontrivial order parameter profile, which we also calculate, where the average value of a given spin depends on the distance from the seam with the opposite bond in the system. It is interesting to note that under both boundary conditions, the one-dimensional case exhibits Schottky anomaly. Full article
(This article belongs to the Section Condensed Matter Theory)
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25 pages, 14449 KiB  
Article
Formation Mechanism of Muji Travertine in the Pamirs Plateau, China
by Haodong Yang, Xueqian Wu, Huqun Cui, Wen Wang, Yuanfeng Cheng, Xiangkuan Gong, Xilu Luo and Qingxia Lin
Minerals 2024, 14(12), 1192; https://doi.org/10.3390/min14121192 - 23 Nov 2024
Viewed by 1159
Abstract
The Muji spring travertines, located in the Muji Basin in the eastern Pamirs Plateau, represent a typical spring deposit found on plateaus that is characterized by arid and semi-arid climatic conditions. However, its formation mechanisms remain poorly understood. This study aims to explore [...] Read more.
The Muji spring travertines, located in the Muji Basin in the eastern Pamirs Plateau, represent a typical spring deposit found on plateaus that is characterized by arid and semi-arid climatic conditions. However, its formation mechanisms remain poorly understood. This study aims to explore the recharge processes of the spring, the sedimentary environment, and the genetics of Muji spring travertines through a comparative analysis of conventional hydrochemistry, H-O stable isotope analysis of both spring and river water, and petrographic observation, as well as in situ analysis of major and trace elements present in calcite within travertines. The basin is surrounded by mountains with a topography that facilitates groundwater convergence within it. Carbonate-bearing strata are extensively developed around the basin, which serves as a crucial material foundation for travertine development. It infiltrates underground through fractures and faults, interacting with carbonate rocks to produce significant amounts of HCO3, Ca2+, and Mg2+. The observed range of isotopic compositions (δ2H, −102.27‰ to −96.43‰; δ18O, −14.90‰ to −14.36‰) in water samples suggests that their primary origin was from glacial and snowmelt sources. The concentration of HCO3 in spring water samples exhibits significant variability, with the highest value being 1646 mg·L−1, which deviates significantly from the typical composition of karst groundwater. During its migration, groundwater undergoes the dissolution of gaseous CO2 derived from deep metamorphic processes, leading to variable degrees of mixing with geothermal groundwater containing elevated concentrations of dissolved components that enhance the dissolution potential of carbonate rocks. Eventually, upwelling occurs along the Southwestern Boundary Fault of Muji, resulting in the formation of linear springs characterized by CO2 escape. The Muji laminated travertines exhibit distinct white and dark laminae, and radial coated grains consisting of micritic and sparry layers. Chemical composition analyses reveal significant differences in the trace and rare-earth element composition, as well as the Mg/Ca ratio, of the two types of travertines. Specifically, the micritic laminae of the pisoid (Mg/Ca = 0.019; Sr = 530 × 10−6; Ba = 64.6 × 10−6) and the dark laminae of the laminated travertine (Mg/Ca = 0.014; Sr = 523 × 10−6; Ba = 48.1 × 10−6) exhibit generally higher Mg/Ca ratios and Sr, Ba contents than the neighboring sparry laminae (Mg/Ca = 0.012; Sr = 517 × 10−6; Ba = 36.6 × 10−6) and white laminae (Mg/Ca = 0.006; Sr = 450 × 10−6; Ba = 35.6 × 10−6). The development of laminated travertines and radial coated grains here is attributed to periodic changes in groundwater recharge induced by seasonal temperature fluctuations, as evidenced by the structural characteristics of the two types of travertines and the trace element analysis of different layers. Algae play a role in forming the dark laminae of laminated travertines and the micritic laminae of pisoids. Full article
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30 pages, 6762 KiB  
Article
Linking Meteorological Variables and Particulate Matter PM2.5 in the Aburrá Valley, Colombia
by Juan C. Parra, Miriam Gómez, Hernán D. Salas, Blanca A. Botero, Juan G. Piñeros, Jaime Tavera and María P. Velásquez
Sustainability 2024, 16(23), 10250; https://doi.org/10.3390/su162310250 - 23 Nov 2024
Cited by 2 | Viewed by 1633
Abstract
Environmental pollution indicated by the presence of PM2.5 particulate matter varies based on prevailing atmospheric conditions described by certain meteorological variables. Consequently, it is important to understand atmospheric behavior in areas such as the Aburrá Valley, which experiences recurrent pollution events [...] Read more.
Environmental pollution indicated by the presence of PM2.5 particulate matter varies based on prevailing atmospheric conditions described by certain meteorological variables. Consequently, it is important to understand atmospheric behavior in areas such as the Aburrá Valley, which experiences recurrent pollution events twice a year. This study examines the behavior of specific meteorological variables and PM2.5 particulate matter in the Aburrá Valley. By using statistical analysis tools such as correlation coefficients, principal component analysis (PCA), and multiple linear regression models, the research identifies relationships between PM2.5 and daily cycles of temperature, rainfall, radiation, and wind speed and direction. Datasets were analyzed considering periods before and after the COVID-19 lockdown (pre-pandemic and pandemic, respectively), and specific pollution events were also analyzed. Furthermore, this work considers the relationships between PM2.5 and meteorological variables, contrasting the pre-pandemic and pandemic periods. This study characterizes diurnal cycles of meteorological variables and their relationship with PM2.5. There are consistent patterns among temperature, atmospheric boundary layer (ABL) height, and solar radiation, whereas precipitation and relative humidity show the opposite behavior. PM2.5 exhibits similar relative frequency functions during both daytime and nighttime, regardless of rainfall. An inverse relationship is noted between PM2.5 levels and ABL height at different times of the day. Moreover, the PCA results show that the first principal component explains around 60% of the total variance in the hydrometeorological data. The second PC explains 10%, and the rest of the variance is distributed among the other three to eight PCs. In this sense, there is no significant difference between the two PCAs with hydrometeorological data from a pre-pandemic period and a COVID-19 pandemic period. Multiple regression analysis indicates a significant and consistent dependence of PM2.5 on temperature and solar radiation across both analyzed periods. The application of Generalized Additive Models (GAMs) to our dataset yielded promising results, reflecting the complex relationship between meteorological variables and PM2.5 concentrations. The metrics obtained from the GAM were as follows: Mean Squared Error (MSE) of 98.04, Root Mean Squared Error (RMSE) of 9.90, R-squared (R2) of 0.24, Akaike Information Criterion (AIC) of 110,051.34, and Bayesian Information Criterion (BIC) of 110,140.63. In comparison, the linear regression model exhibited slightly higher MSE (100.49), RMSE (10.02), and lower R-squared (0.22), with AIC and BIC values of 110,407.45 and 110,460.67, respectively. Although the improvement in performance metrics from GAM over the linear model is not conclusive, they indicate a better fit for the complexity of atmospheric dynamics influencing PM2.5 levels. These findings underscore the intricate interplay of meteorological factors and particulate matter concentration, reinforcing the necessity for advanced modeling techniques in environmental studies. This work presents new insights that enhance the diagnosis, understanding, and modeling of environmental pollution, thereby supporting informed decision-making and strengthening management efforts. Full article
(This article belongs to the Special Issue Air Pollution Management and Environment Research)
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