Search Results (1,707)

This study investigates the behavior of phosphate ion transport through two structurally distinct anion-exchange membranes—AMV (homogeneous) and HC-A (heterogeneous)—in an electrodialysis system under both static and stirred conditions at varying pH levels. Chronopotentiometric and current–voltage analyses were used to investigate the influence of pH and hydrodynamics on ion transport. Under underlimiting (ohmic) conditions, the AMV membrane exhibited simultaneous transport of H₂PO₄⁻ and HPO₄²⁻ ions at neutral and mildly alkaline pH, while such behavior was not verified at acidic pH and in all cases for the HC-A membrane. Under overlimiting current conditions, AMV favored electroconvection at low pH and exhibited significant water dissociation at high pH, leading to local pH shifts and chemical equilibrium displacement at the membrane–solution interface. In contrast, the HC-A membrane operated predominantly under strong electroconvective regimes, regardless of the pH value, without evidence of water dissociation or equilibrium change phenomena. Stirring significantly impacted the electrochemical responses: it altered the chronopotentiogram profiles through the emergence of intense oscillations in membrane potential drop at overlimiting currents and modified the current–voltage behavior by increasing the limiting current density, reducing electrical resistance, and compressing the plateau region that separates ohmic and overlimiting regimes. Additionally, both membranes showed signs of NH₃ formation at the anodic-side interface under pH 7–8, associated with increased electrical resistance. These findings reveal distinct ionic transport characteristics and hydrodynamic sensitivities of the membranes, thus providing valuable insights for optimizing phosphate recovery via electrodialysis. Full article

The aim of this study was to determine the connection between oscillations in operating pressure values and the appearance of various irregularities on machined surfaces. Such oscillations are a consequence of the high water pressure generated during abrasive water jet machining. Oscillations in the operating pressure values are periodic, namely due to the cyclic operation of the intensifier and the physical characteristics of water. One of the most common means of reducing this phenomenon is installing an attenuator in the hydraulic system or a phased intensifier system. The main hypothesis of this study was that the topography of a machined surface is directly influenced by the inability of the pressure accumulator to fully absorb water pressure oscillations. In this study, we monitored changes in hydraulic oil pressure values at the intensifier entrance and their connection with irregularities on the machined surface—such as waviness—when cutting aluminum AlMg3 of different thicknesses. Experimental research was conducted in order to establish this connection. Aluminum AlMg3 of different thicknesses—from 6 mm to 12 mm—was cut with different traverse speeds while hydraulic oil pressure values were monitored. The pressure signals thus obtained were analyzed by applying the fast Fourier transform (FFT) algorithm. We identified a single-sided pressure signal amplitude spectrum. The frequency axis can be transformed by multiplying inverse frequency data with traverse speed; in this way, a single-sided amplitude spectrum can be obtained, examined against the period in which striations are expected to appear (in millimeters). In the lower zone of the analyzed samples, striations are observed at intervals determined by the dominant hydraulic oil pressure harmonics, which are transferred to the operating pressure. In other words, we demonstrate how the machined surface topography is directly induced by water jet pressure frequency characteristics. Full article

The dynamics of the vibrational mode of motion of the driving member of a nonideal system, a mixing–whipping device based on a simple slide-crank mechanism, was studied. The highly nonlinear differential equations of motion were solved numerically by the Runge–Kutta method. The interaction of the mixing–whipping device with the nonideal excitation source causes the rotational speed of the engine shaft and the rotation angle of the driving member to fluctuate, accomplishing a damped process. The parameters of the device and the nonideal energy source have an effect on the kinematic, vibrational and energy characteristics of the system. An increase in the engine’s torque, crank length, number and radius of piston holes, and piston mass, as well as a decrease in the fluid’s density, leads to a reduction in the oscillation range of the crank angle, amplitude and period of angular velocity oscillations of the engine shaft and the mixing–whipping force power. The effects of a nonideal energy source may be used in designing a mixing–whipping device based on a slider-crank mechanism to select effective system parameters and an energy-saving motor in accordance with the requirements of technological processes and products. Full article

Gantry cranes play a pivotal role in industrial production. Gantry cranes exhibit clear double-swing characteristics in actual working conditions, complicating anti-swing control. Most existing anti-swing control methods are based on a simplified single-pendulum model. The present paper puts forward a double-pendulum model for gantry cranes and proposes an adaptive hierarchical sliding mode control based on a neural network according to the actual working conditions. The use of a neural network and adaptive layered sliding mode control can effectively inhibit chattering, thus improving control performance and stability and achieving the goal of anti-shaking control, thus effectively inhibiting residual oscillation. This method has been demonstrated to be effective in achieving the objective of anti-shudder control, thereby effectively suppressing residual oscillation. Compared with hierarchical sliding mode control, the proposed method reduces the maximum residual oscillation angle of the hook and payload by approximately 80%. In comparison with the conventional sliding mode control, the maximum residual oscillation angle is reduced by approximately 84%. Furthermore, the control force amplitude is reduced to 5.23 N, representing decreases of 30.2% and 37.4%, respectively. These comparative results demonstrate the superior oscillation suppression. The system also shows a reliable performance against potential disturbances. Full article

Grid-forming (GFM) energy storage can be utilized as a backup power source for the power grid to ensure the security of the power grid. GFM energy storage can also enhance the strength of the power grid and improve its stability. However, the GFM energy storage inherits the characteristics of the synchronous generator. Low-frequency oscillations may occur in GFM energy storage, which affect the stable operation of the power system. This paper proposed an additional damping control strategy for GFM energy storage to address the low-frequency oscillation. Firstly, this paper builds the state-space small-signal mathematical model of the GFM energy storage grid-connected system to analyze the participation factors of the low-frequency oscillation mode and clarify the key control parameters affecting the GFM energy storage grid-connected system the low-frequency oscillation. Then, this paper proposed an additional damping control strategy to increase the damping ratio of the low-frequency oscillation mode and improve the stability of the GFM energy storage grid-connected system. Finally, semi-physical experiments verified the effectiveness of the proposed additional damping control strategy. Full article

An analog joint source-channel coding (AJSCC) based on Shannon–Kotel’nikov (S-K) mapping transmitting discrete-time encoded samples in orthogonal frequency division multiplexing (OFDM) systems over wireless channel has exhibited excellent performance. However, the phenomenon of carrier frequency offset (CFO) caused by the frequency mismatch between the transmitter’s and receiver’s local oscillators often exists in actual scenarios; thus, in this paper the performance of AJSCC-OFDM with CFO is analyzed and the S-K mapping is optimized. A joint optimization strategy is developed to maximize the signal-to-distortion ratio (SDR) subject to CFO constraints. Considering that the optimized AJSCC-OFDM strategies will change the amplitude distribution of encoded symbol, the peak-to-average power ratio (PAPR) characteristics under different AJSCC parameters are also analyzed. Full article

During the process of flexible aerial refueling, the flexible structure of the hose drogue assembly is affected by internal and external interference, such as docking maneuvering, deformation of the hose, attitude changes, and body vibrations, causing the hose to swing and the whipping phenomenon, which greatly limits the success rate and safety of aerial refueling operations. Based on a 2.4 m transonic wind tunnel, high-speed wind tunnel test technology of a flexible aerial refueling hose–drogue system was established to carry out experimental research on the coupling characteristics of aerodynamics and multi-body dynamics. Based on the aid of Videogrammetry Model Deformation (VMD), high-speed photography, dynamic balance, and other wind tunnel test technologies, the dynamic characteristics of the hose–drogue system in a high-speed airflow and during the approach of the receiver are obtained. Adopting flexible multi-body dynamics, a dynamic system of the tanker, hose, drogue, and receiver is modeled. The cable/beam model is based on an arbitrary Lagrange–Euler method, and the absolute node coordinate method is used to describe the deformation, movement, and length variation in the hose during both winding and unwinding. The aerodynamic forces of the tanker, receiver, hose, and drogue are modeled, reflecting the coupling influence of movement of the tanker and receiver, the deformation of the hose and drogue, and the aerodynamic forces on each other. The tests show that during the approach of the receiver (distance from 1000 mm to 20 mm), the sinking amount of the drogue increases by 31 mm; due to the offset of the receiver probe, the drogue moves sideways from the symmetric plane of the receiver. Meanwhile, the oscillation magnitude of the drogue increases (from 33 to 48 and from 48 to 80 in spanwise and longitudinal directions, respectively). The simulation results show that the shear force induced by the oscillation of the hose and the propagation velocity of both the longitudinal and shear waves are affected by the hose stiffness and Mach number. The results presented in this work can be of great reference to further increase the safety of aerial refueling. Full article

The proliferation of power electronics in renewable-integrated grids exacerbates the challenges of nonlinearity and multivariable coupling. While the modal series method (MSM) offers theoretical foundations, it fails to provide tools to systematically quantify dynamic interactions in these complex systems. This study proposes a unified nonlinear modal analysis framework integrating second-order analytical solutions with novel nonlinear indices. Validated across diverse systems (DC microgrids and grid-connected PV), the framework yields significant findings: (1) second-order solutions outperform linearization in capturing critical oscillation/damping distortions under realistic disturbances, essential for fault analysis; (2) nonlinear effects induce modal dominance inversion and generate governing composite modes; (3) key interaction mechanisms are quantified, revealing distinct voltage regulation pathways in DC microgrids and multi-path dynamics driving DC voltage fluctuations. This approach provides a systematic foundation for dynamic characteristic assessment and directly informs control design for power electronics-dominated grids. Full article

A comprehensive analysis of the evolution of rainfall characteristics in Catalonia, NE Spain, was conducted using monthly data from 72 rain gauges over the period 1950–2022. A moving-window approach was applied at annual, seasonal, and monthly scales, calculating mean values, coefficients of variation (CV), and trends across 43 overlapping 31-year periods. To assess trends in these moving statistics, a modified Mann–Kendall test was applied to both the 31-year means and CVs. Results revealed a significant 10% decrease in annual rainfall, with summer showing the most pronounced decline, as nearly 90% of stations exhibited negative trends, while the CV showed negative trends in coastal areas and mostly positive trends inland. At the monthly scale, February, March, June, August, and December exhibited negative trends at more than 50% of stations, with rainfall reductions ranging from 20% to 30%. Additionally, the temporal evolution of Mann–Kendall trend coefficients within each 31-year moving window displayed a fourth-degree polynomial pattern, with a periodicity of 30–35 years at annual and seasonal scales, and for some months. Finally, at the annual scale and in two centennial series, the 80-year oscillations found were inversely correlated with the large-scale climate indices North Atlantic Oscillation (NAO) and Atlantic Multidecadal Oscillation (AMO). Full article

This study investigates the fabrication, nanomechanical behavior, and tribological performance of nanostructured superlattice coatings (NSCs) composed of alternating TiAlSiNb-N/TiCr-CN bilayers. Deposited via High-Power Ion-Plasma Magnetron Sputtering (HiPIPMS) onto 100Cr6 steel substrates, the coatings achieved nanohardness values of ~25 GPa and elastic moduli up to ~415 GPa. A novel empirical method was applied to extract stress–strain field (SSF) gradient and divergence profiles from nanoindentation load–displacement data. These profiles revealed complex, depth-dependent oscillations attributed to alternating strain-hardening and strain-softening mechanisms. Fourier analysis identified dominant spatial wavelengths, DWL, ranging from 4.3 to 42.7 nm. Characteristic wavelengths WL1 and WL2, representing fine and coarse oscillatory modes, were 8.2–9.2 nm and 16.8–22.1 nm, respectively, aligning with the superlattice period and grain-scale features. The hyperfine structure exhibited non-stationary behavior, with dominant wavelengths decreasing from ~5 nm to ~1.5 nm as the indentation depth increased. We attribute the SSF gradient and divergence spatial oscillations to alternating strain-hardening and strain-softening deformation mechanisms within the near-surface layer during progressive loading. This cyclic hardening–softening behavior was consistently observed across all NSC samples, suggesting it represents a general phenomenon in thin film/substrate systems under incremental nanoindentation loading. The proposed SSF gradient–divergence framework enhances nanoindentation analytical capabilities, offering a tool for characterizing thin-film coatings and guiding advanced tribological material design. Full article

The barotropic sea level difference (SLD) across the Korea/Tsushima Strait (KTS) is considered an index of the volume transport into the East/Japan Sea. This study investigates the interannual variability of the barotropic SLD (the KTS inflow) from 1985 to 2017 and its relationship to upper-ocean (<300 m) current variability in the western North Pacific. An increase in the KTS inflow is associated with a weakening of the Kuroshio current through the Tokara Strait and upper-ocean cooling in the North Pacific Subtropical Gyre, characteristic of a La Niña-like state. Diagnostic analysis reveals that the KTS inflow variability is linked to at least two statistically distinct and concurrent modes of oceanic variability. The first mode is tied to the El Niño–Southern Oscillation through large-scale changes in the Kuroshio system. The second mode, which is linearly uncorrelated with the first, is associated with regional eddy kinetic energy variability in the western North Pacific. The identification of these parallel pathways suggests a complex regulatory system for the KTS inflow. This study provides a new framework for understanding the multi-faceted connection between the KTS and upstream oceanic processes, with implications for the predictability of the ocean environmental conditions in the East/Japan Sea. Full article

This article uses FLUENT to construct a two-dimensional axisymmetric numerical model of a cryogenic hydrogen charging pipeline. By loading with initial temperature gradient and transient initial pressure disturbance, the basic characteristics of low-temperature hydrogen Taconis thermoacoustic oscillation are calculated, including temperature, heat flux density distribution, pressure amplitude, and frequency. The instability boundary of hydrogen TAO is also obtained. The results show that (1) the temperature distribution and flow characteristics of the gas inside the pipeline exhibit significant periodic changes. In the first half of the oscillation period, the cold-end gas moves towards the end of the pipeline. Low-viscosity cold hydrogen is easily heated and rapidly expands. In the second half of the cycle, the expanding cold gas pushes the hot-end gas to move towards the cold end, forming a low-pressure zone and causing gas backflow. (2) Thermoacoustic oscillation can also cause additional thermal leakage on the pipeline wall. The average heat flux during one cycle is 1150.1 W/m² for inflow and 1087.7 W/m² for outflow, with a net inflow heat flux of 62.4 W/m². (3) The instability boundary of the system is mainly determined by the temperature ratio of the cold and hot ends α, temperature gradient β, and length ratio of the cold and hot ends ξ. Increasing the pipe diameter and minimizing the pipe length can effectively weaken the amplitude of thermoacoustic oscillations. This study provides theoretical support for predicting thermoacoustic oscillations in low-temperature hydrogen transport pipeline systems and offers insights for system stability control and design verification. Full article

In recent years, under the influence of climate change and human activities, droughts and floods have occurred frequently in the Yangtze River Basin (YRB), seriously threatening socioeconomic development and ecological security. The topography and climate of the YRB are complex, so it is crucial to develop appropriate drought and flood policies based on the drought and flood characteristics of different sub-basins. This study calculated the water storage deficit index (WSDI) based on the Gravity Recovery and Climate Experiment (GRACE) and GRACE-Follow On (GFO) mascon model, extended WSDI to the bidirectional monitoring of droughts and floods in the YRB, and verified the reliability of WSDI in monitoring hydrological events through historical documented events. Combined with the wavelet method, it revealed the heterogeneity of climate responses in the three sub-basins of the upper, middle, and lower reaches. The results showed the following. (1) Compared and verified with the Standardized Precipitation Evapotranspiration Index (SPEI), self-calibrating Palmer Drought Severity Index (scPDSI), and documented events, WSDI overcame the limitations of traditional indices and had higher reliability. A total of 21 drought events and 18 flood events were identified in the three sub-basins, with the lowest frequency of drought and flood events in the upper reaches. (2) Most areas of the YRB showed different degrees of wetting on the monthly and seasonal scales, and the slowest trend of wetting was in the lower reaches of the YRB. (3) The degree of influence of teleconnection factors in the upper, middle, and lower reaches of the YRB had gradually increased over time, and, in particular, El Niño Southern Oscillation (ENSO) had a significant impact on the droughts and floods. This study provided a new basis for the early warning of droughts and floods in different sub-basins of the YRB. Full article

Species characterized by undetermined clade affiliations, limited research coverage, and deficient systematic investigation serve as enigmatic entities in plant and animal taxonomy, yet hold critical significance for exploring phylogenetic relationships and evolutionary trajectories. Subgenus Cyathophora (Allium, Amayllidaceae), a small taxon comprising approximately five species distributed in the Qinghai–Tibet Plateau (QTP) and adjacent regions might contain an enigmatic species that has long remained unexplored. In this study, we collected data on species from subgenus Cyathophora and its close relatives in subgenus Rhizirideum, as well as the enigmatic species Allium siphonanthum. Combining phylogenomic datasets and morphological evidence, we investigated species relationships and the underlying mechanism of phylogenetic discordance. A total of 1662 single-copy genes (SCGs) and 150 plastid loci were filtered and used for phylogenetic analyses based on concatenated and coalescent-based methods. Furthermore, to systematically evaluate phylogenetic discordance and decipher its underlying drivers, we implemented integrative analyses using multiple approaches, such as coalescent simulation, Quartet Sampling (QS), and MSCquartets. Our phylogenetic analyses robustly resolve A. siphonanthum as a member of subg. Cyathophora, forming a sister clade with A. spicatum. This relationship was further corroborated by their shared morphological characteristics. Despite the robust phylogenies inferred, extensive phylogenetic conflicts were detected not only among gene trees but also between SCGs and plastid-derived species trees. These significant phylogenetic incongruences in subg. Cyathophora predominantly stem from incomplete lineage sorting (ILS) and reticulate evolutionary processes, with historical hybridization events likely correlated with the past orogenic dynamics and paleoclimatic oscillations in the QTP and adjacent regions. Our findings not only provide new insights into the phylogeny of subg. Cyathophora but also significantly enhance our understanding of the evolution of species in this subgenus. Full article

The resonant frequency of an SAW oscillator can be modulated by varying the signal amplitude, due to non-linear acoustic interactions within the chemoselective layer. In this study, we developed an explicit model to describe the amplitude–frequency behavior of a tunable SAW oscillator. A polymeric layer of variable thickness was deposited in a circular area (radius 1.1 mm) at the center of the piezoactive surface. Increasing the oscillator loop attenuation resulted in a continuous increase in the resonant frequency by up to 1.8 MHz. The layer was modeled as a succession of non-interacting sub-layers of varying thicknesses. As a result, the function model consists of a superposition of terms, each corresponding to a layer region of distinct length and thickness. The maximum difference between the experimental data and function model (also known as residual of the fit) was below 1% (13.02 kHz) of the resonant frequency variation, thus supporting the validity of our approach. While our model proved successful, the results suggest that some interactions are unaccounted for, as evidenced by the periodicity of the residuals of fit and unrealistically large variation in acoustic wave velocity. Full article