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15 pages, 9065 KiB  
Article
An Analysis of Multi-Coal Seam Mining Impacting Aquifer Water Based on Self-Organizational Maps
by Zhonglin Wei, Yuan Ji, Yuan Li, Huiming Fang, Donglin Dong and Lujia Yu
Water 2025, 17(4), 598; https://doi.org/10.3390/w17040598 - 19 Feb 2025
Cited by 2 | Viewed by 551
Abstract
The degradation of groundwater quality due to mining activities is a major public concern globally. This study employed a combination of methods (multivariate statistics, Self-organizing mapping, and PHREEQC hydrogeochemical simulation) to uncover the hydrochemical characteristics and processes of mine water in the Kailuan [...] Read more.
The degradation of groundwater quality due to mining activities is a major public concern globally. This study employed a combination of methods (multivariate statistics, Self-organizing mapping, and PHREEQC hydrogeochemical simulation) to uncover the hydrochemical characteristics and processes of mine water in the Kailuan mining area. Self-organizing mapping (SOM) clustering divided the mine water into three groups, TDS values gradually increased from the first to the third group, and the hydrogeochemical type of mine water gradually changed from Na-HCO3 and CaMg-HCO3 to CaMg-SO4, Na-Cl, and mixed types. Principal component analysis (PCA) revealed that water–rock action and evaporation concentration were major ion concentration factors. According to the molar ion concentration ratio method, the main ions in mine water in Kailuan mining area originate from silicate and sulfate, and a small amount from carbonate rock weathering, and they are influenced by cation exchange. As a result of the PHReactor EQuilibrium Code (PHREEQC) simulation results, it can be concluded that better hydrodynamic conditions in mines are primarily controlled by carbonate dissolution. Mine water with poorer hydrodynamic conditions is mainly controlled by sulfate and carbonate dissolution, with sulfate dissolution having a greater effect. The results of this study provide an important scientific basis for the safe mining of mines and the protection of groundwater resources. Full article
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20 pages, 606 KiB  
Article
Dynamic Response and Dispersion Analysis of a Damped Heterogeneous Coating over a Homogeneous Elastic Half-Space
by Sadia Munir, Fiazud Din Zaman, Ashfaque H. Bokhari, Ali M. Mubaraki and Rahmatullah Ibrahim Nuruddeen
Coatings 2025, 15(2), 188; https://doi.org/10.3390/coatings15020188 - 6 Feb 2025
Cited by 3 | Viewed by 820
Abstract
This study models the dynamic response of a damped heterogeneous coating layer over a homogeneous elastic half-space via the shear horizontal equation of motion. The so-called partial nonhomogeneous has been considered in the coating, where only the density of the material features the [...] Read more.
This study models the dynamic response of a damped heterogeneous coating layer over a homogeneous elastic half-space via the shear horizontal equation of motion. The so-called partial nonhomogeneous has been considered in the coating, where only the density of the material features the inhomogeneity parameter. This unusual consideration, motivated by the viscoelasticity setting, gives rise to the realization of Airy’s differential equation in the coating layer that poses Airy’s functions of the first and the second kinds, respectively. Moreover, the resulting dispersion relation has been utilized and analyzed, assessing the impact of the involved parameters. The study realized that an increase in both the damping coefficient and the inhomogeneity parameter accelerates the dispersion of waves in the media. Additionally, once the case of the doubly coated half-space is analyzed, as an extension of the earlier setup, it is noted that the case of a doubly coated half-space is more responsive to the excitations, which is pretty geared by the composition of different layers. In addition, more modes are noted when more coatings are wrapped over the half-space. Full article
(This article belongs to the Special Issue Machine Learning-Driven Advancements in Coatings)
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16 pages, 6321 KiB  
Article
The Prediction of Coalbed Methane Layer in Multiple Coal Seam Groups Based on an Optimized XGBoost Model
by Weiguang Zhao, Shuxun Sang, Sijie Han, Deqiang Cheng, Xiaozhi Zhou, Zhijun Guo, Fuping Zhao, Jinchao Zhang and Wei Gao
Energies 2024, 17(23), 6060; https://doi.org/10.3390/en17236060 - 2 Dec 2024
Viewed by 790
Abstract
The prediction of the optimal coalbed methane (CBM) layer plays a significant role in the efficient development of CBM in multiple coal seam groups. In this article, the XGBoost model optimized by the tree-structured Parzen estimator (TPE) algorithm was established to automatically predict [...] Read more.
The prediction of the optimal coalbed methane (CBM) layer plays a significant role in the efficient development of CBM in multiple coal seam groups. In this article, the XGBoost model optimized by the tree-structured Parzen estimator (TPE) algorithm was established to automatically predict the optimal CBM layer in complex multi-coal seams of the Dahebian block in Guizhou Province, China. The research results indicate that the TPE XGBoost model has higher evaluation metrics than traditional machine learning models, with higher accuracy and generalization ability. The optimal coalbed methane layer predicted by the model for the Dacong 1–3 well is the 11th coal seam. In addition, the interpretation results of the model indicate that sonic (AC) and caliper logging (CAL) are relatively important in determining the optimal CBM layer. The favorable layers for coalbed methane development are distributed in coal seams with developed fractures and high gas content. The TPE-XGBoost model can help us objectively analyze the significance of different types of logging, quickly predict the optimal layer in complex multiple coal seam groups, and greatly reduce costs and subjective impact. It provides a new approach to predict the best CBM layer in multiple coal seam groups in the Guizhou Province in the southwest of China. Full article
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18 pages, 32081 KiB  
Article
Monitoring and Law Analysis of Secondary Deformation on the Surface of Multi-Coal Seam Mining in Closed Mines
by Xiaofei Liu, Jiangtao Wang, Sen Du, Kazhong Deng, Guoliang Chen and Xipeng Qin
Remote Sens. 2024, 16(17), 3223; https://doi.org/10.3390/rs16173223 - 30 Aug 2024
Cited by 1 | Viewed by 1323
Abstract
A large number of mines have been closed due to resource depletion, failure to meet safety production requirements, and other reasons. To effectively ensure the safety of the ecological environment above these closed mines along with the safety of engineering construction, it is [...] Read more.
A large number of mines have been closed due to resource depletion, failure to meet safety production requirements, and other reasons. To effectively ensure the safety of the ecological environment above these closed mines along with the safety of engineering construction, it is necessary to monitor the secondary deformation of closed mines. Based on TerraSAR-X, Sentinel-1A data, and InSAR technology, this study obtained high-density secondary surface deformation data on the Jiahe Coal Mine and Pangzhuang Coal Mine in the western Xuzhou area. Combining mining geological data, we analyzed the spatiotemporal variation patterns and mechanisms of secondary deformation in multi-seam mining of closed mines. It was found that when mining multiple seams involves large interlayer spacing, the secondary deformation pattern shows a “W” shape. In this situation, the deformation can be divided into five stages: subsidence, uplift, re-subsidence, re-uplift, and relative stability. This study provides technical support for the evaluation and prevention of secondary deformation hazards in closed mines. Full article
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24 pages, 12757 KiB  
Article
Finite–Discrete Element Method Simulation Study on Development of Water-Conducting Fractures in Fault-Bearing Roof under Repeated Mining of Extra-Thick Coal Seams
by Longquan Mai and Hao Li
Sustainability 2024, 16(12), 5177; https://doi.org/10.3390/su16125177 - 18 Jun 2024
Cited by 3 | Viewed by 1415
Abstract
The formation of water-conducting fractures in overlying strata caused by underground coal mining not only leads to roof water inrush disasters, but also water-conducting fractures penetrate the aquifer, resulting in the occurrence of a mine-water-inrush disaster and the loss of water resources. It [...] Read more.
The formation of water-conducting fractures in overlying strata caused by underground coal mining not only leads to roof water inrush disasters, but also water-conducting fractures penetrate the aquifer, resulting in the occurrence of a mine-water-inrush disaster and the loss of water resources. It destroys the sustainability of surface water and underground aquifers. This phenomenon is particularly significant in extra-thick coal seams and fault-bearing areas. Numerical simulation is an effective method to predict the failure range of mining overburden rock with low cost and high efficiency. The key to its accuracy lies in a reasonable constitutive model and simulation program. In this study, considering that the three parts of penetrating cracks, non-penetrating cracks, and intact rock blocks are often formed after rock failure, the contact state criterion and shear friction relationship of discrete rock blocks and the mixed fracture displacement–damage–load relationship are established, respectively. Combined with the Mohr–Coulomb criterion, the constitutive model of mining rock mass deformation–discrete block motion and interaction is formed. On this basis, according to the engineering geological conditions of Yushupo Coal Mine, a numerical model for the development of water-conducting cracks in the roof with faults under repeated mining of extra-thick coal seams is established. The results show the following: The constitutive relation of the continuous deformation–discrete block interaction of overlying strata and the corresponding finite element–discrete element FDEM numerical program and VUSDFLD multi-coal seam continuous mining subroutine can numerically realize the formation process of faults and water flowing fractures in overlying strata under continuous mining of extra-thick multi-coal seams. The toughness of sand mudstone is low, and the fracture will be further developed under the repeated disturbance of multi-thick coal seam mining. Finally, it is stabilized at 216–226 m, and the ratio of fracture height to mining thickness is 14.1. When the working face advances to the fault, the stress concentration occurs in the fault and its overlying rock, which leads to the local fracture of the roof rock mass and the formation of cracks. The fault group makes this phenomenon more obvious. The results have been preliminarily applied and tested in Ningwu mining area, which provides theoretical support for further development of roof water disaster control under the condition of an extra-thick coal seam and avoids the loss of water resources in surface water and underground aquifers. Full article
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23 pages, 12133 KiB  
Article
A Prediction Approach Based on Clustering Reconstruction for Abnormal Mining Pressure of Longwall Face under Residual Coal Pillars
by Haodong Hu, Yinghu Li, Qiangling Yao, Xuehua Li, Gang Huang, Kai Li and Qiang Xu
Processes 2024, 12(2), 283; https://doi.org/10.3390/pr12020283 - 27 Jan 2024
Cited by 2 | Viewed by 1285
Abstract
In multi-coal seam mining, when the lower coal seam mining face passes over the goaf, residual coal pillars, and other geological anomaly areas of the overlying coal seam, abnormal mine pressure appears, and the hydraulic support monitoring system is inaccurate in identifying the [...] Read more.
In multi-coal seam mining, when the lower coal seam mining face passes over the goaf, residual coal pillars, and other geological anomaly areas of the overlying coal seam, abnormal mine pressure appears, and the hydraulic support monitoring system is inaccurate in identifying the pressure, which brings great hidden dangers to the safe production of the mining face. It is very necessary to carry out the prediction and early warning of the mine pressure of this kind of mining face. In order to improve the reliability of the prediction model, this paper takes the 31317 mining faces of the Chahasu coal mine as the engineering background, studies the mechanism of the disaster caused by the abnormal mine pressure of the residual coal pillar, uses the clustering analysis algorithm to divide the abnormal mine pressure area of the mining face, reconstructs the abnormal mine pressure type and number based on the prediction results of CEEMDAN–Transformer deep learning, and proposes the disaster criterion of the abnormal mine pressure. The research results show that, when the 31317 mining face enters the goaf of the overlying 31203 and 31201 coal seams, the residual coal pillars are accompanied by the instability of the interlayer rotation, and the dynamic and static loads are superimposed to form the additional stress of the residual coal pillars and transfer downward, causing the abnormal mine pressure of the mining face to appear; based on the hydraulic support resistance data of the mining face within the range of 3921.4–5050.4 m advance, the clustering analysis results show that there are six abnormal mine pressures during this period, and the types are cutting eye, residual coal pillar, square breaking, previous working face goaf square breaking, double square breaking, and geological damage zone. The clustering analysis is used to reconstruct the abnormal mine pressure area based on the prediction results of the mine pressure time series (MPTS) after interpolation completion, decomposition, and noise reduction preprocessing, and the MAE values are all lower than 2000 kN, predicting that there will be one abnormal pressure between the 80#–129# hydraulic supports in the process of advancing to 5050.4–5219.5 m, corresponding to the 18th square breaking area of the working face. Through the verification in the actual production, the prediction result is accurate; when the predicted value of the hydraulic support working resistance is greater than 19,000 KN, measures should be taken to speed up the advancing speed of the mining face, quickly pass through the abnormal mine pressure area, and prevent the disaster caused by the abnormal mine pressure. The prediction clustering analysis reconstruction abnormal pressure analysis method based on mining working face mine pressure data proposed in this paper provides a new direction and guidance for the abnormal mine pressure prediction analysis of mining working face and has good foresight, good intelligent prediction, and a good analysis method for the intelligent empowerment of mine safety production. Full article
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24 pages, 13172 KiB  
Article
Design and Machining of a Spherical Shell Rotor for a Magnetically Levitated Momentum Ball
by Limei Ma, Yongheng Zhang, Yuli Niu, Yong Zhao, Shaoya Guan, Zijing Wang and Tuoda Wu
Aerospace 2024, 11(1), 61; https://doi.org/10.3390/aerospace11010061 - 9 Jan 2024
Cited by 1 | Viewed by 2080
Abstract
Ball-shell rotors with non-standard shapes, non-uniform conductive coatings, and eccentric masses machined by conventional processes constrain the improvement of levitation and torque accuracy of magnetically levitated momentum balls. This paper focuses on the machining method of multilayer ball-shell rotors to develop a ball-shell [...] Read more.
Ball-shell rotors with non-standard shapes, non-uniform conductive coatings, and eccentric masses machined by conventional processes constrain the improvement of levitation and torque accuracy of magnetically levitated momentum balls. This paper focuses on the machining method of multilayer ball-shell rotors to develop a ball-shell rotor with a standard shape and uniform conductive coating, which can improve the levitation and torque accuracy of magnetically levitated momentum balls. In this paper, a machining method for multi-coated ball-shell rotors is proposed. The machining process combining hemispherical surface and workpiece is adopted, and the whole sphere is assembled by threading, which effectively reduces the machining error. The influence of the cutting depth and feed rate of the tool on the cutting force of the ball shell was analyzed through the cutting force model. The effect of cutting force on the deformation of the ball shell was analyzed by the finite element method. The superiority of the machining method was verified by measuring the dimensions of the ball shell with a coordinate measuring machine. Compared with the traditional machining process and assembly method, the proposed ball-shell rotor machining method effectively improves the dimensional accuracy, reduces the center of mass to center of mass deviation, and ensures the levitation accuracy and output torque accuracy of the magnetically levitated momentum ball. Measurement results show that the diameter values of the pure iron ball shell are between 98.694 and 98.707 mm with a machining error of ±0.007 mm, and the diameter values of the spray-painted ball shell are between 99.490 and 99.510 mm with a machining error of ±0.01 mm. The machining static equilibrium of the pure iron ball shell and the spray-painted ball shell is good by the static equilibrium test method. Full article
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18 pages, 7157 KiB  
Article
A Numerical Simulation of the Subsidence Reduction Effect of Different Grouting Schemes in Multi-Coal Seam Goafs
by Hai Wang, Yan Qin, Yuxi Guo and Nengxiong Xu
Appl. Sci. 2023, 13(9), 5522; https://doi.org/10.3390/app13095522 - 28 Apr 2023
Cited by 1 | Viewed by 1469
Abstract
Grouting is the most widely used technology for treating coal goafs. In this study, a numerical simulation method was used to establish a model of multi-seam goafs with different spacing conditions to investigate the subsidence reduction effects of various grouting schemes on multi-coal [...] Read more.
Grouting is the most widely used technology for treating coal goafs. In this study, a numerical simulation method was used to establish a model of multi-seam goafs with different spacing conditions to investigate the subsidence reduction effects of various grouting schemes on multi-coal seam goafs. By varying the range and opportunity of grouting treatments, the effects of coal seam spacing, grouting treatment range, and grouting opportunity on subsidence reduction were analyzed. The results showed that: (1) With constant overburden (OB), the subsidence reduction ratio of the subgrade center increases linearly as the interburden (IB) decreases (1 ≤ OB/IB ≤ 2), then increases exponentially (2 < OB/IB), and eventually becomes stable. (2) When treatment is conducted based on the half-width of the subgrade, the width of the subgrade, and the range of the trapezoid, residual surface subsidence tends to adopt an inclined ‘W’-shape in open cutting. The surface residual subsidence exhibits a symmetrical ‘W’-shape when full-range grouting is adopted. (3) For a multi-coal seam goaf with longer mining stoppage time, the subsidence reduction ratio of the subgrade center is lower, and it is exponentially related to the grouting opportunity. As the grouting opportunity is extended and OB/IB decreases, the subsidence reduction ratio of the subgrade center declines exponentially. Full article
(This article belongs to the Special Issue Geo-Environmental Problems Caused by Underground Construction)
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12 pages, 3971 KiB  
Article
Impact Resistance of CVD Multi-Coatings with Designed Layers
by Jiedong Deng, Feng Jiang, Xuming Zha, Tao Zhang, Hongfei Yao, Dongwei Zhu, Hongmei Zhu, Hong Xie, Fuzeng Wang, Xian Wu and Lan Yan
Coatings 2023, 13(5), 815; https://doi.org/10.3390/coatings13050815 - 22 Apr 2023
Cited by 1 | Viewed by 2018
Abstract
Coated cutting tools are widely used in the manufacturing industry due to their excellent properties of high heat resistance, high hardness, and low friction. However, the milling process is a dynamic process, so the coatings of milling tools suffer severe cyclic impact loads. [...] Read more.
Coated cutting tools are widely used in the manufacturing industry due to their excellent properties of high heat resistance, high hardness, and low friction. However, the milling process is a dynamic process, so the coatings of milling tools suffer severe cyclic impact loads. Impact resistance is important for the life of milling tools. Multi-coatings with different layer thickness may influence their impact resistance, but few studies focus on this topic. In this study, CVD coating with a structure of TiN layer, Al2O3 layer, and TiCN layer was selected as the research objective. Four different CVD coatings with different layer thicknesses were designed and prepared. The impact resistance test method was proposed to simulate the impact due to cut-in during down the milling process. We obtained the load by setting an impact depth of 25/30/35 µm, recording the impact force during the impact process, and calculating the contact stress; it was found that, at the impact depth of 25/30/35 µm, the download loads were around 9/11/13 N, while the contact stresses were all around 1 GPa. The failure morphology of the coating surface was investigated after the impact process. By comparing the contact stress and the surface morphology of the designed coatings, the impact resistance of four kinds of designed CVD coatings were evaluated. Experiments have shown that an increase in coating thickness and total coating thickness reduces impact resistance by about 10%. The impact resistance of coating samples without a TiN surface layer also decreased by about 10%. When the surface layer of TiN was thinner than 1 µm, the surface layer of TiN was prone to chipping and peeling off. Decreasing the thickness of the middle layer of Al2O3 and increasing the thickness of the inner layer of TiCN obviously lowered the impact resistance. Full article
(This article belongs to the Special Issue Recent Advances in the Development of Thin Films)
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9 pages, 1154 KiB  
Article
Multilayered Edible Coatings to Enhance Some Quality Attributes of Ready-to-Eat Cherimoya (Annona cherimola)
by Giovanna Rossi-Márquez, Cristian Aarón Dávalos-Saucedo, Netzahualcóyotl Mayek-Pérez and Prospero Di Pierro
Coatings 2023, 13(1), 41; https://doi.org/10.3390/coatings13010041 - 26 Dec 2022
Cited by 6 | Viewed by 2366
Abstract
Multilayer coating can be applied on fresh fruit to protect and enhance its shelf life. This study evaluated the application of a multilayer protein and chitosan coating on fresh cherimoya. To determinate the effect of the multilayer coating on the shelf life on [...] Read more.
Multilayer coating can be applied on fresh fruit to protect and enhance its shelf life. This study evaluated the application of a multilayer protein and chitosan coating on fresh cherimoya. To determinate the effect of the multilayer coating on the shelf life on the fruit, total phenolic content, pH, °Brix, weight loss, and hardness values were tested. The ripening process is associated with an increase of soluble solids, and results showed that the presence of the multilayered coating maintains the total phenolic content, pH, and °Brix values over time while reducing the water loss. This effect is probably due to the presence of the coating that creates a barrier on the food surface that reduces the respiration rate and affects the ripening process, demonstrating the method’s feasibility to be used to enhance the shelf life of fresh-cut cherimoya. Full article
(This article belongs to the Special Issue Advanced Edible Films and Coatings for Food Packaging)
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15 pages, 4139 KiB  
Article
Study on the Coal Pillar Weakening Technology in Close Distance Multi-Coal Seam Goaf
by Jie Zhang, Qingsong Zhuo, Sen Yang, Tao Yang, Bin Wang, Wenyong Bai, Jianjun Wu and Shaoliang Xie
Energies 2022, 15(18), 6532; https://doi.org/10.3390/en15186532 - 7 Sep 2022
Cited by 13 | Viewed by 1690
Abstract
The pressure relief of coal pillars in close-distance multi-coal seam goaf is a complex engineering problem with the characteristics of “dynamic mine pressure”. Hence, this paper studies such problems. First, the influence factors of the coal pillar in the goaf on the mine [...] Read more.
The pressure relief of coal pillars in close-distance multi-coal seam goaf is a complex engineering problem with the characteristics of “dynamic mine pressure”. Hence, this paper studies such problems. First, the influence factors of the coal pillar in the goaf on the mine pressure of the mining face of the lower coal seam under this condition were theoretically analyzed, and it was concluded that vertical stress is the most important element, followed by horizontal stress. Next, a physical similarity simulation experiment was designed to study the stress distribution law of the coal pillar floor in the goaf before and after pressure release and the damage depth. Finally, a technology and monitoring method for coal pillar blasting pressure alleviation in goaf were introduced and implemented in engineering practice. After the pressure is alleviated, the surrounding rock stress of the lower coal seam mining face is redistributed, and the vertical stress is decreased by 20%. The adjacent rock’s deformation is improved. This technology’s cost and safety advantages are extraordinary and helpful for mining coal seams over close distances. Full article
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21 pages, 6746 KiB  
Case Report
Interaction Mechanism of the Upper and Lower Main Roofs with Different Properties in Close Coal Seams: A Case Study
by Shengrong Xie, Yiyi Wu, Fangfang Guo, Dongdong Chen, En Wang, Xiao Zhang, Hang Zou, Ruipeng Liu, Xiang Ma and Shijun Li
Energies 2022, 15(15), 5533; https://doi.org/10.3390/en15155533 - 30 Jul 2022
Cited by 10 | Viewed by 1842
Abstract
Close-distance coal seams are widely distributed in China, and the mining of overlying coal seams leads to floor damage. To grasp the properties and the fracture spans of the damaged main roof in the underlying coal seam, combining the calculation of the floor [...] Read more.
Close-distance coal seams are widely distributed in China, and the mining of overlying coal seams leads to floor damage. To grasp the properties and the fracture spans of the damaged main roof in the underlying coal seam, combining the calculation of the floor damage depth with rock damage theory and the formulas for calculating the first and periodic weighting intervals of the damaged main roof and the instability conditions of the damaged key blocks are obtained. Three interaction stability mechanics models are proposed for key blocks with different properties of the upper and lower main roof, and the instability conditions of the lower damaged key blocks are obtained when the fracture lines overlap. When combined with a specific example, the field monitoring verified the calculation results. The research results are as follows: (1) The first and periodic weighting intervals, horizontal thrust between blocks, and critical load of instability of the damaged main roof are significantly reduced. Still, there are differences in its reduction under different loads, rotation angles, and lumpiness. (2) When the fracture lines of the upper and lower main roofs overlap, the stability of the damaged key blocks is the lowest. There are three linkage stability regions in the critical load curves of the two key blocks. (3) In this case, the damage equivalent of the main roof is 0.397, which belongs to the local damage type. Its first and periodic weighting intervals are 40 m and 16 m, which is 22% and 24% less than when there is no damage. (4) A supporting load of 0.489 MPa is required to maintain the stability of the upper key block, and the lower damaged key block is prone to rotary and sliding instability during the first and periodic weighting, respectively. Thus, the supports need to bear a total of 0.988 MPa and 0.761 MPa to maintain the stability of the two key blocks simultaneously. The ground pressure data monitored on-site is in accord with the calculation results. Full article
(This article belongs to the Topic Mining Safety and Sustainability)
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15 pages, 2933 KiB  
Article
Online Ash Content Monitor by Automatic Composition Identification and Dynamic Parameter Adjustment Method in Multicoal Preparation
by Anghong Yu, Haizeng Liu, Chuanzhen Wang, Jintao Lv, Feng Wang, Siyang He and Lei Wang
Processes 2022, 10(8), 1432; https://doi.org/10.3390/pr10081432 - 22 Jul 2022
Cited by 11 | Viewed by 2196
Abstract
The online measurement of coal ash has overcome the shortcomings of chemical tests. However, there could be large fluctuations and errors in the results of online ash monitors because of the transient change in coal quality resulting from different geological conditions in the [...] Read more.
The online measurement of coal ash has overcome the shortcomings of chemical tests. However, there could be large fluctuations and errors in the results of online ash monitors because of the transient change in coal quality resulting from different geological conditions in the mining process. In this study, to resolve the problems of the dual-energy γ-ray online ash monitor in the Linhuan Coal Preparation Plant, we investigated the internal factors, such as the composition of multimineral and multicoal, and external factors, such as the moisture and impurities, which affect the measurement results of the coal ash monitor. Furthermore, we developed a mathematical model to determine the effect of relevant factors on the coefficient of the online ash monitor, which revealed the relationship between coal composition and the parameters of the ash monitor, ensuring the stable and accurate measurement of ash in clean coal. The method of determining parameters used in the case of coal blending has been applied in the Linhuan Coal Preparation Plant. By comparing with tested ash content, the average absolute error and relative error for daily ash content measured in April are 0.21 and 2.18%, respectively. Meanwhile, it shows certain accuracy and reproducibility while opposed to the daily average absolute error of 0.22 and relative error of 2.39% in May. Full article
(This article belongs to the Section Chemical Processes and Systems)
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31 pages, 6813 KiB  
Article
The Holes of Zn Phosphate and Hot Dip Galvanizing on Electrochemical Behaviors of Multi-Coatings on Steel Substrates
by Thiago Duarte, Yuri A. Meyer and Wislei R. Osório
Metals 2022, 12(5), 863; https://doi.org/10.3390/met12050863 - 18 May 2022
Cited by 40 | Viewed by 3756
Abstract
The aim of this investigation is focused on the evaluation of distinctive coatings commonly applied in the automotive industry. The resulting corrosion behavior is analyzed by using electrochemical impedance spectroscopy (EIS), equivalent circuit (EC) and potentiodynamic polarization curves. The novelty concerns a comparison [...] Read more.
The aim of this investigation is focused on the evaluation of distinctive coatings commonly applied in the automotive industry. The resulting corrosion behavior is analyzed by using electrochemical impedance spectroscopy (EIS), equivalent circuit (EC) and potentiodynamic polarization curves. The novelty concerns a comparison between tricationic phosphate (TCP), cataphoretic electrodeposition (CED) of an epoxy layer, TCP + CED and HDG (hot-dip galvanized) + TCP + CED multi-coatings. Both the naturally deposited and defect-induced damage (incision) coatings are examined. The experimental impedance parameters and corrosion current densities indicate that multi-coating system (HDG + TCP + CED layers) provides better protection. Both planar and porous electrode behaviors are responsible to predict the corrosion mechanism of the majority of samples examined. Although induced-damage samples reveal that corrosion resistances decreased up to 10×, when compared with no damaged samples, the same trend of the corrosion protection is maintained, i.e., TCP < CED < TCP + CED < HDG + TCP + CED. It is also found that the same trend verified by using electrochemical parameters is also observed when samples are subjected under salt spray condition (500 h). It is also found that porous electrode behavior is not a deleterious aspect to corrosion resistance. It is more intimately associated with initial thickness coating, while corrosion resistance is associated with adhesion of the CED layer on TCP coating. The results of relative cost-to-efficiency to relative coating density ratios are associated with fact that a CED coating is necessary to top and clear coating applications and the TCP + CED and the HDG/TCP + CED coating systems exhibit the best results. Full article
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15 pages, 4281 KiB  
Article
Study on the Mineralogical and Geochemical Characteristics of Arsenic in Permian Coals: Focusing on the Coalfields of Shanxi Formation in Northern China
by Liqun Zhang, Liugen Zheng and Meng Liu
Energies 2022, 15(9), 3185; https://doi.org/10.3390/en15093185 - 27 Apr 2022
Cited by 3 | Viewed by 1854
Abstract
The Huainan Coalfield is a typical multi-coal seam coalfield. In order to systematically investigate the distribution, occurrence, and integration of arsenic (As) in Shanxi coal, 26 coal samples and three rock samples were collected in the No. 1 coal seam of Huainan coalfield. [...] Read more.
The Huainan Coalfield is a typical multi-coal seam coalfield. In order to systematically investigate the distribution, occurrence, and integration of arsenic (As) in Shanxi coal, 26 coal samples and three rock samples were collected in the No. 1 coal seam of Huainan coalfield. The minerals, major element oxides, and As were analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM), polarized light microscopy, X-ray fluorescence spectroscopy (XRF) and inductively coupled plasma-mass spectrometry (ICP-MS). The results indicated that the coals of Shanxi Formation were characterized by very low ash yields and low total sulfur contents. The identified minerals by XRD in the studied coals are dominated by kaolinite, quartz, calcite, and a lesser amount of pyrite. The As content ranges from 10.33 mg/kg to 95.03 mg/kg, with an average of 44.74 mg/kg. Compared with world coals, the studied coals have higher contents of As, which are characterized by enrichment. Based on statistical analyses, As shows an affinity to ash yield and possible association with silicate minerals. The contents of As in all occurrence fractions were ranked from high to low as follows: residual > Fe-Mn oxides > organic > exchangeable > carbonate. Using B, w(Sr)/w(Ba) and w(B)/w(Ga) geochemical parameter results to invert the depositional environment of the Huainan Shanxi Formation, a suitable coal-forming environment can cause relatively enriched As in coal. Full article
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