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11 pages, 2306 KB  
Article
Optical Path Design of an Integrated Cavity Optomechanical Accelerometer with Strip Waveguides
by Chengwei Xian, Pengju Kuang, Zhe Li, Yi Zhang, Changsong Wang, Rudi Zhou, Guangjun Wen, Yongjun Huang and Boyu Fan
Photonics 2025, 12(8), 785; https://doi.org/10.3390/photonics12080785 - 4 Aug 2025
Viewed by 305
Abstract
To improve the efficiency and stability of the system, this paper proposes a monolithic integrated optical path design for a cavity optomechanical accelerometer based on a 250 nm top silicon thickness silicon-on-insulator (SOI) wafer instead of readout through U-shape fiber coupling. Finite Element [...] Read more.
To improve the efficiency and stability of the system, this paper proposes a monolithic integrated optical path design for a cavity optomechanical accelerometer based on a 250 nm top silicon thickness silicon-on-insulator (SOI) wafer instead of readout through U-shape fiber coupling. Finite Element Analysis (FEA) and Finite-Difference Time-Domain (FDTD) methods are employed to systematically investigate the performance of key optical structures, including the resonant modes and bandgap characteristics of photonic crystal (PhC) microcavities, transmission loss of strip waveguides, coupling efficiency of tapered-lensed fiber-to-waveguide end-faces, coupling characteristics between strip waveguides and PhC waveguides, and the coupling mechanism between PhC waveguides and microcavities. Simulation results demonstrate that the designed PhC microcavity achieves a quality factor (Q-factor) of 2.26 × 105 at a 1550 nm wavelength while the optimized strip waveguide exhibits a low loss of merely 0.2 dB over a 5000 μm transmission length. The strip waveguide to PhC waveguide coupling achieves 92% transmittance at the resonant frequency, corresponding to a loss below 0.4 dB. The optimized edge coupling structure exhibits a transmittance of 75.8% (loss < 1.2 dB), with a 30 μm coupling length scheme (60% transmittance, ~2.2 dB loss) ultimately selected based on process feasibility trade-offs. The total optical path system loss (input to output) is 5.4 dB. The paper confirms that the PhC waveguide–microcavity evanescent coupling method can effectively excite the target cavity mode, ensuring optomechanical coupling efficiency for the accelerometer. This research provides theoretical foundations and design guidelines for the fabrication of high-precision monolithic integrated cavity optomechanical accelerometers. Full article
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15 pages, 3813 KB  
Article
Dual-Gate Metal-Oxide-Semiconductor Transistors: Nanoscale Channel Length Scaling and Performance Optimization
by Huajian Zheng, Zhuohang Ye, Baiquan Liu, Mengye Wang, Li Zhang and Chuan Liu
Electronics 2025, 14(7), 1257; https://doi.org/10.3390/electronics14071257 - 22 Mar 2025
Viewed by 1135
Abstract
Dual-gate metal-oxide-semiconductor transistors have attracted considerable interest due to their high threshold voltage control capability, higher drain current, and the ability to alleviate the impact of carrier surface scattering at the channel/dielectric interface. However, their applications in the monolithic integration of scaled devices [...] Read more.
Dual-gate metal-oxide-semiconductor transistors have attracted considerable interest due to their high threshold voltage control capability, higher drain current, and the ability to alleviate the impact of carrier surface scattering at the channel/dielectric interface. However, their applications in the monolithic integration of scaled devices encounter challenges stemming from the interaction between the pre-treated channel layer and its covering dielectric. Here, we demonstrate the successful realization of a scaled back-end-of-line (BEOL) compatible dual-gate indium–gallium–zinc oxide (IGZO) transistor with a channel length (Lch) scaled down to 150 nm and a channel thickness (Tch) of 4.2 nm. After precisely adjusting the metal ratio to In0.24Ga0.58Zn0.18O and employing O3 as an oxygen precursor for the deposition of Al2O3 as the top-gate dielectric layer, a high maximum current of 1.384 mA was attained under top-gate control, while a high current of 1.956 mA was achieved under bottom-gate control. Additionally, a high current on/off ratio (Ion/off > 109) was achieved for the dual gate. Careful calculations reveal that the field-effective mobility (μeff) reaches 11.68 cm2V−1s−1 under top-gate control and 22.46 cm2V−1s−1 under bottom-gate control. We demonstrate excellent dual-gate low-voltage modulation performance, with a high current switch ratio of 3 × 105 at Lch = 300 nm and 2 × 104 at Lch = 150 nm achieved by only 1 V modulation voltage, accompanied by a normalized current variation higher than 106. Overall, our devices show the remarkable electrical performance characteristics, highlighting their potential applications in high-performance electronic circuits. Full article
(This article belongs to the Special Issue Optoelectronics, Energy and Integration)
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22 pages, 7497 KB  
Article
An Experimental Study on the Seismic Performance of New Precast Prestressed Concrete Exterior Joints Based on UHPC Connection
by Xueyu Xiong, Zhisheng Wei, Dawei Zhang, Ju Liu, Yifan Xie and Liang He
Buildings 2025, 15(5), 729; https://doi.org/10.3390/buildings15050729 - 24 Feb 2025
Cited by 4 | Viewed by 842
Abstract
Traditional monolithic precast and precast prestressed concrete joints often face challenges such as complex steel reinforcement details and low construction efficiency. Grouting sleeve connections may also suffer from quality issues. To address these problems, a new precast prestressed concrete frame beam-column exterior joint [...] Read more.
Traditional monolithic precast and precast prestressed concrete joints often face challenges such as complex steel reinforcement details and low construction efficiency. Grouting sleeve connections may also suffer from quality issues. To address these problems, a new precast prestressed concrete frame beam-column exterior joint using ultra-high-performance concrete (UHPC) for connection (PPCFEJ-UHPC) is proposed. This innovative joint lessens the amount of stirrups in the core area, decreases the anchorage length of beam longitudinal reinforcement, and enables efficient lap splicing of column longitudinal reinforcement, thereby enhancing construction convenience. Cyclic loading tests were conducted on three new exterior joint specimens (PE1, PE2, PE3) and one cast-in-place joint specimen (RE1) to evaluate their seismic performance. The study concentrated on failure modes, energy dissipation capacity, displacement ductility, strength and stiffness degradation, shear stress, and deformation’s influence on the longitudinal reinforcement anchoring length and axial compression ratio. The results indicate that the new joint exhibits beam flexural failure with minimal damage to the core area, unlike the cast-in-place joint, which suffers severe core area damage. The novel joint exhibits at least 21.7% and 6.1% improvement in cumulative energy consumption and ductility coefficient, respectively, while matching the cast-in-place joint’s bearing capacity. These characteristics are further improved by 5.5% and 10.7% when the axial compression ratio is increased. The new joints’ seismic performance indices all satisfy the ACI 374.1-05 requirements. Additionally, UHPC significantly improves the anchoring performance of steel bars in the core area, allowing the anchorage length of beam longitudinal bars to be reduced from 16 times of the diameter of reinforcement to 12 times. Full article
(This article belongs to the Special Issue Research on Soil–Structure Interaction for Civil Structures)
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20 pages, 8245 KB  
Article
Prediction of Thermal Cracking During Construction of Massive Monolithic Structures
by Vasilina Tyurina, Anton Chepurnenko and Vladimir Akopyan
Appl. Sci. 2025, 15(3), 1499; https://doi.org/10.3390/app15031499 - 1 Feb 2025
Viewed by 916
Abstract
The problem of early crack formation caused by temperature stresses in hardening concrete is very relevant for massive monolithic reinforced concrete structures. The aim of the work is to develop a method for thermal cracking risk prediction during the construction of massive monolithic [...] Read more.
The problem of early crack formation caused by temperature stresses in hardening concrete is very relevant for massive monolithic reinforced concrete structures. The aim of the work is to develop a method for thermal cracking risk prediction during the construction of massive monolithic reinforced concrete structures. The innovation of the research consists in taking into account the dependence of the concrete elastic modulus and strength on the time and temperature of hardening. The significance of the study lies in analysis of methods for reducing the risk of early cracking using the example of a real structure. The object of the study is a fragment of a massive monolithic dock wall. The analysis is performed by the finite element method using a program developed by the authors in the MATLAB environment. Verification of the developed software was performed by comparison with the solution in ANSYS using a linear elastic model without time dependence of the elastic modulus. Next, various options were used to set the dependence of the mechanical characteristics of concrete on the time and temperature of hardening. An analysis was conducted of the possibility of reducing the risk of early cracking by reducing the length of the concrete block, correcting the heat exchange conditions of the surfaces, and reducing the heat generation of concrete. Full article
(This article belongs to the Section Civil Engineering)
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15 pages, 5787 KB  
Review
A Review of Ku-Band GaN HEMT Power Amplifiers Development
by Jihoon Kim
Micromachines 2024, 15(11), 1381; https://doi.org/10.3390/mi15111381 - 15 Nov 2024
Cited by 3 | Viewed by 3287
Abstract
This review article investigates the current status and advances in Ku-band gallium nitride (GaN) high-electron mobility transistor (HEMT) high-power amplifiers (HPAs), which are critical for satellite communications, unmanned aerial vehicle (UAV) systems, and military radar applications. The demand for high-frequency, high-power amplifiers is [...] Read more.
This review article investigates the current status and advances in Ku-band gallium nitride (GaN) high-electron mobility transistor (HEMT) high-power amplifiers (HPAs), which are critical for satellite communications, unmanned aerial vehicle (UAV) systems, and military radar applications. The demand for high-frequency, high-power amplifiers is growing, driven by the global expansion of high-speed data communication and enhanced national security requirements. First, we compare the main GaN HEMT process technologies employed in Ku-band HPA development, categorizing the HPAs into monolithic microwave integrated circuits (MMICs) and internally matched power amplifier modules (IM-PAMs) and examining their respective characteristics. Then, by reviewing the literature, we explore design topologies, major issues like oscillation prevention and bias circuits, and heat sink technologies for thermal management. Our findings indicate that silicon carbide (SiC) substrates with gate lengths of 0.25 μm and 0.15 μm are predominantly used, with ongoing developments enabling MMICs and IM-PAMs to achieve up to 100 W output power and 30% power-added efficiency. Notably, the performance of MMIC power amplifiers is advancing more rapidly than that of IM-PAMs, highlighting MMICs as a promising direction for achieving higher efficiency and integration in future Ku-band applications. This paper can provide insights into the overall key technologies for Ku-band GaN HPA design and future development directions. Full article
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20 pages, 5610 KB  
Article
Impact Resistance Performance and Damage Characteristics of Mortise-and-Tenon Joint Prefabricated Bridge Piers
by Shukun Li, Jiahe Mi, Xingjun Qi, Yudong Jin and Yupeng Guo
Buildings 2024, 14(9), 2666; https://doi.org/10.3390/buildings14092666 - 27 Aug 2024
Cited by 1 | Viewed by 1061
Abstract
The mortise-and-tenon joint prefabricated connection combines the assembly form of mortise-and-tenon joints and cast-in-place wet joints. It achieves reliable joint connections through small joint depths and lap-spliced reinforcement lengths. To study the impact resistance and damage characteristics of the assembled pier, a nonlinear [...] Read more.
The mortise-and-tenon joint prefabricated connection combines the assembly form of mortise-and-tenon joints and cast-in-place wet joints. It achieves reliable joint connections through small joint depths and lap-spliced reinforcement lengths. To study the impact resistance and damage characteristics of the assembled pier, a nonlinear finite element analysis was performed on the assembled and monolithic pier model piers to study the effects of mortise-and-tenon joint depths, lap reinforcement, and grout on the response of the piers to vehicle impact. The results showed that, after impact, the damage to the prefabricated pier was similar to that of the monolithic one. The failure mode involved opening of the seam at the impact face-pier bottom junction and localized concrete compression at the back-impact face pier bottom, and damage accumulated from the column base towards the column centerline. The mortise-and-tenon joint provided substantial horizontal constraint for the pier, imparting excellent resistance to lateral stiffness. Consequently, both piers showed nearly identical peak impact forces, yet the prefabricated pier exhibited a lesser degree of bending deformation compared to the monolithic one. The depth of the mortise-and-tenon joints was a critical factor affecting the impact response of the prefabricated bridge pier. When the depth reached 0.4D or more, it ensured good impact resistance and joint connection, enhancing energy absorption capability and reducing pier damage. The length of lap-spliced reinforcement significantly affected the overall integrity of prefabricated component connections. Lap lengths of 10d or more greatly reduced the probability of failure in the connection between pier columns and cap beams, lowering damage to the pier columns, joints, and pier cap beams, thus ensuring good impact resistance. The diameter of the lap-spliced reinforcement and the elastic modulus of the grouting material affected the local stiffness near the joints. Increasing the diameter of the lap-spliced reinforcement appropriately prevented excessive local damage, while altering the elastic modulus had minimal impact on improving pier damage. Full article
(This article belongs to the Topic Resilient Civil Infrastructure)
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19 pages, 8891 KB  
Article
Numerical Simulation and Calculation Method Study on Seamless Construction of Super-Length Raft Structures Based on Novel Magnesium Oxide Expansive Strengthening Band Method
by Hong Liao, Yuan Tan, Chao Dai, Jie Pu and Bin Han
Buildings 2024, 14(6), 1531; https://doi.org/10.3390/buildings14061531 - 25 May 2024
Viewed by 1107
Abstract
The drive for continuous innovation in large-scale infrastructure necessitates advancements in techniques, addressing the challenges of constructing super-length concrete structures. This study investigated the emerging shift from traditional united expanding agent (UEA) to magnesia expansive agent (MEA) in conjunction with expansive strengthening bands [...] Read more.
The drive for continuous innovation in large-scale infrastructure necessitates advancements in techniques, addressing the challenges of constructing super-length concrete structures. This study investigated the emerging shift from traditional united expanding agent (UEA) to magnesia expansive agent (MEA) in conjunction with expansive strengthening bands (ESBs), marking a pivotal transition in ensuring monolithic integrity. Despite a decade of exploration, MEA–ESB implementation in real-world projects remains underdocumented, with scholarly focus primarily confined to material characterization. This research integrated empirical on-site tests of MEA–ESB with high-fidelity numerical simulations in ABAQUS. The finite element model (FEM) validation against actual test data underscored the precision of our modeling, capturing the complex thermomechanical behavior of the system. We introduced a sophisticated parametric analysis framework, elucidating the influence of critical parameters like the ESB-to-raft-width ratio and MEA concrete expansion rates. This granular understanding facilitated the fine-tuning of design parameters, advancing the practical application of MEA methodologies. A groundbreaking contribution entailed the formulation of predictive models for early-stage cracking, anchored in the guidelines of the ACI Committee 207 and refined through extensive parametric exploration. These formulae empower engineers to anticipate and mitigate cracking risks during the design phase, thereby enhancing project safety and efficiency. Notably, this study identified limitations in current prediction models, highlighting the need for future research to incorporate comprehensive lifecycle considerations, including hydration heat effects and time-dependent mechanical property evolution. Full article
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20 pages, 7714 KB  
Article
Experimental Investigation of the Effect of Compressive Interface Stress on Interfaces in Reinforced Concrete Elements under Cyclic Action
by Vasiliki Palieraki, Christos Zeris and Elizabeth Vintzileou
Appl. Sci. 2024, 14(11), 4350; https://doi.org/10.3390/app14114350 - 21 May 2024
Cited by 1 | Viewed by 1090
Abstract
Reinforced concrete interfaces, either cracks within monolithic elements or joints between concretes cast at different times may become critical under cyclic actions, due to stiffness and interface resistance degradation. Among the numerous parameters affecting the behavior of interfaces, this paper focuses on the [...] Read more.
Reinforced concrete interfaces, either cracks within monolithic elements or joints between concretes cast at different times may become critical under cyclic actions, due to stiffness and interface resistance degradation. Among the numerous parameters affecting the behavior of interfaces, this paper focuses on the effect of externally applied compressive stress. In conjunction with this parameter, the diameter of the reinforcing bars crossing the interface, their embedment length, and the anchorage of the interface reinforcement, by bond or using epoxy resin, are investigated. Roughened concrete interfaces crossed by reinforcing bars were subjected to cyclic shear slips, with or without compressive stress normal to the interface. The presented experimental results prove the beneficial effect of the external compressive stress on the ultimate shear resistance of interfaces, accompanied by the reduction of the effect of small embedment length of the interface reinforcement, due to its reduced contribution: the externally imposed compression leads to smaller crack openings at the interface, in most cases smaller than 0.40 mm, and to reduction of the reinforcement clamping effect. The shear resistance is activated at reduced shear slip values (0.20 mm–0.40 mm compared to 0.20–0.80 mm for interfaces under zero external compression), while the interface resistance degradation is also reduced (e.g., during the second load cycle, to 15% on average, compared to 30% for interfaces under zero external compression). Finally, an equation previously proposed by the authors is applied for the prediction of the shear resistance of interfaces under normal force, leading to satisfying accuracy. Full article
(This article belongs to the Special Issue Advances in Building Materials and Concrete, 2nd Edition)
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29 pages, 16669 KB  
Article
Influence of Monolith Length on Temperature Field of Concrete Gravity Dams
by Uroš Mirković, Vladan Kuzmanović and Goran Todorović
Appl. Sci. 2024, 14(8), 3248; https://doi.org/10.3390/app14083248 - 12 Apr 2024
Cited by 1 | Viewed by 1264
Abstract
This paper examines the influence of monolith length on the temperature field of concrete gravity dams built using the block method. The developed 3D model is capable of conducting a thermal analysis of a 95.0 m high concrete gravity dam built using the [...] Read more.
This paper examines the influence of monolith length on the temperature field of concrete gravity dams built using the block method. The developed 3D model is capable of conducting a thermal analysis of a 95.0 m high concrete gravity dam built using the block method, where each newly cast block represents a new analysis phase. The calculation accounts for the period of construction, the filling of the reservoir, and the service for a total duration of about 5 years. The thermal properties of the material, the influence of cement hydration heat, the temperature of the surrounding rock mass, the temperature of the fresh concrete mixture, and the corresponding boundary conditions defining a heat transfer were taken into account. The height and width of the blocks, as well as the sequence of concreting, were considered invariable, while the length of the blocks (dimension in the direction of the dam’s axis equal to the monolith length) varied, with values of 10.0, 12.5, 15.0, and 20.0 m. The obtained calculation results for the control nodes showed that the maximum reduction in the monolith length (from 20.0 m to 10.0 m) caused a decrease in the maximum temperature values of the concrete (from 1.6 to 3.4 °C, depending on the control node). Also, the results showed that, by reducing the length of the monolith, there was a delay in the moment at which the maximum temperature values of the concrete appeared in the selected control node. The delay in reaching the maximum, in relation to the 10.0 m long monolith, was from 7 days (for points on the crest dam) to 49 days (for points in the central zone of the monolith) for the other considered monolith lengths. The above indicates the importance of concrete temperature control for longer monoliths, especially during construction in extreme air temperatures. The main contribution of the conducted analysis is the development of insight into temperature field changes depending on monolith length, which can help engineers during the design and construction of new, as well as the maintenance of existing, dams. Full article
(This article belongs to the Section Civil Engineering)
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9 pages, 4203 KB  
Communication
A Compact Triplexer Based on InP/InGaAsP-MMI Coupler with Channel-Shaped Core Layer for 50G PON
by Fei Guo, Dan Lu, Hao Song, Yueying Niu, Daibing Zhou and Lingjuan Zhao
Photonics 2024, 11(3), 232; https://doi.org/10.3390/photonics11030232 - 4 Mar 2024
Cited by 1 | Viewed by 1786
Abstract
A novel wavelength triplexer based on Channel-Shaped Multimode Interference (C-MMI) structures on the InP platform is proposed for multi-channel integration compatibility in a 50G passive optical network (PON) system. Performance analysis of the proposed device is carried out by using the 3D Beam [...] Read more.
A novel wavelength triplexer based on Channel-Shaped Multimode Interference (C-MMI) structures on the InP platform is proposed for multi-channel integration compatibility in a 50G passive optical network (PON) system. Performance analysis of the proposed device is carried out by using the 3D Beam Propagation Method (3D-BPM), which shows excellent properties with insertion loss < 0.5 dB and low crosstalk < −14 dB for the 1342 nm in the Original band (1260–1360 nm), 1490 nm in the Short wavelength band (1460–1530 nm), and 1577 nm in the Long wavelength band (1565–1625 nm), also known as the OSL wavelengths band. Furthermore, the passbands of the three downlink channels of 1342 nm, 1490 nm, and 1577 nm, reach 14 nm, 20 nm, and 64 nm, respectively, which is wide enough to meet the 50G PON optical line terminal (OLT) requirement. Additionally, the proposed device is extremely compact with a total length of only 448 μm, making it attractive in the monolithic integrated laser chip and OLT packaged module. Full article
(This article belongs to the Special Issue Enabling Technologies for Optical Communications and Networking)
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15 pages, 4627 KB  
Article
Investigating the Influence of All-Ceramic Prosthetic Materials on Implants and Their Effect on the Surrounding Bone: A Finite Element Analysis
by Saniya Juneja, Glynis Miranda, Afiya Eram, Nisha Shetty, Chethan K N and Laxmikant G. Keni
Prosthesis 2024, 6(1), 74-88; https://doi.org/10.3390/prosthesis6010006 - 17 Jan 2024
Cited by 9 | Viewed by 1958
Abstract
This study aims to assess and compare the impact of Monolithic Zirconia (MZ) and In-Ceram Zirconia (ZP) superstructures on stress distribution within implants and D2/D4 bone densities under 200 N vertical and oblique occlusal loads using three-dimensional finite element analysis via ANSYS WORKBENCH [...] Read more.
This study aims to assess and compare the impact of Monolithic Zirconia (MZ) and In-Ceram Zirconia (ZP) superstructures on stress distribution within implants and D2/D4 bone densities under 200 N vertical and oblique occlusal loads using three-dimensional finite element analysis via ANSYS WORKBENCH R2. The analysis employed maximum and minimum von Mises stress values. Modeling an implant (4.2 mm diameter, 10 mm length) and abutment (0.47 mm diameter), with an 8 mm diameter and 6 mm length single crown, the research identified lower von Mises stresses in D2 cancellous bone with the MZ model under vertical loading. Conversely, under oblique loading, the ZP model exhibited maximum von Mises stresses in D4 bone around the implant. This underscores the critical need to consider physical and mechanical properties, beyond mere aesthetics, for sustained implant success. The findings highlight the effect of material composition and stress distribution, emphasizing the necessity of durable and effective implant treatments. Full article
(This article belongs to the Collection Oral Implantology: Current Aspects and Future Perspectives)
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25 pages, 3033 KB  
Article
SAINT (Small Aperture Imaging Network Telescope)—A Wide-Field Telescope Complex for Detecting and Studying Optical Transients at Times from Milliseconds to Years
by Grigory Beskin, Anton Biryukov, Alexey Gutaev, Sergey Karpov, Gor Oganesyan, Gennady Valyavin, Azamat Valeev, Valery Vlasyuk, Nadezhda Lyapsina and Vyacheslav Sasyuk
Photonics 2023, 10(12), 1352; https://doi.org/10.3390/photonics10121352 - 7 Dec 2023
Cited by 2 | Viewed by 2279
Abstract
In this paper, we present a project of a multi-channel wide-field optical sky monitoring system with high temporal resolution—Small Aperture Imaging Network Telescope (SAINT)— mostly built from off-the-shelf components and aimed towards searching and studying optical transient phenomena on the shortest time scales. [...] Read more.
In this paper, we present a project of a multi-channel wide-field optical sky monitoring system with high temporal resolution—Small Aperture Imaging Network Telescope (SAINT)— mostly built from off-the-shelf components and aimed towards searching and studying optical transient phenomena on the shortest time scales. The instrument consists of twelve channels each containing 30 cm (F/1.5) GENON Max objectives mounted on separate ASA DDM100 mounts with pointing speeds up to 50 deg/s. Each channel is equipped with a 4128 × 4104 pixel Andor Balor sCMOS detector and a set of photometric griz filters and linear polarizers. At the heart of every channel is a custom-built reducer-collimator module allowing rapid switching of an effective focal length of the telescope—due to it the system is capable of operating in either wide-field survey or narrow-field follow-up modes. In the first case, the field of view of the instrument is 470 square degrees (39 sq.deg. for a single channel) and the detection limits (5σ level at 5500 Å) are 12.5, 16.5, 19, 21 with exposure times of 20 ms, 1 s, 30 s and 20 min, correspondingly. In the second, follow-up (e.g., upon detection of a transient of interest by either a real-time detection pipeline, or upon receiving an external trigger) regime, all telescopes are oriented towards the single target, and SAINT becomes an equivalent to a monolithic 1-meter telescope, with the field of view reduced to 11 × 11, and the exposure times decreased down to 0.6 ms (1684 frames per second). Different channels may then have different filters installed, thus allowing a detailed study—acquiring both color and polarization information—of a target object with the highest possible temporal resolution. The telescopes are located in two pavilions with sliding roofs and are controlled by a cluster of 25 computers that both govern their operation and acquire and store up to 800 terabytes of data every night, also performing its real-time processing using a dedicated fast image subtraction pipeline. Long-term storage of the data will require a petabyte class storage. The operation of SAINT will allow acquiring an unprecedented amount of data on various classes of astrophysical phenomena, from near-Earth to extragalactic ones, while its multi-channel design and the use of commercially available components allows easy expansion of its scale, and thus performance and detection capabilities. Full article
(This article belongs to the Special Issue Optical Systems for Astronomy)
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22 pages, 5803 KB  
Article
Discriminant Analysis Based on the Patch Length and Crack Depth to Determine the Convergence of Global–Local Non-Intrusive Analysis with 1D-to-3D Coupling
by Matías Jaque-Zurita, Jorge Hinojosa, Emilio Castillo-Ibarra and Ignacio Fuenzalida-Henríquez
Symmetry 2023, 15(11), 2068; https://doi.org/10.3390/sym15112068 - 15 Nov 2023
Cited by 1 | Viewed by 1298
Abstract
Reducing the time spent on computational simulations is an active area in solid mechanics, and efforts are being made to implement novel techniques and apply them to time-sensitive areas in the industry and research. One of these techniques is called global–local non-intrusive analysis, [...] Read more.
Reducing the time spent on computational simulations is an active area in solid mechanics, and efforts are being made to implement novel techniques and apply them to time-sensitive areas in the industry and research. One of these techniques is called global–local non-intrusive analysis, a methodology that enriches a local patch model using 3D elements with non-linear behavior (such as crack propagation), coupled with a linear, global 1D frame model that solves iteratively, thereby reducing overall times compared to a monolithic solution. However, engineers do not know the length of the local model (also known as the patch model) to be considered, which affects the convergence, computational time, and overall quality of the solution. Therefore, this study considered the use of categorical analyses for performing linear and quadratic discriminant solvers for a given set of simple cases with symmetric crack propagation within the local model and defining the convergence boundary with a certain probability of a successful convergence. In addition, a practical case was analyzed for different lengths of the local model, giving strong correlations to the results of the discriminant analysis. The solution of all the cases was also analyzed, considering the number of degrees of freedom, computational times, and the number of iterations for convergence. This aimed to establish a functional relation for engineering practice, enabling the determination of a suitable patch length for performing global–local non-intrusive analysis with crack propagation in doubly symmetric steel sections. Full article
(This article belongs to the Special Issue Emerging Applications of Machine Learning in Smart Systems Symmetry)
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16 pages, 3493 KB  
Article
Au-Nanorods Supporting Pd and Pt Nanocatalysts for the Hydrogen Evolution Reaction: Pd Is Revealed to Be a Better Catalyst than Pt
by Ayoub Laghrissi and Mohammed Es-Souni
Nanomaterials 2023, 13(13), 2007; https://doi.org/10.3390/nano13132007 - 5 Jul 2023
Cited by 2 | Viewed by 2048
Abstract
Ordered thin films of Au nanorods (NRs) on Ti/Au/Si heterostructure substrates are electrodeposited in thin film aluminum oxide templates and, after template removal, serve as supports for Pd and Pt nanocatalysts. Based on previous work which showed a better electrocatalytic performance for layered [...] Read more.
Ordered thin films of Au nanorods (NRs) on Ti/Au/Si heterostructure substrates are electrodeposited in thin film aluminum oxide templates and, after template removal, serve as supports for Pd and Pt nanocatalysts. Based on previous work which showed a better electrocatalytic performance for layered Au/Pd nanostructures than monolithic Pd, electrodeposited 20 nm Pd discs on Au-NRs are first investigated in terms of their catalytic activity for the hydrogen evolution reaction (HER) and compared to monolithic 20 nm Pd and Pt discs. To further boost performance, the interfacial interaction area between the Au-NRs supports and the active metals (Pt and Pd) was increased via magnetron sputtering an extremely thin layer of Pt and Pd (20 nm overall sputtered thickness) on the Au-NRs after template removal. In this way, the whole NR surface (top and lateral) was covered with Pt and Pd nanoparticles, ensuring a maximum interfacial contact between the support and the active metal. The HER performance obtained was substantially higher than that of the other nanostructures. A Salient result of the present work, however, is the superior activity obtained for sputtered Pd on Au in comparison to that of sputtered Pt on Au. The results also show that increasing the Au-NR length translates in a strong increase in performance. Density functional theory calculations show that the interfacial electronic interactions between Au and Pd lead to suitable values of hydrogen adsorption energy on all possible sites, thus promoting faster (barrier-free diffusion) hydrogen adsorption and its recombination to H2. A Volmer–Heyrovsky mechanism for HER is proposed, and a volcano plot is suggested based on the results of the Tafel plots and the calculated hydrogen adsorption energies. Full article
(This article belongs to the Special Issue 1D and 2D Nanomaterials for Energy Storage and Conversion)
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13 pages, 1495 KB  
Article
Programmable Low-Pressure Chromatographic Sub-90 s Assay of Parabens in Cosmetics with Post-Column Chemiluminescence Detection
by Margarita Barbatsi and Anastasios Economou
Separations 2023, 10(6), 350; https://doi.org/10.3390/separations10060350 - 11 Jun 2023
Cited by 1 | Viewed by 1791
Abstract
This work describes a new programmable low-pressure chromatography method with post-column chemiluminescence (CL) detection for the rapid and cost-effective determination of four parabens in cosmetic products. Elution of the target analytes was achieved using a programmable mobile phase prepared by implementing a linear [...] Read more.
This work describes a new programmable low-pressure chromatography method with post-column chemiluminescence (CL) detection for the rapid and cost-effective determination of four parabens in cosmetic products. Elution of the target analytes was achieved using a programmable mobile phase prepared by implementing a linear solvent gradient protocol based on appropriate flow rate modulation of 2 MilliGAT pumps. A 5 mm monolithic C18 column was used to separate the parabens. Post-column reaction of the eluted parabens with an acidic Ce(IV)-rhodamine 6G (Rho 6G) medium was carried out by introducing a flow stream of the reactants into the column eluate. The light generated from the CL reaction was detected with a flow-through CL detector fabricated in-house. The whole sequence of operations (including sample injection, generation of the mobile phase, addition of the post-column reaction reagents and signal acquisition) was under full computer control. Various operational parameters (the mobile phase composition and gradient conditions, the CL reagents’ concentrations and flow rates and the length of the reaction coil) were studied. The method was validated and applied to the analysis of various cosmetic products. The proposed approach allows sub-90 s separation of the four parabens and their determination with a limit of quantification of 0.2 μg L−1 with a sample throughput of 24 samples h−1. In addition, the method is economical, makes use of low-cost low-pressure components, is fully automated and produces a low amount of waste. Full article
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