Search Results (56)

In this work, we investigated the use of a piezoelectric flexible device for energy harvesting. The main goal of the study was to fill the nanostructured pores of anodic aluminum oxide (AAO) films with piezoelectric polymer (PVDF-TrFE) via a modified conventional screen printing technique using blade printing. In this way, it is possible to obtain a composite from nanostructured thin films of polymer nanorods that shows improved charge generation ability compared to other non-nanostructured composites or pure (non-composite) aluminum with similar dimensions. This behavior is due to the effect of the highly developed surface of the material used to fill in the AAO nanopore template and its ability to withstand the application of higher mechanical loads to the structured piezoelectric material during deformation. The contact blade print filling technique can produce nanostructured piezoelectric polymer films with precise geometric parameters in terms of thickness and nanorod diameters, at around 200 nm, and a length of 12 μm. At a low frequency of 17 Hz, the highest root-mean-square (RMS) voltage generated using the nanostructured AAO/PVDF-TrFE sample with aluminum electrodes was around 395 mV. At high frequencies above 1700 Hz, the highest RMS voltage generated using the nanostructured AAO/PVDF-TrFE sample with gold electrodes was around 680 mV. The RMS voltage generated using a uniform (non-nanostructured) layer of PVDF-TrFE was 15% lower across the whole frequency range. Full article

Poly(lactic acid)/barium titanate (PLA/BT) composites exhibit piezoelectric properties desirable for bone tissue engineering, but their low biodegradability limits implant resorption. In this study, riboflavin (RF) is introduced as a dual-function additive that enhances biodegradation in PLA/BT composites. Its addition led to significantly increased microbial colonization and a five-fold higher mass loss compared to unmodified samples. These observations are consistent with the known polarity of RF and its role as a cofactor in microbial metabolism. The PLA/BT/RF composites are subjected to full characterization, including thermogravimetric analysis (TG), differential scanning calorimetry (DSC), tensile testing, dynamic mechanical analysis (DMA), dielectric permittivity measurements, and determination of piezoelectric coefficient d₃₃. Compared to PLA/BT, RF-containing composites exhibit significantly accelerated biodegradation, with mass loss reaching up to 16% after 28 days, while maintaining functional piezoelectricity (d₃₃ ≈ 3.9 pC/N). Scanning electron microscopy (SEM) performed after biodegradation reveals intensified microbial colonization and surface deterioration in the RF-modified samples. The data confirm that riboflavin serves as an effective modifier, enabling controlled biodegradation without compromising electromechanical performance. These results support the use of PLA-based piezoelectric composites for resorbable biomedical implants. Full article

Piezoelectric polymer composites, particularly polyvinylidene fluoride (PVDF) blended with barium titanate (BT), show promise for wearable technologies as both energy harvesters and haptic actuators. However, these composites typically exhibit limited electromechanical coupling and insufficient β-phase formation. This study presents a novel approach using ionic liquids (ILs) to enhance PVDF-based piezoelectric composite performance. Through solution-casting methods, we examined the effect of IL concentration on the structural, mechanical, and piezoelectric properties of PVDF/BT composites. Results demonstrate that the use of IL significantly improves β-phase crystallization in PVDF while enhancing electrical properties and mechanical flexibility, which are key requirements for effective energy harvesting and haptic feedback applications. The optimized composites show a 25% increase in β-phase content, enhanced flexibility, and a 100% improvement in piezoelectric voltage output compared to other more conventional PVDF/BT systems. The IL-modified composite exhibits superior piezoelectric response, generating an output voltage of 9 V and an output power of 40.1 µW under mechanical excitation and a displacement of 138 nm when subjected to 13 V peak-to-peak voltage, making it particularly suitable for haptic interfaces. These findings establish a pathway toward high-performance, flexible piezoelectric materials for multifunctional wearable applications in human–machine interfaces. Full article

Fast steering mirrors (FSMs), actuated by piezoelectric ceramics, play pivotal roles in satellite laser communication, distinguished by their high bandwidth and fast responsiveness, thereby facilitating the precise pointing and robust tracking of laser beams. However, the dynamic performance of FSMs is notably impaired by the hysteresis nonlinearity inherent in piezoelectric ceramics. Under dynamic conditions, rate-dependent hysteresis models and Hammerstein models are predominantly employed to characterize hysteresis nonlinearity. By combining the advantages of these two models, a hysteresis model termed modified Hammerstein-like (MHL) model is proposed. This model integrates an input time delay, a rate-dependent hysteresis term, and a linear dynamic term in a cascaded structure, effectively capturing the dynamic characteristics of hysteresis systems across a broad frequency range. Additionally, a composite control strategy is tailored for the MHL model which consists of a feedforward compensator based on a rate-dependent hysteresis inverse model and a proportional–integral (PI) controller for closed-loop regulation. Experimental results demonstrate the effectiveness of the proposed modeling and composite control methods. Full article

Piezoelectric materials based on polyvinylidene fluoride (PVDF) are widely regarded as ideal candidates for the fabrication of piezoelectric energy harvesters (PEHs). However, the relatively low power output of PVDF limits its widespread application and poses a significant challenge to the advancement of PEHs. To address this issue, we have designed a novel PEH using silver-modified lead zirconate titanate/PVDF (pPZT@Ag/PVDF), which achieves a remarkable balance between high output performance and long-term stability. The pPZT@60Ag/PVDF PEH generates a peak voltage of 14.33 V, which is about 2.6 times that of the pure lead zirconate titanate/PVDF (pPZT/PVDF) PEH. This enhancement is attributed to the confined structure within the PVDF fibers, as well as the enhancement in dipole orientation alignment and the local electric field induced by silver nanoparticle modification. Furthermore, the pPZT@60Ag/PVDF PEH demonstrates a peak power density of 0.58 μW/cm², with negligible degradation in output voltage after 6000 bending cycles, and efficiently harvests mechanical energy from human movement. This study presents an effective method for fabricating high-performance PEHs, which is expected to advance the development of next-generation energy harvesting devices. Full article

An epoxy/glass microbeads-based 1-3 piezoelectric composite is proposed, to enhance electromechanical conversion efficiency. Firstly, based on the series-parallel theory, the theoretical model is established. Secondly, the epoxy resin/glass microbeads-based 1-3 piezoelectric composite is simulated by finite element software. The effects of polymers with different acoustic impedances, the thicknesses of piezoelectric composites, and ceramic volume fractions are analyzed systematically. After parameter optimization, the epoxy/glass microbeads-based 1-3 piezoelectric composite is prepared. The experimental results agree well with the theoretical and simulation results. When the ceramic volume fraction is 60.0%, its electromechanical coupling factor is the largest, which is 0.714. Compared with the prepared traditional 1-3 piezoelectric composites with the same parameters, its electromechanical coupling factor is increased by 7.8%. Therefore, the epoxy/glass microbeads-based 1-3 piezoelectric composite can enhance the sensitivity and resolution of the transducers, which has potential advantages for improving the performance of transducers. Full article

Polyetheretherketone (PEEK) has gained significant attention in biomedical applications due to its excellent mechanical properties and biocompatibility. In this work, the fabrication of electroactive poly(vinylidenefluoride-co-trifluoroethylene) (PVTF) coatings on PEEK surfaces to enhance osteogenesis is explored. PEEK substrates were prepared with different surface treatments to optimize adhesion, followed by PVTF coating through drop-casting and polarization. Morphological, chemical, and thermal characterizations revealed uniform β-phase crystallization in the PVTF layer, achieving a peak piezoelectric coefficient (d₃₃) of 16 pC/N under a 4 kV polarization voltage. Cell culture experiments demonstrated improved biocompatibility, with polarized surfaces showing enhanced bone marrow mesenchymal stem cell (BMSC) adhesion, proliferation, and osteogenic differentiation. ALP activity, a key marker of osteogenesis, was significantly higher on polarized samples. Furthermore, the modified surfaces exhibited strong adhesion between PVTF and PEEK, as well as sustained surface potential in physiological conditions. These test results indicate that the PEEK/PVTF composite, with its enhanced electroactive properties and biocompatibility, shows great potential as an electroactive material for biomedical implants. Full article

A novel piezoelectric material, polyacrylonitrile (PAN) nanofibers, exhibits significant piezoelectric effects when a high content of planar zigzag structures is present. To enhance the contribution of planar zigzag structures to energy conversion while preserving the structure of PAN nanofibers, a novel approach was developed to increase planar zigzag content by incorporating cellulose nanocrystals (CNCs) rather than modifying conventional synthesis conditions. In this study, CNCs were introduced during the electrospinning process of PAN formation, and the increased planar zigzag content was confirmed through X-ray diffraction (XRD), electrical characterization, and Fourier transform infrared spectroscopy (FTIR) analyses. This study, for the first time, demonstrates that CNC addition to PAN enhances the mechanical properties and piezoelectric performance by promoting the formation of zigzag structures, which play a crucial role in the piezoelectric effect. The PAN–CNC composite holds great potential for applications in new piezoelectric devices. With CNC incorporation, the voltage increased by 68.9%, and the current increased by 80% compared to regular PAN. The generated energy is suitable for human applications and can also power commercial devices, making these findings pivotal for the advancement of piezoelectric materials and devices. Full article

Damage in composite laminates evolves through complex interactions of different failure modes, influenced by load type, environment, and initial damage, such as from transverse impact. This paper investigates damage growth in cross-ply polymeric matrix laminates under tensile load, focusing on three primary failure modes: transverse matrix cracks, delaminations, and fiber breaks in the primary loadbearing 0-degree laminae. Acoustic emission (AE) techniques can monitor and quantify damage in real time, provided the signals from these failure modes can be distinguished. However, directly observing crack growth and related AE signals is challenging, making numerical simulations a useful alternative. AE signals generated by the three failure modes were simulated using modified step impulses of appropriate durations based on incremental crack growth. Linear elastic finite element analysis (FEA) was applied to model the AE signal propagating as Lamb waves. Experimental attenuation data were used to modify the simulated AE waveforms by designing arbitrary magnitude response filters. The propagating waves can be detected as surface displacements or surface strains depending upon the type of sensor employed. This paper presents the signals corresponding to surface strains measured by surface-bonded piezoelectric sensors. Fiber break events showed higher-order Lamb wave modes with frequencies over 2 MHz, while matrix cracks primarily exhibited the fundamental S₀ and A₀ modes with frequencies ranging up to 650 kHz, with delaminations having a dominant A₀ mode and frequency content less than 250 kHz. The amplitude and frequency content of signals from these failure modes are seen to change significantly with source–sensor distance, hence requiring an array of dense sensors to acquire the signals effectively. Furthermore, the reasonable correlation between the simulated waveforms and experimental acoustic emission signals obtained during quasi-static tensile test highlights the effectiveness of FEA in accurately modeling these failure modes in composite materials. Full article

This article is devoted to a mathematical model of a new piezoelectric sensor used for measuring bending strains. The first simple model of a piezoelectric sensor of bending deformations (we will call it a classical sensor) was presented in our previous paper. The classical sensor is a one-dimensional three-layer structure, in which the two outer layers are made of piezoelectric ceramic with preliminary polarization across the thickness of the sensor, and one elastic middle layer is located between these piezoelectric layers. In the present modified model of the new sensor, piezoelectric stacks are used instead of simple piezoelectric elements. As shown in the paper, this kind of piezoelectric composite sensor with stacks allows us to significantly increase the value and stability of the measured electrical signal and increase the accuracy of strains measurement. Piezoelectric ceramic is a brittle material. The use of stacks significantly reduces brittleness by enclosing thin layers of piezoelectric ceramic in a metal matrix. Piezoelectric laminated stacks have a periodic structure, and we will use the mathematical homogenization method to correctly determine their effective moduli (physical constants). Increasing the reliability of the proposed sensors, as well as the accuracy and stability of their deformation measurements, is aimed at enhancement of the mechanical safety of building structures, increasing the efficiency of their monitoring. The most important characteristic of any sensor is its efficiency. Our first classical bending strain sensor has a simple structure and an efficiency approaching the value of the coupling coefficient k₃₁ (k₃₁ is a constant describing a known physical property of a piezoelectric material). Our classic piezoelectric flexural strain sensor has an efficiency of the order of the coupling coefficient k₃₁. For piezoelectric materials with a strong piezoelectric effect, the k₃₁ value is approximately 0.30–0.35. The efficiency of our classical sensor is hundreds of times greater than the efficiency of the most popular tangential (longitudinal) strain sensor, developed by Lord Kelvin. The efficiency of the flexural strain sensor using stacks is of the order of the coupling coefficient k₃₃. For the sensor with piezoelectric stacks, the value of efficiency is approximately 0.60–0.70. Note that the efficiency of the improved sensor is twice as high as the efficiency of our classic flexural strain sensor. Full article

The flexible piezoelectric pressure sensor is essential in areas such as machine sensing and human activity monitoring. Here, 0-dimensional PZT piezoelectric ceramic nanoparticles with carbon coating were synthesized by a surface-modified technique. The excellent electrical conductivity of the carbon shell causes redistribution and accumulation of mobile charges in the carbon layer, resulting in a greatly increased piezoelectric effect by inducing an enhanced electric field. A series of organic–inorganic composite films were prepared by the spin-coating method using polydimethylsiloxane (PDMS) as the matrix. The as-fabricated flexible PZT@C/PDMS composite film with 40 wt% PZT@C powder exhibits an excellent output voltage of ~74 V, a peak of output current ~295 nA, as well as a big sensitivity of 5.26 V N⁻¹. Moreover, the composite film can be used as a pressure sensor to detect changes in force as well as for monitoring limb movements such as finger flexion, wrist flexion, and pedaling. This study reveals the promising applications of flexible 40%PZT@C/PDMS composite film for limb motion monitoring and pressure sensing. Full article

A wireless monitoring system based on piezoelectric energy harvesting (PEH) is presented to provide fatigue data of wind turbine blades in operation. The system comprises three subsystems, each respectively providing the following functions: (i) the conversion of mechanical to electric energy by exploiting the bistable vibration of a composite beam with piezoelectric patches in post-buckling, (ii) harvesting the converted energy by means of a modified, commercial, off-the-shelf (COTS) circuit to feed a LiPo battery and (iii) the battery-powered acquisition and wireless transmission of sensory signals to the cloud to be elaborated upon by the end-user. The system was verified with ground tests under representative operation conditions, which demonstrated the fulfillment of the design requirements. The measurements indicated that the system provided 23% of the required power for fully autonomous operation when subjected to white noise base excitation of 1 g acceleration in the range of 1–20 Hz. Full article

With the advent of the Internet of Things, self-powered wearable sensors have become increasingly prevalent in our daily lives. The utilization of piezoelectric composites to harness and sense surrounding mechanical vibrations has been extensively investigated during the last decades. However, the poor interface compatibility between ceramics nanofillers and polymers matrix, as well as low piezoelectric performance, still serves as a critical challenge. In this work, we employed Di(dioctylpyrophosphato) ethylene titanate (DET) as the coupling agent for modifying barium titanate (BTO) nanofillers. Compared to the BTO/PVDF counterpart, the DET-BTO/PVDF nanofibers exhibit an augmented content of piezoelectric β phase (~85.7%) and significantly enhanced stress transfer capability. The piezoelectric coefficient (d₃₃) is up to ~40 pC/N, which is the highest value among reported BTO/PVDF composites. The piezoelectric energy harvesters (PEHs) present benign durability and attain a high instantaneous power density of 276.7 nW/cm² at a matched load of 120 MΩ. Furthermore, the PEHs could sense various human activities, with the sensitivity as high as 0.817 V/N ranging from 0.05–0.1 N. This work proposes a new strategy to boosting the piezoelectric performance of PVDF-based composites via DET-doping ceramics nanoparticles, and in turn show significantly improved energy harvesting and sensing capability. Full article

Civil engineering structures need to be protected from earthquakes, representing a new area of research that is growing continuously and very rapidly. Design engineers are always searching for lightweight, stronger, and stiffer materials to be applied as vibration-damping materials. Stability in dynamics necessitates an active, robust, and convenient mechanism that can absorb the kinetic energy of vibration to prevent the structural system from resonance. Recently, many researchers have successfully used nanomaterials to develop energy-absorbing materials that are lightweight and cost-effective. Traditional damping treatments are based on combinations of viscoelastic, elastomeric, magnetic, and piezoelectric materials. In this paper, a review of various damping techniques for composites made of cement modified by various nanomaterials like Nano Al2O₃ (Aluminum Dioxide), Nano SiO₂ (Silicon Dioxide), Nano TiO₂ (Titanium Dioxide), Graphene, and CNTs (Carbon Nanotubes) is presented. The designs of various nano-composite dampers are presented to strengthen the information progress in this field. The current study’s goal is to discover how nanoparticles impact the cement-based material’s damping properties. The study examined several nanomaterials in cement composites at differing concentrations. With the help of the Dynamic Mechanical Analysis (DMA) method and the Logarithmic Decrement approach, the damping properties of these composites were examined. Scanning Electron Microscopy (SEM) was used to examine the effects of nanomaterials on the microstructure and pore size distribution of the composite. Increasing the quantity of nanoparticles in cement paste may improve its capacity to lessen vibration. The experiments also showed that certain nanomaterials may improve load transmission inside the cement matrix and connect neighboring hydration products, helping to reduce energy loss during the loading process. These nanoparticles will eventually replace the large machinery employed to dampen vibrations in buildings due to their small weight, increased mechanical strength, and effective damping properties. Full article

The resonant magnetoelectric (ME) effect of Fe₇₈Si₉B₁₃/Pb(Zr,Ti)O₃ (FeSiB/PZT) composites with a surface-modified Fe₇₈Si₉B₁₃ amorphous alloy has been studied. The surface-modified FeSiB can improve the ME coefficient at the resonant frequency by optimizing the magnetomechancial power conversion efficiency. The maximum ME coefficient of the surface-modified ribbons combined with soft PZT (PZT5) is two-thirds larger than that of the composites with fully amorphous ribbons. Meanwhile, the maximum value of the ME coefficient with surface-modified FeSiB ribbons and hard PZT (PZT8) is one-third higher compared with the fully amorphous composites. In addition, experimental results of magnetomechanical coupling properties of FeSiB/PZT composites with or without piezoelectric layers indicate that the power efficiency of the composites first decreases and then increases with the increase in the number of FeSiB layers. When the surface crystalline FeSiB ribbons are combined with a commercially available hard piezoelectric ceramic plate, the maximum magnetoelectric coupling coefficient of the ME composite reaches 5522 V/(Oe*cm), of which the electromechanical resonant frequency is 23.89 kHz. Full article