Search Results (894)

The Junggar Basin contains a large amount of coal resources and is an important coal production base in China. The coal seam in Zhundong coalfield has a large single-layer thickness and high content of inertinite, but large particle Fe-sulphide minerals are associated with coal seams in some mining areas. A series of economic and environmental problems caused by the combustion of large-grained Fe-sulphide minerals in coal have seriously affected the economic, clean and efficient utilization of coal. In this paper, the ultra-thick coal seam of the Xishanyao formation in the Yihua open-pit mine of the Zhundong coalfield is taken as the research object. Through the analysis of coal quality, X-ray fluorescence spectrometer test of major elements in coal, inductively coupled plasma mass spectrometry test of trace elements, SEM-Raman identification of Fe-sulphide minerals in coal and LA-MC-ICP-MS test of sulfur isotope of marcasite, the coal quality characteristics, main and trace element characteristics, macro and micro occurrence characteristics of Fe-sulphide minerals and sulfur isotope characteristics of marcasite in the ultra-thick coal seam of the Xishanyao formation are tested. On this basis, the occurrence state and genesis of large particle Fe-sulphide minerals in the ultra-thick coal seam of the Xishanyao formation are clarified. The main results and understandings are as follows: (1) the occurrence state of Fe-sulphide minerals in extremely thick coal seams is clarified. The Fe-sulphide minerals in the extremely thick coal seam are mainly marcasite, and concentrated in the YH-2, YH-3, YH-8, YH-9, YH-14, YH-15 and YH-16 horizons. Macroscopically, Fe-sulphide minerals mainly occur in three forms: thin film Fe-sulphide minerals, nodular Fe-sulphide minerals, and disseminated Fe-sulphide minerals. Microscopically, they mainly occur in four forms: flake, block, spearhead, and crack filling. (2) The difference in sulfur isotope of marcasite was discussed, and the formation period of marcasite was preliminarily divided. The overall variation range of the δ³⁴S value of marcasite is wide, and the extreme values are quite different. The polyflake marcasite was formed in the early stage of diagenesis and the δ³⁴S value was negative, while the fissure filling marcasite was formed in the late stage of diagenesis and the δ³⁴S value was positive. (3) The coal quality characteristics of the thick coal seam were analyzed. The organic components in the thick coal seam are mainly inertinite, and the inorganic components are mainly clay minerals and marcasite. (4) The difference between the element content in the thick coal seam of the Zhundong coalfield and the average element content of Chinese coal was compared. The major element oxides in the thick coal seam are mainly CaO and MgO, followed by SiO₂, Al₂O₃, Fe₂O₃ and Na₂O. Li, Ga, Ba, U and Th are enriched in trace elements. (5) The coal-accumulating environment characteristics of the extremely thick coal seam are revealed. The whole thick coal seam is formed in an acidic oxidation environment, and the horizon with Fe-sulphide minerals is in an acidic reduction environment. The acidic reduction environment is conducive to the formation of marcasite and is not conducive to the formation of pyrite. (6) There are many matrix vitrinite, inertinite content, clay content, and terrigenous debris in the extremely thick coal seam. The good supply of peat swamp, suitable reduction environment and pH value, as well as groundwater leaching and infiltration, together cause the occurrence of large-grained Fe-sulphide minerals in the extremely thick coal seam of the Xishanyao formation in the Zhundong coalfield. Full article

In this study, alkali-activated coal gangue-slag material (AACGS) was prepared using coal gangue and slag as precursors, and its feasibility as conductive mortar substrate material was preliminarily investigated. Firstly, this study employed Response Surface Methodology (RSM) to develop statistical models correlating the alkali equivalent, water-to-binder ratio, and slag content with the compressive strength, flexural strength, and resistivity of AACGS, aiming to identify the optimal mix proportions. Secondly, based on the optimal ratio identified above and using carbon fibers (CF) as the conductive phase, an alkali-activated conductive mortar (CF-AACGS) was prepared, and its compressive strength, flexural strength, and resistivity were tested. Lastly, XRD and SEM-EDS were conducted to characterize the mineral composition and microstructure of CF-AACGS. The results indicate that when the alkali equivalent, water-to-binder ratio, and slag content are 13.34%, 0.54, and 57.52%, respectively, the AACGS achieves compressive strength, flexural strength, and resistivity of 72.5 MPa, 7.0 MPa, and 62.41 Ω·m at 28 days. Under the action of the alkali activator, coal gangue and slag undergo hydration reactions, forming a denser N, C-(A)-S-H gel. This effectively improves the interface transition zone between the CF and AACGS, endowing the CF-AACGS with superior mechanical properties. Furthermore, the AACGS matrix enhances the conductive contact point density by optimizing CF dispersion, which significantly reduces the resistivity of the CF-AACGS. Full article

Coal miners’ unsafe behavior is the primary reason for accidents. This research aims to examine the effect of male coal miners’ shared work crew identity on their safety behavior. A 2-2-1 multilevel mediation model is established based on social identity theory and safety climate theory. To validate the model, a paper-and-pencil survey with male coal miners was carried out in Henan Province, China. A total of 212 valid responses from male coal miners nested in 53 work crews were secured, and Mplus was used to analyze the data. Results show that work crew safety climate fully mediates the effect of male coal miners’ shared work crew identity on their safety behavior. In theory, the findings support that social identity brings a safety climate. In practice, the findings highlight that making safety part of work crew norms improves male coal miners’ safety behavior. Limitations and future research are also discussed. Full article

Corrosion-related failures have emerged as a critical driver of premature support bolt failures in underground mines, emphasizing the urgency of understanding the phenomenon with respect to enhancing safety in underground environments. This study investigated key factors influencing bolt degradation through extensive experimental evaluation of cable bolts in simulated underground bolt environments. Multi-stranded cable specimens were exposed to saturated clay, coal, mine water, and grout/cement environments. Water samples were collected weekly from critical packing sections and analyzed for pH, electrical conductivity, and dissolved oxygen. The mineralogy and atmospheric conditions were identified as principal corrosion factors, and clay-rich and coal matrices accelerated corrosion, linked to high ion mobility and oxygen diffusion. Secondary factors correlated context-dependently: pH was negatively associated with corrosion in mineral-packed environments, while conductivity was correlated with non-mineral matrices. Notably, multi-stranded cables exhibited higher localized galvanic corrosion in inter-strand zones, highlighting design vulnerabilities. This work provides pioneering evidence that geological conditions are primary drivers for corrosion-related failures, offering actionable guidance for corrosion mitigation strategies in mining infrastructure. Full article

To address the limitations of traditional hardened concrete road surfaces in coal mine tunnels, which are prone to damage and entail high maintenance costs, this study proposes using modular concrete blocks composed of fly ash and coal gangue as an alternative to conventional materials. These blocks offer advantages including ease of construction and rapid, straightforward maintenance, while also facilitating the reuse of substantial quantities of solid waste, thereby mitigating resource wastage and environmental pollution. Initially, the mineral composition of the raw materials was analyzed, confirming that although the physical and chemical properties of Liangshui Well coal gangue are slightly inferior to those of natural crushed stone, they still meet the criteria for use as concrete aggregate. For concrete blocks incorporating 20% fly ash, the steam curing process was optimized with a recommended static curing period of 16–24 h, a temperature ramp-up rate of 20 °C/h, and a constant temperature of 50 °C maintained for 24 h to ensure optimal performance. Orthogonal experimental analysis revealed that fly ash content exerted the greatest influence on the compressive strength of concrete, followed by the additional water content, whereas the aggregate particle size had a comparatively minor effect. The optimal mix proportion was identified as 20% fly ash content, a maximum aggregate size of 20 mm, and an additional water content of 70%. Performance testing indicated that the fabricated blocks exhibited a compressive strength of 32.1 MPa and a tensile strength of 2.93 MPa, with strong resistance to hydrolysis and sulfate attack, rendering them suitable for deployment in weakly alkaline underground environments. Considering the site-specific conditions of the Liangshuijing coal mine, ANSYS 2020 was employed to simulate and analyze the mechanical behavior of the blocks under varying loads, thicknesses, and dynamic conditions. The findings suggest that hexagonal coal gangue blocks with a side length of 20 cm and a thickness of 16 cm meet the structural requirements of most underground mine tunnels, offering a reference model for cost-effective paving and efficient roadway maintenance in coal mines. Full article

As global demand for rare earth elements (REEs) increases, maintaining the production and supply chain is critical. Technologies capable of being used in the field and in situ in the subsurface for rapid REE detection and quantification facilitates the efficient mining of known resources and exploration of new and unconventional resources. Laser-induced breakdown spectroscopy (LIBS) is a promising technique for rapid elemental analysis both in the laboratory and in the field. Multiple articles have been published evaluating LIBS for detection and quantification of REEs; however, REEs in their natural deposits have not been adequately studied. In this work, detection and quantification of two REEs, La and Nd, have been studied in both synthetic and natural mineral matrices at concentrations relevant to REE extraction. Measurements were performed on REE-containing rock and coal samples (natural and synthetic) utilizing different LIBS instruments and techniques, specifically a commercial benchtop instrument, a custom benchtop instrument (single- and double-pulse modes), and a custom LIBS probe currently being developed for in situ, subsurface, borehole wall detection and quantification of REEs. Plasma expansion, emission intensity, detection limits, and double-pulse signal enhancement were studied. The limits of detection (LOD) were found to be 10/14 ppm for La and 15/25 ppm for Nd in simulated coal/rock matrices in single-pulse mode. Signal enhancement of 3.5 to 6-fold was obtained with double-pulse mode as compared to single-pulse operation. Full article

Under deep, high-intensity mining conditions, a high mineral pressure develops at the working face, which can easily cause floor heave deformation of the roadway. In this paper, with the geological conditions of Buertai coal mine as the background, through on-site monitoring and numerical simulation, the mechanism of strong dynamic pressure roadway floor heave is clarified and a cooperative control method for roadway floor heave deformation is proposed. The main conclusions are as follows: (1) The overall strength of the floor of this strong dynamic pressure roadway is low, which can easily cause roadway floor heave, and on-site multivariate monitoring of the mine pressure is carried out, which clarifies the evolution law of the mine pressure of the mining roadway and along-the-airway roadway. (2) Combined with FLAC3D numerical simulation software, we analyze the influence of coal seam depth and floor lithology on the stability of the roadway floor and find that both have a significant influence on the stability of the roadway. Under the condition of high-intensity mining, the floor will deteriorate gradually, forming a wide range of floor heave areas. (3) Based on the deformation and damage mechanism of the roadway floor, a synergistic control method of “roof cutting and pressure relief + floor anchor injection” is proposed and various technical parameters are designed. An optimized design scheme is designed for the control of floor heave in Buertai coal mine. Full article

Capturing CO₂ emitted by coal chemical enterprises and injecting it into oil reservoirs not only effectively improves the recovery rate and development efficiency of tight oil reservoirs in the Ordos Basin but also addresses the carbon emission problem constraining the development of the region. Since initiating field experiments in 2012, the Ordos Basin has become a significant base for CCUS (Carbon capture, Utilization, and Storage) technology application and demonstration in China. However, over the years, projects have primarily focused on enhancing the recovery rate of CO₂ flooding, while issues such as potential reservoir damage and its extent have received insufficient attention. This oversight hinder the long-term development and promotion of CO₂ flooding technology in the region. Experimental results were comprehensively analyzed using techniques including nuclear magnetic resonance (NMR), X-ray diffraction (XRD), scanning electron microscopy (SEM), inductively coupled plasma (ICP), and ion chromography (IG). The findings indicate that under current reservoir temperature and pressure conditions, significant asphaltene deposition and calcium carbonate precipitation do not occur during CO₂ flooding. The reservoir’s characteristics-high feldspar content, low carbon mineral content, and low clay mineral content determine that the primary mechanism affecting physical properties under CO₂ flooding in the Chang 4 + 5 tight sandstone reservoir is not, as traditional understand, carbon mineral dissolution or primary clay mineral expansion and migration. Instead, feldspar corrosion and secondary particles migration are the fundamental reasons for the changes in reservoir properties. As permeability increases, micro pore blockage decreases, and the damaging effect of CO₂ flooding on reservoir permeability diminishes. Permeability and micro pore structure are therefore significant factors determining the damage degree of CO₂ flooding inflicts on tight reservoirs. In addition, temperature and pressure have a significant impact on the extent of reservoir damage caused by CO₂ flooding in the study region. At a given reservoir temperature, increasing CO₂ injection pressure can mitigate reservoir damage. It is recommended to avoid conducting CO₂ flooding projects in reservoirs with severe pressure attenuation, low permeability, and narrow pore throats as much as possible to prevent serious damage to the reservoir. At the same time, the production pressure difference should be reasonably controlled during the production process to reduce the risk and degree of calcium carbonate precipitation near oil production wells. Full article

The investigation of the pore structure and fractal characteristics of coal-bearing shale is critical for unraveling reservoir heterogeneity, storage-seepage capacity, and gas occurrence mechanisms. In this study, 12 representative Upper Paleozoic coal-bearing shale samples from the Yangquan Block of the Qinshui Basin were systematically analyzed through field emission scanning electron microscopy (FE-SEM), high-pressure mercury intrusion, and gas adsorption experiments to characterize pore structures and calculate multi-scale fractal dimensions (D₁–D₅). Key findings reveal that reservoir pores are predominantly composed of macropores generated by brittle fracturing and interlayer pores within clay minerals, with residual organic pores exhibiting low proportions. Macropores dominate the total pore volume, while mesopores primarily contribute to the specific surface area. Fractal dimension D₁ shows a significant positive correlation with clay mineral content, highlighting the role of diagenetic modification in enhancing the complexity of interlayer pores. D₂ is strongly correlated with the quartz content, indicating that brittle fracturing serves as a key driver of macropore network complexity. Fractal dimensions D₃–D₅ further unveil the synergistic control of tectonic activity and dissolution on the spatial distribution of pore-fracture systems. Notably, during the overmature stage, the collapse of organic pores suppresses mesopore complexity, whereas inorganic diagenetic processes (e.g., quartz cementation and tectonic fracturing) significantly amplify the heterogeneity of macropores and fractures. These findings provide multi-scale fractal theoretical insights for evaluating coal-bearing shale gas reservoirs and offer actionable recommendations for optimizing the exploration and development of Upper Paleozoic coal-bearing shale gas resources in the Yangquan Block of the Qinshui Basin. Full article

With the large-scale closure of coal mines leading to groundwater pollution, in order to systematically identify the sources of major chemical ions in surface water and groundwater. This study comprehensively applied methods such as Piper’s trilinear diagram, linear fitting, and correlation analysis to quantitatively analyze the hydrochemical characteristics of closed coal mining areas in southwest Shandong and to clarify the sources of geochemical components in surface water and groundwater, and the PMF model was used to analyze the sources of chemical components in mine water and karst water. The results show that the concentrations of TDS ( Total Dissolved Solids), SO₄²⁻, Fe, and Mn in the mine water of the closed coal mine area are higher than in the karst water. Both water bodies are above groundwater quality standards. Ca²⁺, SO₄²⁻, and HCO₃⁻ dominate the ionic components in surface water and different types of groundwater. The hydrochemical types of surface, pore, and mine waters are mainly SO₄-HCO₃-Ca, whereas SO₄-HCO₃-Ca and HCO₃-SO₄-Ca dominate karst waters. SO₄²⁻ is the leading ion in the TDS of water bodies. The mineralization process of surface water is mainly controlled by the weathering of silicate minerals, while that of the groundwater is mainly controlled by the dissolution of carbonate minerals. The impact of mining activities on surface water and groundwater is significant, while the impact of agricultural activities on surface water and groundwater is relatively small. The degree of impact of coal mining activities on SO₄²⁻ concentrations in surface water, pore water, and karst water, in descending order, is karst water, surface water, and pore water. The PMF (Positive Matrix Factorization) model analysis results indicate that dissolution of carbonate minerals with sulphate and oxidation dissolution of sulfide minerals are the main sources of chemical constituents in mine waters. Carbonate dissolution, oxidation dissolution of sulfide minerals, domestic sewage, and dissolution of carbonate minerals with sulphate are ranked as the main sources of chemical constituents in karst water from highest to lowest. These findings provide a scientific basis for the assessment and control of groundwater pollution in the areas of closed coal mines. Full article

Fossil fuels, including coal, are a basis of energy systems in many countries worldwide. However, coal mining is associated with several difficulties, which include high temperatures within the coal mining area. It causes a need for cooling for safety reasons and also for the comfort of miners’ work. Typical cooling systems in mines are based on central systems, in which chilled water is generated in the compressor or absorption coolers on the ground and transported via pipelines to the air coolers in the areas of mining. The progressive mining operation causes a gradual increase in the distance between chilled water generators and air coolers, causing a decrease in the efficiency of the entire system and insufficient cooling capacity. As a result, it is necessary to increase the diameter of the chilled water pipelines and increase the cooling capacity of the chillers, which is associated with additional investment and technical problems. One solution to this problem may be the use of so-called ice slurry instead of chilled water in the existing mine cooling system. This article presents the cooling system, located in the mine LW Bogdanka S.A., based on ice slurry. The structure of the system and its key parameters are presented. The results show that switching from cooling water to ice slurry allowed the cooling capacity of the entire system to increase by 50% while maintaining the existing piping. This demonstrates the very high potential for the use of ice slurry, not only in mines, but wherever further increases in piping diameters to maintain the required cooling capacity are not possible or cost-effective. Full article

The accelerated industrialization in China has precipitated a dramatic surge in solid waste generation, causing severe land resource depletion and posing substantial environmental contamination risks. Simultaneously, the cement industry has become characterized by the intensive consumption of natural resources and high carbon emissions. This review aims to investigate the current technological advances in utilizing industrial solid waste for cement production, with a focus on promoting resource recycling, phase transformations during hydration, and environmental management. The feasibility of incorporating coal-based solid waste, metallurgical slags, tailings, industrial byproduct gypsum, and municipal solid waste incineration into active mixed material for cement is discussed. This waste is utilized by replacing conventional raw materials or serving as active mixed material due to their content of oxygenated salt minerals and oxide minerals. The results indicate that the formation of hydration products can be increased, the mechanical strength of cement can be improved, and a notable reduction in CO₂ emissions can be achieved through the appropriate selection and proportioning of mineral components in industrial solid waste. Further research is recommended to explore the synergistic effects of multi-waste combinations and to develop economically efficient pretreatment methods, with an emphasis on balancing the strength, durability, and environmental performance of cement. This study provides practical insights into the environmentally friendly and efficient recycling of industrial solid waste and supports the realization of carbon peak and carbon neutrality goals. Full article

In the coal industry, miner safety is increasingly challenged by growing mining depths and complex environments. The failure to wear Personal Protective Equipment (PPE) is a frequent issue in accidents, threatening lives and reducing operational efficiency. Additionally, existing PPE datasets are inadequate for model training due to their small size, lack of diversity, and poor labeling. Current methods often struggle with the complexity of multi-scenario and multi-type PPE detection, especially under varying environmental conditions and with limited training data. In this paper, we propose a novel minersPPE dataset and an improved algorithm based on YOLOv8, enhanced with Dilated-CBAM (Dilated Convolutional Block Attention Module) and DBB (Diverse Branch Block) Detection Block (YOLOv8-DCDB), to address these challenges. The minersPPE dataset constructed in this paper includes 14 categories of protective equipment needed for various body parts of miners. To improve detection performance under complex lighting conditions and with varying PPE features, the algorithm incorporates the Dilated-CBAM module. Additionally, a multi-branch structured detection head is employed to effectively capture multi-scale features, especially enhancing the detection of small targets. To mitigate the class imbalance issue caused by the long-tail distribution in the dataset, we adopt a K-fold cross-validation strategy, optimizing the detection results. Compared to standard YOLOv8-based models, experiments on the minersPPE dataset demonstrate an 18.9% improvement in detection precision, verifying the effectiveness of the proposed YOLOv8-DCDB model in multi-scenario, multi-type PPE detection tasks. Full article

A quantitative characterization of the change in coal molecular structures with different cyclical microwave modification parameters and a better understanding of the reaction mechanism of the modification are of great significance for the commercial extraction of coal bed methane (CBM). Therefore, long-flame coal samples obtained from the Ordos Basin, China, were modified by microwave radiation with different times, and the long-flame coal molecular structure parameters were determined by solid-state ¹³C nuclear magnetic resonance (ss¹³C NMR), Fourier transform infrared (FTIR) spectrometry, and X-ray photoelectron spectrometry (XPS). Atomistic representations of the raw long-flame coal molecular model and modified long-flame coal molecular models were established. The temperature rise, pore volume increase, mineral removal, and functional group changes after the modification have a negative effect on methane adsorption. After the modification, the decrease in surface area of the micropores reduced the adsorption site of methane in coal. As a result, the methane adsorption amount decreased linearly with the decreasing surface area. The CH₄ adsorption isotherms of the long-flame models were dynamically simulated and analyzed. The results of this study can prove that after multiple cycles of microwave modifications, the functional groups in long-flame coal were fractured, and the number of micropores was reduced, which effectively decreased the methane adsorption performance in long-flame coal seams, thereby promoting methane extraction. Microwave modification is a promising method for enhancing CBM recovery. Full article

In this study, a comprehensive experimental framework was developed to quantitatively characterize the pore structure of a deep coal-rock (DCR; reservoirs below [3000 m]) gas reservoir. Experimentally, petrological and mineral characteristics were determined by performing proximate analysis and scanning electron microscopy (SEM) as well as by measuring vitrinite reflectance and maceral components. Additionally, physisorption and high-pressure mercury injection (HPMI) tests were conducted to quantitatively characterize the nano- to micron-scale pores in the DCR gas reservoir at multiple scales. The DCR in the NQ Block is predominantly composed of vitrinite, accounting for approximately 77.75%, followed by inertinite. The pore space is predominantly characterized by cellular pores, but porosity development is relatively limited as most of such pores are extensively filled with clay minerals. The isothermal adsorption curves of CO₂ and N₂ in the NQ Block and the DJ Block exhibit very similar variation patterns. The pore types and morphologies of the DCR reservoir are relatively consistent, with a significant development of nanoscale pores in both blocks. Notably, micropore metrics per unit mass (pore volume (PV): 0.0242 cm³/g; and specific surface area (SSA): 77.7545 m²/g) indicate 50% lower gas adsorption potential in the DJ Block. In contrast, the PV and SSA of the mesopores per unit mass in the NQ Block are relatively consistent with those in the DJ and SF Blocks. Additionally, the peak mercury intake in the NQ Block occurs within the pore diameter < 20 nm, with nearly 60% of the mercury beginning to enter in large quantities only when the pore size exceeds 20 nm. This indicates that nanoscale pores are predominantly developed in the DCR of the NQ block, which aligns with the findings from physical adsorption experiments and SEM analyses. Overall, the development characteristics of multi-scale pores in the DCR formations of the NQ Block and the eastern part of the Basin are relatively similar, with both total PV and total SSA showing an L-shaped distribution. Due to the disparity in micropore SSA, however, the total SSA of the DJ Block is approximately twice that of the NQ Block. This discovery has established a robust foundation for the subsequent exploitation of natural gas resources in DCR formations within the NQ Block. Full article