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20 pages, 6922 KB  
Article
Surface Deformation Monitoring and Analysis of the Bayan Obo Rare Earth Mining Area Using Dual-Ascending SBAS-InSAR Data Fusion
by Yanliu Ding, Xixi Liu, Jing Tian, Shiyong Yan, Lixin Lin and Han Ma
Geosciences 2026, 16(3), 121; https://doi.org/10.3390/geosciences16030121 - 16 Mar 2026
Viewed by 359
Abstract
The Bayan Obo Mining District, recognized as the largest rare-earth resource base worldwide, has experienced significant surface instability due to intensive mining and large-scale dumping activities. To address the challenges posed by complex geological conditions and mining-induced disturbances, this study employs dual-ascending Sentinel-1A [...] Read more.
The Bayan Obo Mining District, recognized as the largest rare-earth resource base worldwide, has experienced significant surface instability due to intensive mining and large-scale dumping activities. To address the challenges posed by complex geological conditions and mining-induced disturbances, this study employs dual-ascending Sentinel-1A C-band Synthetic Aperture Radar (SAR) datasets (Path 11 and Path 113) and applies the Small Baseline Subset Interferometric Synthetic Aperture Radar (SBAS-InSAR) technique to retrieve time-series deformation along the line-of-sight (LOS) direction for each track. Through temporal normalization and spatial matching, paired LOS observations from the two tracks were established. Based on the SAR observation geometry and under the assumption that the north–south component is negligible, a LOS projection model was constructed and a geometric decomposition was performed to derive the east–west and vertical two-dimensional deformation fields. The results indicate that the study area is generally stable, while significant subsidence occurs in the northern pit and adjacent waste-dump zones, with local maximum rates approaching 50 mm/year, predominantly controlled by the vertical component. The two-dimensional deformation analysis reveals that vertical displacement dominates surface motion, whereas east–west movement shows smaller amplitudes but clear directional concentration. In particular, the east–west slopes exhibit slightly higher velocities, suggesting a lateral adjustment tendency along this direction, likely related to the overall east–west geometric configuration of the open-pit and waste-dump areas. Time-series observations further reveal that precipitation-related surface deformation occurs with an approximate two-month delay, reflecting the hydrological–mechanical coupling processes of rainfall infiltration, pore-water pressure propagation, and dump-material consolidation. Overall, this study reveals the multi-dimensional deformation characteristics and precipitation-driven stage-wise response of the mining area, demonstrating the effectiveness of the dual-ascending SBAS-InSAR for two-dimensional deformation monitoring in highly disturbed environments, and providing a scientific basis for surface stability assessment and geohazard prevention. Full article
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17 pages, 2720 KB  
Article
Studying Natural Radioactivity of Coals and Ash and Slag Waste as Potential Raw Materials for Quality Assessment and Extraction of Rare Earth Elements
by Yuriy Pak, Dmitriy Pak, Pyotr Kropachev, Vladimir Matonin, Diana Ibragimova, Anar Tebayeva, Pavel Timoshenko, Natalya Tsoy and Yelena Tseshkovskaya
Geosciences 2025, 15(11), 420; https://doi.org/10.3390/geosciences15110420 - 4 Nov 2025
Cited by 3 | Viewed by 1087
Abstract
A significant portion of coal mined in Kazakhstan is mainly used for fuel energy and metallurgy. Approximately 60% of electricity is generated by coal-fired power engineering. About 19 million tons of ash and slag waste (ASW) are annually sent to dumps. After coal [...] Read more.
A significant portion of coal mined in Kazakhstan is mainly used for fuel energy and metallurgy. Approximately 60% of electricity is generated by coal-fired power engineering. About 19 million tons of ash and slag waste (ASW) are annually sent to dumps. After coal combustion, in ASW not only are natural radioactive nuclides NRN (U238, Th232, K40) concentrated, but also rare and rare earth elements (REE). In this regard, ASW that essentially turns into quasi-technogenic deposits of NRN and REE, requires systemic measures for their utilization. The possibilities of extracting REE from coal power-industry waste are estimated based on the analysis of the concentration of REE (Ce, La, Nd, Sm, etc.), NRN (U238, Th232 and their decay products, K40) and the established significant correlations between rare earth and radioactive elements. The purpose of this paper is to study the natural radioactivity of coals and ash and slag waste as potential raw materials for assessing the quality and extracting rare earth metals. The stated purpose involves solving the following problems: studying the features of the NRN and REE distribution in coals and ash and slag waste; assessing the possibility of using ash and slag waste as a promising source of REE extraction based on nuclear radiometric studies; and studying the spectrometry of natural gamma radiation for assessing the quality of coals. Full article
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18 pages, 15231 KB  
Article
Stereo Vision-Based Underground Muck Pile Detection for Autonomous LHD Bucket Loading
by Emilia Hennen, Adam Pekarski, Violetta Storoschewich and Elisabeth Clausen
Sensors 2025, 25(17), 5241; https://doi.org/10.3390/s25175241 - 23 Aug 2025
Cited by 2 | Viewed by 1565
Abstract
To increase the safety and efficiency of underground mining processes, it is important to advance automation. An important part of that is to achieve autonomous material loading using load–haul–dump (LHD) machines. To be able to autonomously load material from a muck pile, it [...] Read more.
To increase the safety and efficiency of underground mining processes, it is important to advance automation. An important part of that is to achieve autonomous material loading using load–haul–dump (LHD) machines. To be able to autonomously load material from a muck pile, it is crucial to first detect and characterize it in terms of spatial configuration and geometry. Currently, the technologies available on the market that do not require an operator at the stope are only applicable in specific mine layouts or use 2D camera images of the surroundings that can be observed from a control room for teleoperation. However, due to missing depth information, estimating distances is difficult. This work presents a novel approach to muck pile detection developed as part of the EU-funded Next Generation Carbon Neutral Pilots for Smart Intelligent Mining Systems (NEXGEN SIMS) project. It uses a stereo camera mounted on an LHD to gather three-dimensional data of the surroundings. By applying a topological algorithm, a muck pile can be located and its overall shape determined. This system can detect and segment muck piles while driving towards them at full speed. The detected position and shape of the muck pile can then be used to determine an optimal attack point for the machine. This sensor solution was then integrated into a complete system for autonomous loading with an LHD. In two different underground mines, it was tested and demonstrated that the machines were able to reliably load material without human intervention. Full article
(This article belongs to the Section Sensing and Imaging)
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19 pages, 6727 KB  
Article
Soil Contamination and Related Ecological Risks: Complex Analysis of the Defor Petrila Tailings Dump, Romania
by Emilia-Cornelia Dunca, Mădălina-Flavia Ioniță and Sorin Mihai Radu
Land 2025, 14(7), 1492; https://doi.org/10.3390/land14071492 - 18 Jul 2025
Cited by 2 | Viewed by 834
Abstract
Assessing the risks associated with waste disposal is essential for environmental protection and sustainable development, especially given concerns about the impact of industrial activities on the environment. This study analyses soil contamination in the Defor Petrila tailings-dump area caused by the deposition of [...] Read more.
Assessing the risks associated with waste disposal is essential for environmental protection and sustainable development, especially given concerns about the impact of industrial activities on the environment. This study analyses soil contamination in the Defor Petrila tailings-dump area caused by the deposition of waste material resulting from coal exploitation. To characterise the heavy-metal contamination in detail, we applied a comprehensive methodology that includes the calculation of the geo-accumulation index (Igeo), contamination factor (Cf), and potential ecological risk index (PERI), along with an analysis of the heavy-metal concentration isolines and a statistical analysis using the Pearson correlation coefficient. The results reveal varying levels of heavy-metal concentrations, as indicated by the calculated indices. The findings underscore the need for remediation and ongoing monitoring to mitigate the environmental impacts. This study provides a scientific basis for decision making in environmental management and highlights the importance of assessing mining-waste disposal near human settlements using various contamination-assessment methods. Full article
(This article belongs to the Section Land Use, Impact Assessment and Sustainability)
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16 pages, 9468 KB  
Article
Recovery of Tetrahedrite from Mining Waste in Spain
by Ester Boixereu-Vila, Paula Adánez-Sanjuán, Ramón Jiménez-Martínez, Concepción Fernández-Leyva and Dulce Gómez-Limón
Minerals 2025, 15(7), 703; https://doi.org/10.3390/min15070703 - 30 Jun 2025
Viewed by 1036
Abstract
The present study is part of the Horizon Europe-START project, which aims to recover tetrahedrite-group minerals present in mine dumps to be used as raw materials for the manufacture of thermoelectric devices. The aim of this work is to identify the mining waste [...] Read more.
The present study is part of the Horizon Europe-START project, which aims to recover tetrahedrite-group minerals present in mine dumps to be used as raw materials for the manufacture of thermoelectric devices. The aim of this work is to identify the mining waste facilities selected in Spain for the recovery of tetrahedrite and to outline the mineral processing operations performed on samples from each site to separate and concentrate this mineral. Ore deposits across Spain were selected based on the potential presence of tetrahedrite in their mining waste. A total of five deposits have been sampled, at which subsequent mineral separation and concentration tests have been conducted. A separation flowsheet is proposed in order to extract a high-purity tetrahedrite concentrate. Experimental results indicate two distinct options for separation approaches, depending on a key parameter that proves decisive in the processing of this mineral, which is whether the mineral paragenesis includes siderite. This study has demonstrated the technical feasibility of concentrating minerals of the tetrahedrite group through simple, cost-effective physical separation techniques—specifically magnetic and gravity separation—where the liberation size of the tetrahedrite exceeds 0.063 mm. Full article
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22 pages, 3312 KB  
Review
A Review of the Impact of Spontaneous Combustion on Slope Stability in Coal Mine Waste Dumps
by Phu Minh Vuong Nguyen
Appl. Sci. 2025, 15(13), 7138; https://doi.org/10.3390/app15137138 - 25 Jun 2025
Cited by 1 | Viewed by 2083
Abstract
Mining waste from both underground and open-pit mines is typically placed in surface sites known as mine waste dumps. Over time, as large volumes of mining waste accumulate, these dumps become higher due to the limited surface area allocated to dumping. Ensuring the [...] Read more.
Mining waste from both underground and open-pit mines is typically placed in surface sites known as mine waste dumps. Over time, as large volumes of mining waste accumulate, these dumps become higher due to the limited surface area allocated to dumping. Ensuring the stability of mine waste dumps is a major concern for both mining operations and local governments due to safety risks to the dumps themselves and their surrounding environments. In some cases of mine waste dump, spontaneous combustion poses a significant challenge, affecting not only the environment but also the slope stability of mine waste dumps. This review synthesizes existing research on the mechanisms of spontaneous combustion, its thermal effects, and the implications for geomechanical stability in mine waste dumps. It also examines methods for monitoring and controlling these processes, identifies gaps in the current research, and suggests directions for future studies. The review also reveals that combustion-induced temperature changes, material degradation, and gas generation significantly impact the geotechnical properties of building material dumps, contributing to slope failure. This review is expected to provide valuable insights that help mining authorities assess risks, minimize impacts, and implement preventive measures to mitigate unexpected spontaneous combustion-induced slope failures in mine waste dumps. Full article
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15 pages, 4502 KB  
Article
Research on the Distribution and Escape Characteristics of Dust at the Blasting Pile in an Open-Pit Mining Area
by Yong Cao, Xiaoliang Jiao, Rong Liu, Haoran Wang, Yi He, Jie Chen, Xiang Lu and Huangqing Zhang
Geosciences 2025, 15(7), 238; https://doi.org/10.3390/geosciences15070238 - 20 Jun 2025
Cited by 2 | Viewed by 1224
Abstract
In open-pit mines, substantial amounts of dust are generated at various stages. Due to the long duration, repeated mechanical disturbance, and large volume of material handled during the shoveling and loading of blasting piles, this stage is recognized as one of the primary [...] Read more.
In open-pit mines, substantial amounts of dust are generated at various stages. Due to the long duration, repeated mechanical disturbance, and large volume of material handled during the shoveling and loading of blasting piles, this stage is recognized as one of the primary contributors to overall dust emissions in open-pit mining operations. The objective of this study is to investigate the spatial dispersion characteristics of dust at blasting piles and evaluate the influence of wind direction on dust migration and escape behavior. This study uses a full-scale numerical model to analyze the airflow and dust migration characteristics at blasting piles under different wind directions. Simulation results show that dust particles of different sizes exhibit distinct dispersion patterns: large particles settle near the source, medium particles migrate a moderate distance, and fine particles (PM2.5 and PM10) travel further and are more likely to escape from the pit. The leeward slope and pit bottom are identified as critical zones of dust accumulation and escape. Under both dump-side and stope-side wind conditions, respirable dust (d < 5 μm) accounts for more than 50% of the escaped particles, posing potential health risks to workers. These findings establish a scientific basis for targeted dust suppression strategies, supporting safer and more sustainable mine site management. Full article
(This article belongs to the Section Geomechanics)
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13 pages, 3791 KB  
Article
Thermoelectric Properties of Tetrahedrites Produced from Mixtures of Natural and Synthetic Materials
by Beatriz A. Santos, Luís Esperto, Isabel Figueira, João Mascarenhas, Elsa B. Lopes, Rute Salgueiro, Teresa P. Silva, José B. Correia, Daniel de Oliveira, António P. Gonçalves and Filipe Neves
Materials 2025, 18(6), 1375; https://doi.org/10.3390/ma18061375 - 20 Mar 2025
Cited by 1 | Viewed by 1046
Abstract
Thermoelectric materials have considerable potential in the mitigation of the global energy crisis, through their ability to convert heat into electricity. This study aims to valorize natural resources, and potentially reduce production costs, by incorporating tetrahedrite–tennantite (td) ores from the Portuguese Iberian Pyrite [...] Read more.
Thermoelectric materials have considerable potential in the mitigation of the global energy crisis, through their ability to convert heat into electricity. This study aims to valorize natural resources, and potentially reduce production costs, by incorporating tetrahedrite–tennantite (td) ores from the Portuguese Iberian Pyrite Belt into synthetic samples. The ore samples were collected in a mine waste at Barrigão and as “dirty-copper” pockets of ore from the Neves Corvo mine. Subsequently, high-energy ball milling and hot pressing were employed in the production of thermoelectric materials. These are characterized by XRD, SEM/EDS, and thermoelectrical properties. The complete dissolution of the dump material sulfides with the synthetic tetrahedrite constituents led to an increase in the amount of the tetrahedrite–tennantite phase, which was made up of a tetrahedrite–tennantite–(Fe) solid solution. The thermoelectric characterization of these materials is provided, revealing that most of the combined synthetic ore samples displayed better results than the pristine tetrahedrite, mostly due to higher Seebeck coefficient values. Furthermore, the best thermoelectric performance is achieved with 10% of ore, where a power factor of 268 µW.K−2.m−1 is reached at room temperature. Full article
(This article belongs to the Section Energy Materials)
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17 pages, 1794 KB  
Article
Spatial Variability in Geotechnical Properties Within Heterogeneous Lignite Mine Spoils
by Ioannis E. Zevgolis, Alexandros I. Theocharis and Nikolaos C. Koukouzas
Geosciences 2025, 15(3), 97; https://doi.org/10.3390/geosciences15030097 - 8 Mar 2025
Cited by 1 | Viewed by 1417
Abstract
During surface coal mining, vast amounts of overburden waste materials—called spoils—are excavated and dumped, forming massive heaps, the sustainable exploitation of which is a top priority globally. This study addresses the advanced geotechnical characterization of spoil materials, focusing on lignite mine spoil heaps, [...] Read more.
During surface coal mining, vast amounts of overburden waste materials—called spoils—are excavated and dumped, forming massive heaps, the sustainable exploitation of which is a top priority globally. This study addresses the advanced geotechnical characterization of spoil materials, focusing on lignite mine spoil heaps, which are often ignored due to their highly heterogeneous nature. This research quantifies the spatial variability in spoil materials from a large heap in Greece, highlighting the importance of a robust geotechnical framework for their effective reclamation. Using statistical analysis and variogram modeling, the scale of fluctuation (SoF) was derived for both the vertical and horizontal directions. The SoF values for spoil properties are found to be on the high end of the natural soil range. Vertical correlations are observed for distances over 10 m, occasionally reaching 20 m, indicating significant spatial variability; in the horizontal direction, the SoF reaches up to 285 m. These findings suggest that spoil elements exhibit important spatial dependence, which is critical for their proper design and exploitation. The results provide a basis for future research and the use of advanced numerical tools, such as the random finite element method, to support geotechnical design and the sustainable exploitation of spoil heaps. Full article
(This article belongs to the Section Geomechanics)
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29 pages, 13791 KB  
Article
Autogenously Calcined Clays from Coal Tailings Dumps as Supplementary Cementitious Material: From Exploratory Investigations to an Industrial Trial
by Steffen Overmann and Anya Vollpracht
Materials 2025, 18(5), 993; https://doi.org/10.3390/ma18050993 - 24 Feb 2025
Cited by 2 | Viewed by 1065
Abstract
Autogenously calcined clays from tailings dumps, which are formed by the ignition of the contained residual coal, represent a huge resource of potentially pozzolanic material worldwide. This work presents preliminary studies of samples from the Western coal regions in Germany and investigations on [...] Read more.
Autogenously calcined clays from tailings dumps, which are formed by the ignition of the contained residual coal, represent a huge resource of potentially pozzolanic material worldwide. This work presents preliminary studies of samples from the Western coal regions in Germany and investigations on the first industrially produced cement with autogenously calcined tailings concerning its suitability as supplementary cementitious material (SCM). Samples of the tailings materials and blended cements were thoroughly characterized physically, chemically and mineralogically. The reactivity was studied using the R3 test and mortar compressive strength testing. The influence on cement hydration was studied using X-ray diffractometry (XRD) and isothermal calorimetry. The preliminary investigations showed that the material is basically suitable as SCM, as it consists mainly of SiO2 and Al2O3, which partially occurs in X-ray amorphous form and has a low content of impurities, which can impair cement properties such as carbon or sulfur. The R3 reactivity and the relative compressive strength differed significantly depending on the sample. For the industrial cement production trial, low-processed material was used which still contained inert fractions. The average sample showed a relatively low R3 reactivity but still significantly higher than mostly inert materials such as limestone or quartz powder. Calorimetry and XRD investigations on cement pastes showed that the clinker reactions remain basically unaffected by the tailings. Mortar tests showed that the material contributes to strength development at a late age. It can be concluded that the tailings are basically suitable as SCM and, in appropriate blends, the clinker factor and, thus, the CO2 footprint of cement can be reduced. Full article
(This article belongs to the Section Construction and Building Materials)
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22 pages, 10940 KB  
Article
Assessment of the Influence of Aluminum, Iron, and Manganese Forms on the Phytocenoses of Post-Mining Lands in the Lengerskoye Brown Coal Mine
by Akmaral Issayeva, Waldemar Spychalski, Elźbieta Wilk-Woźniak, Dariusz Kayzer, Radosław Pankiewicz, Wojciech Antkowiak, Bogusława Łeska, Akmaral Alikhan, Assel Tleukeyeva and Zbigniew Rozwadowski
Sustainability 2025, 17(4), 1642; https://doi.org/10.3390/su17041642 - 17 Feb 2025
Cited by 1 | Viewed by 1979
Abstract
Post-mining land in areas where mineral extraction has occurred may constitute a significant portion of the land used for various purposes. Such land serves as soil-forming parent material for developing anthropogenic soils, which sometimes exhibit unfavorable physicochemical properties. The toxicity of the waste [...] Read more.
Post-mining land in areas where mineral extraction has occurred may constitute a significant portion of the land used for various purposes. Such land serves as soil-forming parent material for developing anthropogenic soils, which sometimes exhibit unfavorable physicochemical properties. The toxicity of the waste generated during lignite mining is due to a number of factors, whose determination permits the identification of its origin for the subsequent design of technologies for the waste reclamation. The purpose of the study, in consistence with sustainable development, is to identify the causes of the toxicity of brown coal waste from the Lengerskoye deposit, in southern Kazakhstan. These studies have provided the results essential for planning remedial actions necessary to improve the well-being of the local population, in accordance with the principles of sustainable development. The studies were performed using single extraction; forms of Al, Fe, and Mn; soil texture; elemental analysis; phytocoenosis analysis; and diffractometric, IR spectroscopic, SEM, route reconnaissance, and comparative statistical methods. A decrease in the biodiversity of plant species was noted, with a gradual increase with distance from the waste storage sites. The most resistant plant species in the vicinity of the waste dump were Cynodon dactylon (L.) Pers and Alhagi pseudalhagi (M. Bieb.) Desv. ex B. Keller & Shap., while Dodartia orientalis (L.) was the only plant species found at the edge of the waste dump. The high toxicity of lignite waste is determined by such factors as low pH values, about 3.0; high content of active forms of aluminum, iron, and manganese (344.0, 0.90, and 20 mg/kg); high electrical conductivity—2835 µS/cm; waste composition poor in nutrients; and climate aridity. It has been observed that a content of exchangeable aluminum above 100 mg/kg resulted in an almost complete lack of vegetation. Full article
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15 pages, 1734 KB  
Article
Effects of Soil Modification Materials on the Quality of Sandy Soil in Mine Dumps
by Luying Shao, Shichao Chen, Qing Zhang, Juan Li and Zhi Jia
Sustainability 2025, 17(3), 1201; https://doi.org/10.3390/su17031201 - 2 Feb 2025
Cited by 1 | Viewed by 1468
Abstract
Large-scale coal mine dumps are formed during the mining process of coal resources. These coal mine dumps comprise impoverished soil, posing significant challenges for vegetation restoration. To address this problem, soil microbial (EM) agents and fly ash have effectively improved soil quality. However, [...] Read more.
Large-scale coal mine dumps are formed during the mining process of coal resources. These coal mine dumps comprise impoverished soil, posing significant challenges for vegetation restoration. To address this problem, soil microbial (EM) agents and fly ash have effectively improved soil quality. However, the effects of different application ratios on the quality of sandy soil in coal mine dumps are still unclear. This study aims to explore the applicable ratio for sandy soil in coal mine dumps. This study employed a field-based potted experiment design. A two-factor complete factorial experimental setup was utilized, with four levels of EM microbial agent to sandy soil weight ratio (0 g/kg, 0.1 g/kg, 0.2 g/kg, and 0.3 g/kg) and four levels of fly ash to sandy soil weight ratio (0 g/kg, 25 g/kg, 50 g/kg, and 75 g/kg), and the mixing of EM microbial agents and fly ash with the sandy soil was carried out at different ratios. Subsequently, the study examined the impacts of various dosages on the physicochemical properties of soil within the mine spoil heap, and a soil quality index was derived to quantify these effects. The application of EM microbial and fly ash resulted in significant improvements in the physicochemical properties of the soil compared to the control group. Notably, the combined application of EM microbial agent and fly ash exhibited superior effects on soil physicochemical properties compared to the individual applications of EM microbial agent or fly ash. Specifically, when the EM microbial agent concentration was 0.2 g/kg and the fly ash content was 75 g/kg, the enhancement in soil quality was most pronounced, with a soil quality index of 0.78. Mantel analysis revealed that the growth index and photosynthetic index of Corethrodendron fruticosum were primarily driven by soil total nitrogen and organic carbon. The research results can provide guidance and technical support for soil improvement in mining areas. Full article
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17 pages, 14354 KB  
Article
Development of a Recycling Process for the Recovery of Gypsum Stone from Stockpile Material
by Jacob Fenner, Julius Luh, Bengi Yagmurlu and Daniel Goldmann
Recycling 2025, 10(1), 12; https://doi.org/10.3390/recycling10010012 - 16 Jan 2025
Viewed by 2864
Abstract
Due to changes in the German government’s energy concept, the amount of gypsum produced in flue gas desulfurisation plants (FGD gypsum) will fall from 5 million tons per year to 1 million tons or less by 2038 at the latest. As of 2016, [...] Read more.
Due to changes in the German government’s energy concept, the amount of gypsum produced in flue gas desulfurisation plants (FGD gypsum) will fall from 5 million tons per year to 1 million tons or less by 2038 at the latest. As of 2016, FGD gypsum accounts for 55% of German gypsum mix. The resulting raw material gap must be closed through innovative recycling concepts, such as the processing of existing mine dumps. The process development aims to achieve a calcium sulfate dihydrate content of 85% and a reduction in the stockpile volume by 50%. The main components of the stockpiles are calcium sulfate in the form of gypsum stone as well as clay minerals and organic matter. Successful laboratory tests were transferred to a pilot scale jigging machine with dewatering screening. The process water is circulated throughout the entire process. The gypsum content in the heavy fraction is 76% when measured with ICP OES and 87% when measured via thermogravimetric methods. Furthermore, pilot-scale dry screening on the stockpile took place, and up to 1500 tons of material could be processed. Due to fluctuating weather conditions, the screening quality was subject to significant variations. Under optimal conditions, up to 60% of the feed could be recovered as gypsum stone; however, the screening process was nearly impossible during rain; therefore, a process combination of screening and a downstream jigging machine is recommended. Full article
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20 pages, 4697 KB  
Article
Utilization of Copper Flotation Tailings in Geopolymer Materials Based on Zeolite and Fly Ash
by Marija Štulović, Dragana Radovanović, Jelena Dikić, Nataša Gajić, Jovana Djokić, Željko Kamberović and Sanja Jevtić
Materials 2024, 17(24), 6115; https://doi.org/10.3390/ma17246115 - 14 Dec 2024
Cited by 7 | Viewed by 2112
Abstract
Copper flotation tailings (FTs), resulting from the separation and beneficiation processes of ores, are a significant source of environmental pollution (acid mine drainage, toxic elements leaching, and dust generation). The most common disposal method for this industrial waste is dumping. However, due to [...] Read more.
Copper flotation tailings (FTs), resulting from the separation and beneficiation processes of ores, are a significant source of environmental pollution (acid mine drainage, toxic elements leaching, and dust generation). The most common disposal method for this industrial waste is dumping. However, due to their favorable physical and chemical properties—the high content of aluminosilicate minerals (60–90%)—flotation tailings can be effectively treated and reused through geopolymerization technology, thereby adding value to this waste. The objective of this study was to evaluate the potential of utilizing the geopolymerization of FTs to produce sustainable materials. Geopolymers based on natural zeolite (NZ), sodium-modified natural zeolite (NaZ), and fly ash (FA) were prepared using 20%, 35%, and 50% of FTs, activated with a 10 M NaOH solution. The study investigated the influence of Ca/Si, Si/Al, and Na/Al molar ratios on the structural, thermal, and mechanical properties (XRD, TG/DTG and unconfined compressive strength, UCS), and contaminant immobilization (TCLP method) of geopolymers. Geochemical modeling via the PHREEQC program was employed to interpret the results. The findings indicated that the UCS value decreased in zeolite-based geopolymers as the content of FT increased due to the inertness of the tailings and the low calcium content in the system (Ca/Si ≤ 0.3), in contrast to the FA-based geopolymer. The highest UCS of 44.3 MPa was recorded in an FA-based geopolymer containing 50% flotation tailings, with optimal molar ratios of 0.4 for Ca/Si, 3.0 for Si/Al, and 1.1 for Na/Al. In conclusion, the geopolymerization process has been determined to be a suitable technological approach for the sustainable treatment and reuse of FTs. Full article
(This article belongs to the Section Polymeric Materials)
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21 pages, 3672 KB  
Article
How Ecological Filters Influence the Dynamics of Re-Built Plant Communities and Functional Composition in Open-Pit Mine over 14 Years
by Xue Qi, Antonio Macros Miranda Silva, Guoqing Chen, Altangerel Altanchimeg and Mingjiu Wang
Sustainability 2024, 16(23), 10609; https://doi.org/10.3390/su162310609 - 3 Dec 2024
Viewed by 1562
Abstract
The traditional ecological reclamation measurements and assessments for the grassland areas damaged by open-pit mining often fall short in revealing the dynamics of plant communities affected by environmental filters during reconstruction, making reclamation efforts crucial. The trait-based community framework has been widely applied [...] Read more.
The traditional ecological reclamation measurements and assessments for the grassland areas damaged by open-pit mining often fall short in revealing the dynamics of plant communities affected by environmental filters during reconstruction, making reclamation efforts crucial. The trait-based community framework has been widely applied due to its great potential to predict the restoration process and provide insight into its mechanisms, but how the traits and environmental factors interact to form communities over time is still uncertain. Therefore, to make this process clear, we used the trait-based community framework, defining target species, non-target species, and common grass species, examining how the mix seed sowing and environment (two surface-covering materials applied to mine dump) affect re-vegetation composition, diversity, and functional traits in 14 years. Four treatments were tested: bio-fence surface-covering materials + sowing (BFS), plant-barrier surface-covering materials + sowing (PBS), sowing without any surface-covering materials (SOW), and a control without seeding and covering (CK). Natural grassland sites were regarded as reference (REF). Our findings indicated that the mix seed sowing and the interaction of surface-covering and time were primarily driving the dynamics of the plant community, affecting composition, the value of diversity, coverage, numbers, richness, and functional traits, such as the community-weighted mean (CWM) and functional diversity (FD), which increased and approached the sites REF. There were significant differences between the treatments and CK for the most traits. Although several results in the treatments approached the REF, significant differences still remained in the last observation year. With the sowing and surface-covering treatment, the re-built communities became more resource-acquisitive in terms of the CWM traits; even the value of the specific leaf area (SLA) exceed the REF after 14 years reclamation. We found those communities were dominated by target species that had a higher traits value than the non-target species, while the CK treatment became more resource-conservative over time due to non-target species dominating. The CWM in treatments tended toward reference levels for specific leaf area (SLA), leaf dry matter content (LDMC), and root dry matter content (RDMC), but not for seed mass (SM), thereby indicating that the above- and below-ground productivity of restored sites gradually overcame abiotic (surface-covering) and biotic (sowing) filters and approached target values. The functional diversity (FD) generally increased, with higher multivariate functional dispersion in the treatments containing more target species, suggesting that re-built communities achieve more resistance to invasion and disturbance over time. Hence, the trajectory of species and communities changing highlights the effectiveness of a trait-based approach in identifying better reclamation treatments and candidate species and provides a positive outlook for future re-vegetation community succession. Full article
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