Search Results (31)

Ti6Al4V titanium alloy is one of the most studied for its properties after additive manufacturing. Due to its widely use in medical applications, its properties are investigated in various aspects of surface layer property improvement and later compared to conventionally manufactured Ti-6Al-4V. In this study, the corrosion behavior in a 0.9% NaCl solution of shot peened Ti-6Al-4V prepared using direct metal laser sintering (DMLS) was examined using corrosion electrochemical testing and compared with conventionally forged titanium alloy. Shot peening was performed on previously polished samples and subsequently treated with the CrNi steel shots. Two sets of peening pressure were selected: 0.3 and 0.4 MPa. X-ray diffraction analysis (XRD), X-ray micro-computed tomography (Micro-CT), scanning electron microscope (SEM) tests with roughness and hardness measurements were used to characterize the samples. The conventional samples were characterized by an α + β structure, while the additive samples had an α’ + β martensitic structure. The obtained results indicate that the corrosion resistance of the conventionally forged Ti-6Al-4V alloy was higher than DMLSed Ti-6Al-4V alloy. The lowest corrosion rates were noted for untreated surfaces of CM/ref and DMLS/ref samples and reached 0.041 and 0.070 µA/cm², respectively. Moreover, the development of the surface has an influence on corrosion behavior. Therefore, increasing pressure results in inferior corrosion resistance. However, better performance for shot peened samples was reported in the low frequency range. This is due to the refinement of the grain acquired after the peening process. All the results obtained, related to the corrosion behavior, were satisfactory enough that the all samples can be characterized as materials suitable for implant applications. Full article

Quench–polish–quench (QPQ) nitro-carburizing of AISI 4140 steel in a salt bath was performed in this study. Nitro-carburizing in a salt bath enhanced the formation of Fe-nitride on the outer surface layer. Moreover, the oxidizing treatment formed a thin oxide layer decorated on the outermost part of the QPQ-treated sample. The dense compound layer formed after nitro-carburizing in a salt bath consisted of refined granular Fe₃N and transformed to Fe₂N after post-oxidation treatment. Micro-shot peening (MSP) was adopted before QPQ treatment to increase the treated steel’s fatigue performance. The results indicated that MSP slightly increased the thickness of the compound layer and harden depth, but it had little effect on improving the fatigue strength/life of the QPQ-treated sample (SP-QPQ) compared to the non-peened one (NP-QPQ). A deep compressive residual stress (CRS) field (about 200 μm) and a hard nitrided layer showed a noticeable improvement in the fatigue performance of the QPQ-treated ones relative to the 4140 substrates tempered at 570 °C. The ease of slipping or deforming on the substrate surface was responsible for its poor resistance to fatigue failure. The cracking and spalling of the brittle surface layer were the causes for the fatigue crack initiation and growth of all of the QPQ-treated samples fatigue-loaded at/above 875 MPa. It was noticed that fatigue crack initiation at the subsurface inclusions was more likely to occur in the SP-QPQ sample fatigue-loading at 850 MPa or slightly above the fatigue limit. Full article

Mechanical gears are essential in power transmission systems across various industrial applications. Their performance is critically influenced by residual stresses from manufacturing processes like induction hardening, case hardening, and shot peening. Surface compressive residual stresses enhance resistance to pitting fatigue, bending fatigue and crack propagation, improving overall hardness. In the present work, a Non-Destructive Thermographic method (Active thermography), based on measurement of the thermal diffusivity parameter, is presented to characterize the surface treatments applied to gears. Surface hardness was measured using a micro-hardness tester, and residual stresses were determined with an X-Ray diffractometer, showing variations due to surface treatments. The variation in the thermal diffusivity parameter, obtained using the Slope Method, was found to be an indicator of the surface treatments’ effectiveness. Full article

Surface modifications, including laser surface melting (LSM) and micro-shot peening (MSP), were applied to improve the fatigue performance of the Ni-Al bronze (NAB) alloy. LSM could homogenize the NAB into a uniform microstructure with refined columnar grains in the laser-melted zone but introduced residual tensile stress (RTS). The bombardment and generated heat induced by MSP could not entirely remove the granular κ_II precipitates and lamellar κ_III phase in the peened zone of the shot-peened sample (NSP sample) but introduced residual compressive stress (RCS) into the NSP sample under the peening intensity of this work. The results of fatigue tests revealed that the LSM sample had the poorest fatigue performance, but the NSP sample showed the best fatigue performance among the tested samples. The fatigue limit of the NAB alloy was about 325 MPa; meanwhile, the fatigue performance of the LSP (LSM + MSP) sample was equivalent to or a little better than that of the NAB alloy (NBM sample). The RTS and aligned columnar grains accounted for the degraded fatigue resistance of the LSM sample. By contrast, the high RCS and the refined structure were responsible for the improved fatigue strength/life of the NSP sample relative to that of the other samples. The fatigue limit of the NSP sample was as high as 450 MPa. However, the increase in fatigue strength of the NSP sample occurred in service life regions above 3 × 10⁵ cycles. Full article

In order to further improve the corrosion resistance of 7075-T6 aluminum alloy after shot peening, corrosion-resistant superhydrophobic coatings (EP-HDTMS@SiO₂) containing epoxy resin (EP), cetyltrimethoxysilane (HDTMS), and nano-silica (SiO₂) were prepared by a simple spraying method on the surface of shot-peened AA 7075-T6 aluminum alloy. The effects of different EP/SiO₂ mass ratios on the micro-morphology, surface wettability, and corrosion resistance of the superhydrophobic composite coatings were analyzed. Due to the combination of microstructure and the modification of low surface energy organics, the contact angle of EP-HDTMS@SiO₂ coatings reached the superhydrophobic level (152.6°). The electrochemical tests showed that the corrosion current densities (I_corr) of the EP-HDTMS@SiO₂ composite coatings were both significantly lower than those of the EP-HDTMS coatings and matrix aluminum alloys. The addition of SiO₂ nanoparticles could improve the hydrophobicity and corrosion resistance of epoxy-based composite coatings. Due to the increase in surface roughness and epoxy resin, the shot-peened AA 7075-T6 alloy coating had high adhesion after the peel test. The prepared coatings also showed excellent corrosion resistance in the neutral salt spray test. This study provides a simple method for preparing stable superhydrophobic coatings on metal surfaces, which is expected to expand the application of 7075 aluminum alloy in harsh environments. Full article

There is a concern regarding sub-surface pores within laser powder bed fusion of Ti-6Al-4V, which can initiate cracks and reduce mechanical properties, especially after machining for surface finishing. This study investigated the effect of laser scanning speed and fine shot peening on the pore characteristics, hardness, and residual stress of Ti-6Al-4V fabricated by laser powder bed fusion using scanning electron microscopy, X-ray micro-computed tomography, Vickers hardness, and X-ray diffraction. As the laser scanning speed increased, the number of pores and pore size increased, which reduced the hardness of Ti-6Al-4V. Most pores were less than 20 µm in size and randomly distributed. The fine shot peening generated plastic deformation and compressive residual stress on the surface, leading to higher hardness, with similar surface properties at all scanning speeds. The depth of compressive residual stress by fine shot peening varied corresponding to the scanning speeds. Increasing the scanning speed accelerated the rate of conversion between the compressive and tensile residual stresses, and decreased the depth of the maximum hardness by the fine shot peening from initial tensile residual stress within Ti-6Al-4V fabricated by laser powder bed fusion, thus reducing the enhancement achieved by the fine shot peening. Full article

Two austenitic stainless steel (ASS) plates, 304L and 316L, were cold-rolled (304R and 316R) with a 10% reduction in thickness and then subjected to laser welding. Cold rolling caused slight surface hardening and introduced residual tensile stress into the ASS plates. The susceptibility to stress corrosion cracking (SCC) of the welds (304RW and 316RW) was determined using the U-bend test pieces in a salt spray. To highlight the stress concentration at the weld’s fusion boundary (FB), the top weld reinforcement was not ground off before bending. Moreover, micro-shot peening (MSP) was performed to mitigate the SCC of the welds by imposing high residual compressive stress and forming a fine-grained structure. Cold rolling increased the susceptibility of the 304R specimen to pitting corrosion and intergranular (IG) microcracking. Moreover, pitting corrosion and SCC were found more often at the FBs of the 304RW. The corrosion pits of the peened 304RW (304RWSP) were finer but greater in amount than the those of the un-peened one. The results also indicated that the 316L ASS welds with MSP were resistant to the incidence of pitting corrosion and SCC in a salt spray. The better reliability and longer service life of dry storage canisters could be achieved by using 316L ASS for the construction and application of MSP on it. Full article

In order to increase the performance of tool or mold/die, there are a lot of micro features on the surface to provide special functions, such as anti-adhesion or lubrication. The MPB (Micro Particle Bombarding) process provides a powerful technology to enhance the surface quality without damaging the micro features. The effect of MPB parameters were investigated by bombarding the surface with extremely small particles (20~200 µm in diameter) at a high velocity and pressure to obtain a better surface integrity. -The MPB has two functions, one is micro blasting for cleaning purposes and the other is micro shot peening for surface strengthening. The regression relationship between particle bombarding time and micro hardness is established to predict the surface hardness after MPB process. The experimental results reveal that the surface hardness of cermet is increased 14~66% (HV2167~HV3163) by micro particle bombarding. The micro shot peening provides a good surface integrity due to thebetter surface roughness of 0.1 μmRa and higher compress residual stress of −1393.7 MPa, which is up to 26% enhancement compared with the base material cermet. After micro shot peening, the surface hardness of the SKD11 tool steel increased from HV 686 to HV 739~985. The surface roughness of SKD 11 after micro shot peening was 0.31–0.48 μmRa, while the surface roughness after micro blasting was 0.77–1.15 μmRa. It is useful to predict the residual stress for micro blasting by surface roughness, and to estimate the residual stress after micro shot peening by surface hardness by applying the MPB process in industry in the case of SKD 11 tool steel. Full article

Micro-shot peening under two Almen intensities was performed to increase the fatigue endurance limit of anodized AA 7075 alloy in T6 condition. Compressive residual stress (CRS) and a nano-grained structure were present in the outermost as-peened layer. Microcracks in the anodized layer obviously abbreviated the fatigue strength/life of the substrate. The endurance limit of the anodized AA 7075 was lowered to less than 200 MPa. By contrast, micro-shot peening increased the endurance limit of the anodized AA 7075 to above that of the substrate (about 300 MPa). Without anodization, the fatigue strength of the high peened (HP) specimen fluctuated; this was the result of high surface roughness of the specimen, as compared to that of the low peened (LP) one. Pickling before anodizing was found to erode the outermost peened layer, which caused a decrease in the positive effect of peening. After anodization, the HP sample had a greater fatigue strength/endurance limit than that of the LP one. The fracture appearance of an anodized fatigued sample showed an observable ring of brittle fracture. Fatigue cracks present in the brittle coating propagated directly into the substrate, significantly damaging the fatigue performance of the anodized sample. The CRS and the nano-grained structure beneath the anodized layer accounted for a noticeable increase in resistance to fatigue failure of the anodized micro-shot peened specimen. Full article

The FeCoNiCrMo_0.2 high entropy alloy coatings were deposited on BS960 high strength steel by plasma spraying method with four different current intensities (250 A, 350 A, 450 A, 550 A). These coatings were then subjected to a subsequent micro-shot peening treatment. Surface characteristics including surface morphology, microhardness and phase composition were characterized, and the wear resistance of the coatings was assessed by reciprocal friction and wear tests. The results showed that the high entropy alloy coatings had FCC structure. XRD results showed that no new phase was formed during the spraying process. At the same time, shot peening treatment could effectively improve the hardness of the coating surface. Under the four processes, the coating surface prepared with the current intensity of 350 A had the highest microhardness and uniformity before and after shot peening, and the hardness values were 473 ± 10.21 and 504 ± 8.62 HV_0.2, respectively. The friction and wear test results showed that the friction coefficients of the four coatings were close to each other at 10 N load, which was about 0.4. When the test load reached 25 N, the friction coefficient of the coating with current intensity of 350 A was lower, and it showed better friction performance. After shot peening, the friction coefficient of the four coatings further decreased to about 0.3 under 10 N loading due to the existence of hardened surface layer. When the test load reached 25 N, the hardened layer would be worn through and the friction coefficient would suddenly rise. Under the 25 N test load, the hardened layer of the high-entropy alloy coating with current intensity of 350 A illustrated better friction resistance. Full article

The present study reveals for the first time the dry sliding wear behavior of a powder metallurgical pure titanium alloy (Cp-Ti) modified by shot peening. Cp-Ti samples were manufactured via powder metallurgy, and then their surface and subsurface features were modified using a custom-made, fully automated shot-peening system. The texture isotropy rate and the highest orientation angle of the shot-peened samples were 71.5% and 36°, respectively. The Abbott curves of the shot-peened surfaces revealed that the most common areal roughness value was 5.177 μm, with a frequency of 8.1%. Shot-peened surfaces exhibited an ~20% lower wear rate than unpeened surfaces under dry sliding wear, whereas the coefficient of friction was the same for both surfaces. Micro-ploughing, micro-cutting, oxidation, and three-body abrasion wear mechanisms were observed on the shot-peened and unpeened surfaces. High resolution 3D surface topographies of worn unpeened and shot-peened surfaces revealed micro-scratches and inhomogeneities along wear tracks, which are indicative of three-body abrasion mechanisms during contact. In addition, vertical and horizontal microcracks were visible just beneath the wear track, suggesting a clear indication of plastic deformation during contact. The cross-sectional hardness maps of shot-peened samples revealed the formation of a work-hardened surface layer with shot peening, which improved the wear resistance. These findings support that shot peening can be a useful tool to modify the surface and tribological properties of powder metallurgical Cp-Ti alloys. Full article

Micro-shot peening on AISI 304 and 316 stainless steel (SS) laser welds was performed to evaluate its effect on the susceptibility to stress corrosion cracking (SCC) in a salt spray containing 10% NaCl at 80 °C. The cracking susceptibility of the welds was disclosed by testing U-bend specimens in a salt spray. Micro-shot peening caused an intense but narrow deformed layer with a nanocrystal structure and residual compressive stress. Austenite to martensite transformation occurred heavily on the top surface of the micro-shot peened welds. SCC microcracks were more likely to be initiated at the fusion boundary (FB) of the non-peened welds. However, fine pits were formed more easily on the micro-shot peened 304 fusion zone (FZ), which was attributed to the extensive formation of strain-induced martensite. The nanograined structure and induced residual compressive stress in the micro-shot peened layer suppressed microcrack initiation in the 304 and 316 welds in a salt spray. Compared with the other zones in the welds in a salt spray, the high local strain at the FB was the cause of the high cracking susceptibility and could be mitigated by the micro-shot peening treatment. Full article

Ga-ion micro-ring-core FIB-DIC evaluation of residual stresses in shot peened VT6 (Ti-6Al-4V) alloy was carried out and cross-validated against other non-destructive and semi-destructive residual stresses evaluation techniques, namely, the conventional ${\sin }^2\psi$ X-ray diffraction and mechanical hole drilling. The Korsunsky FIB-DIC method of Ga-ion beam micro-ring-core milling within FIB-SEM with Digital Image Correlation (DIC) deformation analysis delivered spatial resolution down to a few micrometers, while the mechanical drilling of circular holes of ~2 mm diameter with laser speckle interferometry monitoring of strains gave a rough spatial resolution of a few millimeters. Good agreement was also found with the X-ray diffraction estimates of residual stress variation profiles as a function of depth. These results demonstrate that FIB-DIC provides rich information down to the micron scale, it also allows reliable estimation of macro-scale residual stresses. Full article

AA1050 Al alloy samples were shot-peened using stainless-steel shots at shot peening (SP) pressures of 0.1 and 0.5 MPa and surface cover rates of 100% and 1000% using a custom-designed SP system. The hardness of shot-peened samples was around twice that of unpeened samples. Hardness increased with peening pressure, whereas the higher cover rate did not lead to hardness improvement. Micro-crack formation and embedment of shots occurred by SP, while average surface roughness increased up to 9 µm at the higher peening pressure and cover rate, indicating surface deterioration. The areal coverage of the embedded shots ranged from 1% to 5% depending on the peening parameters, and the number and the mean size of the embedded shots increased at the higher SP pressure and cover rate. As evidenced and discussed through the surface and cross-sectional SEM images, the main deformation mechanisms during SP were schematically described as crater formation, folding, micro-crack formation, and material removal. Overall, shot-peened samples demonstrated improved mechanical properties, whereas sample surface integrity only deteriorated notably during SP at the higher pressure, suggesting that selecting optimal peening parameters is key to the safe use of SP. The implemented methodology can be used to modify similar soft alloys within confined compromises in surface features. Full article

Shot peening can be an effective solution for the prevention or retardation of scale formation, and subsequent exfoliation, upon exposure of the inner tube to steam in coal-fired power plants. In this study, specimens of T91 tubes were shot peened and then exposed to 1-bar steam for 100–1000 h at 650 °C, and were then analyzed using Vickers hardness test and microscopic techniques OM, SEM, TEM, etc. The analysis indicates that the oxide scales are typically Fe₂O₃ on the topmost layer, Fe₃O₄ below, and a FeCr₂O₄ spinel on the bottom in both shot peening treated and untreated specimens. However, the oxide scale thicknesses of shot peened specimens are thinner, indicating that shot peened specimens have better oxidation resistance. In addition, numerous defects, such as voids and micro-cracks, were found in the untreated specimens, which are believed to cause exfoliation of the uppermost Fe₂O₃ layers of the specimens exposed to steam for 800 and 1000 h. By contrast, the shot peened specimens maintained a dense contact oxide scale with fewer defects. Full article