Search Results (412)

Poly(vinyl chloride) (PVC) undergoes thermal degradation during processing and operation, which necessitates the use of effective thermal stabilizers. The purpose of this work is to comprehensively evaluate the potential of new hierarchically structured titanium phosphates (TiP) with controlled morphology as thermal stabilizers of plasticized PVC, focusing on the effect of morphology and Ti/P ratio on their stabilizing efficiency. The thermal stability of the compositions was studied by thermogravimetric analysis (TGA) in both inert (Ar) and oxidizing (air) atmospheres. The effect of TiP concentration and its synergy with industrial stabilizers was analyzed. An assessment of the key degradation parameters is given: the temperature of degradation onset, the rate of decomposition, exothermic effects, and the carbon residue yield. In an inert environment, TiPMSI/TiPMSII microspheres demonstrated an optimal balance by increasing the temperature of degradation onset and the residual yield while suppressing the rate of decomposition. In an oxidizing environment, TiPR rods and TiPMSII microspheres provided maximum stability, enhancing resistance to degradation onset and reducing the degradation rate by 10–15%. Key factors of effectiveness include ordered morphology (spheres, rods); the Ti-deficient Ti/P ratio (~0.86), which enhances HCl binding; and crystallinity. The stabilization mechanism of titanium phosphates is attributed to their high affinity for hydrogen chloride (HCl), which catalyzes PVC chain scission, a catalyst for the destruction of the PVC chain. The unique microstructure of titanium phosphate provides a high specific surface area and, as a result, greater activity in the HCl neutralization reaction. The formation of a sol–phosphate framework creates a barrier to heat and oxygen. An additional contribution comes from the inhibition of oxidative processes and the possible interaction with unstable chlorallyl groups in PVC macromolecules. Thus, hierarchically structured titanium phosphates have shown high potential as multifunctional PVC thermostabilizers for modern polymer materials. Potential applications include the development of environmentally friendly PVC formulations with partial or complete replacement of toxic stabilizers, the optimization of thermal stabilization for products used in aggressive environments, and the use of hierarchical TiP structures in flame-resistant and halogen-free PVC-based compositions. Full article

This study reports the development of a sustainable biocatalyst system for free fatty acid (FFA) production from cocoa bean shell (CBS) oil using Burkholderia cepacia lipase (BCL). CBS was explored as both a support material and a reaction substrate. Six immobilized systems were prepared using organic (CBS), inorganic (silica), and hybrid (CBS–silica) supports via physical adsorption or covalent binding. Among them, the covalently immobilized enzyme on CBS (ORG-CB) showed the most balanced performance, achieving a catalytic efficiency (Ke) of 0.063 mM⁻¹·min⁻¹ (18.6% of the free enzyme), broad pH–temperature tolerance, and over 50% activity retention after eight reuse cycles. Thermodynamic analysis confirmed enhanced thermal resistance for ORG-CB (Ed = 32.3 kJ mol⁻¹; ΔH‡ = 29.7 kJ mol⁻¹), while kinetic evaluation revealed that its thermal deactivation occurred faster than for the free enzyme under prolonged heating. In application trials, ORG-CB reached 60.1% FFA conversion from CBS oil, outperforming the free enzyme (49.9%). These findings validate CBS as a dual-function material for enzyme immobilization and valorization of agro-industrial waste. The results also reinforce the impact of immobilization chemistry and support composition on the operational and thermal performance of biocatalysts, contributing to the advancement of green chemistry strategies in enzyme-based processing. Full article

Sustainable building design is significantly impacted by the local climate response knowledge ingrained in traditional architecture. However, its integration and dissemination with contemporary green technologies are limited by the absence of a comprehensive quantitative analysis of the regulation of its humid and temperature environment. The Ganzhou Wei family compound from China’s wind–heat environmental regulation systems are examined in this study. We statistically evaluate the synergy between spatial morphology, material qualities, and microclimate using field data with Thsware and Ecotect software in a multiscale simulation framework. The findings indicate that the compound’s special design greatly controls the thermal and wind conditions. Cold alleyways and courtyards work together to maximize thermal environment regulation and encourage natural ventilation. According to quantitative studies, courtyards with particular depths (1–4 m) and height-to-width ratios (e.g., 1:1) reduce wind speed loss. A cool alley (5:1 height–width ratio) creates a dynamic wind–speed–temperature–humidity balance by lowering summer daytime temperatures by 2.5 °C. It also serves as a “cold source area” that moderates temperatures in the surrounding area by up to 2.1 °C. This study suggests a quantitative correlation model based on “spatial morphology–material performance–microclimate response,” which offers a technical route for historic building conservation renovation and green renewal, as well as a scientific foundation for traditional buildings to maintain thermal comfort under low energy consumption. Although based on a specific geographical case, the innovative analytical methods and strategies of this study are of great theoretical and practical significance for promoting the modernization and transformation of traditional architecture, low-carbon city construction, and sustainable building design. Full article

This study investigates the effects of incorporating recycled concrete powder (RCP) as a supplementary cementitious material in Portland cement composites at replacement levels of 5–30% by weight. A comprehensive characterization using isothermal calorimetry, electrical conductivity measurements, thermogravimetric analysis, FT-IR spectroscopy, and scanning electron microscopy revealed that RCP modified the hydration behavior and microstructural development. The results showed a linear 16.5% reduction in the total heat of hydration (from 145.38 to 121.44 J/g) at 30% RCP content, accompanied by a 26.5% decrease in peak electrical conductivity (19.16 to 14.08 mS/cm) and delayed reaction kinetics. Thermal analysis demonstrated an increased stability of hydration products, with portlandite decomposition temperatures rising by up to 10.8 °C. Microstructural observations confirmed the formation of denser but more amorphous C–S–H phases alongside increased interfacial porosity at higher RCP contents. The study provides quantitative evidence of RCP’s dual functionality as both an inert filler and a nucleation agent, identifying an optimal 20–25% replacement range that balances performance and sustainability. These findings advance the understanding of construction waste utilization in cementitious materials and provide practical solutions for developing more sustainable building composites while addressing circular economy objectives in the construction sector. Full article

The escalating demand for efficient thermal management in lithium-ion batteries necessitates precise characterization of their thermal behavior under diverse operating conditions. This study develops a three-dimensional (3D) electrochemical–thermal coupling model grounded in porous electrode theory and energy conservation principles. The model solves multi-physics equations such as Fick’s law, Ohm’s law, and the Butler–Volmer equation, to resolve coupled electrochemical and thermal dynamics, with temperature-dependent parameters calibrated via the Arrhenius equation. Simulations under varying discharge rates reveal that high-rate discharges exacerbate internal heat accumulation. Low ambient temperatures amplify polarization effects. Forced convection cooling reduces surface temperatures but exacerbates core-to-surface thermal gradients. Structural optimization strategies demonstrate that enhancing through-thickness thermal conductivity reduces temperature differences. These findings underscore the necessity of balancing energy density and thermal management in lithium-ion battery design, proposing actionable insights such as preheating protocols for low-temperature operation, optimized cooling systems for high-rate scenarios, and material-level enhancements for improved thermal uniformity. Full article

The construction sector presently consumes about 40% of global energy and generates 36% of CO₂ emissions, making facade retrofits a priority for decarbonising buildings. This review clarifies how ventilated facades (VFs), wall assemblies that interpose a ventilated air cavity between outer cladding and the insulated structure, address that challenge. First, the paper categorises VFs by structural configuration, ventilation strategy and functional control into four principal families: double-skin, rainscreen, hybrid/adaptive and active–passive systems, with further extensions such as BIPV, PCM and green-wall integrations that couple energy generation or storage with envelope performance. Heat-transfer analysis shows that the cavity interrupts conductive paths, promotes buoyancy- or wind-driven convection, and curtails radiative exchange. Key design parameters, including cavity depth, vent-area ratio, airflow velocity and surface emissivity, govern this balance, while hybrid ventilation offers the most excellent peak-load mitigation with modest energy input. A synthesis of simulation and field studies indicates that properly detailed VFs reduce envelope cooling loads by 20–55% across diverse climates and cut winter heating demand by 10–20% when vents are seasonally managed or coupled with heat-recovery devices. These thermal benefits translate into steadier interior surface temperatures, lower radiant asymmetry and fewer drafts, thereby expanding the hours occupants remain within comfort bands without mechanical conditioning. Climate-responsive guidance emerges in tropical and arid regions, favouring highly ventilated, low-absorptance cladding; temperate and continental zones gain from adaptive vents, movable insulation or PCM layers; multi-skin adaptive facades promise balanced year-round savings by re-configuring in real time. Overall, the review demonstrates that VFs constitute a versatile, passive-plus platform for low-carbon buildings, simultaneously enhancing energy efficiency, durability and indoor comfort. Future advances in smart controls, bio-based materials and integrated energy-recovery systems are poised to unlock further performance gains and accelerate the sector’s transition to net-zero. Emerging multifunctional materials such as phase-change composites, nanostructured coatings, and perovskite-integrated systems also show promise in enhancing facade adaptability and energy responsiveness. Full article

This study develops a comprehensive artificial neural network (ANN) model for predicting the mechanical properties of carbon–manganese cast steel, specifically, the yield strength (YS), tensile strength (TS), elongation (El), and reduction of area (RA), based on the chemical composition (16 alloying elements) and heat treatment parameters. The neural network model, employing a 20-44-44-4 architecture and trained on 400 samples from an industrial dataset of 500 samples, achieved 90% of test predictions within a 5% deviation from actual values, with mean prediction errors of 3.45% for YS and 4.9% for %EL. A user-friendly graphical interface was developed to make these predictive capabilities accessible, without requiring programming expertise. Sensitivity analyses revealed that increasing the copper content from 0.05% to 0.2% enhanced the yield strength from 320 to 360 MPa while reducing the ductility, whereas niobium functioned as an effective grain refiner, improving both the strength and ductility. The combined effects of carbon and manganese demonstrated complex synergistic behavior, with the yield strength varying between 280 and 460 MPa and the tensile strength ranging from 460 to 740 MPa across the composition space. Optimal strength–ductility balance was achieved at moderate compositions of 1.0–1.2 wt% Mn and 0.20–0.24 wt% C. The model provides an efficient alternative to costly experimental trials for optimizing C-Mn steels, with prediction errors consistently below 6% compared with 8–20% for traditional empirical methods. This approach establishes quantitative guidelines for designing complex multi-element alloys with targeted mechanical properties, representing a significant advancement in computational material engineering for industrial applications. Full article

Despite the availability of various materials for chimney applications, ongoing research seeks alternatives with improved thermal and chemical resistance. Geopolymers are a promising solution, exhibiting exceptional resistance to high temperatures, fire, and aggressive chemicals. This study investigates fly ash-based lightweight geopolymer concretes that incorporate expanded clay aggregate (E.C.A.), perlite (P), and foamed geopolymer aggregate (F.G.A.). The composites were designed to ensure a density below 1200 kg/m³, reducing overall weight while maintaining necessary performance. Aggregate content ranged from 60 to 75 wt.%. Physical (density, thickness, water absorption), mechanical (flexural and compressive strength), and thermal (conductivity, resistance) properties were evaluated. F.G.A. 60 achieved a 76.8% reduction in thermal conductivity (0.1708 vs. 0.7366 W/(m·K)) and a 140.4% increase in thermal resistance (0.1642 vs. 0.0683). The F.G.A./E.C.A./P 60 mixture showed the highest compressive strength (18.069 MPa), reaching 52.7% of the reference concrete’s strength, with a 32.3% lower density (1173.3 vs. 1735.0 kg/m³). Water absorption ranged from 4.9% (REF.) to 7.3% (F.G.A. 60). All samples, except F.G.A. 70 and F.G.A. 75, endured heating up to 800 °C. The F.G.A./E.C.A./P 60 composite demonstrated well-balanced performance: low thermal conductivity (0.2052 W/(m·K)), thermal resistance up to 1000 °C, flexural strength of 4.386 MPa, and compressive strength of 18.069 MPa. The results confirm that well-designed geopolymer lightweight concretes are suitable for chimney and flue pipe linings operating between 500 and 1000 °C and exposed to acidic condensates and aggressive chemicals. This study marks the initial phase of a broader project on geopolymer-based prefabricated chimney systems. Full article

High-Bandwidth Memory (HBM) enables the bandwidth required by modern AI and high-performance computing, yet its three dimensional stack traps heat and amplifies thermo mechanical stress. We first review how conventional solutions such as heat spreaders, microchannels, high density Through-Silicon Vias (TSVs), and Mass Reflow Molded Underfill (MR MUF) underfills lower but do not eliminate the internal thermal resistance that rises sharply beyond 12layer stacks. We then synthesize recent hybrid bonding studies, showing that an optimized Cu pad density, interface characteristic, and mechanical treatments can cut junction-to-junction thermal resistance by between 22.8% and 47%, raise vertical thermal conductivity by up to three times, and shrink the stack height by more than 15%. A meta-analysis identifies design thresholds such as at least 20% Cu coverage that balances heat flow, interfacial stress, and reliability. The review next traces the chain from Coefficient of Thermal Expansion (CTE) mismatch to Cu protrusion, delamination, and warpage and classifies mitigation strategies into (i) material selection including SiCN dielectrics, nano twinned Cu, and polymer composites, (ii) process technologies such as sub-200 °C plasma-activated bonding and Chemical Mechanical Polishing (CMP) anneal co-optimization, and (iii) the structural design, including staggered stack and filleted corners. Integrating these levers suppresses stress hotspots and extends fatigue life in more than 16layer stacks. Finally, we outline a research roadmap combining a multiscale simulation with high layer prototyping to co-optimize thermal, mechanical, and electrical metrics for next-generation 20-layer HBM. Full article

The decarbonization of residential cooling systems requires innovative solutions to overcome the mismatch between the renewable energy availability and demand. Integrating latent thermal energy storage (LTES) with heat pump/air conditioning (HP/AC) units can help balance energy use and enhance efficiency. However, the dynamic behavior of such integrated systems, particularly under low-load conditions, remains underexplored. This study investigates a 5 kW HP/AC unit coupled with an 18 kWh LTES system using a bio-based Phase Change Material (PCM) with a melting temperature of 9 °C. Two configurations were tested: charging the LTES using either a thermostatic bath or the HP/AC unit. Key parameters such as the stored energy, temperature distribution, and cooling capacity were analyzed. The results show that, under identical conditions (2 °C inlet temperature, 16 L/min flow rate), the energy stored using the HP/AC unit was only 6.3% lower than with the thermostatic bath. Nevertheless, significant cooling capacity fluctuations occurred with the HP/AC unit due to compressor modulation and anti-frost cycles. The compressor frequency varied from 75 Hz to 25 Hz, and inefficient on-off cycling appeared in the final phase, when the power demand dropped below 1 kW. These findings highlight the importance of integrated system design and control strategies. A co-optimized HP/AC–LTES setup is essential to avoid performance degradation and to fully exploit the benefits of thermal storage in residential cooling. Full article

Recycled aluminum–silicon alloys provide significant environmental benefits by reducing the consumption of raw materials and lowering carbon emissions. However, their industrial application is limited by the presence of iron-based intermetallic compounds and the insufficient investigation in the literature regarding their effects on mechanical behavior. This study focuses on a recycled EN 42000 alloy, comprising 95% recycled aluminum, with a focus on the effect of its elevated iron content (0.447 wt%) on aging behavior and mechanical performance. Laboratory-scale specimens were produced through gravity die casting and subjected to T6 heat treatment, consisting of solution, quenching, and artificial aging from 160 °C to 190 °C for up to 8 h. To investigate overaging, analyses were conducted at 160 °C and 170 °C for durations up to 184 h. Tensile tests were conducted on specimens aged under the most promising conditions. Based on innovative quality indices and predictive modeling, aging at 160 °C for 4.5 h was identified as the optimal condition, providing a well-balanced combination of strength and ductility (YS = 258 MPa, UTS = 313 MPa, and e% = 3.9%). Mechanical behavior was also assessed through microstructural and fractographic analyses, highlighting the capability of EN 42000 to achieve properties suitable for high-performance automotive components. Full article

The use of a rock-bed accumulator for a short-term heat storage and air exchange in a building facility is an economical and energy-efficient technological solution to balance and optimize the energy supplied to the facility. Existing scientific studies have not addressed, as yet, the environmental impacts of using a rock bed for heat storage. The purpose of the research is the environmental life cycle assessment (LCA) of a heat storage system in a rock-bed accumulator supported by a photovoltaic installation. The boundaries of the analyzed system include manufacturing the components of the storage device, land preparation for the construction of the accumulator, the entire construction process, including transportation of materials, and its operation in cooperation with a horticultural facility (foil tunnel) during one growing season, as well as the photovoltaic installation. The functional unit in the analysis is 1 square meter of rock-bed accumulator surface area. SimaPro 8.1 software and Ecoinvent database were used to perform the LCA, applying the ReCiPe model to analyze environmental impact. The analysis showed the largest negative environmental impact occurs during raw materials extraction and component manufacturing (32.38 Pt). The heat stored during one season (April to October) at a greenhouse facility reduces this negative impact by approx. 7%, mainly due to the reduction in the use of fossil fuels to heat the facility. A 3 °C increase in average air temperature results in an average reduction of 0.7% per year in the negative environmental impact of the rock-bed thermal energy storage system. Full article

The miniaturization of heat exchangers requires advanced manufacturing methods, as conventional techniques such as milling or casting are insufficient for producing complex microscale geometries. This study investigates the feasibility of using selective laser melting (SLM) with 316L stainless steel powder to fabricate compact heat exchangers with minichannels. The exchanger was designed using Autodesk Inventor 2023.3 software and produced under optimized process parameters. Measurements using a hydrostatic balance demonstrated that the applied process parameters resulted in a relative material density of 99.5%. The average microhardness in the core region of the SLM-fabricated samples was 255 HV, and the chemical composition of the final material differed only slightly from that of the feedstock material (stainless steel powder). Dimensional accuracy, surface quality, and internal structure integrity were assessed using computed tomography, optical microscopy, and contact profilometry. The fabricated component demonstrated high geometric fidelity and channel permeability, with local surface deformations associated with the absence of support structures. The average surface roughness (Ra) of the minichannels was 11.11 ± 1.63 µm. The results confirm that SLM technology enables the production of functionally viable heat exchangers with complex geometries. However, limitations remain regarding dimensional accuracy, powder removal, and surface roughness. These findings highlight the potential of metal additive manufacturing for heat transfer applications while emphasizing the need for further research on performance testing under real operating conditions, especially involving two-phase flow. Full article

Single-lip deep-hole drilling is a key technology for the precision machining of high-temperature nickel-based alloy pore structures in aero engines. However, the intense thermo-mechanical coupling effects during machining can easily lead to surface integrity deterioration, and the correlation mechanism between microstructure and properties remains unclear. By adjusting the spindle speed and feed rate, a series of orthogonal experiments were carried out to study the integrity characteristics of the machined surface, including surface morphology, roughness, work hardening, and subsurface microstructure. The results reveal gradient structural features along radial depth: a dynamic recrystallized layer (RL) at the surface and a plastically deformed layer (PDL) containing high-density subgrains/distorted grains in the subsurface. With the increase in the spindle speed, the recrystallization phenomenon is intensified, the RL ratio of the machined-affected zone (MAZ) is increased, and the surface roughness is reduced to ~0.5 μm. However, excessive heat input will reduce the nanohardness. Low feed rates (<0.012 mm/rev) effectively suppress pit defects, whereas high feed rates (≥0.014 mm/rev) trigger pit density resurgence through shear instability. Progressive material removal rate (MRR) elevation drives concurrent PDL thickness reduction and RL proportion growth. Optimal medium MRR range (280–380 mm³/min) achieves synergistic RL/PDL optimization, reducing machining-affected zone thickness (MAZ < 35 μm) while maintaining fatigue resistance. These findings establish theoretical foundations for balancing efficiency and precision in aerospace high-temperature component manufacturing. Full article

The Volumetric Neutron Source (VNS) is a pivotal facility proposed for advancing fusion nuclear technology, particularly for the qualification of breeding blanket systems, a key component of DEMO and future fusion reactors. This study focuses on the design and optimisation of the VNS Thermal Shield, adopting a multidisciplinary approach to address its thermal and structural behaviours. The Thermal Shield plays a crucial role in protecting superconducting magnets and other cryogenic components by limiting heat transfer from higher-temperature regions of the tokamak to the cryostat, which operates at temperatures between 4 K and 20 K. To ensure both thermal insulation and structural integrity, multiple design iterations were conducted. These iterations aimed to reduce electromagnetic (EM) forces induced during magnet charge and discharge cycles by introducing strategic cuts and reinforcements in the shield design. The optimisation process included the evaluation of various aluminium alloys and composite materials to achieve a balance between rigidity and weight while maintaining structural integrity under EM and mechanical loads. Additionally, an integrated thermal study was performed to ensure effective temperature management, maintaining the shield at an operational temperature of around 80 K. Cooling channels were incorporated to homogenise temperature distribution, improving thermal stability and reducing thermal gradients. This comprehensive approach demonstrates the viability of advanced material solutions and design strategies for thermal and structural optimisation. The findings reinforce the importance of the VNS as a dedicated platform for testing and validating critical fusion technologies under operationally relevant conditions. Full article