Search Results (66)

This study investigated the effects of four heat treatment processes on the microstructure, damping capacity, and mechanical properties of Mn-Cu alloys. The results indicated that the alloy did not undergo spinodal decomposition and twinning after solution treatment. After solution and aging treatment, the alloy underwent spinodal decomposition and formed Mn-rich regions, increasing the martensitic transformation temperature (M_s), promoting martensitic transformation, forming twin boundaries, and enhancing damping capacity and mechanical properties. The cryogenic treatment and furnace cooling process facilitated the process, promoted the formation of twin boundaries, and improved damping capacity, and the degree of promotion by furnace cooling process was more significant. In addition, cryogenic treatment promoted grain refinement, increased dislocation density, improved strength, and facilitated the improvement of mechanical properties. This provided a reference for preparing high-damping Mn-Cu alloys with good comprehensive performance. Full article

The titanium matrix composites (TMCs) fabricated via Directed Energy Deposition (DED) effectively overcome the issue of coarse columnar grains typically observed in additively manufactured titanium alloys. In this study, systematic annealing heat treatments were applied to in situ (TiB + TiC)/Ti-6Al-4V composites to refine the microstructure and tailor mechanical properties. The results reveal that the plate-like α phase in the as-deposited composites gradually transforms into an equiaxed morphology with increasing annealing temperature and holding time. Notably, when the annealing temperature exceeds 1000 °C, significant coarsening of the TiC phase is observed, while the TiB phase remains morphologically stable. Annealing promotes decomposition of acicular martensite and stress relaxation, leading to a reduction in hardness compared to the as-deposited state. However, the reticulated distribution of the TiB and TiC reinforcement phases contributes to enhanced tensile performance. Specifically, the as-deposited composite achieves a tensile strength of 1109 MPa in the XOY direction, representing a 21.6% improvement over the as-cast counterpart, while maintaining a ductility of 2.47%. These findings demonstrate that post-deposition annealing is an effective strategy to regulate microstructure and achieve a desirable balance between strength and ductility in DED-fabricated titanium matrix composites. Full article

In this study, the phase transformation mechanism during the decomposition of undercooled austenite and its effect on the deformation behavior of a high-strength medium Mn steel were studied. The results indicate that the austenite formation during heating (α → γ) is a relatively fast reaction. However, the transformation of undercooled prior austenite above the martensite start (M_s) temperature (γ → α) is difficult due to its high thermal stability. Only martensite transformation occurred during the final air-cooling stage following a 120-h isothermal treatment at 360 °C (slightly above M_s). The growth of martensite laths was limited by the boundaries of prior austenite grains and martensite packets. High-strength tensile properties were achieved, with a yield strength of 955 MPa, ultimate tensile strength of 1228 MPa, and total elongation of 11.6%. These properties result from the synergistic hardening effects of grain refinement, high-density lattice distortion, and an increased boundary length per unit area. The composition design with medium Mn content increased the processing window for high-strength martensite transformation, providing a theoretical basis for an energy-saving approach that depends on the decomposition transformation of undercooled austenite. Full article

To address the insufficient bonding performance between TC4 (Ti-6Al-4V) coating and carbon fiber-reinforced thermoplastic (CFRP) matrices that limits engineering applications of composite structures, TC4 coatings were fabricated on CFRP polymer composites via laser cladding and analyzed using scanning electron microscopy (SEM) and transmission electron microscopy (TEM) to examine the interface morphology, microstructure, and phase composition. The influence of laser processing parameters on the cladding quality was assessed based on the mechanical performance of the TC4 coating. The findings revealed that insufficient laser power (<230 W) or excessive scanning speed (>1.4 m/min) led to incomplete melting of TC4 powder, preventing the formation of intermetallic compound (IMC) layers. Conversely, excessive laser power (>270 W) or a low scanning speed (<1.0 m/min) caused thermal decomposition of the CFRP due to its limited thermal resistance, leading to interfacial defects such as cracks and pores. The interface between the CFRP and TC4 coating primarily comprised granular TiC and acicular α′ martensite, with minor TiS₂ detected. Optimal mechanical performance was achieved at a laser power of 250 W and a scanning speed of 1.2 m/min, yielding a maximum interfacial shear strength of 18.5 MPa. These findings provide critical insights for enhancing the load-bearing capacity of TC4/CFRP aeronautical composites, enabling their reliable operation in extreme aerospace environments. Full article

To investigate the effect of tempering temperature on the hardness and its underlying mechanisms in 14Cr12Ni3Mo2VN martensitic stainless steel after high-frequency induction quenching (HFIQ), the microstructure, energy-dispersive spectroscopy (EDS) of precipitated particles, residual austenite, residual stress, and microhardness of the material tempered at different temperatures were examined and analyzed. The results reveal that a secondary hardening phenomenon occurs during the tempering process in 14Cr12Ni3Mo2VN martensitic stainless steel. Overall, with increasing tempering temperature, the microhardness initially decreases slightly, then rises to a secondary hardening peak, and finally drops rapidly. The secondary hardening peak corresponds to a tempering temperature of approximately 440 °C, with a microhardness of about 483 HV_0.1. The secondary hardening phenomenon is likely attributed to the dispersion strengthening caused by the precipitation of alloy carbides during tempering. The precipitation and coarsening of carbides reduce lattice distortion and solid solution strengthening, while the release of residual stress diminishes stress-induced strengthening. Additionally, the decomposition of the martensitic structure leads to the formation of ferrite and carbides. The combined effects of these factors result in a decrease in hardness. Full article

With superior manufacturing freedom capability, Selective Laser Melting (SLM) technology is capable of fabricating high-strength Ti-6Al-2Zr-1Mo-1V (TA15) complex titanium alloy parts, thereby finding extensive applications in the aerospace sector. This paper primarily investigates the influence of process parameters on the relative density, microstructure, and mechanical properties of SLMed TA15 under conditions of similar laser linear energy density. The results indicate that the laser linear energy density significantly affects the single-track morphology of SLMed TA15; excessive energy density leads to keyhole defects, while insufficient energy density causes balling phenomena, resulting in discontinuous clad tracks. When the laser linear energy density is appropriate, the scanning spacing affects the forming density of the parts, with both excessively large and small spacings having adverse effects. With a fixed scanning spacing of 100 μm, high-density samples can be produced within a suitable range of linear energy density. However, when the laser linear energy density is comparable, a lower scanning speed leads to heat accumulation, causing in situ decomposition of the α’ martensite and the formation of coarser α + β phases, which reduces strength and hardness but improves plasticity. At a laser power of 90 W, a scanning speed of 400 mm/s, and a scanning spacing of 100 μm, the specimen exhibits a tensile strength of 1233 MPa and an elongation of 8.4%, achieving relatively excellent comprehensive properties. Full article

In this study, microstructure evolution during prior austenite decomposition and reverse phase transformation processes was revealed in a high-strength medium-Mn steel. Furthermore, the relationship between deformed prior austenite characteristics and deformation behavior was studied. The results indicated that the recovery and recrystallization of the deformed prior austenite were significantly inhibited during hot rolling in the non-recrystallized zone, the grain size was obviously refined along the normal direction (ND), and that the strain hardening of prior austenite via hot deformation could increase the resistance of shear transformation, resulting in the preservation of high-density lattice defects in the quenched martensite matrix. Before the nucleation of intercritical austenite, the dislocation and grain boundary can provide fast diffusion paths for C and Mn, and the enrichment of C and Mn before intercritical austenite formation can reduce the critical temperature of ferrite/austenite transformation. The nucleated sites and driving force for intercritical austenite were strongly increased by rolling in the non-recrystallization region. The resistance of crack propagation was found to be enhanced by the sustained transformation-induced plasticity (TRIP) effect (via retained austenite with different stability) and for the laminated microstructure, the optimum properties were obtained as being a combination of yield strength of 748 MPa, tensile strength of 952 MPa, and total elongation of 26.2%. Full article

This paper deals with the influence of micro-pulsed direct current on microstructure and mechanical properties of gas tungsten arc welding (GTAW) weldments of Ti-6Al-4V (Ti-64). Bead-on-plate GTA welds were made on the samples in the un-pulsed and micro-pulsed (125 Hz and 250 Hz) conditions. Post-weld heat treatment (PWHT) was performed on a few coupons at 700 °C for 3 h in an inert atmosphere, followed by furnace cooling. In the microstructure, the fusion zone (FZ), base metal (BM), and heat-affected zone (HAZ) can be easily distinguished. The top surface of the FZ has large columnar grains because of lower heat loss to the surrounding atmosphere, and the bottom region of the FZ has comparatively smaller equiaxed grains. The micro-pulsed samples’ FZ grain size was lower than that of those made without pulsing. This shows that high-frequency current has substantially refined prior β grains. The microstructure of the FZ is characterized by an acicular morphology composed of α, martensitic α′, and retained β phases. The FZ’s hardness was higher than the BM due to the presence of martensitic α′. Additionally, the hardness in the HAZ was elevated due to the formation of finer martensitic α′. Micro-pulsed DC welding led to improved mechanical properties, including higher hardness, ultimate tensile strength (UTS), and ductility compared to un-pulsed welding. This enhancement is attributed to the grain refinement achieved with micro-pulsed DC. After PWHT, the prior β grain size remained relatively unchanged compared to the as-welded condition. However, the hardness in the FZ decreased due to the decomposition of α′ into α and β phases. The ductility of all samples improved as a result of the widening of the diffusional α phase. Full article

This work studied the microstructure and mechanical properties of Ti-6Al-4V in situ alloyed with 3 wt% Cr by laser powder bed fusion (LPBF). Specimens with a relative density of 99.14 ± 0.11% were produced, showing keyhole and lack of fusion pores. Due to incomplete mixing of the components during melting, chemical inhomogeneities were observed in the solidified material. The addition of Cr promoted thermal supercooling during solidification and induced a reduction in the primary β grain size in the longitudinal direction and a weakening of the otherwise strong ⟨100⟩_β texture, both typical issues for Ti-6Al-4V produced by LPBF. The primary β at first transformed martensitically to α’, but by preheating the substrate plate to 500 °C and cyclically reheating the material by melting subsequent layers, in situ martensite decomposition was achieved, resulting in a fine lamellar α + β microstructure. In addition, the B19 phase was detected in the β matrix, presumably caused by Fe impurities in the Cr powder feedstock. Specimens exhibited a hardness of 402 ± 18 HV₁₀, and an excellent ultimate tensile strength of 1450 ± 22 MPa at an elongation at break of 4.5 ± 0.2%. Full article

In this study, the decomposition of a martensite/austenite (M/A) microconstituent in bainitic steels was analyzed using differential scanning calorimetry (DSC) data in conjunction with Kissinger’s and Johnson–Mehl–Avrami–Kolmogorov (JMAK)’s formulas. In bainitic steel subjected to austempering heat treatment, the presence of an M/A microstructure adversely affects the mechanical properties. According to the kinetic equations derived, it is observed that after tempering the sample at 600 °C for 4000 s, the generation of each phase reaches its maximum. The SEM images taken before and after tempering reveal extensive decomposition of the M/A constituent in the microstructure. The proportion of the M/A microstructure decreased significantly from about 10% before tempering to less than 1% after. Additionally, the content of residual austenite also reduced nearly to zero. These observations are consistent with the predictions of the kinetic equations. Full article

Three types of solution treatment and aging were designed to reveal the α’ decomposition and its effect on the mechanical properties of near-α Ti-80 alloy, as follows: solution at 970 °C then quenching (ST), ST + aging at 600 °C for 5 h (STA-1), and ST + aging 600 °C for 24 h (STA-2). The results show that the microstructures of the ST samples were mainly composed of equiaxed α_p and acicular α’, with a large number of dislocations confirmed by the KAM results. After subsequent aging for 5 h, α’ decomposed into acicular fine α_s and nano-β (intergranular β, intragranular β) in the STA-1 specimen, which obstructed dislocation motion during deformation, resulting in the STA-1 specimen exhibiting the most excellent yield strength (1012 MPa) and maintaining sufficient elongation (8.1%) compared with the ST (898 MPa) and STA-2 (871 MPa) samples. By further extending the aging time to 24 h, the size of acicular α_s and nano-β gradually increased while the density of dislocations decreased, which resulted in a decrease in strength and an increase in plasticity. Based on this, a microstructures–properties correlation model was proposed. This study provides a new method for strength–plasticity matching of near-α titanium alloys through α’ decomposition to acicular α_s+nano-β. Full article

The research focus in the field of medical titanium alloys has recently shifted towards the development of low-modulus and high-strength titanium alloys. In this study, the influence of aging temperature on the microstructure and mechanical properties of a β-type Ti-20Zr-40Ta alloy (TZT) was investigated. It was found that the recovery and the recrystallization occurred in the as-rolled alloy depended on the aging temperature. The periodically distributed Ta-lean phase (β1) and Ta-rich phase (β2) were produced by the spinodal decomposition in all the samples aged at different temperatures. The spinodal decomposition significantly influenced the mechanical properties and deformation mechanisms of the TZT alloy. Upon aging at 650 °C and 750 °C, the as-rolled alloy exhibited a double-yield phenomenon during tensile testing, indicating a stress-induced martensitic transformation; however, its ductility was limited due to the presence of ω phases. Conversely, aging at 850 °C resulted in an alloy with high strength and good ductility, which was potentially attributed to the enhanced strength resulting from modulated structures introduced with spinodal decomposition. Full article

In this study, the refinement of two microstructures was controlled in medium carbon 25Cr2Ni3MoV steel via multi-step tempering and partition (MTP) to achieve high cryogenic strength–ductility combinations. Microstructure evolution, the distribution of stress concentration, and microcrack formation and propagation during cryogenic Charpy impact testing were investigated. Compared with their performance in the quenching and tempering states (QT), the MTP steels showed a significant improvement in yield strength (1300 MPa), total elongation (25%), and impact toughness (>25 J) at liquid nitrogen temperature (LNT). The strengthening contributions mainly originated from the high dislocation density and refinement cementite (size: 70 nm) in the martensite lath (width: 1.5 μm) introduced by refined reversed austenite and its latter decomposition. The instrumented Charpy impact results indicated that cracks nucleated in the primary austenite grain (PAG) boundary for two steels due to the strain concentration band preferring to appear near PAGs, while cracks in the QT and MTP samples propagated along the PAGs and high-angle grain boundary (HAGB), respectively. The crystallized plasticity finite element simulation revealed that the PAG boundary with cementite precipitates of large size (>200 nm) was less able to dissipate crack propagation energy than the HAGBs by continuously forming a high strain concentration area, thus leading to the low-impact toughness of the QT steel. Full article

Ti6Al4V alloy (Ti64) is a popular material used in the aerospace, medical, and automotive industries due to its excellent mechanical properties. Laser Powder Bed Fusion (LPBF) is a promising manufacturing technique that can produce complex and net-shaped components with comparable mechanical properties to those produced using conventional manufacturing techniques. However, during LPBF, the rapid cooling of the material can limit its ductility, making it difficult to achieve high levels of ductility while maintaining the required tensile strength for critical applications. To address this challenge, this study presents a novel approach to controlling the microstructure of Ti64 during LPBF by using a border design surrounding the main parts. It is hypothesized that the design induces in situ martensitic decomposition at different levels during the fabrication process, which can enhance the ductility of the material without compromising its tensile strength. To achieve this aim, a series of Ti64 samples were fabricated using LPBF with varying border designs, including those without borders and with gaps from 0.5 to 4 mm. The microstructure, composition, and mechanical properties of the Reference sample were compared with those of the samples fabricated with the surrounding border design. It was found that the latter had a more homogenized microstructure, a higher density, and improvements in both ductility and tensile strength. Moreover, it was discovered that the level of property improvement and martensitic transformation can be controlled by adjusting the gap space between the border and the main part, providing flexibility in the fabrication process. Overall, this study presents a promising approach for enhancing the mechanical properties of Ti64 produced via LPBF, making it more suitable for critical applications in various industries. Full article