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Keywords = mafic–ultramafic complexes

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20 pages, 10834 KiB  
Article
Genesis of Basalts of the Raohe Subduction–Accretion Complex in the Wandashan Block, NE China, and Its Inspirations for Evolution of the Paleo-Pacific Ocean
by Qing Liu, Cui Liu, Jixu Liu, Jinfu Deng and Shipan Tian
Appl. Sci. 2025, 15(15), 8139; https://doi.org/10.3390/app15158139 - 22 Jul 2025
Viewed by 189
Abstract
The Raohe subduction–accretion complex (RSAC) in the Wandashan Block, NE China, comprises ultramafic rocks, gabbro, mafic volcanic rocks, deep-sea and hemipelagic sediments, and trench–slope turbidites. We investigate the basalts within the RSAC to resolve debates on its origin. Zircon U-Pb dating of pillow [...] Read more.
The Raohe subduction–accretion complex (RSAC) in the Wandashan Block, NE China, comprises ultramafic rocks, gabbro, mafic volcanic rocks, deep-sea and hemipelagic sediments, and trench–slope turbidites. We investigate the basalts within the RSAC to resolve debates on its origin. Zircon U-Pb dating of pillow basalt from Dadingzi Mountain yields a concordant age of 117.5 ± 2.1 Ma (MSWD = 3.6). Integrating previous studies, we identify three distinct basalt phases. The Late Triassic basalt (210 Ma–230 Ma) is characterized as komatites–melilitite, exhibiting features of island arc basalt, as well as some characteristics of E-MORB. It also contains high-magnesium lava, suggesting that it may be a product of a juvenile arc. The Middle Jurassic basalt (around 159 Ma–172 Ma) consists of a combination of basalt and magnesium andesite, displaying features of oceanic island basalt and mid-ocean ridge basalt. Considering the contemporaneous sedimentary rocks as hemipelagic continental slope deposits, it is inferred that these basalts were formed in an arc environment associated with oceanic subduction, likely as a result of subduction of the young oceanic crust. The Early Cretaceous basalt (around 117 Ma) occurs in pillow structures, exhibiting some characteristics of oceanic island basalt but also showing transitional features towards a continental arc. Considering the regional distribution of the rocks, it is inferred that this basalt likely formed in a back-arc basin. Integrating the formation ages, nature, and tectonic attributes of the various structural units within the RSAC, as well as previous research, it is inferred that subduction of the Paleo-Pacific Ocean had already begun during the Late Triassic and continued into the Early Cretaceous without cessation. Full article
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26 pages, 6169 KiB  
Article
Petrogenesis of Mafic–Ultramafic Cumulates in the Mayudia Ophiolite Complex, NE Himalaya: Evidence of an Island Arc Root in Eastern Neo-Tethys
by Sapneswar Sahoo, Alik S. Majumdar, Rajagopal Anand, Dwijesh Ray and José M. Fuenlabrada
Minerals 2025, 15(6), 572; https://doi.org/10.3390/min15060572 - 27 May 2025
Viewed by 507
Abstract
Amphibole-rich cumulates provide crucial information pertaining to the petrogenetic history of suprasubduction zone ophiolites and are, therefore, helpful in constraining the evolution and closure of the Neo-Tethys during the late Cretaceous to the early Tertiary period. Following this, the present contribution examines the [...] Read more.
Amphibole-rich cumulates provide crucial information pertaining to the petrogenetic history of suprasubduction zone ophiolites and are, therefore, helpful in constraining the evolution and closure of the Neo-Tethys during the late Cretaceous to the early Tertiary period. Following this, the present contribution examines the meta-hornblendite and meta-hornblende-gabbro lithologies in the Mayudia ophiolite complex (MdOC), NE Himalaya, based on their field and petrographic relations, constituent mineral compositions, whole rock major and trace element chemistry and bulk strontium (Sr)—neodymium (Nd) isotope systematics. MdOC cumulates potentially represent the fossilized record of an island arc root, where amphibole + titanite + magnetite was fractionally crystallized from a super hydrous magma (10.56–13.61 wt.% melt water content) prior to plagioclase in a stable physico-chemical condition (T: 865–940 °C, P: 0.8–1.4 GPa, logfO2: −8.59–−11.19 unit) at lower crustal depths (30–38 km). Such extreme hydrous nature in the parental magma was generated by the flux melting of the sub-arc mantle wedge with aqueous inputs from the dehydrating slab. A super hydrous magmatic reservoir was, therefore, extant at sub-arc mantle depths in the eastern Neo-Tethys, which has likely modulated the composition of the oceanic crust during intraoceanic subduction. Full article
(This article belongs to the Special Issue Tectonic Evolution of the Tethys Ocean in the Qinghai–Tibet Plateau)
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36 pages, 16597 KiB  
Article
Geochemistry, Isotope Characteristics, and Evolution of the Kesikköprü Iron Deposit (Türkiye)
by Erkan Yılmazer and Mustafa Haydar Terzi
Minerals 2025, 15(5), 528; https://doi.org/10.3390/min15050528 - 15 May 2025
Viewed by 583
Abstract
The Kesikköprü iron deposit, located in the Central Anatolian Crystalline Complex, occurs in the triple contact of Kesikköprü granitoid, mafic–ultramafic rocks, and marble. The causative Kesikköprü granitoid, consisting of diorite, granodiorite, and granite, is classified as sub-alkaline, calc-alkaline, and shoshonitic, displaying metaluminous to [...] Read more.
The Kesikköprü iron deposit, located in the Central Anatolian Crystalline Complex, occurs in the triple contact of Kesikköprü granitoid, mafic–ultramafic rocks, and marble. The causative Kesikköprü granitoid, consisting of diorite, granodiorite, and granite, is classified as sub-alkaline, calc-alkaline, and shoshonitic, displaying metaluminous to partially peraluminous properties. Sr-Nd isotope data and the geochemical characteristics of the Kesikköprü granitoid indicate a metasomatized mantle origin, with its ultimate composition arising from crustal contamination and magma mixing along with fractional crystallization in a post-collisional setting. The 40Ar/39Ar geochronology reveals a total fusion age of 73.41 ± 0.32 Ma for the biotite of the Kesikköprü granitoid. The alteration pattern in the deposit is characterized by an endoskarn zone comprising garnet–pyroxene (±phlogopite ± epidote) and an exoskarn zone displaying a zoning of garnet (±pyroxene ± phlogopite), pyroxene (±garnet ± phlogopite ± epidote), epidote–garnet, and epidote-rich subzones. Magnetite is extracted from massive lenses within the exoskarn zones and shows vein, disseminated, banded, massive, and brecciated textures. The low potassium content of phlogopites which are associated with magnetite mineralization prevents the determination of a reliable alteration age. δ18O thermometry reveals a temperature range between 462 and 528 °C for the magnetite mineralization. According to geochemical (trace and rare earth elements), stable (δ18O, δ2H, δ34S, and δ13C), and radiogenic (87Sr/86Sr and 143Nd/144Nd) isotope data, the hydrothermal fluid responsible for the alteration and mineralization is related to the Kesikköprü granitoid, from which a significant magmatic component originates initially, followed by meteoric fluids at lower temperatures (123 °C) during the late-stage formation of calcite–quartz veins. Full article
(This article belongs to the Section Mineral Deposits)
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21 pages, 2036 KiB  
Article
Quantifying Natural Hydrogen Generation Rates and Volumetric Potential in Onshore Serpentinization
by Reza Rezaee
Geosciences 2025, 15(3), 112; https://doi.org/10.3390/geosciences15030112 - 20 Mar 2025
Cited by 1 | Viewed by 2413
Abstract
This study explores the generation of natural hydrogen through the serpentinization of onshore ultramafic rocks, highlighting its potential as a clean energy resource. By investigating critical factors such as mineral composition, temperature, and pressure, the research develops an empirical model using multiple regression [...] Read more.
This study explores the generation of natural hydrogen through the serpentinization of onshore ultramafic rocks, highlighting its potential as a clean energy resource. By investigating critical factors such as mineral composition, temperature, and pressure, the research develops an empirical model using multiple regression analysis to predict hydrogen generation rates under varying geological conditions. A novel five-stage volumetric calculation methodology is introduced to estimate hydrogen production from ultramafic rock bodies. The application of this framework to the Giles Complex, an ultramafic-mafic intrusion in Australia, suggests a hydrogen generation potential of approximately 2.24 × 1013 kg of hydrogen through partial serpentinization. This estimate is based on the assumed mineral composition, depth, and temperature conditions within the intrusion, which influence the extent of serpentinization reactions. The findings demonstrate the significant potential of ultramafic complexes for natural hydrogen production and provide a foundation for advancing natural hydrogen exploration, refining predictive models, and supporting sustainable energy development. Full article
(This article belongs to the Section Geochemistry)
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15 pages, 4397 KiB  
Article
Apatite in Pegmatoid Gabbro (Khudolaz Differentiated Complex, Southern Urals): Electron-Microprobe and LA-ICP-MS Geochemical Study in Context of Petrogenesis
by Ildar R. Rakhimov
Minerals 2024, 14(12), 1271; https://doi.org/10.3390/min14121271 - 13 Dec 2024
Viewed by 863
Abstract
The conducted study shows that apatite is one of the key accessory minerals in the ultramafic-mafic rocks of the Khudolaz differentiated complex in the Southern Urals, including late pegmatoid gabbro. Petrographic and mineralogical investigations determine apatite crystallizing simultaneously with hornblende in pegmatoid gabbro [...] Read more.
The conducted study shows that apatite is one of the key accessory minerals in the ultramafic-mafic rocks of the Khudolaz differentiated complex in the Southern Urals, including late pegmatoid gabbro. Petrographic and mineralogical investigations determine apatite crystallizing simultaneously with hornblende in pegmatoid gabbro from the residual water-saturated melt after plagioclase crystallization at a temperature of 990–800 °C, a pressure of 1–3 kbar, oxygen fugacity from −13.9 to −10.7, and water content of 3.9–5.5 wt. %. Pegmatoid gabbro apatite (Appg) from the Severnyi Buskun composite massif differs from early ultramafic-mafic apatite having a fairly high potential for sulfide-platinum metal mineralization in low chlorine and high fluorine content. Low sulfur concentrations in Appg testify to the lack of sulfide-platinum metal mineralization potential of pegmatoid gabbro, but a scanty potential for rare-metal mineralization (e.g., REE) is possible. Appg is quite poor in REE despite the enrichment of pegmatoid gabbros in REE relative to early ultramafic-mafics, which indicates REE accumulation in the fluid. The ratios of cerium and europium anomalies characterize the Appg crystallization under conditions transitional from the magmatic to the hydrothermal stage. Generally, apatite is a good indicator of the difference in the conditions of formation of late pegmatoid gabbro and early ultramafic-mafic rocks, which determines the importance of this mineral in mineralogical and petrological studies. Full article
(This article belongs to the Special Issue LA-ICP-MS and LIBS Applied to Minerals)
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20 pages, 25477 KiB  
Article
Mineralogical Features of Ultramafic and Mafic Rocks of Syum-Keu Ophiolite (Polar Urals, Russia): Implications for Petrology and Paleogeodynamics
by Timur D. Shabutdinov, Dmitry E. Saveliev, Ruslan A. Gataullin and Aidar A. Samigullin
Minerals 2024, 14(12), 1245; https://doi.org/10.3390/min14121245 - 6 Dec 2024
Viewed by 1298
Abstract
The Syum-Keu massif is the northernmost ophiolite complex of the Ural mobile belt. It differs from other massifs of the Polar Urals due to the prominent distribution of lherzolites in the upper mantle section. This feature aligns it more closely to some massifs [...] Read more.
The Syum-Keu massif is the northernmost ophiolite complex of the Ural mobile belt. It differs from other massifs of the Polar Urals due to the prominent distribution of lherzolites in the upper mantle section. This feature aligns it more closely to some massifs in the southern part of the belt (Kraka). Thus, a comparison of the ultramafic rock compositions in these massifs is highly relevant. Thus, comparing the compositions of ultramafic rocks from these massifs is highly relevant and is one of the primary objectives of this study. Our second objective is to study the microstructural features of ultramafic rocks from the upper mantle, as they can indicate modes of subsolidus processes that played a key role in the formation of this massif. Our study utilizes optical microscopy, assessments of bulk rock composition using X-ray fluorescence and ICP-MS, as well as mineralogical methods, such as scanning electron microscopy with energy dispersive spectroscopy and electron backscattered diffraction, for the microstructural analysis of peridotites. In addition to ultramafic rocks from the upper mantle section, the composition and mineralogy of mafic rocks from the crustal section were studied. The microstructural analysis of ultramafic rocks indicates their two-stage evolution. The first is associated with plastic flow under the upper mantle conditions dominated by the olivine slip along the {0kl}[100] system, while the second reflects formation in the lower crust, with lower-temperature deformation along the {110}[001] slip system. Comparing the mineralogy of the Syum-Keu peridotites to lherzolite massifs in the Southern Urals reveals a significant difference in accessory Cr-spinel composition; the former show elevated iron content (Fe trend), indicating intense crustal metamorphism. Similarly, amphiboles in Syum-Keu ultramafic rocks exhibit a significant crustal (metamorphic) component, while the same minerals in the Kraka massif suggest a mantle (magmatic) origin. Mafic rocks in the Syum-Keu massif also typically display a high degree of metamorphism. The obtained results generally corroborate prior findings on a longer evolution of the upper mantle ultramafic rocks of the Syum-Keu massif compared to those of the Kraka massif. Our results are also consistent with the suprasubduction nature of these ultramafic rocks. Our findings can be utilized in further studies of the microstructure and composition of ophiolites from the Polar Urals to provide a more detailed characterization of the partial melting conditions of the mantle source, the plastic flow of peridotites, and their interaction with melts and fluids. Full article
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28 pages, 25856 KiB  
Article
Geophysical Methods Applied to the Mineralization Discovery of Rare-Earth Elements at the Fazenda Buriti Alkaline Complex, Goiás Alkaline Province, Brazil
by Fabrício Pereira dos Santos, Marcelo Henrique Leão-Santos, Welitom Rodrigues Borges and Patrícia Caixeta Borges
Minerals 2024, 14(11), 1163; https://doi.org/10.3390/min14111163 - 17 Nov 2024
Cited by 1 | Viewed by 1768
Abstract
In this case study, exploratory techniques were applied for the selection of potential targets for rare-earth elements (REEs) in the Fazenda Buriti Mafic–Ultramafic Complex, part of the Goiás Alkaline Province. The results of the processing and interpretation of aeromagnetic and radiometric data associated [...] Read more.
In this case study, exploratory techniques were applied for the selection of potential targets for rare-earth elements (REEs) in the Fazenda Buriti Mafic–Ultramafic Complex, part of the Goiás Alkaline Province. The results of the processing and interpretation of aeromagnetic and radiometric data associated with the direct measurements of magnetic susceptibility and radiometry in rock samples collected in the study area allowed for the characterization and delimitation of the geological units. The application of Boolean logic in the radiometric data of uranium (U), thorium (Th), and the U/Th ratio allowed for the generation of a prospective map with the delimitation of two exploration targets. A 100 m deep exploratory drill hole was drilled at the main target, intercepting REE mineralization and validating the developed prospective technique. The results contributed to the detailing of a 1:25,000 scale geological map and the interpretation of shallow and deep magnetic structures. Petrophysical data allowed for the estimation of the magnetite content in the main units of the study area. The delimitation of targets with the applied method proved to be efficient after positive geochemical results for REE from the drilled rocks. The total sum of ∑REEs reached 19,629 ppm in the superficial part of the hole and 3,560 ppm in the fresh rock. Mineralogical results in two follow-up drill core samples indicated that monazite was the main REE mineral. Total REE ranged from 34,746 ppm in HG1 to 30,017 ppm in HG2, with LREEs in its majority. The bulk and clay XRD analyses indicated that monazite consisted of 5.7% (HG1) and 5.1% (HG2). The mineral abundance from the TIMA-X analysis indicated 4.2% (HG1) and 4.4% (HG2) in monazite content. Full article
(This article belongs to the Section Mineral Exploration Methods and Applications)
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13 pages, 23345 KiB  
Article
Clinopyroxenite-Wehrlite Porya Guba Complex with Fe-Ti-V and PGE-Cu-Ni Mineralization in the Northeastern Part of the Fennoscandian Shield: Evidence of Post-Orogenic Formation from Sm-Nd Isotope System
by Pavel A. Serov and Nikolay Yu. Groshev
Minerals 2024, 14(11), 1099; https://doi.org/10.3390/min14111099 - 29 Oct 2024
Viewed by 821
Abstract
The Porya Guba clinopyroxenite–wehrlite complex is located in the core of the Lapland–Kola collisional orogen (~2.0–1.9 billion years old) in the northeastern part of the Fennoscandian Shield and contains iron–titanium–vanadium and nickel–copper mineralization with platinum group elements (PGEs). The controversial geological position of [...] Read more.
The Porya Guba clinopyroxenite–wehrlite complex is located in the core of the Lapland–Kola collisional orogen (~2.0–1.9 billion years old) in the northeastern part of the Fennoscandian Shield and contains iron–titanium–vanadium and nickel–copper mineralization with platinum group elements (PGEs). The controversial geological position of the complex within the mafic granulites of the Kolvitsa mélange (pre-, syn- or post-orogenic) is clarified by Sm-Nd isotopic dating of the rocks and mineralization. The Sm-Nd age of the barren clinopyroxenites that dominate the complex is 1858 ± 34 Ma (εNd(T) = −1.5) and is interpreted as the time of its emplacement as evidenced by a sample from the largest intrusion, named Zhelezny. This age is younger than that of the peak of granulite metamorphism in the host rocks (1925–1915 Ma) and coincides within error with the age of rutile from granulites (1880–1870 Ma), indicating the time at which cooling to 450 °C occurs. Emplacement in the cooled rocks is confirmed by the detection of quenching zones in clinopyroxenites around granulite xenoliths. Magnetite ores, as well as mineralized pyroxenites with sulfide disseminations, are formed during a late stage of the complex development, as suggested by active assimilation of granulite xenoliths by these rocks. The isotopic age of mineralized pyroxenites enriched in PGEs is 1832 ± 35 Ma (εNd(T) = –2.0), while the age of magnetite ores is 1823 ± 19 Ma (εNd(T) = –2.5). Thus, the obtained isotopic data indicate that the emplacement of the Porya Guba complex and probably other small mafic–ultramafic intrusions in the Kolvitsa mélange granulites took place after the end of the Lapland–Kola collision. Full article
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31 pages, 7774 KiB  
Article
Monchegorsk Mafic–Ultramafic Layered PGE-Bearing Complex (2.5 Ga, Kola Region, Russia): On the Problem of Relationships between Magmatic Phases Based on the Study of Cr-Spinels
by Pavel Pripachkin, Tatiana Rundkvist, Artem Mokrushin and Aiya Bazai
Minerals 2024, 14(9), 856; https://doi.org/10.3390/min14090856 - 24 Aug 2024
Viewed by 928
Abstract
The composition of Cr-spinels from rocks of the Monchegorsk layered complex (2.5 Ga) basically corresponds to the evolutionary trend that is typical for layered mafic–ultramafic intrusions (late magmatic phases contain Cr-spinels enriched in Fe and depleted in Mg, Cr, and Al). Cr-spinels within [...] Read more.
The composition of Cr-spinels from rocks of the Monchegorsk layered complex (2.5 Ga) basically corresponds to the evolutionary trend that is typical for layered mafic–ultramafic intrusions (late magmatic phases contain Cr-spinels enriched in Fe and depleted in Mg, Cr, and Al). Cr-spinels within the Dunite Body of the Sopcha massif are almost identical to those within the Dunite Block rocks and are close to those from harzburgite of the NKT massif. Cr-spinels within the satellite bodies of the Ore Layer 330 are shown to have zonal structure, which confirms their origin from a new portion of melt, which may have been injected with several pulses. The composition of accessory Cr-spinels may indicate that the layered complex of rocks of the South Sopcha massif was formed from the most evolved portion of magmatic melt (linked with the Monchetundra intrusion), and its vein complex may be considered the one formed at the final stages of the magmatic system evolution. The composition of Cr-spinels from the Pentlandite Gorge mafic–ultramafic rocks may indicate that they are fragments of the NKT massif and not of the Monchetundra massif, as it was believed earlier. Full article
(This article belongs to the Section Mineral Deposits)
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15 pages, 4363 KiB  
Article
Characteristics and Deep Mineralization Prediction of the Langmuri Copper–Nickel Sulfide Deposit in the Eastern Kunlun Orogenic Belt, China
by Cai Ma, Baochun Li, Jie Li, Peng Wang, Ji’en Dong, Zhaoyu Cui and Shunlong Yang
Minerals 2024, 14(8), 786; https://doi.org/10.3390/min14080786 - 31 Jul 2024
Cited by 1 | Viewed by 1263
Abstract
The discovery of a Cu-Ni sulfide deposit in Langmuri of the Eastern Kunlun Orogenic Belt holds significant geological implications. This study, based on the examination of the metallogenic geological body, metallogenic structure, and metallogenic process characteristics, suggests that the deposit is a magmatic [...] Read more.
The discovery of a Cu-Ni sulfide deposit in Langmuri of the Eastern Kunlun Orogenic Belt holds significant geological implications. This study, based on the examination of the metallogenic geological body, metallogenic structure, and metallogenic process characteristics, suggests that the deposit is a magmatic Cu-Ni sulfide deposit formed in the collision of orogenic and post-extension processes of the Late Ordovician. The early mineralization of the deposit was primarily derived from the differentiation of sulfides in the mafic–ultramafic rock (450–439 Ma) of the Late Ordovician, while the late-stage mineralization underwent significant superimposed modification by the magmatic–hydrothermal activity of crustal-contaminated biotite granite (415 Ma). In addition, this article analyzes the measurements of the geochemical studies of sediments, and the magnetic and gravity measurements carried out in the area, focusing on the geochemical and geophysical anomaly characteristics in the study area, and selects favorable exploration areas, which have been confirmed to have multiple mineral bodies. By integrating comprehensive gravity, magnetic, induced polarization, and audio-frequency magnetotelluric profile measurements, this study analyzes delineated mineralized zones and the deep extensions of surface mineral bodies to assess deep mineralization potential and identify deep ore-finding targets. It suggests that diverse and scattered mafic–ultramafic complexes in the Langmuri mining area have a large-scale distribution of ore-bearing rocks in the deep. Through the analysis and inverse of the geophysical data, a deep mineralization predictive model was established in the basic–ultrabasic rock mass. The study presents prospects for the delineation of the deep-seated mineralization in the Langmuri deposit. Full article
(This article belongs to the Special Issue Geoelectricity and Electrical Methods in Mineral Exploration)
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19 pages, 19576 KiB  
Article
The Tectonic Framework of Parecis Basin: Insights from a Multiphysics Interpretation Workflow
by Elaine M. L. Loureiro, Paulo T. L. Menezes, Pedro V. Zalán and Monica Heilbron
Minerals 2024, 14(8), 783; https://doi.org/10.3390/min14080783 - 31 Jul 2024
Cited by 1 | Viewed by 1598
Abstract
The Parecis Basin, one of Brazil’s most extensive intracratonic basins, holds significant potential for hydrocarbon exploration. Despite its vast size, Parecis has yet to be extensively explored, with only five wildcat wells drilled. So far, no commercial discoveries have been announced. Regional studies [...] Read more.
The Parecis Basin, one of Brazil’s most extensive intracratonic basins, holds significant potential for hydrocarbon exploration. Despite its vast size, Parecis has yet to be extensively explored, with only five wildcat wells drilled. So far, no commercial discoveries have been announced. Regional studies have suggested Paleozoic sedimentation, while recent analyses have revealed a Neoproterozoic infill. Its tectonic model is still a matter of debate, and to date, no detailed structural map for the whole basin has been published. The present work proposes a new detailed structural map of the Parecis Basin based on a four-step interpretation workflow integrating seismic and gravimetric data. The first step includes converting the public 2D seismic lines to the depth domain. The second step is estimating the residual Bouguer anomaly, where the computed residual anomalies should relate to the basin’s tectonic features. The third step comprises the 2D forward modeling of the gravimetric anomalies using the 2D seismic interpretation as a constraint. The final step compiled all the interpreted features into our new structural map. This map reveals the top of the basement, forming a complex framework of horsts and grabens. Normal faults define the main structural style in the basin. Further, we could recognize thick, high-density bodies embedded in the crystalline basement. These bodies consist of Orosian–Calimian (1.8–1.6 Ga) mafic and ultramafic rocks, which may be a potential source for hydrogen exploration in the basin. Subsequent geophysical and geochemical surveys will assess the hydrogen potential in the area. Full article
(This article belongs to the Section Mineral Exploration Methods and Applications)
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15 pages, 6811 KiB  
Article
Petrogenesis of the Dalaku’an Mafic–Ultramafic Intrusion in the East Kunlun, Xinjiang: Constraints from the Mineralogy of Amphiboles
by Yazhou Fan, Yali Deng, Zhaode Xia, Minghao Ren and Jianhan Huang
Minerals 2024, 14(7), 651; https://doi.org/10.3390/min14070651 - 26 Jun 2024
Cited by 1 | Viewed by 1940
Abstract
The Dalaku’an mafic–ultramafic intrusion, located in the western segment of the East Kunlun, presents conducive conditions for the magmatic Cu-Ni sulfide deposits. According to the detailed petrographic observation, the amphiboles within distinct rock types were analyzed by EPMA analysis. The crystallization conditions, such [...] Read more.
The Dalaku’an mafic–ultramafic intrusion, located in the western segment of the East Kunlun, presents conducive conditions for the magmatic Cu-Ni sulfide deposits. According to the detailed petrographic observation, the amphiboles within distinct rock types were analyzed by EPMA analysis. The crystallization conditions, such as temperature, pressure, oxygen fugacity, and water content of the magma, were calculated to explore the genesis of the intrusion. The amphiboles were divided into three types: Amp-I, characterized by low silicon content but enrichment of aluminum, titanium, and alkali, predominantly comprising Tschermakitic hornblende and Magnesio-hornblende with mantle-derived traits; Amp-II, exhibiting elevated silicon content but diminished levels of aluminum, titanium, and alkali, primarily constituted of Magnesio-hornblende; whereas Amp-III manifests as Actinolitic hornblende, indicative of crustal origins. The calculated temperatures of amphiboles ranged between Amp-I (955–880) °C, Amp-II (852–774) °C, and Amp-III (761–760) °C; the pressures ranged between Amp-I (454–274) MPa, Amp-II (194–93) MPa, and Amp-III (101–84) MPa; the oxygen fugacities (△NNO) ranged between Amp-I (0.93–2.17), Amp-II (1.55–2.52), and Amp-III (1.89); and the water contents (H2Omelt) ranged from (6.69–8.67) to (5.90–7.32). The magma experienced multiple stages of crystallization and underwent complex magma evolution at different depths. The high oxygen fugacity and water content could be attributed to the subduction of the oceanic crust. The magma source of the Dalaku’an intrusion was metasomatized by fluids from subducting plates, thereby originating within a post-collision extension. Full article
(This article belongs to the Special Issue Using Mineral Chemistry to Characterize Ore-Forming Processes)
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17 pages, 78887 KiB  
Article
Amphibole Group Minerals in the Ozren Massif Ophiolites of Bosnia and Herzegovina as Petrogenetic Indicators
by Samir Ustalić, Ondrej Nemec, Stanislava Milovská, Marián Putiš, Elvir Babajić, Sergii Kurylo and Peter Ružička
Minerals 2024, 14(3), 239; https://doi.org/10.3390/min14030239 - 26 Feb 2024
Cited by 2 | Viewed by 1975
Abstract
The Ozren ophiolite complex (OOC) of the Dinaridic Ophiolite Belt is one of the six ophiolite complexes in Bosnia and Herzegovina. This paper deals with the mineral chemistry of amphiboles determined by electron probe micro-analysis and micro-Raman spectroscopy. The detected amphibole generations and [...] Read more.
The Ozren ophiolite complex (OOC) of the Dinaridic Ophiolite Belt is one of the six ophiolite complexes in Bosnia and Herzegovina. This paper deals with the mineral chemistry of amphiboles determined by electron probe micro-analysis and micro-Raman spectroscopy. The detected amphibole generations and types in mafic, ultramafic, and metamorphic rocks suggest a polystage evolution and are therefore useful petrogenetic indicators of the investigated OOC. Most gabbroic rocks and dolerites contain primary magmatic amphibole1 (magnesio-hornblende to pargasite, occasionally hastingsite) and prismatic to needle-like aggregates of late magmatic amphibole2 (magnesio-hornblende), while plagiogranite contains ferri-winchite and ferro-ferri-winchite as primary magmatic amphibole. Post-magmatic amphiboles were detected in dolerites, troctolites, and lesser in peridotites. The Na-(Ti)-rich amphibole3 (ferri-winchite and ferro-ferri-winchite to katophorite and ferri-katophorite) with amphibole4 (grunerite) rim formed along the grain boundaries of clinopyroxene, amphibole1, and plagioclase in dolerites. A part of these amphiboles grows into amphibole1, 2. Kaersutite to ferri-kaersutite, associated with phlogopite, occur in troctolites and dunites, while Mhbl was detected in harzburgite. The ultramafic rocks (lherzolites, harzburgites, and dunites) and the gabbroic layer are crosscut by clinopyroxene–plagioclase gabbroic and clinopyroxene–plagioclase–amphibole gabbro–dolerite dykes, suggesting ‘dry’ and ‘hydrated’ percolating melts generated in inferred subridge and supra-subduction settings, respectively. The amphibole3 and 4 in gabbros and dolerites and similar amphibole types in ultramafic rocks could be related to inferred arc-type basaltic and plagiogranitic percolating melts and fluids. Low-Al amphibole5 (tremolite and actinolite) and associated chlorite, albite, and clinozoisite represent the ocean-floor alterations in mafic rocks. Amphibole6 (magnesio-hornblende to pargasite) was identified in metamorphic sole amphibolites. Micro-Raman spectroscopy provided typical Raman spectra for the studied amphiboles, highlighting distinct features such as bands related to CMg content, CFe3+ presence, TO4 ring-breathing mode, TiO6 stretching mode, presence > 0.3 apfu of CTi, and TO4 stretching indicating CFe2+ in the structure. Applied amphibole geothermobarometry revealed the formation P–T conditions of amphibole (Amp)1 (avg. 863 °C at 0.23 GPa), Amp2 (avg. 747 °C at 0.17 GPa), Amp in the mantle rocks (avg. 853 °C at 0.64 GPa), Amp5 (avg. 349 °C at 0.03 GPa), and Amp6 (avg. 694 °C at 0.46 GPa). Full article
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38 pages, 13006 KiB  
Review
Wrapping a Craton: A Review of Neoproterozoic Fold Belts Surrounding the São Francisco Craton, Eastern Brazil
by Alexandre Uhlein, Gabriel Jubé Uhlein, Fabrício de Andrade Caxito and Samuel Amaral Moura
Minerals 2024, 14(1), 43; https://doi.org/10.3390/min14010043 - 29 Dec 2023
Cited by 3 | Viewed by 3770
Abstract
A synthesis of the evolution of the Neoproterozoic belts or orogens surrounding the São Francisco craton (SFC) in northeastern and southeastern Brazil is presented. Emphasis is placed on recognizing the superposition of sedimentary basins, from rift to passive margin to retroarc and foreland, [...] Read more.
A synthesis of the evolution of the Neoproterozoic belts or orogens surrounding the São Francisco craton (SFC) in northeastern and southeastern Brazil is presented. Emphasis is placed on recognizing the superposition of sedimentary basins, from rift to passive margin to retroarc and foreland, as well as identifying three diachronic continental collisions in the formation of the SFC. The Tonian passive margin occurs in the southern Brasília Belt with the Vazante, Canastra, and Araxá Groups. During the Tonian, island magmatic arcs and basins developed in front and behind these arcs (fore- and back-arcs). Subsequently, in the Cryogenian–Ediacaran, a retroarc foreland basin developed with part of the Araxá Group and the Ibiá Group, and finally, a foreland basin developed, which was filled by the Bambuí Group. A tectonic structure of superimposed nappes, with subhorizontal S1–2 foliation, formed between 650 and 610 Ma, is striking. In the northern Brasília Belt, there is the Stenian passive margin of the Paranoá Group, the Tonian intrusion of the Mafic–Ultramafic Complexes, and the Mara Rosa Island magmatic arc, active since the Tonian, with limited volcanic–sedimentary basins associated with the arc. A thrust–fold belt structure is prominent, with S1 foliation and late transcurrent, transpressive tectonics characterized by the Transbrasiliano (TB) lineament. The Cryogenian–Ediacaran collision between the Paranapanema and São Francisco cratons is the first collisional orogenic event to the west. In the Rio Preto belt, on the northwestern margin of the São Francisco craton, the Cryogenian–Ediacaran Canabravinha rift basin is prominent, with gravitational sediments that represent the intracontinental termination of the passive margin that occurs further northeast. The rift basin was intensely deformed at the Ediacaran–Cambrian boundary, as was the Bambuí Group. On the northern and northeastern margins of the São Francisco craton, the Riacho do Pontal and Sergipano orogens stand out, showing a comparable evolution with Tonian and Cryogenian rifts (Brejo Seco, Miaba, and Canindé); Cryogenian–Ediacaran passive margin, where the Monte Orebe ophiolite is located; and Cordilleran magmatic arcs, which developed between 620 and 610 Ma. In the Sergipano fold belt, with a better-preserved outer domain, gravitational sedimentation occurs with glacial influence. A continental collision between the SFC and the PEAL (Pernambuco-Alagoas Massif) occurred between 610 and 540 Ma, with intense deformation of nappes and thrusts, with vergence to the south and accommodation by dextral transcurrent shear zones, such as the Pernambuco Lineament (PE). The Araçuaí belt or orogen was formed at the southeastern limit of the SFC by a Tonian intracontinental rift, later superimposed by a Cryogenian–Ediacaran rift–passive margin of the Macaúbas Group, with gravitational sedimentation and glacial influence, and distally by oceanic crust. It is overlain by a retroarc basin with syn-orogenic sedimentation of the Salinas Formation, partly derived from the Rio Doce cordilleran magmatic arc and associated basins, such as the Rio Doce and Nova Venécia Groups. A third continental collision event (SF and Congo cratons), at the end of the Ediacaran (580–530 Ma), developed a thrust–fold belt that deforms the sediments of the Araçuaí Belt and penetrates the Paramirim Corridor, transitioning to the south to a dextral strike-slip shear zone that characterizes the Ribeira Belt. Full article
(This article belongs to the Special Issue Geological Evolution of South American Cratons)
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29 pages, 58610 KiB  
Article
Geospatial Insights into Ophiolitic Complexes in the Cimmerian Realm of the Afghan Central Block (Middle Afghanistan)
by Hemayatullah Ahmadi, Mohammad Reza Hussaini, Atal Yousufi, Alma Bekbotayeva, Akmaral Baisalova, Bakytzhan Amralinova, Indira Mataibayeva, Abdul Baqi Rahmani, Emrah Pekkan and Naqibullah Sahak
Minerals 2023, 13(11), 1453; https://doi.org/10.3390/min13111453 - 18 Nov 2023
Cited by 3 | Viewed by 3275
Abstract
Ophiolites are remnants of oceanic crust that have been thrust onto continental crust due to tectonic processes. They are composed of mostly mafic and ultramafic rocks, which are genetically associated with gold, silver, platinum group element (PGE), chrome, manganese, titanium, cobalt, copper, and [...] Read more.
Ophiolites are remnants of oceanic crust that have been thrust onto continental crust due to tectonic processes. They are composed of mostly mafic and ultramafic rocks, which are genetically associated with gold, silver, platinum group element (PGE), chrome, manganese, titanium, cobalt, copper, and nickel deposits. The main objective of this research was to identify the spatial distribution of Mesozoic ophiolitic complexes within the Central Afghan Block in Middle Afghanistan using optical remote sensing data and spectral analyses. Distinct algorithms, such as false color composite (FCC), proposed band ratios (PBR), principal component analysis (PCA), and spectral angle mapper (SAM), were used to map the targeted ophiolitic complexes. New band ratios were proposed in this study based on the spectral properties of mafic-ultramafic minerals and rocks, which showed high efficiency. Based on the results, four different ophiolitic complexes were delineated within this study area. These complexes are consistent with previous studies. The accuracy assessment of this study showed an overall accuracy of 72.2%. The findings of this study can significantly contribute to further studies on the emplacement mechanism and paleo-Tethys history of Middle Afghanistan. Also, the spatial distribution of the ophiolitic complexes identified in this study can be used to constrain models of the tectonic evolution of the Central Afghan Block. Additionally, the identification of new band ratios for mapping ophiolitic complexes can be used in future studies of other ophiolite-bearing regions. Full article
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