Search Results (1,852)

Lubricant additives play a crucial role in improving the tribological performance of lubricating oils to reduce frictional energy losses and improve the durability and reliability of mechanical systems. In this study, soft metallic-based core–shell Ag@Cu microparticles were synthesized via an in-situ galvanic displacement method and incorporated into EHC-50 base oil with various concentrations. The tribological performance evaluations indicated that 0.3 wt% Ag@Cu significantly enhanced friction-reducing and anti-wear properties, achieving a stable friction coefficient of 0.12, a 45% reduction, and a wear volume reduction of 75% compared to the pristine oil. Additionally, the surface characterization techniques (SEM/EDS, XPS, XRD, and TOF-SIMS) were employed to explore the wear patterns and related lubrication mechanisms. The results indicated that the synergistic interaction between the micro-bearing effect, physical mending, and tribochemical reactions facilitated the formation of a robust tribofilm composed of metallic Ag, ternary CuFe₃O₂, and sulfides, which achieved higher lubrication performance. Ultimately, this research provides novel metallic micro-additives, offering a facile approach to formulating wear-resistant lubricants with significant potential for saving energy for mechanical tribosystems in industrial applications. Full article

To elucidate the role of environmentally friendly oxide additives in a molybdenum disulfide (MoS₂)-based solid lubricant, this study investigates the tribological behavior of a MoS₂–TiO₂ coating deposited via a spray-bonding process and compares it with a commercial Sb₂O₃-containing formulation (Everlube 620C). Interfacial characteristics and wear-related mechanisms were systematically analyzed using scanning electron microscopy (SEM), focused ion beam (FIB), Raman spectroscopy, and X-ray diffraction (XRD). The MoS₂–TiO₂ coating exhibited a higher steady-state coefficient of friction (0.35–0.45) and wear compared to the baseline. Its wear behavior was governed by fracture-induced three-body abrasion, driven by the hard and brittle nature of TiO₂, which promotes stress concentration at particle–matrix interfaces, crack initiation, particle pull-out, and debris generation. These processes suppress the formation of a desirable MoS₂-rich tribo/transfer film, leading to deformation-dominated friction. Overall, the findings indicate that the intrinsic mechanical properties and interfacial behavior of TiO₂ limit its effectiveness as an additive in MoS₂-based coatings, highlighting the importance of additive selection and compatibility in achieving optimal tribological performance. Notably, this study was performed at an additive volume fraction equivalent to that of Sb₂O₃ in Everlube 620C, serving as a foundation and indicating that further optimization of TiO₂ particle size and concentration is required to achieve comparable performance. Full article

Oxidative stress appears to be implicated in both the initiation and progression of autoimmune thyroiditis. Selenomethionine, which exhibits antioxidant properties, has been shown to reduce thyroid antibody titers in patients with autoimmune thyroiditis. Recent evidence suggests that vitamin E, a fat-soluble antioxidant, may protect against the development of autoimmune thyroiditis, and that its supplementation has been associated with improvements in female sexual function. The objective of the present pilot study was to determine whether vitamin E intake modulates the effects of selenomethionine on female sexual function and depressive symptoms in individuals with thyroid autoimmunity. The study enrolled three groups of reproductive-age women with euthyroid autoimmune thyroiditis, with 26 participants in each group. The groups were matched for age, thyroid peroxidase antibody titers, and TSH levels and differed according to vitamin E intake: adequate intake (group A), low intake (group B), and high intake (group C). All participants received selenomethionine supplementation (200 µg/day) for six months. Antibody titers and hormone levels were measured, and participants completed questionnaires assessing female sexual function (FSFI) and depressive symptoms (BDI-II). At baseline, no differences in biochemical outcomes were observed between the groups, except for testosterone levels. The study groups differed in sexual desire and arousal domain scores, which were higher in group A than in the other two groups. Total FSFI scores, the remaining FSFI domain scores, and BDI-II scores did not differ between groups at baseline. Across all groups, selenomethionine reduced thyroid peroxidase and thyroglobulin antibody titers and increased SPINA-GD and the ratio of free triiodothyronine to free thyroxine; however, the effects on antibody titers were most pronounced in group A. An increase in SPINA-GT and testosterone levels following selenomethionine supplementation was observed only in group A. In this group, selenomethionine also led to significant improvements in total FSFI scores and all individual domain scores. In contrast, in the remaining groups, the effects of supplementation were limited to increases in domain scores for lubrication, sexual satisfaction, and pain. A treatment-related reduction in total BDI-II scores was observed exclusively in women with adequate vitamin E intake. These findings suggest, for the first time, that dietary intake of a natural antioxidant may influence the effects of exogenous selenomethionine on sexual function and depressive symptoms in reproductive-age women with euthyroid autoimmune thyroiditis. Full article

Cermet tools possess favorable mechanical and tribological properties and are widely adopted for machining hard-to-cut materials. However, their performance can further be enhanced with different cooling and lubrication techniques. In this study, the tool wear mechanisms of cermet tools during hard turning of AISI 4340 alloy steel are investigated under dry and minimum quantity lubrication (MQL) environments to identify the prevalent causes of tool failure through comprehensive analysis of tool wear progression, chip temperature, and chip morphological analysis. The results revealed that the application of MQL exhibited prolonged and stable steady-state tool wear progression with retained cutting-edge geometry, thus demonstrated 30.27% improvement in tool life compared to dry cutting. On the contrary, a rapid increase in tool wear due to excessive friction and higher thermal load is noticed with dry cutting in the absence of any heat-dissipating medium. Chip temperature measurements supported these observations, as chip temperature increases sharply from 358 °C (with a fresh tool) to about 1090 °C (with a worn tool) under a dry environment. Conversely, with MQL, the corresponding increase was in the range between 294 °C and 843 °C with a fresh and worn tool, respectively. Chip analysis revealed a serrated type of chip morphology. Dry cutting exhibited intensified feed marks, indicative of severe tool–chip friction, whereas MQL demonstrated smoother morphology with closely spaced saw-tooth patterns. Tool wear mechanisms indicate abrasion, adhesion, and edge chipping as dominant wear mechanisms under both environments; however, in the absence of any lubricant, these mechanisms were more intensified with higher crater formation. Full article

Modern agriculture depends heavily on machinery to maximize operational efficiency and, consequently, profitability, but the wear-and-tear on the mechanical components of machinery due to ageing can lead to reduced efficiency, more downtime, and higher maintenance expenses, thus raising the operative costs. These problems have been addressed by the use of specific lubricant additives for machinery; however, additives have known disadvantages, such as compatibility restrictions and environmental concerns, which represent critical issues especially in case of possible dispersion in the environment. Modern industry is always looking for techniques and solutions to increase efficiency and productivity, and this study investigates the possible advantages of employing nanotechnology in lubricant formulations. Amongst all possible substances, SiO₂ nanoparticles are increasingly promising as lubricant additives due to their unique properties, which include heat resistance, high levels of stability, and good biocompatibility. Moreover, biolubricants, derived from renewable sources, offer an environmentally friendly alternative to conventional lubricants. This article contributes to the field of agricultural technology by demonstrating the potential of SiO₂ nanoparticles in formulations of biolubricants thought to be used in agricultural machines. Key degradation parameters, including density, viscosity, total acid number (TAN), total base number (TBN), oxidation, and elemental composition, were systematically analysed. The results showed that SiO₂ nanoparticles mitigate viscosity loss and density increase, optimize TAN and TBN, reduce oxidation of the biolubricants by up to 17.7% at 1.00 wt% SiO₂, and stabilize elemental composition during ageing. Nanoparticles remained uniformly dispersed without sedimentation for over 30 days. This provides insights that can prevent machinery performance degradation over time, reduce lubricant changes, and suggest a more sustainable and environmentally friendly lubrication solution, thus promoting more sustainable industry. Full article

Cellulose ether, like hypromellose (HM), is an extremely versatile material that is widely used in pharmaceutical products as film coatings. To modify the surface properties of HM films, additives are routinely included during the film formulation process, which are typically hydrophobic lubricants or hydrophilic plasticizers. Plasticizers increase the flexibility and reduce the brittleness of the film. The first goal of this study is to demonstrate that plasticization of HM films by low-molecular-weight (400 g∙mol⁻¹) polyethylene glycol (PEG) allows tuning adhesion and friction properties of HM films, both at nano- and macroscales. Surface morphology, surface energy, nano/macro adhesion, and nano/macro friction coefficient were studied by atomic force microscopy (AFM) in adhesion or friction modes at the nanoscale, wettability, and probe-tack adhesion, as well as pin-on-disk friction experiments at the macroscale. The results show that the addition of PEG decreases the Young’s modulus and the Tg of HM-plasticized films while increasing their strain at break and surface energy. The macroadhesion force increases from 9 to 90 mN by the addition of 40% w/w of PEG, whereas the macrofriction coefficient is reduced by 50%. The hypothesis of insertion of plasticizer molecules in HM chains’ nano-domains is evidenced and explains these results. The second goal of this study is to investigate nanoscale versus macroscale correlation of adhesion and friction properties and the role of adhesion in friction experiments. The results show, first, that the evolution of the adhesion energy at the macroscale as a function of adhesion energy at the nanoscale is linear. On the contrary, a high friction coefficient at the nanoscale corresponds to a low friction coefficient at the macroscale and vice versa, showing a first linear decrease for PEG contents ranging from 0 to 30% (w/w) and the second linear decrease, less pronounced, is observed for PEG contents ranging from 30 to 40% (w/w). The hypothesis of a difference in contact pressure applied on the probe at both scales, as well as HM-PEG surface phase separation at a high PEG content (>30% w/w), is proposed to explain this difference. The variations in friction coefficients are linear according to the PEG plasticizer content and suggest its lubricant role in HM-Plasticized films. Finally, the interplay between adhesion and friction, in friction experiments, is evidenced and appears dominant at the nanoscale. Full article

The water-lubricated piston–cylinder pair is a critical tribological component in hydraulic systems, yet its performance under boundary lubrication is often limited by high friction and severe wear. Conventional epoxy coatings provide only modest improvements. In this study, graphene-modified epoxy composite coatings were developed and applied to piston substrates, then characterized via scanning electron microscopy, white light interferometry, and nanoindentation. Tribological performance was evaluated using a reciprocating tribometer under simulated pump conditions of 16 MPa and 1500 r/min. Compared to the pure epoxy coating, the graphene-modified coating reduced the friction coefficient by 33.9% and the wear rate by 77.2%, while the graphene oxide-modified coating reduced them by 16.1% and 64.5%, respectively. These results demonstrate that graphene-modified epoxy composite coatings offer an effective surface engineering solution for enhancing the durability and efficiency of water-lubricated systems, with promising potential for water hydraulic applications. Full article

The urgent global need for sustainable infrastructure drives the demand for high-value buildings and waste removal. This paper studies the feasibility of using recycled foam concrete aggregate (FCA) as a substitute for natural coarse aggregate (NCA) in concrete and studies its impact on rheology, mechanical degradation, shear resistance, and the full-range replacement ratio (0–100). The experimental results show that the monotonic change in the workability of fresh concrete determines the lubrication threshold at 60% replacement, which is driven by the volume proportion effect. Beyond this value, capillary suction dominates, and the viscosity rises rapidly. From a mechanical perspective, the porous structure of FCA is conducive to “internal curing” so that moisture is released from the drying interface, but it also becomes a source of defects that change the fault topology. Specifically, the critical transition of the shear failure mode shifts from the debonding of the interface to the crushing of the cross-particle aggregate. At this time, the shear capacity decreases substantially, experiencing a reduction of 71.8% when completely replaced. There is a strong correlation between ultrasonic pulse velocity (UPV), rebound number, and compressive strength, and a multivariate nonlinear regression model (R² > 0.85) with non-destructive strength prediction is ultimately obtained. Based on the balance between mechanical capacity and resource cyclability, an optimal alternative zone of 20% to 40% is proposed. This work not only provides a mechanism for multi-scale coupling between pore structure and structural properties but also provides a data-driven method for the safety assessment of lightweight recycled aggregate concrete (RAC). Full article

Supramolecular oleogel lubricants construct a three-dimensional network structure within base oils through gelator-mediated non-covalent interactions, such as hydrogen bonding, van der Waals forces, and π–π stacking. These materials demonstrate unique advantages in mitigating issues inherent to traditional lubricants, including leakage, volatility, creep, and poor heat dissipation. Focusing on structural design and performance regulation, this review systematically summarizes the current development of supramolecular oleogel lubricants in the fields of green lubrication, extreme operating conditions, and nanocomposite lubrication. Specifically, it outlines the structure-property relationships between gelators and base oils in green lubrication systems, and elucidates the applications in radiation-resistant, high-load-bearing, and intelligently responsive lubrication. Strategies for utilizing nanocomposite supramolecular oleogels to resolve nanomaterial dispersion challenges are discussed, and the latest advancements in engineering applications are illustrated. By summarizing the development of supramolecular oleogel materials, this work can provide theoretical references for the future design and preparation of these lubricants. Full article

PEEK coatings have been applied to sliding bearings in marine machinery and equipment, but their low bonding force, poor thermal conductivity and weak oleophilicity result in insufficient anti-adhesive wear performance. To solve this problem, the textured surface of the substrate was fabricated using laser texturing technology to enhance the bonding force. The PEEK coatings were reinforced by introducing oleophilic-modified nano-SiO₂ and graphene. The tribological properties of the PEEK composite coatings were studied using the ball–disc reciprocating friction wear test and Abaqus wear simulation. The results show that the texturing treatment of the substrate surface improves the bonding force of the coating. The addition of nano-SiO₂ and graphene enhances the hardness, thermal conductivity and oleophilicity of the composite coating, which shifts the wear mechanism from adhesive to abrasive. Under dry friction conditions, the composite coating containing 5 wt% SiO₂ and 1 wt% graphene exhibits a low friction coefficient and the lowest wear rate. Under oil lubrication conditions, the composite coating containing 2 wt% graphene shows the lowest friction coefficient and wear rate. In summary, under the load-bearing capacity enhancement of nano-SiO₂ and the thermal conductivity enhancement of graphene, the composite coating exhibits excellent anti-adhesive wear performance. Full article

The wear behavior of 3D-printed polylactic acid (PLA) components produced by fused filament fabrication and used as friction elements in aqueous environments was investigated. Despite the growing use of additively manufactured polymers in wet systems, their wear mechanisms under such conditions remain insufficiently understood. Tests were performed under a 29 N load and 30 rpm to simulate low-speed, moderately loaded applications. PolyTerra™ PLA parallelepiped and ring specimens were analyzed through gravimetric wear testing using a Baroid lubricity tester for 135 min. During the first 105 min, both geometries showed similar mass losses, with differences below 10%. In the final stage, the parallelepiped specimen exhibited accelerated wear, while the ring specimen gained mass due to material transfer. The electrical conductivity of the medium increased significantly, from 4.6 to 1846 µS/cm, and pH rose from 7.01 to 8.04. The recovered residue matched total mass loss, and FTIR analysis confirmed the presence of PLA structures, indicating mechanical wear as the dominant process. This study provides experimental insight into the tribological behavior of 3D-printed PLA in water-lubricated conditions. By combining mass loss evaluation and medium property analysis, it improves understanding of wear mechanisms and supports the reliable design of PLA components for aqueous applications. Full article

In response to the significant challenges posed by ice accumulation and contamination from various fluids in complex operating conditions for metallic materials, this study utilises picosecond laser precision machining to develop a ‘slippery surface’ featuring a micro-channel network structure. The core innovation of this study lies in the use of laser-machined micrometre-scale array textures to overcome the limitations of traditional isolated pores. These globally interconnected micro-channels serve as highly efficient reservoirs and dynamic transport channels for lubricants, significantly enhancing the interfacial capillary locking force of the lubricant. Experimental results demonstrate that this unique network geometry endows the surface with exceptional fluid replenishment and self-healing properties, enabling it to exhibit outstanding broad-spectrum hydrophobicity towards various fluids—including water, crude oil and ethanol (surface tension range: 17.9–72.0 mN m⁻¹)—with sliding angles consistently below 12°, whilst effectively slowing the dehydration and solidification processes of biological fluids. At a low temperature of −15 °C, the surface achieved an ice formation delay of up to 286 s, with an ice adhesion strength of only 33.9 kPa, ensuring that accumulated ice could be spontaneously detached under minimal external force. Furthermore, the micro-channel network structure serves as a key protective mechanism against mechanical wear, maintaining robust slippery properties even after three hours of high-pressure water jet scouring (Weber number of 300). This reliable interface, achieved through structural management, provides an efficient and scalable platform for addressing the all-weather anti-icing and antifouling requirements of outdoor infrastructure. Full article

This study aims to investigate the static performance of water-lubricated rubber bearings (WLRBs) with axial grooves. To achieve this objective, an analytical approach is employed that combines a modified Reynolds equation, accounting for surface groove effects and rubber deformation, with a Winkler model and finite element analysis of pressure distribution. By developing a fluid–structure interaction model that incorporates rubber liner deformation, this research reveals the interaction between WLRB geometry and steady-state performance parameters. The investigation evaluates the influence of geometric characteristics, including groove shape, number, and size, on the performance of elastomeric liner WLRBs, while assessing optimal groove depths under various conditions. The study analyzes five distinct groove geometries, including semi-cylindrical, rectangular prism, and three pyramidal types with different apex positions, in a six-groove bearing configuration, presenting their qualitative effects on the behavior of the examined bearings. The key findings indicate that increasing groove size or quantity reduces maximum pressure and load-carrying capacity while elevating friction coefficients. As groove count rises, supporting surfaces diminish, causing pressure distribution to intensify and minimum film thickness to decrease under a specified external load. A notable result reveals that when groove depth exceeds film thickness, performance becomes geometry-independent; however, shallower grooves exhibit significant geometric effects. Additionally, the study identifies groove ends as critical functional zones where film thickness reduction substantially enhances pressure distribution and static performance. Comparative analysis shows that longitudinal grooves with triangular cross sections outperform semi-circular and rectangular variants, with the backward triangular configuration demonstrating superior characteristics due to optimal end-film properties. In conclusion, this research provides a detailed understanding of how groove geometry influences the static performance of WLRBs, highlighting the importance of groove design, particularly at the groove ends, in optimizing bearing functionality. The findings offer valuable insights for the design and selection of groove configurations in water-lubricated rubber bearing applications. Full article

GH3039 nickel-based alloy, as a key material for thermocouple protection tubes, is susceptible to wear and oxidation failure in high-temperature kiln environment. To address this, boronized, chromized and borochromized coatings were prepared on GH3039 substrate, and the friction-wear properties and high-temperature oxidation resistance of both the substrate and the coatings were systematically characterized. The results show that the borochromized coating, benefiting from the synergistic effect of its relatively high surface hardness and the boric acid lubricating film formed during the wear process, reduces the wear rate by 84.07% (to 1.44 × 10⁻⁵ mm³·N⁻¹·m⁻¹). Meanwhile, it exhibits the optimal oxidation resistance due to its dense Cr-rich layer, which can inhibit oxygen diffusion and supply chromium for protective Cr₂O₃ film. After 100 h of oxidation at 950 °C, its oxidation weight gain is reduced by 78.68% compared with the boronized sample (to 1.20 mg/cm²). Full article

The compressor in automotive air-conditioning systems consumes a significant fraction of the vehicle’s energy, thereby reducing driving range. Consequently, developing more efficient compressor operation is essential for improving overall thermal management. Nano-enhanced lubricants have emerged as a promising passive strategy to reduce compressor power consumption, enhance thermodynamic performance, and improve tribological behavior by minimizing friction and wear. This review critically examines existing nano-lubricant research with a focus on automotive compressor and system-level performance, friction and wear reduction mechanisms, and the influence of nanoparticle type and concentration on lubricant thermo-physical properties. The analysis reveals that nano-lubricants consistently enhance compressor operation by lowering discharge temperature and reducing power consumption, while improving coefficient of performance and cooling capacity. However, these benefits have been validated primarily under cooling-mode conditions and predominantly for reciprocating-piston compressors. Tribological studies further demonstrate substantial reductions in coefficient of friction and surface roughness, with improved anti-wear characteristics compared to virgin lubricants. Four principal mechanisms—rolling, polishing, protective-film formation, and self-repairing—have been identified as contributors to these enhancements. Nevertheless, most tribological investigations rely on simplified test rigs that do not fully represent the complex contact, loading, and thermal environments inside actual automotive compressors. This review underscores the need for system-level, mechanism-driven, and compressor-architecture-specific investigations covering both cooling and heating modes of automotive air-conditioning operation. The insights presented aim to guide future development of reliable, durable, and refrigerant-compatible nano-lubricant technologies for next-generation automotive air-conditioning systems. Full article