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Keywords = low-temperature reservoirs

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20 pages, 36524 KB  
Article
Fluid Evolution of the Dajing Cu-Sn Polymetallic Deposit, Southern Great Xing’an Range: Constraints from Quartz Textures and Trace Elements
by Yanping He, Zhenjun Sun, Henan Yu, Yunsheng Ren, Zhenzhen Li, Mengfan Guan and Zhiwen Zheng
Minerals 2026, 16(9), 867; https://doi.org/10.3390/min16090867 - 25 Aug 2026
Abstract
The Dajing Cu-Sn polymetallic deposit, situated within the southern Great Xing’an Range of northern China, is a representative Mesozoic magmatic–hydrothermal system within a major Cu–Sn–Ag–Pb–Zn metallogenic belt. Located at the junction between the Siberian and North China plates, the deposit occurs within a [...] Read more.
The Dajing Cu-Sn polymetallic deposit, situated within the southern Great Xing’an Range of northern China, is a representative Mesozoic magmatic–hydrothermal system within a major Cu–Sn–Ag–Pb–Zn metallogenic belt. Located at the junction between the Siberian and North China plates, the deposit occurs within a composite tectonic domain overprinted by the Paleo-Asian, Mongol–Okhotsk, and Paleo-Pacific systems. Building on field geological constraints and detailed ore petrography, this study utilizes SEM–CL imaging and in situ LA–ICP–MS trace-element analysis of hydrothermal quartz to reconstruct the multistage physicochemical evolution and fluid dynamics of the ore-forming system. Three quartz generations record successive mineralization stages: early QI forms grain cores associated with Stage I cassiterite–arsenopyrite–quartz mineralization; main-stage QII crystallized during or shortly after Stage II chalcopyrite precipitation and exhibits well-developed oscillatory zoning; and late QIII occurs mainly as rim overgrowths and fracture fillings and postdates Stage III ore-mineral precipitation. Quartz is characteristically Ti-poor (4.7–22.8 ppm), and its trace-element systematics indicate a low- to intermediate-temperature hydrothermal signature and a granitic magmatic–hydrothermal affinity. Al, Li, Na, K, and Ge show coupled behavior consistent with heterovalent substitution and vary markedly among quartz generations, with CL-bright QIIa showing relatively higher Al, Ge, and Na relative to CL-dark QIIb, whereas QIII is generally characterized by lower Al, Li, and Ge. Localized anomalously high Cu and Sn values are mainly attributed to the co-ablation of fine-grained mineral inclusions, metal-rich fluid inclusions, or fracture-filling components. These features indicate a chemically heterogeneous fluid reservoir with inferred relatively acidic conditions during the initial Sn-mineralization stage. The fluid system subsequently experienced recurrent physicochemical fluctuations associated with pulsed fluid input during the principal Cu-mineralization stage. QIII records a trace element-depleted late-fluid system associated with the terminal pyrite–quartz stage. Late fluids migrated along earlier quartz boundaries and fractures and may have undergone further cooling and dilution through fluid mixing and/or water–rock interaction. Overall, the fluid system shows a progressive shift in inferred fluid chemistry, consistent with decreasing acidity during hydrothermal evolution. Full article
(This article belongs to the Section Mineral Deposits)
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24 pages, 9708 KB  
Article
Comparative Numerical Simulation on Heat Transfer Performance of CO2 and Water in Closed-Cycle Geothermal Development Systems
by Zhiyong Zhu, Heqing Lei, Zhiheng Li, Yonggang Yao, Shengyi Li, Jinhe Yang and Yuxiang Cheng
Energies 2026, 19(17), 3956; https://doi.org/10.3390/en19173956 - 23 Aug 2026
Viewed by 128
Abstract
Driven by China’s “Dual Carbon” strategy, medium-deep closed-loop geothermal energy has become a mainstream clean heating technology owing to the advantage of “heat extraction without groundwater production”. However, its large-scale application is restricted by low single-well heat output and an unclear matching mechanism [...] Read more.
Driven by China’s “Dual Carbon” strategy, medium-deep closed-loop geothermal energy has become a mainstream clean heating technology owing to the advantage of “heat extraction without groundwater production”. However, its large-scale application is restricted by low single-well heat output and an unclear matching mechanism between working fluids and wellbores. Taking sandstone geothermal reservoirs in Dezhou, Northwestern Shandong Depression, as the research object, a 3D coupled heat transfer model of the wellbore–reservoir was established via COMSOL Multiphysics. The heat transfer characteristics of water and CO2 under variable injection temperature, mass flow rate and wellbore layout were compared. The results show that: (1) injection temperature dominates the heat extraction performance of water, which matches branched wells and delays overall reservoir thermal depletion during long-term exploitation; (2) CO2 performance is highly sensitive to mass flow rate and suitable for connected wells, and an asymmetric geothermal field with “cooled injection zone and heated production zone” forms under a high flow rate; (3) limited by low specific heat capacity, CO2 delivers lower heat power at an identical flow rate, while equivalent heat yield can be achieved when its flow rate doubles that of water. This study clarifies matched development schemes for two working fluids and provides a theoretical reference for optimized exploitation of closed-loop geothermal systems in sandstone reservoirs in Northwestern Shandong. Full article
(This article belongs to the Special Issue Deep Geothermal Energy Development and Utilization)
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30 pages, 13098 KB  
Article
A Study on Seepage Pressure Forecasting for Concrete Dams Based on Multi-Scale Preprocessing and Dual-Model Integration
by Yutian Zhang, Tao Xu, Yantao Zhu, Shangfa Chen and Haoran Wang
Water 2026, 18(16), 2049; https://doi.org/10.3390/w18162049 - 20 Aug 2026
Viewed by 242
Abstract
Seepage pressure time series of concrete dams are governed by reservoir water level, rainfall, temperature and long-term aging effects, featured by strong nonstationarity and complex multi-scale fluctuations. Existing decomposition–ensemble methods ignore nonlinear coupling among scale components, suffering low prediction accuracy and poor physical [...] Read more.
Seepage pressure time series of concrete dams are governed by reservoir water level, rainfall, temperature and long-term aging effects, featured by strong nonstationarity and complex multi-scale fluctuations. Existing decomposition–ensemble methods ignore nonlinear coupling among scale components, suffering low prediction accuracy and poor physical interpretability. Current model fusion schemes fail to adapt to differentiated evolution mechanisms of frequency-varying seepage components and cannot fully mine implicit cross-scale nonlinear correlations. To overcome these drawbacks, this study proposes a concrete dam seepage pressure prediction approach integrating ensemble empirical mode decomposition, multi-scale preprocessing, and optimized dual-model selection combining ridge regression and Transformer–BiLSTM. Ensemble empirical mode decomposition adaptively denoises and decouples raw seepage series into high-, medium- and low-frequency IMFs according to oscillation cycles. A normalized Comprehensive Optimization Index is constructed to parallelly train ridge regression and Transformer–BiLSTM for each component and select the optimal submodel dynamically. A fully connected nonlinear fusion layer reconstructs multi-scale predictions to retain inherent component coupling features, replacing traditional simple linear superposition. Engineering cases verify that the proposed model efficiently captures periodic laws of key influencing factors, significantly boosting prediction accuracy and generalization capacity, thus possessing prominent theoretical and practical engineering application values. Full article
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15 pages, 11310 KB  
Article
Effects of Cyclic Confining Pressure and Temperature on Static and Dynamic Bulk Compressibility of Reservoir Sandstones
by Yuxiang Wang, Yang Wang, Junxing Ren, Xuguang Dong and Xiaoyang Wang
Geosciences 2026, 16(8), 340; https://doi.org/10.3390/geosciences16080340 - 19 Aug 2026
Viewed by 222
Abstract
Bulk compressibility of reservoir rocks can be characterized dynamically or statically, and both vary with burial depth due to increasing temperature and pressure. To quantify these effects, cyclic hydrostatic compression tests are conducted on two reservoir sandstones under confining pressure up to 50 [...] Read more.
Bulk compressibility of reservoir rocks can be characterized dynamically or statically, and both vary with burial depth due to increasing temperature and pressure. To quantify these effects, cyclic hydrostatic compression tests are conducted on two reservoir sandstones under confining pressure up to 50 MPa at three temperatures (30 °C, 70 °C, and 110 °C). Experimental results show that static bulk compressibility is consistently larger than dynamic values across all tested conditions. As confining pressure increases, static compressibility decreases more sharply than dynamic compressibility, leading to a gradual reduction in their discrepancy. In contrast, temperature exerts a weaker yet more complex influence. Elevated temperature increases dynamic bulk compressibility, but has opposite effects on static compressibility upon loading versus unloading: it reduces static compressibility upon hydrostatic loading but enhances it upon unloading. This complex temperature dependence is attributed to thermally induced stress, which resists hydrostatic compression during loading but assists decompression during unloading. The influence of thermal stress is more pronounced at low confining pressures. These findings highlight that temperature not only alters the magnitude of static compressibility but also introduces path-dependent asymmetry between loading and unloading, which has important implications for reservoir geomechanics, subsidence prediction, and production-induced compaction in high-temperature environments. Full article
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23 pages, 3853 KB  
Article
Deformation and Failure Mechanisms of Extra-Deep Carbonate Rocks Under In Situ Conditions: An Experimental Study
by Shiguo Wang, Yan Jin, Ping Zeng, Yunhu Lu, Yang Xia and Shiming Wei
Appl. Sci. 2026, 16(16), 8088; https://doi.org/10.3390/app16168088 - 13 Aug 2026
Viewed by 175
Abstract
The exploration of oil and gas resources is shifting toward ultra-deep and extra-deep reservoirs, including in the Tarim Basin, where various types of carbonate rocks are buried. Owing to the extreme burial depths, the mechanical behavior of these rocks under extra-deep conditions differs [...] Read more.
The exploration of oil and gas resources is shifting toward ultra-deep and extra-deep reservoirs, including in the Tarim Basin, where various types of carbonate rocks are buried. Owing to the extreme burial depths, the mechanical behavior of these rocks under extra-deep conditions differs significantly from that of shallow formations, making it essential to understand their mechanical responses. This study investigated the mechanical properties and failure modes of carbonate rocks, specifically dolomite, argillaceous limestone, and pure limestone. Samples from extra-deep formations were initially analyzed for mineral composition and microstructure, after which uniaxial and triaxial compression tests were conducted to evaluate strength, static elastic modulus, and axial strain at peak stress. The results indicate that dolomite exhibits the highest mechanical strength and stiffness among the three lithologies. Under conditions of a high confining pressure of 100 MPa and a temperature of 160 °C, its elastic modulus and triaxial compressive strength are 65.4 GPa and 611.2 MPa, respectively, compared with 52.8 GPa and 444.2 MPa for limestone. Strength increases with confining pressure for all lithologies, with dolomite showing the most pronounced strengthening response. Although elevated temperature reduces rock strength, its effect is weaker than that of confining pressure. The failure mode is strongly controlled by confining pressure. At low confining pressures, failure is dominated by localized shear bands and brittle fracturing, whereas increasing confining pressure promotes a transition toward quasi-brittle deformation or ductile plastic flow. Dolomite predominantly maintains a quasi-brittle failure mode, argillaceous limestone exhibits a clear brittle-to-ductile transition, and pure limestone shows the greatest tendency to develop ductile plastic flow under high confining pressure conditions. The results further demonstrate that mineral composition and microstructural characteristics play critical roles in controlling the deformation and failure mechanisms of carbonate rocks. High-calcite pure limestone can exhibit ductile-like deformation behavior due to cataclastic processes, allowing significant strain without localization failure. These insights enhance understanding of carbonate rock behavior under extra-deep formations, informing practical applications in geology science. Full article
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10 pages, 3876 KB  
Article
Dynamic Thermal Relaxation in Metallic Films
by Libin Wang, Dmitry Golubev, Yuri M. Galperin and Jukka P. Pekola
Entropy 2026, 28(8), 908; https://doi.org/10.3390/e28080908 - 13 Aug 2026
Viewed by 240
Abstract
The performance of low-temperature detectors utilizing thermal effects is determined by their energy relaxation properties. Usually, heat transport experiments in mesoscopic structures are carried out in the steady state, where temperature gradients do not change in time. Here, we present an experimental study [...] Read more.
The performance of low-temperature detectors utilizing thermal effects is determined by their energy relaxation properties. Usually, heat transport experiments in mesoscopic structures are carried out in the steady state, where temperature gradients do not change in time. Here, we present an experimental study of dynamic thermal relaxation in a mesoscopic system—thin metallic film. We find that thermal relaxation of hot electrons in copper and silver films is characterized by several time constants, and that the annealing of the films changes them. In most cases, two time constants are observed, and we can model the system by introducing an additional thermal reservoir coupled to the film electrons. We determine the specific heat of this reservoir and its coupling to the electrons. We suspect that multiscale thermal relaxation arises from the complicated morphology of the films, in which the electron–phonon coupling strength in grains with different orientations varies. Full article
(This article belongs to the Special Issue Quantum Thermodynamics in Action)
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39 pages, 13703 KB  
Article
Field-Scale Simulation of CO2 Water-Alternating-Gas Enhanced Oil Recovery in a Mature Waterflooded, Low-Permeability, and Highly Heterogeneous Reservoir
by Yong Liu, Xin Wang, Mingyang Dong and Wenjing Sun
Processes 2026, 14(16), 2585; https://doi.org/10.3390/pr14162585 - 13 Aug 2026
Viewed by 403
Abstract
Water flooding in low-permeability, highly heterogeneous reservoirs often causes a rapid increase in water cut and inefficient pressure maintenance because injected water preferentially flows through high-permeability channels. In this study, a field-scale compositional simulation model was established to evaluate CO2 water-alternating-gas (WAG) [...] Read more.
Water flooding in low-permeability, highly heterogeneous reservoirs often causes a rapid increase in water cut and inefficient pressure maintenance because injected water preferentially flows through high-permeability channels. In this study, a field-scale compositional simulation model was established to evaluate CO2 water-alternating-gas (WAG) enhanced oil recovery in a mature waterflooded reservoir in the Daqing Oilfield. The model was constrained by geological data, experimentally tuned pressure–volume–temperature (PVT) behavior, relative-permeability measurements, and slim-tube tests. The minimum miscibility pressure (MMP) of the CO2-oil system was estimated to be 19.8 MPa. An 187-month production history was matched using field oil rate, water production, water cut, and reservoir-pressure data. At the current development stage, the reservoir has an oil recovery of 23.6%, an average water cut of 61.34%, and an average reservoir pressure of approximately 6.9 MPa. A 30-year prediction was then performed to compare continued water flooding with several CO2-WAG development strategies. Sensitivity analyses were conducted for the pressure-restoration level, pre-injection fluid, well-pattern conversion, slug size, and gas/water slug-size ratio. Continued water flooding increased the final oil recovery to only 28.4% and resulted in a water cut of 92.8%. Sequential scenario screening identified a best-performing case among the tested scenarios, consisting of CO2 pre-injection to restore the average reservoir pressure to 11 MPa, conversion to a staggered line-drive well pattern, a slug size of 0.025 PV, and a gas/water slug-size ratio of 1:1. Under this sequentially selected case, the end-of-forecast oil recovery reached approximately 57.24%, which was the highest value among the cases evaluated in this study and was 28.84 percentage points higher than continued water flooding. The predicted recovery is conditional on the adopted geological, relative-permeability, EOS, and history-matching assumptions. Because the designed average reservoir pressure is below the measured MMP and local pressure above the MMP was not demonstrated, the modeled process is consistently interpreted as immiscible CO2-WAG. The predicted recovery improvement is interpreted as being associated with pressure support, gas-mobility control, improved sweep efficiency, and compositional CO2–oil interactions represented by the model, including CO2 dissolution, oil swelling, and viscosity reduction. The contribution of this work is a field-scale, experimentally constrained workflow for selecting CO2-WAG operating parameters in mature waterflooded low-permeability reservoirs; CO2 storage performance should be quantified separately in future work. This study provides an experimentally constrained and history-validated field-scale workflow for identifying a best-performing CO2-WAG operating case among the tested scenarios in mature waterflooded low-permeability reservoirs. Full article
(This article belongs to the Section Petroleum and Low-Carbon Energy Process Engineering)
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20 pages, 3600 KB  
Systematic Review
Chemical Forensics in Death Investigations: A Comprehensive Review of Stable Isotopes as Postmortem Biomarkers for Food Contamination Tracking
by Thokozani P. Mbonane
Chemistry 2026, 8(8), 111; https://doi.org/10.3390/chemistry8080111 - 13 Aug 2026
Viewed by 285
Abstract
Lethal foodborne illness outbreaks represent a critical intersection of public health surveillance, environmental health, and forensic toxicology. When acute gastrointestinal syndromes lead to sudden death, traditional postmortem investigation techniques are often hindered by tissue autolysis and the overgrowth of putrefactive microflora, which complicate [...] Read more.
Lethal foodborne illness outbreaks represent a critical intersection of public health surveillance, environmental health, and forensic toxicology. When acute gastrointestinal syndromes lead to sudden death, traditional postmortem investigation techniques are often hindered by tissue autolysis and the overgrowth of putrefactive microflora, which complicate conventional microbiological assays. This review establishes a comprehensive framework for chemical forensics by evaluating the utility of stable isotope analysis (SIA) as a supportive, probabilistic chemical proxy to complement traditional epidemiological investigations of postmortem food contamination sources. Following JBI scoping review guidelines and the PRISMA-ScR reporting framework, data from 42 peer-reviewed articles (2000–2026) were charted and synthesized to map natural isotopic variations (δ13C, δ15N, δ18O, δ2H and δ34S) across both forensic decedents and environmental reservoirs. The findings outline a structured, multi-tissue diagnostic cascade governed by biological metabolic turnover rates: unabsorbed gastric chyme provides a direct chemical match to contaminated source food items within a hyper-acute 0–6 h window; high-turnover visceral matrices (liver, blood plasma) shift to reflect acute exposure profiles within 1–7 days; and continuously fixed keratinized matrices (hair, nails) archive multi-month dietary and transcontinental transit histories. Furthermore, compound-specific isotope analysis (CSIA) of individual amino acids offers unprecedented structural resolution, utilizing the carbon discrimination metric (Δ13Cglu-phe) to differentiate pristine agricultural signatures from endogenous metabolic distortions while biochemically verifying pre-mortem physiological stress and hyper-catabolic muscle wasting. Taphonomic thresholds were explicitly defined, establishing that bulk visceral soft tissues remain isotopically stable (±0.3‰) for up to 48 h at room temperature (~21 °C) before microbially induced nitrogen enrichment (δ15N > +2.8‰) alters native profiles, whereas hair and nail keratin maintain absolute isotopic stability for over 180 days postmortem. When pristine multi-isotope signatures are coupled with mandatory chloroform–methanol lipid extraction and processed through spatial Bayesian assignment models, geographic provenance tracking via environmental isoscapes achieves a predictive accuracy of 97%. This review introduces a standardized environmental health protocol designed to harmonize field environmental sampling with medical autopsies. This protocol provides a legally robust strategy for investigating unresolved lethal foodborne illness case-outbreaks, particularly those involving pediatric mortalities linked to the consumption of counterfeit or fraudulent food products in low- and middle-income countries. Furthermore, it aims to strengthen national and municipal legal frameworks and international biosecurity enforcement. Full article
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22 pages, 5578 KB  
Article
Study on CO2 Foam Acid Phase Evolution and Diverting Acidizing Performance in Heterogeneous Carbonate Reservoirs
by Xiuhui Li, Yunjin Wang, Jiacheng Yin, Weibo Ni, Jia Liu, Mengyu Li, Qi Wu and Jiawei Li
Processes 2026, 14(16), 2562; https://doi.org/10.3390/pr14162562 - 11 Aug 2026
Viewed by 308
Abstract
A coupled numerical model was developed to investigate the phase evolution and diverting acidizing performance of CO2-foamed acid in heterogeneous carbonate reservoirs. The model integrates CO2 phase evolution, gas–liquid two-phase Darcy flow, acid–rock reactions, heat transfer, pore-structure evolution, and foam [...] Read more.
A coupled numerical model was developed to investigate the phase evolution and diverting acidizing performance of CO2-foamed acid in heterogeneous carbonate reservoirs. The model integrates CO2 phase evolution, gas–liquid two-phase Darcy flow, acid–rock reactions, heat transfer, pore-structure evolution, and foam mobility control. By dynamically updating CO2 thermophysical properties in response to local temperature and pressure variations, the model captures the coupled effects of phase behavior on foam quality, apparent viscosity, flow resistance, and acid redistribution between high- and low-permeability layers. The effects of reservoir temperature, foam quality, and permeability contrast on wormhole propagation, foam distribution, and stimulation depth in the low-permeability layer were systematically evaluated. Under the simulated conditions, low-permeability-layer stimulation initially increased with reservoir temperature, reached its maximum near 393 K, and declined at 413 K. This non-monotonic behavior reflects the balance among CO2 phase behavior, foam stability, and acid–rock reaction rate: moderate temperatures promote the formation of a favorable foam region and effective diversion, whereas excessive temperatures weaken foam stability and accelerate acid consumption near the wellbore. Foam quality also exhibited a non-monotonic influence on diversion performance. Foam qualities of 60–80% provided strong mobility control and effective acid redistribution, while a foam quality of 90% restricted liquid-acid transport because of excessive near-wellbore foam accumulation. In contrast, the pure-acid system preferentially entered the high-permeability layer and broke through at approximately 0.3 PV. Increasing permeability contrast weakened foam retention and intensified preferential channeling; at a permeability contrast of 8, the wormhole length in the low-permeability layer was less than 50% of that obtained at a contrast of 4. These results demonstrate that phase-dependent foam resistance can redirect acid from preferential high-permeability channels toward low-permeability regions. This study defines an effective operating window for CO2-foamed-acid diversion and provides a theoretical basis for designing diverting acidizing treatments in heterogeneous, high-temperature carbonate reservoirs. Full article
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16 pages, 9080 KB  
Article
Experimental Investigation of Oxygen-Reduced Air Injection Mechanisms for Enhanced Oil Recovery
by Cheng Yang, Shu Jiang, Zhengbin Wu, Huasong Rui, Huiyu Zhang, Yao Liu and Hongmin Wang
Energies 2026, 19(16), 3725; https://doi.org/10.3390/en19163725 - 8 Aug 2026
Viewed by 203
Abstract
This study investigates the mechanisms and performance of oxygen-reduced air flooding (ORAF) and oxygen-reduced air gravity drainage (ORAGF) through laboratory experiments on crude oil and cores from the Kunbei Oilfield. PVT experiments show that injecting N2 or oxygen-reduced air (5% and 10% [...] Read more.
This study investigates the mechanisms and performance of oxygen-reduced air flooding (ORAF) and oxygen-reduced air gravity drainage (ORAGF) through laboratory experiments on crude oil and cores from the Kunbei Oilfield. PVT experiments show that injecting N2 or oxygen-reduced air (5% and 10% O2) increases saturation pressure and reduces oil viscosity comparably. Low-temperature oxidation (LTO) tests reveal that oxygen consumption rate declines exponentially with decreasing initial O2 concentration; at 5% O2, oxidation products are nearly indistinguishable from the original crude oil. Long-core displacement experiments demonstrate that vertical (gravity-assisted) injection significantly outperforms horizontal injection, with oil recovery reaching 39.8% (10% O2) versus 26.2% horizontally, owing to gravity segregation suppressing gas fingering and enhancing oil–gas contact. Among injection strategies, gas-assisted gravity drainage (GAGD) and water-alternating-gas (WAG) improve recovery by 7.7% and 7.2% over continuous waterflooding, respectively, with GAGD being more suitable for high water cut reservoirs. Reservoir rhythm and permeability contrast affect performance and gravity-driven injection mobilizes low-permeability layers more effectively than horizontal injection, exhibiting good adaptability to heterogeneous reservoirs. Fracture orientation relative to injection direction plays a critical role—horizontal fractures achieve the highest recovery (~50%), whereas through-going fractures impair performance. These findings provide experimental guidance for optimizing oxygen-reduced air gravity flooding in tight and heterogeneous oil reservoirs. Full article
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31 pages, 39361 KB  
Article
Application of Microbial Cold Recovery Technology in Shallow Low-Temperature High-Viscosity In Situ Oil Sands: A Case Study of the Upper Cretaceous Oil Sands in the Central–Southern Part of the Western Slope of the Songliao Basin
by Lihua Tong, Yaohua Li, Jie Li, Yantong Liu, Lei Shi, Caiqin Bi, Wenjie Xia, Yinbo Xu, Yuan Yuan and Yue Tang
Processes 2026, 14(15), 2517; https://doi.org/10.3390/pr14152517 - 5 Aug 2026
Viewed by 425
Abstract
The Cretaceous shallow oil sands in the Dagang area, located on the western slope of the Songliao Basin, are characterized by a burial depth of ≤182 m, an average reservoir temperature of 11.8 °C, an extremely high crude oil viscosity of 1,750,000 mPa·s [...] Read more.
The Cretaceous shallow oil sands in the Dagang area, located on the western slope of the Songliao Basin, are characterized by a burial depth of ≤182 m, an average reservoir temperature of 11.8 °C, an extremely high crude oil viscosity of 1,750,000 mPa·s at 15 °C, and water-bearing layers in both the roof and floor. Conventional thermal recovery methods such as SAGD and CSS are geologically unsuitable for this deposit and suffer from high energy consumption and carbon emissions. As microbial oil recovery is a technically advanced enhanced oil recovery technology that leverages microbial growth, reproduction and metabolism in the reservoir to alter the properties of oil, rock, gas and water through interaction with these components, and petroleum biotechnology research confirms that microorganisms can degrade high-molecular-weight petroleum hydrocarbons to reduce crude oil viscosity and improve its fluidity, this study explores the technical feasibility of microbial cold recovery for in situ extraction of such low-temperature, high-viscosity oil sands. The study adopts a five-well pilot pattern (one injector and four producers) with an integrated approach combining reservoir unblocking, microbial viscosity reduction, and vibration-assisted production. Systematic screening identified Pseudomonas, Chryseobacterium, and Citrobacter as the most efficient indigenous microbial strains. Pseudomonas exhibited a crude oil degradation rate of 32.17%, reducing asphaltene content from 7.47% to 3.56%, and achieved large-scale proliferation (2.5 × 108 cfu/mL) at 15 °C. It also achieved a 40.8% reduction in crude oil viscosity and a desulfurization rate, alongside 56.6% denitrification. With the optimal activator No. 3, the viscosity reduction rate reached 45.18%, and the viable cell count exceeded 9.45 × 108 cfu/mL. The synergistic action of Pseudomonas and an A-type nano-microemulsion surfactant reduced the oil–water interfacial tension from 49.56 to 1.25 mN/m (a 97.48% reduction) and lowered the crude oil viscosity at 25 °C from 302,000 to 11,023 mPa·s (a 96.35% reduction). Core flooding tests demonstrated an incremental oil recovery of 7.38% compared with the water-flooded control, with interfacial tension dropping from 48.21 to 1.18 mN/m. In the field trial, composite perforation (32 shots/m, 1610 mm penetration) and two cycles of oil-based fermentation fluid huff-n-puff reduced injection pressure from 2.0 to 2.5 MPa to 1.0–1.8 MPa. A total of 1489 m3 of microbial agent was injected into five wells, followed by a 125-day shut-in period. Nano-microemulsion single-well huff-n-puff (579 m3 over 87 days) further decreased injection pressure to 0 MPa. A downhole harmonic vibration source (≤20 Hz) was also applied during the trial. During the production phase, Pseudomonas was found to dominate the produced fluid, with its peak relative abundance exceeding 70%. Cumulative fluid production reached 4114 m3, yielding 21 m3 of oil sand oil. Wells with vibration assistance showed significantly higher oil content and better emulsification performance than wells without vibration assistance. Full article
(This article belongs to the Special Issue Advances in Heavy Oil Reservoir Development)
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21 pages, 2990 KB  
Article
Fabrication and Performance Evaluation of Multi-Stimuli-Responsive Hydrogels Constructed from Hyperbranched Skeletons
by Xue Wang, Jun Wang, Gen Li, Yang Zhao, Zhihua Guo and Keliang Wang
Gels 2026, 12(8), 694; https://doi.org/10.3390/gels12080694 - 4 Aug 2026
Viewed by 286
Abstract
Long-lasting, high-strength plugging materials are required for deep profile control in low-permeability fractured reservoirs. In this study, a series of hyperbranched copolymer hydrogels was prepared through an aza-Michael addition-amidation-one-pot end-group coupling strategy. Linear alkylamines were used as cores to synthesize amino-terminated generation 1.0 [...] Read more.
Long-lasting, high-strength plugging materials are required for deep profile control in low-permeability fractured reservoirs. In this study, a series of hyperbranched copolymer hydrogels was prepared through an aza-Michael addition-amidation-one-pot end-group coupling strategy. Linear alkylamines were used as cores to synthesize amino-terminated generation 1.0 G broom-shaped hyperbranched macromolecular backbones via a divergent route. The resulting backbones were subsequently crosslinked with linear α,ω-diepoxy-terminated poly(ethylene glycol), affording three structurally well-defined hydrogels, denoted as C2HG, C6HG, and C8HG. Structural and physicochemical characterization showed that all hydrogels possessed interconnected three-dimensional porous networks, good thermal stability, and a lower critical solution temperature of approximately 37 °C. Rheological analysis demonstrated predominantly elastic behavior, with the storage modulus (G′) consistently exceeding the loss modulus (G″), together with pronounced shear-thinning characteristics favorable for injection into deep, low-permeability formations. By varying the alkyl-chain length of the hyperbranched backbone, the balance between environmental tolerance and plugging performance could be effectively regulated. These findings establish a structure–property relationship between backbone hydrophobicity and hydrogel performance and demonstrate that PEG-crosslinked hyperbranched copolymer hydrogels are promising candidates for deep-profile control and water shutoff in high-salinity, low-permeability fractured reservoirs. Full article
(This article belongs to the Special Issue Advances in Functional and Intelligent Hydrogels)
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23 pages, 8637 KB  
Article
Molecular Simulation of H2/CH4 Competitive Adsorption and Diffusion in Representative Reservoir Minerals: Implications for Hydrogen Storage in Depleted Gas Reservoirs
by Bohang He, Shuai Dang and Peng Li
Processes 2026, 14(15), 2487; https://doi.org/10.3390/pr14152487 - 3 Aug 2026
Viewed by 481
Abstract
Underground hydrogen storage in depleted gas reservoirs has emerged as a key technology for large-scale hydrogen energy storage. However, the occurrence state of hydrogen is governed by residual methane and reservoir mineral surfaces. This study combines grand canonical Monte Carlo and molecular dynamics [...] Read more.
Underground hydrogen storage in depleted gas reservoirs has emerged as a key technology for large-scale hydrogen energy storage. However, the occurrence state of hydrogen is governed by residual methane and reservoir mineral surfaces. This study combines grand canonical Monte Carlo and molecular dynamics simulations to investigate the competitive adsorption and diffusion of hydrogen and methane in quartz, kaolinite, and calcite. The results show that at low methane contents (<0.2), the adsorption capacity of hydrogen is primarily governed by its interaction with the mineral surface, exhibiting the strongest adsorption in calcite and the weakest in quartz, whereas the diffusivity follows the opposite trend. As the methane content increases, the occurrence state of hydrogen becomes increasingly controlled by the distribution of methane. The preferential occupation of surface adsorption sites by methane substantially suppresses hydrogen adsorption in quartz and calcite, whereas the abundant methane remaining in the bulk region of kaolinite imposes the strongest restriction on hydrogen diffusion. Increasing temperature promotes methane desorption, releasing interfacial adsorption sites, restoring the near-wall hydrogen adsorption peak, and enhancing hydrogen diffusivity, whereas increasing pressure shifts hydrogen from interfacial adsorption at low pressures to bulk-phase filling at high pressures while reducing its diffusivity. Full article
(This article belongs to the Section Petroleum and Low-Carbon Energy Process Engineering)
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17 pages, 4117 KB  
Article
VyMYB24 Integrates Antioxidant Defense and Cold Acclimation Networks to Enhance Freezing Tolerance in Chinese Wild Grape Vitis yeshanensis ‘Yanshan’
by Ruxin Gai, Yi Wang, Feifei Han, Beibei Li, Xiucai Fan, Ruijin Zhou and Guirong Li
Plants 2026, 15(15), 2348; https://doi.org/10.3390/plants15152348 - 30 Jul 2026
Viewed by 298
Abstract
Cold stress severely impairs grapevine (Vitis vinifera L.) growth, development, and productivity, necessitating the identification of elite cold-resistance genes for breeding tolerant cultivars. Chinese wild grape germplasm, particularly the endemic Vitis yeshanensis ‘Yanshan’ ecotype, represents a valuable reservoir of stress-resistance alleles with [...] Read more.
Cold stress severely impairs grapevine (Vitis vinifera L.) growth, development, and productivity, necessitating the identification of elite cold-resistance genes for breeding tolerant cultivars. Chinese wild grape germplasm, particularly the endemic Vitis yeshanensis ‘Yanshan’ ecotype, represents a valuable reservoir of stress-resistance alleles with exceptional cold hardiness. In this study, we isolated an R2R3-MYB transcription factor gene VyMYB24 from ‘Yanshan’ grape and systematically characterized its function in low-temperature responses. VyMYB24 expression was rapidly and strongly induced by cold stress, with transcript levels peaking at 12 h after treatment. Heterologous overexpression of VyMYB24 in transgenic tobacco (Nicotiana benthamiana) induced pronounced architectural changes. Transgenic plants exhibited a dwarf and compact stature with enhanced lateral branching, thickened stems, and robust root systems. In addition, anatomical analysis revealed markedly increased xylem and phloem thickness. Under cold stress, transgenic lines outperformed wild-type plants, with reduced wilting, lower water loss, and improved survival and recovery rates. Physiologically, VyMYB24 activated the antioxidant defense system, elevated the activities of key reactive oxygen species (ROS)-scavenging enzymes, suppressed H2O2 and superoxide accumulation, and reduced malondialdehyde content and electrolyte leakage, thereby preserving cellular homeostasis. This study provides functional evidence for the positive regulatory role of VyMYB24 in cold tolerance via heterologous expression, underscores the genetic value of ‘Yanshan’ grape germplasm, and lays a preliminary foundation for improving crop stress resistance through the utilization of native wild germplasm genes. Full article
(This article belongs to the Section Horticultural Science and Ornamental Plants)
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Article
Techno-Economic Optimization of Hot-Water Flooding and Injection Conversion Strategies for a Heavy Oil Reservoir: A Case Study of the A66 Block
by Guangming Ren, Haotian Zhang, Ming Zhu, Yuwei Feng, Tianyu Liu and Yi Liu
Processes 2026, 14(15), 2455; https://doi.org/10.3390/pr14152455 - 30 Jul 2026
Viewed by 351
Abstract
Heavy oil reservoirs typically suffer from low recovery efficiency and high development costs during thermal production. This study investigates the A66 heavy oil reservoir and proposes an integrated hot-water flooding and hot-to-cold injection strategy. Laboratory experiments, numerical simulations, and techno-economic analysis are combined [...] Read more.
Heavy oil reservoirs typically suffer from low recovery efficiency and high development costs during thermal production. This study investigates the A66 heavy oil reservoir and proposes an integrated hot-water flooding and hot-to-cold injection strategy. Laboratory experiments, numerical simulations, and techno-economic analysis are combined to optimize injection temperature, conversion timing, and injection parameters. Results show that injection temperature strongly affects oil recovery. Increasing temperature from 40 °C to 60 °C significantly improves recovery by reducing oil viscosity and enhancing mobility. However, further increases to 80 °C and 100 °C provide only marginal additional improvement, indicating a clear diminishing return effect. Considering both recovery performance and energy consumption, 60 °C is identified as the optimal injection temperature. Simulation results indicate that the timing of hot-to-cold conversion has a limited impact on final recovery, while significantly affecting development cost. A conversion window at a water cut of 10–20% achieves a balanced performance between displacement efficiency and thermal cost reduction. In addition, unstable injection improves sweep efficiency by dynamically adjusting flow paths and enhancing both areal and vertical displacement. A coupled hot-to-cold injection strategy is therefore proposed. It integrates temperature optimization, injection mode design, and conversion timing to improve both recovery and economic performance. Compared with conventional constant-temperature flooding, the proposed strategy better accounts for the time-dependent evolution of reservoir thermal conditions and fluid properties. Techno-economic evaluation confirms that the optimized scheme achieves higher economic efficiency while maintaining stable recovery improvement, demonstrating strong potential for field application in similar heavy oil reservoirs. Full article
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