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Keywords = light spectral modification

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20 pages, 5837 KB  
Article
Metabolomics Reveals the Mechanism of Browning Inhibition by Transient Light Quality in Tea Plant Tissue Culture
by Yi Ding, Haitao Huang and Yun Zhao
Plants 2025, 14(22), 3539; https://doi.org/10.3390/plants14223539 - 20 Nov 2025
Viewed by 687
Abstract
The absence of a high-efficiency and stable genetic transformation system has been a critical bottleneck, impeding both functional gene characterization and precision breeding efforts in Camellia sinensis (tea), and browning is the first problem encountered in tissue culture of tea. In this paper, [...] Read more.
The absence of a high-efficiency and stable genetic transformation system has been a critical bottleneck, impeding both functional gene characterization and precision breeding efforts in Camellia sinensis (tea), and browning is the first problem encountered in tissue culture of tea. In this paper, to identify optimal spectral conditions for minimizing browning in tissue culture, we subjected three tea plant cultivars to distinct light quality treatments and conducted comprehensive metabolomic profiling of their phytochemical contents. This study demonstrates that wavelength-specific light treatments can induce reversible modifications in the physicochemical characteristics of tea leaves, effectively reducing the accumulation of flavonoid compounds, including polyphenols, in plant tissues. Notably, tissues subjected to optimized wavelength conditions exhibit superior performance as explant sources for in vitro culture systems, demonstrating significantly lower browning rates. Comparative analysis of 460 nm, 660 nm, and 730 nm irradiation treatments revealed consistent suppression of polyphenol biosynthesis across all examined cultivars. However, the wavelength eliciting maximal reduction showed significant cultivar-dependent variation, indicating genotype-specific photoresponsive regulation of secondary metabolism. Full article
(This article belongs to the Special Issue Biosynthesis and Regulation of Tea Plant Specialized Metabolites)
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20 pages, 2430 KB  
Article
Shade Nets Increase Plant Growth but Not Fruit Yield in Organic Jalapeño Pepper (Capsicum annuum L.)
by Mamata Bashyal, Timothy W. Coolong and Juan Carlos Díaz-Pérez
Agriculture 2025, 15(16), 1757; https://doi.org/10.3390/agriculture15161757 - 16 Aug 2025
Viewed by 3026
Abstract
Colored shade nets have gained attention due to their ability to reduce light intensity and alter the light spectrum, thereby influencing vegetable crop quality and yield. However, limited research has examined their effects on jalapeño pepper (Capsicum annuum L.) growth and yield. [...] Read more.
Colored shade nets have gained attention due to their ability to reduce light intensity and alter the light spectrum, thereby influencing vegetable crop quality and yield. However, limited research has examined their effects on jalapeño pepper (Capsicum annuum L.) growth and yield. This study evaluated the impact of four nets—black, red, silver, and white (40% shade factor)—compared to an unshaded control. The red net altered light quality by increasing the proportion of red and far-red wavelengths, while the other nets reduced light intensity without spectral modification. Although differences in mean air temperature were minimal between shaded and unshaded conditions, root zone temperatures were consistently lower under shade nets. Shade treatments significantly increased plant height, stem diameter, and leaf chlorophyll content relative to the unshaded control. The highest rates of leaf transpiration and stomatal conductance were recorded under unshaded and white net conditions. Net photosynthesis, electron transport rate, intercellular CO2 concentration, or photosynthetic water use efficiency were similar among net treatments. Marketable and total yields did not differ significantly among net treatments in either year; however, in 2021, they were positively associated with light intensity. In conclusion, while colored shade nets promoted vegetative growth, they did not enhance fruit yield relative to unshaded conditions in jalapeño pepper. Full article
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17 pages, 920 KB  
Article
Enhancing Early GI Disease Detection with Spectral Visualization and Deep Learning
by Tsung-Jung Tsai, Kun-Hua Lee, Chu-Kuang Chou, Riya Karmakar, Arvind Mukundan, Tsung-Hsien Chen, Devansh Gupta, Gargi Ghosh, Tao-Yuan Liu and Hsiang-Chen Wang
Bioengineering 2025, 12(8), 828; https://doi.org/10.3390/bioengineering12080828 - 30 Jul 2025
Cited by 3 | Viewed by 1358
Abstract
Timely and accurate diagnosis of gastrointestinal diseases (GIDs) remains a critical bottleneck in clinical endoscopy, particularly due to the limited contrast and sensitivity of conventional white light imaging (WLI) in detecting early-stage mucosal abnormalities. To overcome this, this research presents Spectrum Aided Vision [...] Read more.
Timely and accurate diagnosis of gastrointestinal diseases (GIDs) remains a critical bottleneck in clinical endoscopy, particularly due to the limited contrast and sensitivity of conventional white light imaging (WLI) in detecting early-stage mucosal abnormalities. To overcome this, this research presents Spectrum Aided Vision Enhancer (SAVE), an innovative, software-driven framework that transforms standard WLI into high-fidelity hyperspectral imaging (HSI) and simulated narrow-band imaging (NBI) without any hardware modification. SAVE leverages advanced spectral reconstruction techniques, including Macbeth Color Checker-based calibration, principal component analysis (PCA), and multivariate polynomial regression, achieving a root mean square error (RMSE) of 0.056 and structural similarity index (SSIM) exceeding 90%. Trained and validated on the Kvasir v2 dataset (n = 6490) using deep learning models like ResNet-50, ResNet-101, EfficientNet-B2, both EfficientNet-B5 and EfficientNetV2-B0 were used to assess diagnostic performance across six key GI conditions. Results demonstrated that SAVE enhanced imagery and consistently outperformed raw WLI across precision, recall, and F1-score metrics, with EfficientNet-B2 and EfficientNetV2-B0 achieving the highest classification accuracy. Notably, this performance gain was achieved without the need for specialized imaging hardware. These findings highlight SAVE as a transformative solution for augmenting GI diagnostics, with the potential to significantly improve early detection, streamline clinical workflows, and broaden access to advanced imaging especially in resource constrained settings. Full article
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17 pages, 2608 KB  
Article
Colorimetric and Photobiological Properties of Light Transmitted Through Low-Vision Filters: Simulated Potential Impact on ipRGCs Responses Considering Crystalline Lens Aging
by Ana Sanchez-Cano, Elvira Orduna-Hospital and Justiniano Aporta
Life 2025, 15(2), 261; https://doi.org/10.3390/life15020261 - 8 Feb 2025
Cited by 1 | Viewed by 3180
Abstract
This study aims to investigate the potential impact of commercial low-vision filters on intrinsically photosensitive retinal ganglion cells (ipRGCs), which have significantly advanced our understanding of non-image-forming visual functions. A comprehensive analysis by modeling the potential responses of ipRGCs to commercially available low-vision [...] Read more.
This study aims to investigate the potential impact of commercial low-vision filters on intrinsically photosensitive retinal ganglion cells (ipRGCs), which have significantly advanced our understanding of non-image-forming visual functions. A comprehensive analysis by modeling the potential responses of ipRGCs to commercially available low-vision filters was conducted, focusing on how the spectral properties of these filters could alter ipRGC function. Additionally, the influence of aging on the crystalline lens was considered. Colorimetric changes in the transmitted light by these filters were also analyzed, highlighting variations based on the manufacturer. The study uncovered the diverse responses of ipRGCs to fifty low-vision filters, shedding light on the potential modifications in ipRGC stimulation and visual function. Notably, the consideration of aging in the crystalline lens revealed significant alterations in ipRGC response. Furthermore, the analysis of colorimetric changes demonstrated substantial differences in the light transmitted by these filters, with variations dependent on the manufacturer. This research underscores the nuanced relationship between low-vision filters and ipRGCs, providing insights into their potential impact on visual function. The varying responses observed, coupled with the influence of aging on the crystalline lens, emphasize the complexity of this interaction. Additionally, the distinct colorimetric changes based on filter manufacturer suggest the need for tailored approaches in enhancing visual perception for individuals with visual impairments. Full article
(This article belongs to the Special Issue Feature Paper in Physiology and Pathology: 2nd Edition)
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13 pages, 4036 KB  
Article
Improving Visible Light Photocatalysis Using Optical Defects in CoOx-TiO2 Photonic Crystals
by Alexia Toumazatou, Elias Sakellis and Vlassis Likodimos
Materials 2024, 17(23), 5996; https://doi.org/10.3390/ma17235996 - 7 Dec 2024
Cited by 4 | Viewed by 1825
Abstract
The rational design of photonic crystal photocatalysts has attracted significant interest in order to improve their light harvesting and photocatalytic performances. In this work, an advanced approach to enhance slow light propagation and visible light photocatalysis is demonstrated for the first time by [...] Read more.
The rational design of photonic crystal photocatalysts has attracted significant interest in order to improve their light harvesting and photocatalytic performances. In this work, an advanced approach to enhance slow light propagation and visible light photocatalysis is demonstrated for the first time by integrating a planar defect into CoOx-TiO2 inverse opals. Trilayer photonic crystal films were fabricated through the successive deposition of an inverse opal TiO2 underlayer, a thin titania interlayer, and a photonic top layer, whose visible light activation was implemented through surface modification with CoOx nanoscale complexes. Optical measurements showed the formation of “donor”-like localized states within the photonic band gap, which reduced the Bragg reflection and expanded the slow photon spectral range. The optimization of CoOx loading and photonic band gap tuning resulted in a markedly improved photocatalytic performance for salicylic acid degradation and photocurrent generation compared to the additive effects of the constituent monolayers, indicative of light localization in the defect layer. The electrochemical impedance results showed reduced recombination kinetics, corroborating that the introduction of an optical defect into inverse opal photocatalysts provides a versatile and effective strategy for boosting the photonic amplification effects in visible light photocatalysis by evading the constraints imposed by narrow slow photon spectral regions. Full article
(This article belongs to the Special Issue Feature Papers in Materials Physics (2nd Edition))
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11 pages, 3194 KB  
Article
Theoretical Design of Smart Bionic Skins with Self-Adaptive Temperature Regulation
by Yubo Wang, Yungui Ma and Rui Chen
Materials 2024, 17(22), 5580; https://doi.org/10.3390/ma17225580 - 15 Nov 2024
Viewed by 1465
Abstract
Thermal management presents a significant challenge in electric design, particularly in densely packed electronic systems. This study proposes a theoretical model for radiative bionic skin that emulates human skin, enabling the self-adaptive modulation of the thermal exhaustion rate to maintain homeostasis for objects [...] Read more.
Thermal management presents a significant challenge in electric design, particularly in densely packed electronic systems. This study proposes a theoretical model for radiative bionic skin that emulates human skin, enabling the self-adaptive modulation of the thermal exhaustion rate to maintain homeostasis for objects covered by the skin in fluctuating thermal environments. The proposed artificial skin consists of phase change material (VO2) nanoparticles embedded in a low-loss matrix situated on a metallic substrate with a minimal thickness of several micrometers. The findings from our theoretical analyses indicate that substantial alterations in thermal radiation power around the phase transition temperature of 340 K enable a silicone substrate to sustain a relatively stable temperature, with variations confined to ±6 K, despite external heat fluxes ranging from 150 to 450 W/m2. Furthermore, to improve the spectral resemblance to natural skin, a plasmonic surface composed of self-assembled silver nanocubes is incorporated, allowing for modifications to the visible light properties of the bionic skin while maintaining its infrared characteristics. This theoretical investigation offers a cost-effective and conformal approach to the design of ultra-compact, fully passive, and versatile thermal management solutions for robotic systems and related technologies. Full article
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5 pages, 2232 KB  
Proceeding Paper
Synthesis and Spectral Properties of a New Spirophotochromic Molecule
by Artur Khuzin and Liliya Khuzina
Chem. Proc. 2024, 16(1), 23; https://doi.org/10.3390/ecsoc-28-20103 - 14 Nov 2024
Viewed by 720
Abstract
Due to their ability to reversibly isomerize under the influence of external stimuli, spiropyrans represent the most interesting class of organic photochromic molecules. The photochromic properties of the isomeric forms of spiropyrans differ significantly from each other, which makes it possible to use [...] Read more.
Due to their ability to reversibly isomerize under the influence of external stimuli, spiropyrans represent the most interesting class of organic photochromic molecules. The photochromic properties of the isomeric forms of spiropyrans differ significantly from each other, which makes it possible to use these photochromes as sensors, optoelectronic and holographic devices, memory elements, etc. Also, an undoubted advantage of spiropyrans compared to other classes of organic photochromes is the relative ease of their preparation and chemical transformation. At the same time, modification of the structure of spiropyrans by introducing various functional groups opens up great synthetic possibilities for obtaining new photochromic molecules with various spectral-kinetic characteristics. In the development of research aimed at expanding the boundaries of the use of spirophotochromic compounds, in order to obtain new light-controlled materials with different characteristics, as well as to study the influence of functional groups in the spirophotochromic molecule on the spectral and photochromic properties, we have synthesized a new spiropyran. In this work, we synthesized a new salt of photochromic spiropyran containing various functional groups (–CHO, –NO2, –OCH3, –(CH2)5N(CH3)2*HBr), capable of reversibly responding to external influences. Photoinduced transformations and the spectral and kinetic characteristics of the synthesized compound were studied. Full article
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12 pages, 3832 KB  
Article
Laser Control of Specular and Diffuse Reflectance of Thin Aluminum Film-Isolator-Metal Structures for Anti-Counterfeiting and Plasmonic Color Applications
by Michał P. Nowak, Bogusz Stępak, Mateusz Pielach, Yuriy Stepanenko, Tomasz Wojciechowski, Bartosz Bartosewicz, Urszula Chodorow, Marcin Jakubaszek, Przemysław Wachulak and Piotr Nyga
Coatings 2024, 14(10), 1298; https://doi.org/10.3390/coatings14101298 - 11 Oct 2024
Cited by 2 | Viewed by 3083
Abstract
Plasmonic structural color originates from the scattering and absorption of visible light by metallic nanostructures. Stacks consisting of thin, disordered semicontinuous metal films are attractive plasmonic color media, as they can be mass-produced using industry-proven physical vapor deposition techniques. These films are comprised [...] Read more.
Plasmonic structural color originates from the scattering and absorption of visible light by metallic nanostructures. Stacks consisting of thin, disordered semicontinuous metal films are attractive plasmonic color media, as they can be mass-produced using industry-proven physical vapor deposition techniques. These films are comprised of random nano-island structures of various sizes and shapes resonating at different wavelengths. When irradiated with short-pulse lasers, the nanostructures are locally restructured, and their optical response is altered in a spectrally selective manner. Therefore, various colors are obtained. We demonstrate the generation of structural plasmonic colors through femtosecond laser modification of a thin aluminum film–isolator–metal mirror (TAFIM) structure. Laser-induced structuring of TAFIM’s top aluminum film significantly alters the sample’s specular and diffuse reflectance depending on the fluence value and the number of times a region is scanned. A “negative image” effect is possible, where a dark field observation mode image is a negative of a bright field mode image. This effect is visible using an optical microscope, the naked eye, and a digital camera. The use of self-passivating aluminum results in a long-lasting, non-fading coloration effect. The reported technique could be used in anti-counterfeiting and security applications, as well as in plasmonic color printing and macroscopic and microscopic marking for personalized fine arts and aesthetic products such as jewelry. Full article
(This article belongs to the Special Issue Optical Coatings: From Materials to Applications)
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10 pages, 2868 KB  
Article
Improved UV Photoresponse Performance of ZnO Nanowire Array Photodetector via Effective Pt Nanoparticle Coupling
by Nan Wang, Jianbo Li, Chong Wang, Xiaoqi Zhang, Song Ding, Zexuan Guo, Yuhan Duan and Dayong Jiang
Nanomaterials 2024, 14(17), 1442; https://doi.org/10.3390/nano14171442 - 4 Sep 2024
Cited by 11 | Viewed by 2295
Abstract
Ultraviolet (UV) photodetectors (PDs) based on nanowire (NW) hold significant promise for applications in fire detection, optical communication, and environmental monitoring. As optoelectronic devices evolve towards lower dimensionality, multifunctionality, and integrability, multicolor PDs have become a research hotspot in optics and electronic information. [...] Read more.
Ultraviolet (UV) photodetectors (PDs) based on nanowire (NW) hold significant promise for applications in fire detection, optical communication, and environmental monitoring. As optoelectronic devices evolve towards lower dimensionality, multifunctionality, and integrability, multicolor PDs have become a research hotspot in optics and electronic information. This study investigates the enhancement of detection capability in a light-trapping ZnO NW array through modification with Pt nanoparticles (NPs) via magnetron sputtering and hydrothermal synthesis. The optimized PD exhibits superior performance, achieving a responsivity of 12.49 A/W, detectivity of 4.07 × 1012 Jones, and external quantum efficiency (EQE) of 4.19 × 103%, respectively. In addition, the Pt NPs/ZnO NW/ZnO PD maintains spectral selectivity in the UV region. These findings show the pivotal role of Pt NPs in enhancing photodetection performance through their strong light absorption and scattering properties. This improvement is associated with localized surface plasmon resonance induced by the Pt NPs, leading to enhanced incident light and interfacial charge separation for the specialized configurations of the nanodevice. Utilizing metal NPs for device modification represents a breakthrough that positively affects the preparation of high-performance ZnO-based UV PDs. Full article
(This article belongs to the Special Issue Nanophotonic: Structure, Devices and System)
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17 pages, 3108 KB  
Article
Effects of Shading Nets Color on the Internal Environmental Conditions, Light Spectral Distribution, and Strawberry Growth and Yield in Greenhouses
by Ibrahim M. Alhelal, Ammar A. Albadawi, Abdullah A. Alsadon, Mekhled M. Alenazi, Abdullah A. Ibrahim, Mohamed Shady and Abdulhakim A. Al-Dubai
Plants 2024, 13(16), 2318; https://doi.org/10.3390/plants13162318 - 20 Aug 2024
Cited by 4 | Viewed by 4444
Abstract
Greenhouses are used to create the appropriate environment for plant growth. Controlling the level of lighting using shading nets is one of the most commonly used methods for making suitable environmental modifications in greenhouses. The objective of this study was to examine the [...] Read more.
Greenhouses are used to create the appropriate environment for plant growth. Controlling the level of lighting using shading nets is one of the most commonly used methods for making suitable environmental modifications in greenhouses. The objective of this study was to examine the impact of three colored shading nets (green, black, and beige at shading rates of 50%) on inside air temperature, relative humidity, and spectral distribution of light in a greenhouse, as well as their effect on the growth and yield of strawberry plants. Data were collected during winter (December and January) and spring (March and April) months from shaded and unshaded blocks. The green net had the highest transmittance to solar radiation (τSR) during the two periods (38% and 35%, respectively) and the highest transmittance to photosynthetically active radiation (τPAR) of 34% during spring months, while the beige net had the highest τPAR of 27% during winter months. The black net had the smallest τPAR values during the two periods (22% and 29%, respectively). The lowest total light levels per season for solar radiation (SR) and photosynthetically active radiation (PAR) (746.8 and 293.7 MJ·m−2, respectively) were obtained under the black net, compared with (906.7 and 320.8 MJ·m−2, respectively) for the beige net, and (969.6 and 337.2 MJ·m−2, respectively) for the green net. The ratio of PAR to SR (PAR:SR) was 41% and 44% outside and inside the greenhouse for the control (without shade), respectively. The black net had the highest ratio of PAR:SR (39%) among the treatment nets. The green net transmitted more light in the blue–green region (400 to 570 nm) and transmitted the highest photon flux at 480 nm, while the beige net increased the infrared radiation flux from 730 nm and above and transmitted the highest photon flux at 604 nm. The study found that the green net increased the ratio of blue to red light (B/R), while the beige and green nets reduced the red to far-red light (R/FR) ratio. The photosynthetic rate, conductance to water, and transpiration were significantly higher for strawberries grown under the beige net. These results indicate that the beige net positively influenced leaf and stem characteristics, leading to improved strawberry yields. The best yields of strawberries were obtained under the beige net and the control group (no shade), surpassing the yields achieved under the black net by 26.3% and 21.4%, respectively. Full article
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28 pages, 6536 KB  
Article
The Condition of Contemporary Murals in Sun-Exposed Urban Environments: A Model Study Based on Spray-Painted Mock-Ups and Simulated Light Ageing
by Varvara Marazioti, Antonios M. Douvas, Evangelia C. Vouvoudi, Dimitrios Bikiaris, Kyriaki Papadokostaki, Dimitrios Nioras, Evangelos Gogolides, Spyros Orfanoudakis, Thomas Stergiopoulos, Stamatios Boyatzis and Yorgos Facorellis
Heritage 2024, 7(8), 3932-3959; https://doi.org/10.3390/heritage7080186 - 30 Jul 2024
Cited by 9 | Viewed by 2001
Abstract
The present work investigates the physicochemical stability of spray paints when irradiated with artificial solar light (at spectral range 300–800 nm). This research highlights the importance of understanding the materials used in street art and public murals, recognising them as a significant component [...] Read more.
The present work investigates the physicochemical stability of spray paints when irradiated with artificial solar light (at spectral range 300–800 nm). This research highlights the importance of understanding the materials used in street art and public murals, recognising them as a significant component of contemporary cultural heritage. By examining the stability and degradation of spray paints toward solar light exposure, the study aims to contribute to the preservation of contemporary murals, which reflect current social and cultural narratives. A physicochemical approach was employed for the study of spray paints’ physical and thermal properties, as well as the effect of specific photochemical ageing reactions/processes. The photochemical ageing results were compared with reference (unaged) samples. Specifically, a multi-technique approach was applied using stereo microscopy, scanning electron microscopy (SEM), atomic force microscopy (AFM), contact angle measurement, colorimetry, glossimetry, differential scanning calorimetry (DSC), UV-Vis spectroscopy, attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR), and pyrolysis-GC/MS (Py-GC/MS). The photodegradation of the spray paints occurred from the first 144 h of solar light irradiation, resulting in changes in morphology, colour, gloss, roughness, and wettability. Regarding photochemical stability, ageing seems to affect the binders more than the synthetic organic pigments and the inorganic fillers. In particular, acrylic binders showed small chemical changes, whereas the alkyd, nitrocellulose, and styrene binders underwent severe chemical modification. The results suggest that simulated daylight irradiation prompts the migration of additives toward the surface of the spray paint films. In addition, the results of the analyses on the white spray paints in comparison with the coloured paints (from the same manufacturer) showed that there seems to be an active distinct photoageing mechanism involving titanium dioxide, but the whole issue needs further investigation. Full article
(This article belongs to the Section Cultural Heritage)
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10 pages, 2000 KB  
Article
Daylight and Electric Lighting in Primary and Secondary School Classrooms in the UK—An Observational Study
by Luke L. A. Price, Annegret Dahlmann-Noor and Marina Khazova
Int. J. Environ. Res. Public Health 2024, 21(7), 942; https://doi.org/10.3390/ijerph21070942 - 19 Jul 2024
Cited by 2 | Viewed by 3330
Abstract
Only a few recent studies report direct assessment or monitoring of light levels in the indoor learning environment, and no consensus exists on minimum exposures for children’s health. For instance, myopia is a common progressive condition, with genetic and environmental risk factors. Reduced [...] Read more.
Only a few recent studies report direct assessment or monitoring of light levels in the indoor learning environment, and no consensus exists on minimum exposures for children’s health. For instance, myopia is a common progressive condition, with genetic and environmental risk factors. Reduced daylight exposure, electric lighting changes, increased near-work for school children, greater academic focus, and use of display screens and white boards may have important detrimental influences. Published assessment methods had varied limitations, such as incomplete compliance from participants wearing light loggers for extended periods. Climate-Based Daylight Modelling is encouraged in UK school design, but design approaches are impractical for post-occupancy assessments of pre-existing classrooms or ad hoc modifications. In this study, we investigated the potential for direct assessment and monitoring of classroom daylight and lighting measurements. Combined with objective assessments of outdoor exposures and class time use, the classroom data could inform design and light exposure interventions to reduce the various health impacts of inadequate daylight exposure. The relevant environmental measure for myopia depends on the hypothesized mechanism, so the illuminance, spectral distribution, and temporal light modulation from the electric lighting was also assessed. Full article
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10 pages, 6251 KB  
Article
Wavelength Tuning in Resonant Cavity Interband Cascade Light Emitting Diodes (RCICLEDs) via Post Growth Cavity Length Adjustment
by Nicolas Schäfer, Robert Weih, Julian Scheuermann, Florian Rothmayr, Johannes Koeth and Sven Höfling
Sensors 2024, 24(12), 3843; https://doi.org/10.3390/s24123843 - 14 Jun 2024
Cited by 1 | Viewed by 2304
Abstract
We demonstrate substrate-emitting resonant cavity interband cascade light emitting diodes (RCICLEDs) based on a single distributed Bragg reflector (DBR). These devices operate in continuous wave mode at room temperature. Compared to standard ICLEDs without a cavity, we achieved an 89% reduction in the [...] Read more.
We demonstrate substrate-emitting resonant cavity interband cascade light emitting diodes (RCICLEDs) based on a single distributed Bragg reflector (DBR). These devices operate in continuous wave mode at room temperature. Compared to standard ICLEDs without a cavity, we achieved an 89% reduction in the emission spectrum width, as indicated by the Full Width Half Maximum (FWHM) of 70 nm. Furthermore, we observed far-field narrowing and improved thermal stability. A single DBR configuration allows the cavity length to be adjusted by adding refractive index-matched material to the top of the epitaxial structure after epitaxial growth. This modification effectively shifts the cavity response towards longer wavelengths. We fabricated emitters comprising two cavities of different lengths, resulting in the emission of two distinct spectral lines that can be independently controlled. This dual-color capability enables one of the emission lines to serve as a built-in reference channel, making these LEDs highly suitable for cost-effective gas-sensing applications. Full article
(This article belongs to the Section Optical Sensors)
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18 pages, 4141 KB  
Article
Carbon Dot Synthesis in CYTOP Optical Fiber Using IR Femtosecond Laser Direct Writing and Its Luminescence Properties
by Ruyue Que, Jean-Frédéric Audibert, Enrique Garcia-Caurel, Olivier Plantevin, Kyriacos Kalli, Matthieu Lancry, Bertrand Poumellec and Robert B. Pansu
Nanomaterials 2024, 14(11), 941; https://doi.org/10.3390/nano14110941 - 27 May 2024
Cited by 2 | Viewed by 1865
Abstract
Luminescent carbon dots (CDs) were locally synthesized in the core of CYTOP fibers using IR femtosecond laser direct writing (FLDW), a one-step simple method serving as a post-treatment of the pristine fiber. This approach enables the creation of several types of modifications such [...] Read more.
Luminescent carbon dots (CDs) were locally synthesized in the core of CYTOP fibers using IR femtosecond laser direct writing (FLDW), a one-step simple method serving as a post-treatment of the pristine fiber. This approach enables the creation of several types of modifications such as ellipsoid voids. The CDs and photoluminescence (PL) distribute at the periphery of the voids. The PL spectral properties were studied through the excitation/emission matrix in the visible range and excitation/emission spectra in the UV/visible range. Our findings reveal the presence of at least three distinct luminescent species, facilitating a broad excitation range extending from UV to green, and light emission spanning from blue to red. The average laser power and dose influence the quantity and ratio of these luminescent CD species. Additionally, we measured the spatially resolved lifetime of the luminescence during and after the irradiation. We found longer lifetimes at the periphery of the laser-induced modified regions and shorter ones closer to the center, with a dominant lifetime ~2 ns. Notably, unlike many other luminophores, these laser-induced CDs are insensitive to oxygen, enhancing their potential for display or data storage applications. Full article
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14 pages, 60654 KB  
Article
Broadband-Tunable Vanadium Dioxide (VO2)-Based Linear Optical Cavity Sensor
by Rana M. Armaghan Ayaz, Amin Balazadeh Koucheh and Kursat Sendur
Nanomaterials 2024, 14(4), 328; https://doi.org/10.3390/nano14040328 - 7 Feb 2024
Cited by 2 | Viewed by 2518
Abstract
Sensors fabricated by using a silicon-on-insulator (SOI) platform provide promising solutions to issues such as size, power consumption, wavelength-specific nature of end reflectors and difficulty to detect ternary mixture. To address these limitations, we proposed and investigated a broadband-thermally tunable vanadium dioxide (VO [...] Read more.
Sensors fabricated by using a silicon-on-insulator (SOI) platform provide promising solutions to issues such as size, power consumption, wavelength-specific nature of end reflectors and difficulty to detect ternary mixture. To address these limitations, we proposed and investigated a broadband-thermally tunable vanadium dioxide (VO2)-based linear optical cavity sensor model using a finite element method. The proposed structure consists of a silicon wire waveguide on a silicon-on-insulator (SOI) platform terminated with phase-change vanadium oxide (VO2) on each side to provide light confinement. A smooth transmission modulation range of 0.8 (VO2 in the insulator state) and 0.03 (VO2 in the conductive phase state) in the 125 to 230 THz spectral region was obtained due to the of Fabry–Pérot (FP) effect. For the 3.84 μm cavity length, the presented sensor resulted in a sensitivity of 20.2 THz/RIU or 179.56 nm/RIU, which is approximately two orders of magnitude higher than its counterparts in the literature. The sensitivity of the 2D model showed direct relation with the length of the optical cavity. Moreover, the change in the resonating mode line width Δν of approximately 6.94 THz/RIU or 59.96 nm/RIU was also observed when the sensor was subjected to the change of the imaginary part k of complex refractive index (RI). This property of the sensor equips it for the sensing of aternary mixture without using any chemical surface modification. The proposed sensor haspotential applications in the areas of chemical industries, environmental monitoring and biomedical sensing. Full article
(This article belongs to the Special Issue Advanced Nanomaterials and Nanotechnologies for Micro/Nano-Sensors)
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