Search Results (54)

Underground brine as a liquid mineral resource available for development and utilization has attracted widespread attention. However, how the mining process affects the hydrochemical characteristics and evolution of underground brine has yet to be fully understood. Herein, 207 underground brine samples were collected from the Luobei mining area of the Lop Nur region during pre-exploitation (2006), exploitation (2019), and late exploitation (2023) to explore the dynamic change characteristics and evolution mechanisms of the underground brine hydrochemistry using the combination of statistical analysis, spatial interpolation, correlation analysis, and ion ratio analysis. The results indicated that Na⁺ and Cl⁻ were the dominant ionic components in the brine, and their concentrations remained relatively stable throughout the mining process. However, the content of Mg²⁺ increased gradually during the mining process (increased by 45.08% in the middle stage and 3.09% in the later stage). The elevation in Mg²⁺ concentration during the mining process could be attributed to the dissolution of Mg-bearing minerals, reverse cation exchange, and mixed recharge. This research furnishes a scientific foundation for a more in-depth comprehension of the disturbance mechanism of brine-mining activities on the groundwater chemical system in the mining area and for the sustainable exploitation of brine resources. Full article

The efficacy of water resource management and protection hinges on a profound understanding of the controlling factors and regulatory mechanisms that shape groundwater chemistry within aquifers. Despite this, our comprehension of how groundwater chemistry and ion sources vary across diverse aquifer types remained limited. To bridge this gap, our study conducted a detailed hydrochemical and statistical investigation of porous, fissured, and karst aquifers. By applying multivariate statistical techniques, including principal component analysis (PCA) and hierarchical cluster analysis (HCA), the hydrochemical characteristics and main ion sources of each aquifer type, as well as distinct controlling factors and regulation patterns, were determined. Notably, evaporation predominantly affected the hydrochemistry of porous aquifers, whereas mineral dissolution and rock weathering processes played a pivotal role in shaping the groundwater evolution of fissured and karst aquifers. HCO₃⁻ and SO₄²⁻ are the most common anions of all types, while Na⁺ is dominant in porous and fissured aquifers and Ca²⁺ is dominant in karst aquifers. The most common hydrochemical types identified were HCO₃-Ca·Mg (accounting for approximately 56.84%) and SO₄·Cl-Na (constituting approximately 21.75%). PCA results revealed that lateral recharge from fissured aquifers in hilly regions into the groundwater of porous aquifer, and wastewater discharge and agricultural fertilizer application, significantly impact the groundwater chemistry across all three aquifer types. It is worth noting that the dissolution of carbonate minerals, often influenced by human activities, had a profound effect on the hydrochemistry of each aquifer. Conversely, the dissolution of evaporitic minerals affected groundwater chemistry primarily through cation exchange processes. In summary, the hydrochemical characteristics of these aquifer types were predominantly shaped by a complex interplay of mineral dissolution, cation exchange, evaporation, and anthropogenic activities, with notable contributions from fissured aquifer recharge and pollution. These insights were critical for informing national-level strategies for groundwater resource protection and management. Full article

This study systematically unravels the hydrochemical evolution mechanisms and driving forces in multi-aquifer systems of Qingdao, a coastal economic hub. Integrated hydrochemical analysis of porous, fissured, and karst water, combined with PHREEQC modeling and Positive Matrix Factorization (PMF), deciphers water–rock interactions and anthropogenic perturbations. Groundwater exhibits weak alkalinity (pH 7.2–8.4), with porous aquifers showing markedly higher TDS (161.1–8203.5 mg/L) than fissured (147.7–1224.8 mg/L) and karst systems (361.1–4551.5 mg/L). Spatial heterogeneity reveals progressive hydrochemical transitions (HCO₃-Ca → SO₄-Ca·Mg → Cl-Na) in porous aquifers across the Dagu River Basin. While carbonate (calcite) and silicate weathering govern natural hydrochemistry, evaporite dissolution and seawater intrusion drive severe groundwater salinization in the western Pingdu City and the Dagu River Estuary (localized TDS up to 8203.5 mg/L). PMF source apportionment identifies acid deposition-enhanced dissolution of carbonate/silicate minerals, with nitrate contamination predominantly sourced from agricultural runoff and domestic sewage. Landfill leachate exerts pronounced impacts in Laixi and adjacent regions. This study offering actionable strategies for salinity mitigation and contaminant source regulation, thereby providing a scientific framework for sustainable groundwater management in rapidly urbanizing coastal zones. Full article

This study investigated the hydrochemical characteristics, solute sources, and controlling factors of the Qujiang River, a vital tributary of the Qiantangjiang River, on the basis of 61 surface water samples collected from July to September 2019. A multi-method framework integrating ArcGIS spatial analysis, a Piper trilinear diagram, a Gibbs diagram, ion ratio analysis, and principal component analysis (PCA) was systematically applied. The results demonstrate significant spatial heterogeneity in pH values (6.39–7.15 in the upper reaches, 6.31–8.83 in the middle reaches, and 6.85–8.1 in the lower reaches), with hydrochemical facies dominated by Ca-HCO₃ types (87% frequency) in the upper–middle reaches, transitioning to SO₄·Cl-Na and SO₄·Cl-Na·Ca mixed types downstream. Source apportionment indicates that carbonate weathering and atmospheric precipitation are the primary controls on hydrochemistry in the upper and middle reaches, whereas industrial effluents, evidenced by a 2.3-fold increase in SO₄²⁻ concentration, and domestic sewage, with Cl⁻ levels reaching 16.07 mg/L, are the dominant influences in the lower reaches. This study’s innovation lies in the quantitative separation of natural weathering (68% contribution) and anthropogenic activities (32%) through an integrated methodological approach, offering a basin-scale understanding of longitudinal hydrochemical evolution. These results provide valuable insights for the management and ecological conservation of medium- to small-sized basins. Full article

As an important ecological barrier in the upper reaches of the Yangtze River, the Jialing River Basin has complex and sensitive hydrochemical evolutionary mechanisms due to its geological structures and human activities. This study focuses on the groundwater in the Wusheng section of the Jialing River Basin, combining field investigations and Entropy-Weighted Water Quality Index (EWQI) calculations to analyze its hydrochemical characteristics and influencing factors and conduct a water quality assessment. The results show that this regional water body has a pH of 7.05–8.36, presenting weakly alkaline and low-mineralization characteristics, with differences in hydrochemical components between groundwater and surface water. The ions are predominantly controlled by rock weathering, with reactions such as halite and gypsum dissolution occurring during groundwater runoff. Groundwater in the tectonic influence zone exhibits abnormal chemical compositions due to lateral recharge from different strata along fracture channels and long-distance runoff reactions with the surrounding rocks. EWQI values for groundwater range from 6.07 to 104.02, with an average value of 37.46, generally exhibiting a trend of increasing EWQI values near the Jialing Riverbank. In this area, 96.15% of groundwater meets excellent or good quality standards and is suitable for direct drinking. The influence of the intensity of different indicators on groundwater quality decreases in the order of Ca²⁺ > Cl⁻ > Mg²⁺ > SO₄²⁻ > HCO₃⁻ > NO₃⁻. Water quality is primarily influenced by the primary geological background, while agricultural practices may also lead to its deterioration. Full article

Water hardening and NO₃⁻ pollution have affected water quality globally. These environmental problems threaten social sustainability and human health, especially in piedmont agricultural areas. The aim of this study is to determine the biogeochemical mechanisms of HCO³–Ca water and NO₃⁻ pollution in a typical piedmont agricultural area (Qingshui River, Zhangjiakou, China). Here, an extensive biogeochemical investigation was conducted in a typical piedmont agricultural area (Qingshui River, China) using multiple hydrochemical, isotopic (δ²H-H₂O, δ¹⁸O-H₂O and δ¹³C-DIC) and molecular-biological proxies in combination with a forward model. In the region upstream of the Qingshui River, riverine hydrochemistry was dominated by HCO₃–Ca water, with only NO₃⁻ concentrations (3.08–52.8 mg/L) exceeding the acceptable limit (10 mg/L as N) for drinking water quality. The riverine hydrochemistry responsible for the formation of HCO₃–Ca water was mainly driven by carbonate dissolution, with a contribution rate of 49.8 ± 3.96%. Riverine NO₃⁻ was mainly derived from agricultural NH₄⁺ emissions rather than NO₃⁻ emissions, originating from sources such as manure, domestic sewage, soil nitrogen and NH₄⁺-synthetic fertilizer. Under the rapid hydrodynamic conditions and aerobic water environment of the piedmont area, NH₄⁺-containing pollutants were converted to HNO₃ by nitrifying bacteria (e.g., Flavobacterium and Fluviimonas). Carbonate (especially calcite) was preferentially and rapidly dissolved by the produced HNO₃, which was attributed to the strong acidity of HNO₃. Therefore, higher levels of Ca²⁺, Mg²⁺, HCO₃⁻ and NO₃⁻ were simultaneously released into river water, causing riverine HCO₃–Ca water and NO₃⁻ pollution in the A-RW. In contrast, these biogeochemical mechanisms did not occur significantly in the downstream region of the river due to the cement-hardened river channels and strict discharge management. These findings highlight the influence of agricultural HNO₃ on HCO₃–Ca water and NO₃⁻ pollution in the Qingshui River and further improve the understanding of riverine hydrochemical evolution and water pollution in piedmont agricultural areas. Full article

Wetland lakes are crucial ecosystems that serve as vital ecosystems that harbor rich biodiversity and provide essential ecological services, particularly in regulating regional water resources, purifying water quality, and maintaining ecological equilibrium. This study aims to conduct an in-depth investigation into the hydrochemical characteristics and their controlling factors during the dry season of the Hengshui Lake wetland system. By collecting water samples from the lake and shallow groundwater, and using water chemistry diagrams, ion ratios, mineral saturation indices, and multivariate statistical methods, the study systematically analyzes the hydrochemical characteristics of Hengshui Lake Wetland and its controlling factors. The results show: there is significant stratified differentiation in the water chemical composition: the lake water is weakly alkaline and fresh, while the shallow groundwater is highly mineralized and saline. Both are dominated by Na⁺, Mg²⁺, SO₄²⁻, and Cl⁻. Significant differences exist in water chemistry types between the lake and shallow groundwater. The lake water exhibits homogenized characteristics with a dominant SO₄·Cl·HCO₃-Na·Mg type, whereas shallow groundwater displays five distinct hydrochemical facies indicative of multi-source recharge processes. Evaporation–rock interaction mechanisms dominate the system, as evidenced by a Gibbs diagram analysis showing evaporation crystallization as the primary control. Ion ratio calculations demonstrate synergistic effects between silicate weathering and evaporite dissolution, while mineral saturation indices confirm cooperative processes involving calcite/dolomite oversaturation and ongoing gypsum dissolution. Cation exchange indexes combined with chloro-alkaline indices reveal unidirectional recharge from lake water to shallow groundwater accompanied by active cationic exchange adsorption. Although the wetland predominantly maintains natural hydrological conditions, elevated γ(NO₃⁻)/γ(Na⁺) ratios in nearshore zones suggest initial agricultural contamination infiltration. This study shows that, as a typical example of a closed wetland, the hydrochemistry evolution of Hengshui Lake during the dry season is primarily dominated by the coupled effects of evaporation and rock–water interaction, with silicate weathering and evaporation rock dissolution as secondary factors, and human activity having a weak influence. The findings provide new insights into the understanding of the hydrochemical evolution process and its controlling factors in closed lakes, offering valuable data support and theoretical basis for the ecological restoration and sustainable management of closed lakes. Full article

Understanding the characteristics of groundwater chemistry is essential for water resource development and utilization. However, few studies have focused on the chemical evolution processes of shallow groundwater in typical areas of the Huaibei Plain. We analyzed 28 water samples from the study area using hydrogeochemical mapping, multivariate statistical analysis, and other approaches. The study found that the hydrogeochemical facies of groundwater are mainly HCO₃-Ca·Mg (64.3%), mixed SO₄·Cl-Ca·Mg, and SO₄·Cl-Na. The hydrochemical composition is primarily controlled by natural water–rock interactions, including carbonate weathering and cation exchange processes. Correlation analysis and principal component analysis (PCA) revealed that mineral dissolution was the predominant source of Na⁺, Mg²⁺, Cl⁻, and SO₄²⁻ in shallow groundwater, significantly contributing to total dissolved solids (TDS) accumulation. Hierarchical cluster analysis (HCA) identified three characteristic zones: (1) agricultural/urban-influenced areas, (2) high-F⁻/low-hardness zones, and (3) nitrate-contaminated regions. These findings provide critical insights for assessing the geochemical status of groundwater in the Huaibei Plain and formulating targeted resource management strategies. Full article

The Tibetan Plateau, a critical regulator of the global water cycle and climate system, represents a highly sensitive region to environmental changes, with significant implications for sustainable development. This study focuses on Nam Co Lake, the third largest lake on the Tibetan Plateau, and investigates the hydrochemical evolution of the lake and the driving mechanisms in regard to the lake–river–groundwater system within the Nam Co Basin over the last 20 years. Our findings provide critical insights for sustainable water resource management in regard to fragile alpine lake ecosystems. The hydrochemical analyses revealed distinct temporal patterns in the total dissolved solids, showing an increasing trend during the 2000s, followed by a decrease in the 2010s. Piper diagrams demonstrated a gradual change in the anion composition from the Cl type to the HCO₃ type over the study period. The ion ratio analyses identified rock weathering (particularly silicate, halite, sulfate, and carbonate weathering), ion exchange, and evaporation processes as primary controlling processes, with notable differences between water bodies: while all four weathering processes contributed to the lake’s water chemistry, only halite and carbonate weathering influenced river and groundwater compositions. The comparative analysis revealed more pronounced ion exchange processes in lake water than in river and groundwater systems. Climate change impacts were manifested through two primary mechanisms: (1) enhanced evaporation, leading to elevated ion concentrations and isotopic enrichment; and (2) temperature-related effects on the water chemistry through increased dilution from precipitation and glacial meltwater. Understanding these mechanisms is essential for developing adaptive strategies to maintain water security and ecosystem sustainability. The relationships established between climate drivers and hydrochemical responses provide a scientific basis for predicting future changes and informing sustainable management practices for inland lake systems across the Tibetan Plateau. Full article

The sustainable management of groundwater in the Jimma area is complicated by a lack of comprehensive studies on its chemical makeup and the geochemical processes influencing its hydrochemistry. This research aims to fill that gap by examining 51 groundwater samples from various sources, including deep groundwaters, shallow groundwaters, hand-dug well groundwaters, surface waters, and springs within the area primarily consisting of complex volcanic rocks. The goal is to describe the hydrogeochemical characteristics and determine the key processes affecting groundwater composition in this volcanic area. The study identifies clear patterns in cation and anion concentrations. For deep groundwaters, the average cation concentration is ranked as Na⁺ > Ca²⁺ > Mg²⁺ > K⁺, while shallow groundwaters, hand-dug well groundwaters, surface waters, and springs show a ranking of Ca²⁺ > Na⁺ > Mg²⁺ > K⁺. The major anions are typically ordered as HCO₃⁻ > NO₃⁻ > Cl⁻ > SO₄²⁻. The quantitative hydrogeochemical analysis indicates that the freshwater types in the region are primarily Ca-HCO₃ and Ca-Mg-HCO₃, with some highly mineralized Na-HCO₃ waters also detected. The weathering of silicate minerals mainly drives the geochemical processes affecting groundwater chemistry. An increase in mineralization, suggested by saturation indices, points to a longer residence time underground, with deep groundwaters exhibiting the highest saturation levels and springs the lowest. This mineralization is especially significant for Mg-silicates and carbonates. Stability diagrams for feldspar minerals further demonstrate groundwater evolution along flow paths, revealing that shallow systems are in equilibrium with minerals like gibbsite, whereas deeper systems achieve stability with albite, Ca-montmorillonite, and microcline. Higher CO₂ levels (10^−1.5 to 10^0.5 atm), likely from mantle-magma degassing, add more HCO₃⁻ to the deeper aquifers. This study offers the first thorough characterization of the groundwater composition in the Jimma area and provides important insights into the Jimma area’s hydrogeochemical development, establishing a basis for enhanced groundwater management within this intricate volcanic aquifer system. Full article

The Sangu Spring Basin is located in an important economic area, and groundwater is the main source of water for local life and industry. Understanding the sources of chemical components in groundwater is important for the development and utilization of groundwater. In this paper, we analyzed the origin of the chemical components of groundwater and their evolution in the Sangu Spring Basin using statistical analysis, Piper diagrams, Gibbs diagrams, ion ratios, and combined hydrochemistry–isotope analyses. The results show that the groundwater in the Sangu Spring Basin is mainly derived from atmospheric precipitation, that the groundwater in stagnant and confined environment zones was formed under colder climatic conditions, and that the surface water (SW) has a close hydraulic relation with the groundwater. Water–rock interaction is the main factor controlling the composition of groundwater. The compositions of groundwater are mainly derived from carbonate weathering, silicate weathering, and dissolution of gypsum. Na⁺ and K⁺ in groundwater mainly come from the dissolution of albite and potassium feldspar, rather than rock salt. Ion exchange occurs in karst groundwater (KGW) and fissure groundwater (FGW), and ion exchange is dominated by the exchange of Mg²⁺ and Ca²⁺ in the groundwater with Na⁺ and K⁺ in the rock or soil. Sulfate in groundwater is derived from dissolution of gypsum, infiltration of atmospheric precipitation, and leakage of SW. Groundwaters with the highest sulfate content are located in the vicinity of SW, as a result of receiving recharge from SW seepage. Groundwaters with higher sulfate contents are located in the stagnant and deeply buried zones, where sulfate is mainly derived from the dissolution of gypsum. SW seepage recharges groundwater, resulting in increased levels of Cl⁻, NO₃⁻ and SO₄²⁻ in groundwater. These insights can provide assistance in the protection and effective management of groundwater. Full article

The Zaozigou gold deposit is recognized as one of the largest and most significant independent gold deposits in northwest China, representing a colossal orogenic gold-antimony deposit. It is imperative to delve into the hydrochemical characteristics and controlling factors within the mining area to unveil the groundwater circulation evolution process and enhance water resource management. In 2018, a comprehensive collection of 50 groups of groundwater samples was conducted, alongside 17 groups of surface water and underground mine water samples in 2023. Compositional descriptive analysis, correlation analysis, Piper three-plot, Gibbs map, ion ratio method, hydrogeochemical simulation and PCA methods were employed to reveal the chemical characteristics and evolution process of groundwater in the Zaozigou gold mine. Furthermore, employing water isotopes theory allowed for the identification of recharge sources and circulation conditions within the Zaozigou Gold Mine. The findings indicated a transition from HCO₃-Na·Ca type polluted water in 2018 to primarily the SO₄-Ca·Mg type and HCO₃·SO₄-Na·Ca·Mg type groundwater hydrochemistry types by 2023. The hydrochemical characteristics of the study area are closely related to the mining depth and time. The chemical characteristics are influenced by various factors such as rock weathering, mineral dissolution, cation exchange processes, atmospheric precipitation as well as human activities related to pollution from industrial mining activities. Full article

This study aims to investigate the intricate relationship between geological structures, water chemistry, and isotopic composition in order to gain a deeper understanding of the origins and recharge mechanisms of thermal–mineral waters in the Kyllini region. The research integrates tectonic analysis, hydrochemical data, and stable isotope measurements to delineate recharge zones and trace the origin of these unique water sources. The methods used for delineation are the geological and tectonic study of the area, as well as hydrochemical and isotopic data analysis. The findings highlight that tectonic activity creates preferential flow paths and consequently influences the hydrogeological framework, facilitating deep circulation and the upwelling of thermal waters. Monthly analyses of groundwater samples from the Kyllini thermal spring were conducted over one hydrological year (2019–2020) and compared with data from the area collected in 2009. The hydrochemical profiles of major and minor ions reveal distinct signatures corresponding to various water–rock interactions, while stable isotope analysis provides insights into the climatic conditions and altitudes of recharge areas. Hydrochemical analyses reveal the composition of thermal–mineral waters, aiding in the identification of potential sources and their evolution. The conceptualization of Kyllini contributes to the deeper understanding of the intricate interplay between tectonics, hydrochemistry, and stable isotopes. During a hydrological year, the water type of Kyllini’s spring groundwater remains the same (Na-Cl-HCO₃), presenting only slight alterations. Full article

Jinan, renowned as the “Spring City” in China, relies significantly on karst groundwater as an indispensable resource for socio-economic development, playing a crucial role in ecological regulation, tourism, and historical and cultural aspects. The Yufu River basin, situated within Jinan’s karst region, represents a vital riverine leakage zone. Therefore, investigating the evolutionary characteristics and causative mechanisms of surface water and groundwater at different aquifer levels in the Yufu River basin can provide a scientific foundation for the protection of Jinan’s springs. This study, based on hydrogeochemical and isotopic data from the river water, shallow groundwater, deep groundwater, and springs in the Yufu River basin, explored the hydrogeochemical evolution in this region. The findings revealed significant spatial variations in the hydrochemical parameters of the Yufu River basin. Groundwater received contributions from surface water, while springs represented a mixture from both surface water and various recharge aquifers. Dominant ions include Ca²⁺ and HCO₃⁻, with prevailing hydrochemical types being HCO₃·SO₄-Ca and HCO₃-Ca. Atmospheric precipitation served as the primary source of recharge for surface water and groundwater in the Yufu River basin, albeit influenced by pronounced evaporation processes. The hydrochemical composition in the Yufu River basin was primarily attributed to water–rock interactions, mainly driven by the combined effects of carbonate rock, silicate rock, and gypsum weathering and dissolution. Among these, the weathering and dissolution of carbonate rocks played a dominant role, with human activities exerting a relatively minor influence on the hydrochemistry of the Yufu River basin. Full article

The intensification of anthropogenic activities (agriculture, industry, and exploitation of water resources) during urbanization has posed significant challenges to the aquatic environment, particularly in karst regions. Karst aquifers are highly susceptible to surface contaminants and exhibit minimal natural remediation capabilities. Our understanding of the anthropogenic activities involved in these sensitive karst systems remains limited. To address this gap, we conducted a comprehensive study, collecting 285 groundwater samples in Feicheng, northern China, from 1996 to 2015. The overexploitation of karst groundwater has resulted in several concerns. The whole dataset was classified into four groups according to land use. Water quality assessments revealed a yearly decline, particularly in industrial and agricultural areas. The water chemistry transitioned from Ca-Mg-HCO₃ to Ca-Mg-HCO₃-SO₄. Such evolution was attributed to natural hydrogeochemical processes, atmospheric precipitation, and anthropogenic inputs. Natural factors included water-rock interactions (the mineral dissolution) and ion exchange. Absolute principal component scores with multiple linear regression (APCS-MLR) were used to quantitatively estimate the sources of pollution. The results showed that hydrogeological settings (recharge, runoff, and discharge) were crucial in the hydrochemistry evolution of karst groundwater systems. In agricultural areas, it is recognized that much of the NO₃⁻ accumulation in aquifers came from upstream inputs in the groundwater system, not just irrigation and fertilization. Urban areas were affected by Cl⁻ pollution, primarily due to domestic waste. Industrial regions of recharge zones were more susceptible to atmospheric precipitation and industrial waste, with pollutants infiltrating through rainfall and degrading water quality. Mining areas exhibit higher SO₄²⁻ and lower pH due to the oxidation of sulfur-containing minerals. Therefore, the rapid response and low self-purification capacity of groundwater in karst regions necessitate caution in urban planning to mitigate impacts on these fragile systems. Full article